• Title/Summary/Keyword: 계면활성제 재이용

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Characteristics of the Visco-elastic Grout Material in Fresh and Sea Water (해수와 담수에서 점탄성을 갖는 그라우트재의 공학적 특성 평가)

  • Kim, Ukgie;Cho, Samdeok;Park, Bonggeun;Song, Byeongdeok;Kim, Juhyong
    • Journal of the Korean GEO-environmental Society
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    • v.13 no.6
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    • pp.41-50
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    • 2012
  • In general, it is critical that grout consistency permit the complete filling of void space without segregation of ingredients. Recently, the antiwashout agent is used on underwater grout materials for preventing the grout from the segregation in water. This study introduces a new type of antiwashout underwater and flowable grout material using viscous modifiers and its characteristics comparing with conventional grout materials in fresh and sea water. It is found that the antiwashout underwater grout both in fresh and sea water has enough strength and good resistance to segregation.

Alkaline Cleaning Wastewater Treatment Using Ultrafiltration Membranes (한외여과막을 이용한 세척오수의 처리)

  • 장규만;이민수;정건용
    • Proceedings of the Membrane Society of Korea Conference
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    • 1998.04a
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    • pp.117-119
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    • 1998
  • 1. 서론 : 본 연구에서는 한외여과막을 이용하여 대형건물에서 발생하는 오수, 동/식물성 오일과 계면활성제를 함유하는 ㅈ 중국식당 배수 및 자동차 세척 배수를 처리하였다. 대형건물 및 식당 배수에서는 한외여과막 투과수를 재사용하기 위하여 추가적인 공정이 요구되나 자동차 세차배수의 경우, 한외여과막으로 오일 성분만을 효과적으로 제거하고 유효성분인 세척제와 세척용수를 재활용할 수 있을 것으로 판단된다.

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An Experimental Study on the Pore Structure and Thermal Properties of Lightweight Foamed Concrete by Foaming Agent Type (기포제 종류에 따른 경량기포콘크리트의 기포구조 및 열적특성에 관한 실험적 연구)

  • Kim, Jin-Man;Choi, Hun-Gug;Park, Sun-Gyu
    • Journal of the Korea Institute of Building Construction
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    • v.9 no.4
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    • pp.63-73
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    • 2009
  • Recently, the use of lightweight panels in building structures has been increasing. Of the various lightweight panel types, styrofoam sandwich panels are inexpensive and are excellent in terms of their insulation capacity and their constructability. However, sandwich panels that include organic material are quite vulnerable to fire, and thus can numerous casualties in the event of a fire due to the lack of time to vacate and their emission of poisonous gas. On the other hand, lightweight foamed concrete is excellent, both in terms of its insulation ability and its fire resistance, due to its Inner pores. The properties of lightweight concrete is influenced by foaming agent type. Accordingly, this study investigates the insulation properties by foaming agent type, to evaluate the possibility of using light-weight foamed concrete instead of styrene foam. Our research found thatnon-heating zone temperature of lightweight foamed concrete using AP (Aluminum Powder) and FP (animal protein foaming agent) are lower than that of light-weight foamed concrete using AES (alkyl ether lactic acid ester). Lightweight foamed concrete using AES and FP satisfied fire performance requirements of two hours at a foam ratio 50, 100. Lightweight foamed concrete using AP satisfied fire performance requirements of two hours at AP ratio 0.1, 0.15. The insulation properties were better in closed pore foamed concrete by made AP, FP than with open pore foamed concrete made using AES.

Removing Contaminants from the Surface of Jagyeongnu of Changgyeonggung Palace, National Treasure No. 229 (국보 제229호 창경궁 자격루 누기 표면에 고착된 오염물 제거 방법 연구)

  • You, Ha Rim;Jo, Ha Nui;Lee, Jae Sung;Yu, Ji A;Park, Young Hwan;Ryu, Dong Wan
    • Journal of Conservation Science
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    • v.37 no.2
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    • pp.101-119
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    • 2021
  • Korea's National Treasure No. 229, the Jagyeongnu (clepsydra) of Changgyeonggung Palace, is a scientific and cultural property representing the pinnacle of science and technology in the Joseon Dynasty. Currently, only the large, mid-sie, and small Pasuhos (bronze jars) remain. During a nearly two-year conservation project by the Cultural Heritage Conservation Science Center (CHCSC) that began in 2018, conservators identified the contaminants on the surface of the water clock's components. It turned out that the contaminants had been caused by the exposure of squalane and silicone oil, used in an earlier preservation treatment, to the elements. The CHCSC conducted experiments to determine the most effective method to remove the contaminants. First, the conservators tried using an organic solvent, a poultice, and the application of toluene and bentonite, which yielded excellent reactivity and significant color difference changes (𝚫E). However, the reactivity was insufficiently effective to warrant the health hazards to the conservators and the environment (toluene is toxic). Although organic solvents required considerably more effort, time, and human resources, the conservators confirmed that their use achieved a true color difference variation (𝚫E) that was within the same range as the toxic hydrocarbon. Thus, they confirmed that using an organic surfactant was the best method for removing the contaminants.

Mixed Micellar Properties of Cetylpyridinium Chloride(CPC) with Triton X-100(TX-100) in Aqueous Solutions of n-Alcohols (n-알코올 수용액에서 Cetylpyridinium Chloride(CPC)와 Triton X-100(TX-100)의 혼합미셀화에 대한 연구)

  • Chung, Jong Jae;Kim, Yung Cheol;Lee, Yung Cheol
    • Journal of the Korean Chemical Society
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    • v.41 no.6
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    • pp.284-291
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    • 1997
  • The critical micelle concentrations($CMC^*$) of a cationic surfactant cetylpyridinium chloride (CPC) and a nonionic surfactant triton X-100(TX-100) in aqueous solutions of n-alcohols(methanol, ethanol, 1-propanol, 1-butanol and 1-pentanol) were determined by UV spectroscopic method at 25$^{\circ}C$. The various thermodynamic values in 0.1 M n-alcohols were calculated by means of the equation derived from the pseudo-phase separation model and compared with the values in the absence of n-alcohols. The results were a good agreement with the nonideal mixed micelle model, and they showed negative deviation from the ideal behavior.

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유류 오염토양 복원을 위한 물리적 기술의 현장적용에 관한 기초연구

  • 강희만;이주광;이용은;고석오
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2001.04a
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    • pp.160-163
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    • 2001
  • 유류 오염 토양에 pilot scale 규모의 토앙세척법(soil flushing)과 토양증기추출법(SVE)을 설치하여 운전하였다. 토양세척법의 경우 용매인 알콜류를 주입하고 2일 이후부터 계면활성 재인 Tween 80 용액을 주입 한 후 하부에서 추출된 유출수내의 오염물질의 농도를 측정한 결과 BTEX, Diesel 및 n-Alkane의 농도는 계면활성제 수입 전파 후의 비율이 최대 각각 15배 7.8배 및 47배의 농도 증가를 보였으며 TPH 농도의 증가는 약 10배에 이르는 것으로 조사되었다. 또한 토양증기추출법의 경우 가스 추출로 제거된 가스성분의 누적량을 보면 약 19일의 운전기간동안 BTEX와 TPH 총량 기준으로 약 30 kg 및 708 kg이 제거되었으며 BTEX와 TPH에 대한 최대 제거효율은 각각 4 kg/day 및 90 kg/day 였다.

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Application of PCM Technology to Concrete II : Effects of SSMA(Sulfonated Styrene-Maleic Anhydride) on the Properties of the 1-Dodecanol Micro-Capsule (PCM 기술의 콘크리트 적용 II : 계면중합법에 의한 1-도데카놀 마이크로 캡슐에 있어서 계면활성제로 사용된 SSMA의 표면활성도가 마이크로 캡슐의 특성에 미치는 영향)

  • Shin, Se-Soon;Jung, Jae-Yun;Lim, Myung-Kwan;Choi, Dong-Uk;Kim, Young-Ho
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.1 no.1
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    • pp.17-25
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    • 2013
  • Thermal storage technology used for indoor heating and cooling to maintain a constant temperature for a long period of time has an advantage of raising energy use efficiency. This, the phase changing material, which utilizes heat storage properties of the substances, capsulizes substances that melt at a constant temperature. This is applied to construction materials to block or save energy due to heat storage and heat protection during the process in which substances melt or freeze according to the indoor or outdoor temperature. The micro-encapsulation method is used to create thermal storage from phase changing material. This method can be broadly classified in 3 ways: chemical method, physical and chemical method and physical and mechanical method. In the physical and chemical method, a wet process using the micro-encapsulation process utilized. This process emulsifies the core material in a solvent then coats the monomer polymer on the wall of the emulsion to harden it. In this process, a surfactant is utilized to enhance the performance of the emulsion of the core material and the coating of the wall monomer. The performance of the micro-encapsulation, especially the coating thickness of the wall material and the uniformity of the coating, is largely dependent on the characteristics of the surfactant. This research compares the performance of the micro-capsules and heat storage for product according to molecular mass and concentration of the surfactant, SSMA (sulfonated styrene-maleic anhydride), when it comes to micro-encapsulation through interfacial polymerization, in which Dodecan-1 is transformed to melamin resin, a heat storage material using phase changing properties. In addition, the thickness of the micro-encapsulation wall material and residual melamine were reduced by adjusting the concentration of melamin resin microcapsules.

Effects of the Wet Cleaning to the Color Change of the Dyed Fabrics with Natural Dyes (천연염색포의 습식세척에 의한 색상변화)

  • Baek, Young-Mee;Goto-Doshida, Sumiko;Saito, Masako
    • Journal of Conservation Science
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    • v.28 no.1
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    • pp.21-27
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    • 2012
  • In the Chosun period, the noble class usually buried the dead bodies in the lime-covered tomb. Recently their costumes are excavated while maintaining the shape. However, the textiles discovered from the inside have been degradated by a body and moisture. To conserve these textiles one of the most important thing is how to clean these textiles right after the excavation. The purpose of this study is to examine the effects of wet cleaning to minimize the color change of textile remains. For this purpose, silk and cotton were dyed with natural dyes (7 red, 1 blue, 6 yellow, 4 green and 4 purple colors), then they were kept for 6 months with pork meat at $10^{\circ}C$, and were washed by four cleaning solutions (water, anionic surfactant (SDS), non-ionic surfactant (Triton X-100) and natural surfactant (saponin)) at $20^{\circ}C$ and $40^{\circ}C$. The color change was evaluated by color difference (${\Delta}E$) between non-treated and after washed samples. From the results, it was found that the color changes are significantly different depending on the washing temperature, textile material, the cleaning agents and the type of dyes.

Production of Foamed Glass by Induction Heating Method (인덕션 가열법을 이용한 발포유리제조)

  • Sun, Hongshuai;Yoo, In-Sang
    • Applied Chemistry for Engineering
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    • v.28 no.5
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    • pp.513-520
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    • 2017
  • The application possibility of an alternative new method with low energy consumption was studied for the eco-friendly fabrication of foamed glasses from waste glasses. As a result, fabricating temperature can be reduced under $300^{\circ}C$ without using various expensive inorganic oxidants. The foamed glass can be fabricated at a proper mixing ratio of the waste glass powder, water glass, little surfactant and bubble stabilizer by induction heating method. In the experimental range, the assured optimal condition is 4 min heating on the induction machine with a steel-container ($100mm{\times}100mm{\times}20mm$) and followed by evaporating and drying process for 11 min with 110 g of glass powder, 80 g of water glass, 3 g of surfactant and 0.2 g of bubble stabilizer. When the foamed glass was fabricated at the optimal condition, the density of the glass was $0.85g/cm^3$ and the heat conduction was $0.052W/h{\cdot}K$. In addition, the compressive strength of the glass was above $50kg/cm^2$.

A Method to Determine Amount of Adsorbed Oil in Hair Washing Using Absorption Spectroscopy (흡수 분광법을 이용한 세정 과정에서 흡착된 오일의 평가)

  • Song, Sang-Hun;Kim, Hyun young;Son, Seong Gil
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.45 no.2
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    • pp.105-116
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    • 2019
  • Oil adsorption during hair or body washing is responsible for the hair conditioning. In this study, we established a method to extract oil from a substrate, and to determine amount of adsorbed oil upon substrate using a conventional absorption spectroscopy. We controlled the mole fraction of a surfactant in a mixture of anionic and amphoteric surfactants because that it induces the coacervate that regulates amount of adsorbed oil through the alteration of oil viscosity. Based on this, we established the optimized condition for adsorption and extraction for oil. UV absorbance were employed to estimate the amount of adsorbed oil using optical absorbance after extraction via adsorption. The estimation was confirmed by comparing with a mass analysis in HPLC and an adhesive energy in AFM. It has been proved that this method can be applied to all cases of oil adsorption from the results with various cationic polymers and a complex system of the polymers which regulate the oil adsorption.