• Title/Summary/Keyword: 경석고

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Hydration of High-volume GGBFS Cement with Anhydrite and Sodium Sulfate (경석고 및 황산나트륨을 함유한 하이볼륨 고로슬래그 시멘트의 수화특성)

  • Moon, Gyu-Don;Choi, Young-Cheol
    • Journal of the Korea Concrete Institute
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    • v.27 no.2
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    • pp.177-184
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    • 2015
  • In order to use the high-volume slag cement as a construction materials, a proper activator which can improve the latent hydraulic reactivity is required. The dissolved aluminum silicon ions from ground granulated blast furnace slag (GGBFS) react with sulfate ions to form ettringite. The proper formation of ettringite can increase the early-age strength of high-volume GGBFS (80%) cement. The aim of this study is to investigate the hydration properties with sulfate activators (sodium sulfate, anhydrite). In this paper, the effects of $Na_2SO_4$ and $CaSO_4$ on setting, compressive strength, hydration, micro-structure were investigated in high-volume GGBFS cement and compared with those of without activator. Test results indicate that equivalent $SO_3$ content of 3~5% improve the early-age hydration properties such as compressive strength, heat evolution rate, micro-pore structure in high-volume GGBFS cement.

Precision Evaluation of Scanning the Digital Dental Abutment Impression and Dental Gypsum Model according to 3-dimensional Superimposing Different Skills (3차원 중첩 기술 차이에 따른 디지털 치과용 지대치 인상체 및 경석고 모형의 스캐닝 정밀도 평가)

  • Jeon, Jin-Hun
    • The Journal of the Korea Contents Association
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    • v.18 no.12
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    • pp.639-645
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    • 2018
  • The objective of this research was to compare the precision of scanning the digital abutment impression and gypsum model according to 3-dimensional superimposing different skills. There were made with the abutment impression and gypsum model of a maxillary 1st premolar, blue light scanner scanned to obtain the stereolithography (STL) file. After the same process was performed 10 more times without moving them on the scanner table about the abutment impression and gypsum model, respectively (n=11, per types). By superimposing the date of scanning the abutment impression and gypsum model used with no control and best-fit-alignment skills, 10 color-difference maps and root mean square (RMS) data were obtained. The independent t-test was performed to compare RMS data between the each other groups (${\alpha}=0.05$). In the scanning abutment impressions, $RMS{\pm}SD$ of no control, best-fit-alignment showed $6.86{\pm}0.94$, $5.04{\pm}0.24$. in the scanning gypsum model, $4.98{\pm}1.16$, $3.39{\pm}0.07$, all groups showed a significant difference (P<0.001). Trough the this study's result, not only best-fit-alignment but no control is used with digital dental computer-aided design/computer-aided manufacturing (CAD/CAM) research and clinical part.

Reaction Characteristics of the CAC with Various Gypsum Type and Mixing Ratio (석고 종류 및 혼입률에 따른 CAC 반응 특성)

  • Choi, Sun-Mi;Kim, Jin-Man;Koo, Ja-Sul
    • Resources Recycling
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    • v.30 no.1
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    • pp.83-91
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    • 2021
  • Ladle furnace slag is a byproduct of the steel-making process, and it contains the mineral β-C2Sandtherapid-settingmineral (dependingonwhichreducingagenthasbeenused). Ladle furnace slag is often treated through slow cooling, which causes the slag to lose its reactivity. In this study, the properties of air-quenched CAC and pulverized ladle furnace slag containing gypsum were evaluated, and the optimal mixing ratio was determined for broadening their usage. Consequently, the properties of CAC aredemonstrated by the dissolution of gypsum after a period of three hours and the content of gypsum after a period of one day. The optimal mixing ratio of anhydrate and hemihydrate gypsum is found to be within 30% and that of dihydrate gypsum is found to be higher than 35%. Furthermore, based on the results of CAC with dihydrate gypsum, the applicability of the by-product dihydrate gypsum has been verified.

Strength and Shrinkage of Geopolymer Mortar with Mineral Admixtures (혼화재료에 따른 지오폴리머의 강도 및 건조수축)

  • Yang, Joo-Kyoung;Kim, Hyo-Jung
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.1
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    • pp.45-53
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    • 2019
  • Slump flow, compressive strength, flexural strength and drying shrinkage were measured to evaluate workability and mechanical performance of geopolymer. Experimental parameters include the addition of gypsum, blending ratio of blast furnace slag and fly ash and addition of shrinkage reducing agent. Geopolymer using blast furnace slag mixed with gypsum showed larger slump flow than blast furnace slag without gypsum. The slump flow when blending ratio of blast furnace slag and fly ash is 5:5 tended to be larger than the slump flow when blending ratio is 8:2. Geopolymer using blast furnace slag without gypsum showed higher compressive strength and flexural strength than blast furnace slag mixed with gypsum. Compressive strength and flexural strength tended to be higher when blending ratio of blast furnace slag and fly ash was 8:2 than when blending ratio was 5:5. Drying shrinkage decreased with increasing fly ash and blast furnace slag without gypsum, and it was found that shrinkage reducing agent is effective to reduce drying shrinkage of geopolymer.

A Study on the Manufacturing and Properties of High Density Polyethylene Composites Filled with Waste Gypsum (부산 석고를 충전한 고밀도폴리에틸렌 복합재료 제조 및 물성 연구)

  • Jin, Woo Seok;Moon, Junho;Kong, Tae Woong;Kim, Hyang Tae;Choi, Sang Hwan;Oh, Jeong Seok
    • Journal of Adhesion and Interface
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    • v.22 no.3
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    • pp.106-110
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    • 2021
  • Recently, research using waste among eco-friendly materials has been attracting attention. In this study, we investigated the physical properties of blends in which high density polyethylene (HDPE) was filled with waste gypsum (CaSO4) generated during fertilizer manufacturing. Composites were prepared by adding the gypsum content 0~20 wt% using a twin screw extruder. The mechanical, rheological, and thermal properties of the composites were evaluated. It was found that the tensile strength of the composites was less than 4.1% compared to that of unfilled HDPE, so there is no significant deterioration in physical properties. The thermal stability of the composites was improved as the gypsum content increased and the gypsum content had little effect on the viscosities of the composites.

Crystal growth of gypsum by neutralization reaction of waste sulphuric acid using sludge and dust in Pohang Iron & Steel plant (포항제철(주) 슬러지와 Dust를 이용한 폐황산 중화반응에서 얻어진 석고의 결정성장연구)

  • Ji whan Ahn;Ka yeon Kim;Hwan Kim;Sang bop Lee;Eu dug Hwang
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.7 no.4
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    • pp.673-680
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    • 1997
  • NaOH, $Na_2CO_3, CaO, Ca(OH)_2$ and $CaCO_3$ are widely used counteractives for neoutralizing the waste sulphuric acid produced during the metal surface treatment process and/or the metal refining process. To reduce the tremendous expenses for the neutralization treatment of the waste sulphuric acid, the sludge from calcination plant and the stainless refining dust in POSCO (Pohang Iron & Steel co. Ltd.) was utilized. For the sludge, it will be effective to use calcined and then hydrated sludge in strong acid region (pH<2) and to use the sludge itself in weak acid region (pH>2), The gypsum, the by-product of this treatment, was tested to fit the industrial standard of gypsum, so it is expected that it will solve the lack of gypsum supply. For the stainless refining dust, the phase and the morphology of produced gypsum from waste suiphuric acid neutralization was compared with those from pure sulphuric acid. Because of high reactivity and reaction temperature, $CaSO_4$ non-hydrate was obtained in pure sulphuric acid. But $CaSO_4$ dihydrate was obtained in waste sulphuric acid. It is also judged to be a good material for a counteractive of the waste sulphuric acid.

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