• Title/Summary/Keyword: 가스혼합물

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Prediction of Minimum Spontaneous Ignition Temperature(MSIT) of the Mixture of n-Pentanol and Ethylbenzene (n-Pentanol과 Ethylbenzene 혼합물의 최소자연발화온도의 예측)

  • Ha, Dong-Myeong
    • Journal of the Korean Institute of Gas
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    • v.16 no.2
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    • pp.45-51
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    • 2012
  • The MSITs(Minimum Spontaneous Ignition Temperatures) or AITs(Autoignition Temperatures) describe the minimum temperature to which a substance must be heated, without the application of a flame or spark, which will cause that substance to ignite. This study measured the MSITs(Minimum Spontaneous Ignition Temperatures) of n-pentanol+ethylbenzene system by using ASTM E659 apparatus. The MSITs of pure n-pentanol and ethylbenzene were $285^{\circ}C$ and $475^{\circ}C$, respectively. The experimental MSITs of n-pentanol+ethylbenzene system were a in good agreement with the MSIT calculated by the proposed equations with a few A.A.D.(average absolute deviation).

Flame Extinguishing Concentrations and Flue Gas Compositions of n-Heptane by Mixed Inert Gas Agents (불활성 가스계 혼합소화약제의 n-Heptane 불꽃소화농도 및 배가스 조성)

  • 김재덕;김영래;홍승태;이성철
    • Fire Science and Engineering
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    • v.16 no.3
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    • pp.77-83
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    • 2002
  • We measured flame extinguishing concentration and flue gas composition in the n-heptane fuel cup-burner system using inert gas agents such as nitrogen, argon, carbon dioxide and their mixtures. The flame extinguishing concentration of binary gaseous mixture was well predicted by model which contains the flame extinguishing concentration and composition of pure components. The higher average specific gravity of the mixed inert gas agents, the more excellent flame extinguishing performance. And the structure of enclosed space also affects the fire extinguishing. The composition of carbon dioxide in the flue gas was decreased with increasing extinguishing agent used. Nitrogen monoxide production is not related with increasing nitrogen, but increased at rapid mass flow rate of air in the cup-burner.

석탄 촤-수증기 가스화반응에서 알카리 금속염과 전이금속염 혼합물의 촉매활성

  • 이운재;김상돈
    • Proceedings of the Korea Society for Energy Engineering kosee Conference
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    • 1994.05a
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    • pp.9-14
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    • 1994
  • 알카리금속염 (K$_2$CO$_3$, $K_2$SO$_4$). 알카리 토금속염 (Ba(NO$_3$)$_2$), 철족금속염(Ni(NO$_3$)$_2$, FeSO$_4$) 으로 이루어진 여러가지 혼합물들이 반응온도 700~85$0^{\circ}C$ 하의 촤-수증기 가스화반응에서 나타내는 촉매활성을 열천칭 반응기를 사용하여 측정하였다. 비촉매 가스화반응에서 초기반응성은 수증기 분압에 비례하였다. 촉매 가스화반응에서 단일염 촉매의 경우 $K_2$CO$_3$ 가 가장 큰 활성을 나타내었으며, 다른 염들은 낮은 활성을 보였다. 혼합염의 경우 $K_2$SO$_4$에 철족염을 부가함에 따라 반응속도가 향상되었으며, $K_2$SO$_4$+Ni(NO$_3$)$_2$가 가장 큰 촉매활성을 나타내었다. $K_2$SO$_4$와 Ni(NO$_3$)$_2$ 의 촉매 활성은 담지량에 따라 증가하며, 석탄의 등급에 따라 감소하였다. $K_2$SO$_4$와 Ni(NO$_3$)$_2$의 혼합비는 같은 몰비로 혼합하였을때 가장 큰 활성을 나타내었다.

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The Flash Point Measurement for Binary Flammable Mixture (이성분계 가연성 혼합물의 인화점 측정)

  • Ha, Dong-Myeong;Lee, Sungjin
    • Journal of the Korean Institute of Gas
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    • v.18 no.5
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    • pp.60-65
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    • 2014
  • The flash point is the major physical property used to characterize the fire hazard of flammable liquid solutions. In the present study, the main focus is on measuring and estimating the flash points for binary flammable mixture. The flash points for n-propanol+propionic acid were measured by Seta flash closed cup apparatus. The experimental data were correlated with the van Laar and NRTL equations through the optimization method. The results estimated by these correlations were compared with the values calculated by the method based on Raoult's law. The optimization method were found to be better than the method based on the Raoult's law.

Inhibitory Effect of Solid Inhibitors on LPG Combustible Mixtures (LPG 가연성 혼합물에 대한 고형 금지제의 억제 효과)

  • Hamdan, M. A.;Yamin, J. A.;Dabbas, R. K.
    • Journal of the Korean Chemical Society
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    • v.54 no.3
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    • pp.295-299
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    • 2010
  • An experimental rig was constructed in order to study the inhibitory effects of two thermal inhibitors namely; stone and calcium carbonate, on Liquefied Petroleum Gas -air flames. This was achieved by measuring the flammability limits of the combustible mixtures before and after the addition of these inhibitors. It was found that calcium carbonate has superior inhibitory effect on the combustible mixture under investigation while, Stone has a lower inhibitory effect than that of calcium carbonate.

Hydrogasification of mixture composed of plastics and biomass (플라스틱과 바이오매스 혼합물의 수소첨가가스화 반응 연구)

  • You, Seung-Han;Jang, Hyun-Tae;Cha, Wang-Seog
    • Proceedings of the KAIS Fall Conference
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    • 2011.12a
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    • pp.283-285
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    • 2011
  • 수소첨가 가스화반응 특성을 조사하기 위해 $800^{\circ}C$, 8 MPa에서 조업 가능한 회분식반응기를 이용하여 실험을 수행하였다. 실험에 사용한 플라스틱은 폴리에틸렌이었으며 바이오매스는 톱밥이었다. 반응기내 압력감소속도는 기상물 생성속도를 나타냄을 알 수 있었으며 이러한 결과는 반응시간에 따른 전환율 변화로부터 확인할 수 있었다. 기상물 생성량과 플라스틱-바이오매스 혼합물의 전환율은 플라스틱 함량비가 증가할수록 증가하였다.

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Evaluation of Rutting Resistance and Moisture Sensitivity of Warm-Mix Asphalt Mixtures Using the Model Mobile Loading Simulator(MMLS3) (소형 포장 가속시험기를 이용한 중온 아스팔트 혼합물의 소성변형저항성 및 수분민감도 평가)

  • Lee, Jae-Jun;Kim, Yong-Joo;Yang, Sung-Lin;Kwon, Soo-Ahn;Hwang, Sung-Do
    • International Journal of Highway Engineering
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    • v.13 no.2
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    • pp.41-48
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    • 2011
  • Warm-mix asphalt(WMA) technology has been developed to allow asphalt mixtures to be produced and compacted at a significantly lower temperature. The WMA technology was identified as one of means to lower emissions for $CO_2$ and has been spread so quickly in the world. Recently, two innovative WMA additives has been developed to reduce mixing and paving temperatures applied in asphalt paving process in Korea. Since the first public demonstration project in 2008, many WMA projects have successfully been constructed in national highways. In 2010, the WMA field trial was conducted on new national highway construction under Dae-Jeon Regional Construction Management Administration. The two different WMA loose mixtures(WMA and WMA-P) and a HMA mixture were collected at the asphalt plant to evaluate their mechanical performance in the laboratory. The Third-scale Model Mobile Loading Simulator(MMLS3) was adopted to evaluate rutting resistance and moisture damage under different traffic and environmental conditions. In this study, plant-produced WMA mixtures using two WMA additives along with the conventional hot mix asphalt(HMA) mixtures were evaluated with respect to their rutting resistance and moisture susceptibility using MMLS3. Based on the limited laboratory test results, plant-produced WMA mixtures are superior to HMA mixtures in rutting resistance and the moisture susceptibility. The WMA additive was effective for producing and compacting the mixture at $30^{\circ}C$ lower than the temperature for the HMA mixture.

A Study on the Relationship of Explosion Characteristics and Combustion Heat of Gas Mixtures (가스 혼합물의 폭발압력과 연소열의 상관관계 연구)

  • Oh Khy-hyung;Kim Hong;Yoo Joo-hyun;Kim Tae-Jin
    • Journal of the Korean Institute of Gas
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    • v.1 no.1
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    • pp.49-55
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    • 1997
  • Destruction phenomena of structure by gas explosion is due to the explosion pressure and heat. Explosion pressure is a kind of energy converted from the gas mixture explosion. In this paper, we tried to find the relationship between explosion characteristics and combustion heat of the hydrocarbon-oxygen mixtures. Experiment were carried out with the volume of $5916cm^3$ cylindrical explosion vessel. Hydrocarbon gases which used in this study were methane, ethylene, propane, and buthane Experimental parameter was the concentration of the gas mixtures. Explosion characteristics were measured with strain type pressure transducer through the digital storage oscilloscope. From the experimental result, it was found that explosion pressure depend upon the combustion heat.

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Effects of Fuel Composition and Pressure on Autoignition Delay of Biomass Syngas (혼합비율 및 압력 변화가 바이오매스 합성가스의 점화지연 시간에 미치는 영향)

  • Shim, Tae Young;Kang, Ki Joong;Lu, Xingcai;Choi, Gyung Min;Kim, Duck Jool
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.39 no.12
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    • pp.945-952
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    • 2015
  • The autoignition characteristics of biosyngas were investigated both numerically and experimentally. The effects of the temperature, gas composition, and pressure on the autoignition characteristics were evaluated. A shock tube was employed to measure the ignition delay times of the biosyngas. The numerical study on the ignition delay time was performed using the CHEMKIN-PRO software to validate the experimental results and predict the chemical species in the combustion process. The results revealed that the ignition delay time increased with an increase in the hydrogen fraction in the mixture. Under most temperature conditions, the ignition delay time decreased with a pressure increase. However, the ignition delay time increased with an increase in pressure under relatively low temperature conditions.