• Journal of the Computational Structural Engineering Institute of Korea
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• v.23 no.1
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• pp.81-94
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• 2010

This paper deals with the fracture simulation of UHPFRC girder with the interface type model. Based on the existing numerical simulation of quasi-brittle fracture in normal strength concrete, constitutive modeling for UHPFRC I-girder has been improved by including a tensile hardening at the failure surface. The finite element formulation is based on a triangular unit, constructed from constant strain triangles, with nodes along its sides and neither at the vertex nor the center of the unit. Fracture is simulated through a hardening/softening fracture constitutive law in tension, a softening fracture constitutive law in shear as well as in compression at the boundary nodes, with the material within the triangular unit remaining linear elastic. LCP is used to formulate the path-dependent hardening-softening behavior in non-holonomic rate form and a mathematical programming algorithm is employed to solve the LCP. The piece-wise linear inelastic yielding-failure/failure surface is modeled with two compressive caps, two Mohr-Coulomb failure surfaces, a tensile yielding surface and a tensile failure surface. The comparison between test results and numerical results indicates this method effectively simulates the deformation and failure of specimen.

• Polymer(Korea)
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• v.31 no.6
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• pp.526-531
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• 2007

This paper reports the first results of a series of planarization film study for the stainless steel (SS) substrates for flexible displays. Diglycidyl ether of bisphenol A (DGEBA) and octa(dimethylsiloxypropylglycidylether) silsesquioxane (OG) were chosen for the organic and the hybrid epoxies respectively and diaminodiphenylmethane (DDM) was used as a curing agent at 1:2 stoichiometric ratio. These materials were spin-coated on SS substrates and thermal-cured. TGA study indicated that both the pristine and the cured OG were more thermally stable than DGEBA. AFM study showed that the smooth surfaces of $1{\sim}2\;nm$ roughness can be prepared for both DGEBA and OG when the films were thick ($>\;1\;{\mu}$). The electrical properties such as dielectric constant, capacitance and the leakage current with respect to the applied voltage were all stable even after the stress of $100\;V/100^{\circ}C$ was applied for $0{\sim}10000$ seconds indicating that the insulating properties of DGEBA and OG films were very reliable.

• Journal of the Korean Chemical Society
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• v.43 no.1
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• pp.85-91
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• 1999

The second order rate constants for the hydrolysis of substituted phenyl N,N-diethyl-P-benzylphosphonamidates (2,4-$(NO_2)_2$, 4-$NO_2$, 4-CN, 4-Cl, 4-H)in 20% dioxane-water (v/v) have been determined by UV/Vis spectrophotometric method at various temperatures. The activation parameters (Ea, ${\Delta}H^{\neq}$,${\Delta}S^{\neq}$) were calculated from the rate constants and the reaction constant ($\rho$) was also estimated by Hammett equation. The activation entropies of the title reactions show considerably negative values, this result is not consistent with a dissociative mechanism (EA) in which a positive or a slightly negative value of the entropy of activation should be expected. Further, kinetic evidence for an associative mechanism (AE) was obtained from the linear free energy relationship. By the results of kinetic study for the alkaline hydrolysis of substituted phenyl N,N-diethyl-P-benzylphosphonamidates, it may be concluded that these reactions proceed through an associative mechanism.

• Journal of the Korean Chemical Society
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• v.38 no.5
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• pp.391-396
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• 1994

The hydrolysis of $\alpha-benzoxystyrene(1)$ in strong acidic solution has been investigated kinetically. In perchloric acid concentration lower than 5.5 M($H_o$ < -3.0), hydration paramer $\omega$ = + 7.6, and $\Phi$ = + 0.54 were obtained. The solvent isotope effect $k_{H_2O}/K_{D_2O}$ is 0.72. The substituent effect was found to conform to the Hammett $\sigma^+$ constant with $\rho$ = -0.60. On the basis of these results and other evidence, the hydrolysis of the enol ester proceeds by $A_{AL}$2 type mechanism. In concentration greater than 5.5 M($H_o$ > -3.0), isotope effect, $k_{H_2O}/_{D_2O}$ is 3.32, substituent effect, $\rho$ is -1.60 and the rate is linear with the acidity function, $H_o$. Thus, the mechanism changes one involving initial, and rate-determining olefin protonation.

• Journal of the Korean Society of Food Culture
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• v.3 no.4
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• pp.391-396
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• 1988

The method for the measurement of texture hardening phenomena, which is the limiting factor of shelf-life of Yaksik in the market, was established. The changes in the hardening rate by the processing conditions and the storage temperature and time were examined. The standard sample made by traditional method could be kept at room temperature$(20{\circ}C)$ for 3 days and the multipuncture force measured at the end of marketable quality was 700g. The hardening rate increased rapidly by storing at $5^{\circ}C$ and the ratio of hardening rate constants between room temperature and $5^{\circ}C$ storage reached to $1.3{\sim}3.3$ depending on the processing condition. The largest ratio was observed by the sample made from pressure cooker. The addition of corn syrup retarded the hardening rate. The pressure cooking resulted in making too soft product, which diminished the panel preference, but it extend the shelf-life when products were stored at $5^{\circ}C$ microwave cooking resulted in making too hard texture which was not acceptable. The overall quality preference of Yaksik was decided by the textural preference and the latter showed significant inverse correlation with the maximum force of multipuncture test. Therefore, it was concluded that multipuncture test was useful for the measurement of the quality of Yaksik.

• The Journal of the Convergence on Culture Technology
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• v.10 no.6
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• pp.73-79
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• 2024

Cyanoacrylate glue has the property of sticking to human tissue as it reacts with anions in human body fluids and hardens through a polymerization reaction. It was developed as an adhesive for epidermal bonding, but is also widely used in clinical practice for vascular embolization to occlude blood vessels that are bleeding or at risk of bleeding. In vascular embolization, it is necessary to control the curing speed according to the size of the blood vessel and the speed of blood flow, and to achieve this, the speed of the polymer reaction is adjusted by mixing with lipiodol. In this study, we prepared the mixed solutions of industrial ethylcyatoacrylate and medical n-butyl cyanoacrylate glues with Lipiodol and poppy seed oil, the raw material of Lipiodol. Video was filmed of the process in which each cyanoacrylate glue and lipiodol mixture hardened on the surface of the aqueous solution and turned into a solid. When the cyanoacrylate glue came into contact with the surface of the aqueous solution, polymerization occurred immediately at the interface, forming a disk-shaped solid. As the monomers inside the disk escaped and came into contact with the aqueous solution, the secondary polymerization reaction proceeded slowly. NBCA's polymerization reaction time was about 1 minute, increased to about 2 minutes when Lipiodol was 50%, and to about 4 minutes when it was 67%. These observation results are expected to be very useful in understanding vascular occlusion in clinical embolization.

• Proceedings of the Materials Research Society of Korea Conference
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• 2003.11a
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• pp.44-44
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• 2003

Scandium을 소량 첨가한 Al합금은 용체화 처리 후 시효에 의해 강화되며, 합금의 주 강화상은 Ll2 type의 규칙구조를 갖는 A1$_3$Sc상으로 열처리시 아주 미세한 정합의 구형입자로 석출한다. Scandium은 Al합금에서 첨가원소의 at%에 따른 경량화 효과가 Gold 다음으로 크다. 현재까지의 Al-Sc계 합금에 대한 연구는 시효경화에 따른 기계적 특성 변화에 대해서만 이루어져 왔으나 본 연구에서는 투과전자현미경을 이용하여 열처리에 따른 미세조직의 변화, 급냉 상태에서 생성된 A13Sc입자의 형성 및 계면구조, 시효에 따른 석출거동을 규명하였다. 실험에 사용된 alloy는 미국의 Ashurst 사에서 제조된 Al-2wt%Sc모합금과 순도 99.9%의 Al을 혼합하여 Arc melting법으로 제조하였다. Primary A13Sc상은 Ll2 type으로 응고시에 용융상태에서 먼저 핵생성되어 Al의 핵생성 site로 작용한다. 635$^{\circ}C$에서 용체화 처리한 시편에서는 수백 nm 크기를 갖는 $Al_3$Sc상이 계면과 matrix내에 구형으로 존재함을 확인하였다. 수백 nm 크기의 $Al_3$Sc상의 내부에는 역위상 경계(Antiphase boundary)이 존재로 인한 특징적인 contrast가 관찰되었으며, 이 $Al_3$Sc상은 응고시 생성된 작은 $Al_3$Sc상들이 모여져 생성된 것으로 추측된다. 수백 nm 크기 의 $Al_3$Sc사와 Al matrix 사이의 계면에는 격자상수 차이에 의한 많은 edge dislocation들이 관찰된다.

• Journal of the Korean Chemical Society
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• v.41 no.6
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• pp.299-303
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• 1997

The rate constants($k_{OH}$) for the alkaline hydrolysis of the 4-substituted phenyl ethyl benzylphosphonates were determined in various buffer solutions by UV(Vis spectrophotometer. The activation entropies of the title reactions show negative values and this result is not consistent with a dissociative mechanism (EA) for which a positive or slightly negative value of the entropy of activation should be expected. An associative mechanism(AE) is favorable because the negligible negative charge is generated on the leaving group in the rate determining step from a good Hammett relationship(ρ=1.89). By the results of a kinetic study, we conclude that a dissociative mechanism is not proceeded in the title reactions.

• Applied Chemistry for Engineering
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• v.17 no.1
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• pp.33-36
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• 2006

The kinetics of photopolymerization of urethane-acrylate oligomer which has many applications in photopolymerizable adhesives was analysed to investigate the influence of polymerization temperature and functionality of oligomer using the autocatalytic model. It was revealed that the maximum polymerization rate decreased as the polymerization temperature increased. The reaction rate constant, k, showed little change with the increase in polymerization temperature, while exponents m and n exhibited an increase. These results could be related to the diffusion and mobility restriction of reactive species during the cross-linking reaction. The decrease in photopolymerization rate with increase of temperature was mainly controlled by the reaction order n.

• Proceedings of the KIEE Conference
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• 2004.11a
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• pp.227-229
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• 2004

The corrosion rate of buried steel pipes for water works was investigated under soil environment. Steel pipe shows various characteristics caused by complicated environment condition of underground and especially the corrosion rate of it depends on the resistivity of soil controlled by content of water. In this paper, the corrosion behavior of steel pipe was observed by polarization test under soil and the silica sand in the water content range of 0-50%. Generally it is well known that the resistivity of soil decreased rapidly over 15% water content. In fact the corrosion rate, corrosion potential, and corrosion consumption (MPY) of steel pipe were shown very different aspects within 20% water content.