• Elastomers and Composites
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• v.46 no.3
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• pp.257-261
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• 2011

We introduce a novel method that could modify neat asphalt. A polymer-forming monomer, dimethylphenol( DMP) was added to the neat asphalt and polymerization was occurred autonomously, without adding any external catalyst for the polymerization, only with oxygen molecules in the air. The polymer produced in the asphalt was polyphenyleneoxide( PPO) and it enhanced the mechanical properties of the asphalt. Compared with the neat asphalt, the tenacity and toughness of the DMP-modified asphalt were two and half times and three times high, respectively.

• Elastomers and Composites
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• v.45 no.4
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• pp.250-255
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• 2010

From the three element non-Newtonian model of one non-Newtonian viscoelastic Maxwell elements and a elastic spring, the stress relaxation equation was derived. The various model parameters of this equation were evaluated by appling the experimental results of stress relaxation to the stress relaxation equation. The theoretical curves calculated from this model parameters agreed with the experimental stress relaxation curves. From the parameters of nonlinear viscoelastic model, the hole volume, fine structure, viscoelastic properties and mechanical properties of polymer fibers were studied. The experiments of stress relaxation were carried out using the tensile tester with the solvent chamber. The stress relaxation curves of the two types polyacrylonitrile-polyvinylchloride copolymer and another two types PVC monofilament fibers were obtained in air and water of various temperatures.

• Transactions of the Korean Society of Mechanical Engineers A
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• v.34 no.5
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• pp.549-556
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• 2010

In general, materials that can be used to form elastic pads, such as urethane and rubber, are often used in flexible forming processes by inserting the pads between a blank and flexible die for smoothing the forming surface that is formed by a reconfigurable die. In this study, the effects of the elastic pad on formability in the flexible forming process for sheet metals are investigated by performing numerical simulations. In the simulation, the hyperelastic material model is used, where the urethane elastic pads serve as elastic cushions. Case studies are carried out for elastic materials with different hardness values and thicknesses. The results are used to evaluate formability by comparing the configuration of the deformed blank and its major cross-sectional profiles. It is verified that the elastic pad used in the flexible forming process for sheet materials should be hard and that its thickness should be chosen appropriately.

• Membrane Journal
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• v.19 no.2
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• pp.157-164
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• 2009

Bio-butanol recovery by pervaporation was performed with dense and composite polydimethylsiloxane (PDMS) membranes. The pervaporative behavior of the membranes was investigated as a function of operation temperature $(20{\sim}40^{\circ}C)$ and membrane thickness $(100{\sim}1{\mu}m)$ using a series of aqueous BtOH model solutions $(1{\sim}5wt%)$. With the increment of the BtOH concentration in feed, the Butanol concentration in permeate, pervaporation selectivity of Butanol over water and Butanol permeation flux increased. As the operating temperature of feed solutions increased, the BtOH concentration in permeate, pervaporation selectivity and permeation flux increased markedly. As the thickness of the PDMS membrane decreased, permeation flux increased but pervaporation selectivity decreased. These results were explained in terms of high solubility and low diffusion resistance of BtOH over water toward hydrophobic and rubbery PDMS membranes.

• Composites Research
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• v.22 no.3
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• pp.66-73
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• 2009

Total thickness, areal density and mass moment of inertia of materials are important material factors for structural characteristics. In this work, a material-structural optimization was performed up to the maximum ballistic limit of multi-layered composite structures under high impact velocity followed by the investigation of the influence of these factors on an impact absorption performance. A unified model combined with Florence's and Awerbuch-Bonder's models was used in optimizing the multi-layered composite structure consisting of CMC, rubber, aluminum and Al-foam. Total thickness, areal density and mass moment of inertia were used for the optimization constraint. As shown in the results, the ballistic limit determined from a newly developed unified model was closely similar to the finite clement analysis. Additionally, the ballistic limit and impact absorption energy obtained by the optimized structure were improved approximately 16.8% and 26.7%, respectively comparing with a not optimized multi-layered structure.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2005.05a
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• pp.293-298
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• 2005

Insulator is being used for material of railroad vehicles as a barrier of heat and noise. But it shows various fire properties in case of fire. In this study, we compared smoke density(Ds) values of rubber foams with the different thickness of glass fiber cross-Al foil according to the standard of ASTM E 662. The result showed that the insulator and barrier property played an important role in decreasing the value of smoke density

• Transactions of the Korean Society of Mechanical Engineers A
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• v.25 no.4
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• pp.602-609
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• 2001

This paper is concerned with the orthotropic problem of diaphragm-type air springs which consist of rubber linings, nylon reinforced rubber composite and bead ring. The analysis is carried out with a finite element method developed to consider the orthotropic properties, geometric nonlinearity using four-node degenerated shell element with reduced integration. Physical stabilization scheme is used to control the zeroenergy mode of the element. The analysis includes an inflation analysis and a lateral analysis of an air spring for the deformed shape and the spring load with respect to the vertical and l ateral deflection. Numerical results demonstrate the variation of the outer diameter, the fold height, the vertical force and the lateral force with respect to the inflation pressure and the lateral deflection.

• Elastomers and Composites
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• v.45 no.1
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• pp.7-11
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• 2010

The acetylene black/silica composite particles were prepared by a simple and fast method using polyethylenimine (PEI) as a coupling agent. The composite particles were produced via the following two steps; adsorption of PEI on the surface of acetylene black particles and synthesis of silica by sol-gel process. The morphology of the composite particles was a core-shell, and a large number of micropores was created after silica was synthesized on the acetylene black surface.

• Polymer(Korea)
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• v.33 no.5
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• pp.435-440
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• 2009

Thermal degradation behavior of CR (chloroprene) -modified NR (natural rubber) compounds, having different sulfur/accelerator compositions, was studied by non-isothermal TGA method. Data were analyzed using both Kissinger and Flynn-Wall-Ozawa analysis to assess the activation energies. Activation energy obtained from Kissinger analysis was $147.0{\pm}2.0$ kJ/mol for all samples, showing little effect of sulfur/accelerator composition changes in the samples. On the other hand, activation energy from Flynn-Wall-Ozawa analysis exhibited much variations with conversion, showing average value of $211.6{\pm}19.0$ kJ/mol. From the results, it was considered that whole thermal degradation processes of the samples were composed of complex multiple step processes, of which reaction mechanisms were different from each other.

• Elastomers and Composites
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• v.43 no.3
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• pp.173-182
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• 2008

Rubber-pad forming process for materials such as metal in which portions of the die which act upon the material is composed of a natural or synthetic rubber or elastomer material. This makes the rubber pad forming process relatively cheap and flexible, high accuracy for small product series in particular. In this study, we carried out the physical test and finite element analysis of elastomer such as natural rubber and urethane for steel rack rube forming. The non-linear property of elastomer which are described as strain energy function are important parameter to design and evaluate of elastomer component. These are determined by material tests which are uni-axial tension and bi-axial tension. This study is concerned with simulation and investigation of the significant parameters associated with this process.