• Journal of the Korea Institute of Building Construction
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• v.23 no.6
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• pp.727-738
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• 2023

In concrete, the interface between the aggregate and cement paste is often the most critical factor in determining strength, representing the weakest zone. Lightweight aggregate, produced through expansion and firing of raw materials, features numerous surface pores and benefits from low density; however, its overall aggregate strength is compromised. Within concrete, diminished aggregate strength can lead to aggregate fracture. When applying lightweight aggregate to concrete, the interface strength becomes critical due to the potential for aggregate fracture. This study involved coating the surface of the aggregate with blast furnace slag fine powder to enhance the interfacial strength of lightweight aggregate. The impedance of test specimens was measured to analyze interface changes resulting from this surface modification. Experimental results revealed a 4% increase in compressive strength following the coating of the lightweight aggregate surface, accompanied by an increase in resistance values within the impedance measurements corresponding with strength enhancement.

• Journal of the Korea institute for structural maintenance and inspection
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• v.12 no.5
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• pp.133-142
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• 2008

This paper studies the early-aged chloride binding capacity of various blended concretes including OPC(ordinary Portland cement), PFA(pulversied fly ash), GGBFS(ground granulated blast furnace slag) and SF(silica fume) cement paste. Cement pastes with 0.4 of a free water/binder ratio were cast with chloride admixed in mixing water, which ranged from 0.1 to 3.0% by weight of cement and different replacement ratios for the PFA, GGBFS and SF were used. The content of chloride in each paste was measured using water extraction method after 7 days curing. It was found that the chloride binding capacity strongly depends on binder type, replacement ratio and total chloride content. An increase in total chloride results in a decrease in the chloride binding, because of the restriction of the binding capacity of cement matrix. For the pastes containing maximum level of PFA(30%) and GGBFS(60%) replacement in this study, the chloride binding capacity was lower than those of OPC paste, and an increase in SF resulted in decreased chloride binding, which are ascribed to a latent hydration of pozzolanic materials and a fall in the pH of the pore solution, respectively. The chloride binding capacity at 7 days shows that the order of the resistance to chloride-induced corrosion is 30%PFA > 10%SF > 60%GGBFS > OPC, when chlorides are internally intruded in concrete. In addition, it is found that the binding behaviour of all binders are well described by both the Langmuir and Freundlich isotherms.

• Journal of the Korea institute for structural maintenance and inspection
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• v.23 no.2
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• pp.37-43
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• 2019

This study investigated electrical conductivity, electromagnetic shielding effectiveness, and mechanical property to improve electromagnetic shielding performance of high performance fiber reinforced cementitious composites (HPFRCC). Steel fiber, steel slag and carbon black as a conductive material were incorporated into the HPFRCC mixes. In addition, 2% CNT solution which was produced by dispersing multi-wall carbon nanotube (MWCNT) into water was used as a conductive material. In the test results, electrical conductivity of HPFRCC specimens was very low except for the specimen incorporating 1% carbon black. Micro structure of cement matrix was changed as the curing time increased, which negatively affected the conductive network of HPFRCC. In case of HC1 specimen showing a conductive network (0.083 S/cm), the electrical conductivity of the specimen after being dried at $60^{\circ}C$ for 72 hours to exclude the effect of water on electrical conductivity was significantly reduced to 0.0003 S/cm. The most important parameter of electromagnetic shielding effect was found to be a steel fiber while the effect of carbon black and steel slag was very few. The correlation between electrical conductivity and electromagnetic shielding effect does not seem to be clear.

• Journal of the Korean Recycled Construction Resources Institute
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• v.9 no.3
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• pp.268-275
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• 2021

The three factors that determine the strength of concrete are the strength of cement paste, aggregate and ITZ(Interfacial Transition Zone) between aggregate and cement paste. Out of these, the strength of ITZ is the most vulnerable. ITZ is formed in 10~50㎛, the ratio of calcium hydroxide is high, and CSH appears low ratio. A high calcium hydroxide ratio causes a decrease in the bond strength of ITZ. ITZ is due to further weak area. The problem of ITZ appears as a more disadvantageous factor when it used lightweight aggregate. The previous study of ITZ properties have measured interfacial toughness, identified influencing factors ITZ, and it progressed SEM and XRD analysis on cement matrix without using coarse aggregates. also it was identified microstructure using EMPA-BSE equipment. However, in previous studies, it is difficult to understand the microstructure and mechanical properties. Therefore, in this study, a method of measuring electrical resistance using EIS(Electrochemical Impedance Spectroscopy) measuring equipment was adopted to identify the ITZ between natural aggregate and lightweight aggregate, and it was tested the change of ITZ by surface coating of lightweight aggregate with ground granulated blast furnace slag. As a result, the compressive strength of natural aggregate and lightweight aggregate appear high strength of natural aggregate with high density, surface coating lightweight aggregate appear strength higher than natural aggregate. The electrical resistivity of ITZ according to the aggregate appeared difference.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.29 no.1A
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• pp.75-84
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• 2009

The present study assesses the chloride threshold level for corrosion of steel in concrete by examining the properties of four different binders used for blended concrete in terms of chloride binding, buffering of cement matrix to a pH fall and the corrosion behaviour. As binders, ordinary Portland cement (OPC), 30% pulverised fuel ash (PFA), 60% ground granulated blast furnace slag (GGBS) and 10% silica fume (SF) were used in a concrete mix. Testing for chloride binding was carried out using the water extraction method, the buffering of cement matrix was assessed by measuring the resistance to an artificial acidification of nitric acid, and the corrosion rate of steel in mortar with chlorides in cast was measured at 28 days using an anodic polarisation technique. Results show that the chloride binding capacity was much affected by $C_{3}A$ content and physical adsorption, and its order was 60% GGBS>30% PFA>OPC>10% SF. The buffering of cement matrix to a pH fall was varied with binder type and given values of the pH. From the result of corrosion test, it was found that the chloride threshold ranged 1.03, 0.65, 0.45 and 0.98% by weight of cement for OPC, 30% PFA, 60% GGBS and 10% SF respectively, assuming that corrosion starts at the corrosion rate of $0.1-0.2{\mu}A/cm^{2}$. The mole ratio of [$Cl^{-}$]:[$H^{+}$], as a new presentation of the chloride threshold, indicated the value of 0.008-0.009, irrespective of binder, which would be indicative of the inhibitive characteristic of binder.

• Journal of the Korea Institute of Building Construction
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• v.12 no.2
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• pp.203-210
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• 2012

Recently, the interest and demand for large-scale buildings and skyscrapers have been on the rise, and the performance of concrete is an area of high priority. Securing 'mass concrete and high strength concrete' is very important as a key construction technology. For high strength concrete, the high heat of hydration takes place inside the concrete because of the vitality of hydration in cement due to the large amount of powder, and leads to problems such as an increase of thermal stress due to the temperature difference with the outside, which results in cracks and slump loss. For this reason, measures to solve these problems are needed. This study aims to reduce the hydration heat of high strength concrete to control the hydration heat of mass concrete and high strength concrete, by replacing the type of admixture, The purpose of this study is to control the hydration heat of high strength concrete and mass concrete. Our idea for this purpose is to apply not only the types and contents of admixture but also incorporation mixing water to ice-flake. As a result of the test, the use of blast furnace slag and fly ash as admixture, and the use of ice-flake as mixing water can improve the liquidity of concrete and reduce slump loss. Significantly dropping the maximum temperature will contribute greatly to reducing cracks due to hydration heat in mass concrete and high strength concrete, and improve quality.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.11a
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• pp.321-324
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• 2008

Recently increasing interest in high-rise building around the world for more than 100 floor, the trend is the increasing use of high-strength and high-flowable concrete so as of productivity improvements and cost savings to improve the performance of the early strength development. This study is to reach the optimal combination by reviewing the performance of high-rise building which is required. The results show that $30.0{\sim}32.5%$ of W/B, $155㎏/m^3$ of unit water and FA10+SP10 is best properties for early strength of concrete.

• Proceedings of the Korea Concrete Institute Conference
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• 2008.04a
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• pp.1101-1104
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• 2008

Recently, active researches are conducted on high performance concrete(HPC) exhibiting high strength and high fluidity. These researches are resulting in increased applications on real structures. In order to satisfy the required performances, HPC makes use of large quantities of binder and presents low water-cementitious material ratio. Such mixing is increasing significantly the autogenous shrinkage, which subsequently is likely to favor the potential development of cracks. Therefore, we investigated the effect of used materials and mix proportions on the shrinkage properties of HPC, and of the use of expansive additives and shrinkage reducing agents on the HPC. The autogenous shrinkage of HPC using blast furnace slag are tend to be increased, in some case have the potential development of cracks by only the autogenous shrinkage. Also the using method in combination with expansive additive and shrinkage reducing agent is more effective than the separately using method of that.

• Journal of the Korean Ceramic Society
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• v.51 no.6
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• pp.584-590
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• 2014

Air-cooled slag showed grindability approximately twice as good as that of water-cooled slag. While the studied water-cooled slag was composed of glass as constituent mineral, the air-cooled slag was mainly composed of melilite. It is assumed that the sulfur in air-cooled slag is mainly in the form of CaS, which is oxidized into $CaS_2O_3$ when in contact with air. $CaS_2O_3$, then, is released mainly as $S_2O{_3}^{2-}$ion when in contact with water. However, the sulfur in water-cooled slag functioned as a constituent of the glass structure, so the$S_2O{_3}^{2-}$ ion was not released even when in contact with water. When no chemical admixture was added, the blended cement of air-cooled slag showed higher fluidity and retention effect than those of the blended cement of the water-cooled slag. It seems that these discrepancies are caused by the initial hydration inhibition effect of cement by the $S_2O{_3}^{2-}$ ion of air-cooled slag. When a superplasticizer is added, the air-cooled slag used more superplasticizer than did the blast furnace slag for the same flow because the air-cooled slag had higher specific surface area due to the presence of micro-pores. Meanwhile, the blended cement of the air-cooled slag showed a greater fluidity retention effect than that of the blended cement of the water-cooled slag. This may be a combined effect of the increased use of superplasticizer and the presence of released $S_2O{_3}^{2-}$ ion; however, further, more detailed studies will need to be conducted.

• Journal of the Korean Recycled Construction Resources Institute
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• v.10 no.4
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• pp.577-583
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• 2022

In this study, the characteristics of self-healing mortars produced using an inorganic self-healing material consisting of ground granulated blast furnace slag, expansion agent, and anhydrite, were investigated. For three types of self-healing mortars with different amounts of the inorganic healing material, compressive strength was measured and the self-healing performance was evaluated through the constant water head permeability test. The healing rate and equivalent crack width according to crack-induced aging were used as indicies of healing performance evaluation. Considering the development of compressive strength of the self-healing mortars, the change in the healing rate with healing periods, and the economic feasibility, the optimal amount of inorganic self-healing materials was suggested as 20 % of the mass of cement.