• Applied Chemistry for Engineering
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• v.21 no.5
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• pp.581-585
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• 2010

The surface of Alnico, one of the industrial dust waste, was treated with 1,3,5-trivinyl-1,3,5-trimethylcyclotrisilazane (VMS) as a surface treating agent and used as the filler for vibration isolator rubber. Maleated EPDM prepared from bulk polymerization of EPDM with maleic anhydride was copolymerized with ${\alpha},{\omega}$-bis(3-aminopropyl)polydimethylsiloxane to obtain maleated EPDM-polydimethylsiloxane copolymer (MEPDM-PDMS). EPDM/Alnico/MEPDM-PDMS vibration isolator rubber was prepared from compounding with Alnico treated with surface treating agent, 25 and 50 phrs to EPDM, respectvely based on 1 to 10 wt% of MEPDM-PDMS to EPDM. From the measurement of the thermal properties to the rubber, the glass transition temperatures (Tg) for the rubber containing maleated EPDM-PDMS copolymer was slightly lower temperature, $33^{\circ}C$ than EPDM rubber, and also DMA results showed higher tan ${\delta}$ peak to the rubber prepared from compounding with EPDM-PDMS copolymer. From the results, rubber prepared using EPDM-PDMS copolymer had better vibration isolator property.

• Applied Chemistry for Engineering
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• v.23 no.1
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• pp.65-70
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• 2012

Structural changing materials which can induce the physical deformation of materials are interesting research topics with various potential applications. Particularly, light among many driving mechanisms is a non-contact energy source, hence the light-responsive system can be used where non-destructive, local irradiation, and remote control is needed. Here, a mainchain azobenzene polymer is synthesized and its physical and optical properties are observed and compared to that of a polymer having a light-responsive azobenzene moiety on its side chain. Further dispersion onto polyvinylalcohol hydrogel is made and its dual stability and actuation are observed upon UV-visible light irradiation. Extended azobenzene polymer blend films show an anisotropic light-actuation with non-polarized UV light at room temperature. This physical shape change is quite reversible and occurs at lower temperature than that of any other reported systems including liquid crystalline elastomers. It is successfully demonstrated that the simple physical azobenzene/polymer blending has a very good actuation compared to that of LCEs which need an elaborate chemical design and it can be further used in the areas requiring a dimensional shape change.

• Applied Chemistry for Engineering
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• v.19 no.4
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• pp.427-431
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• 2008

The rigid polyurethane foams (PUF) were prepared using polyols with 90, 110, 130, and 150 isocyanate index. The effect of sea water on the physical properties of PUF with the increase in isocyanate (NCO) index and ageing time was investigated. Tensile strengths and compressive strengths of the PUFs decreased up to 10% and 7% with an increase in ageing time, respectively. Cell morphology of the PUF under sea water was turned out to be the same as that in the ambient condition. It was observed that $T_g$ and tensile modulus of the PUF under sea water increased. The results showed an additional cross-link reaction of non-reacted MDI and the change of NCO peak as observed from FT-IR spectrum.

• Analytical Science and Technology
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• v.23 no.6
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• pp.560-565
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• 2010

Perchlorate ion ($ClO_4^-$) has been widely used as oxidizing agent in military weapon system such as rocket and missile fuel propellant. So it has been challenging to remove the pollutant of perchlorate ion. nanoscale zero valence iron (nZVI) particles are widely employing reduction catalyst for decomposition of perchlorate ion. nZVI particles has increasingly been utilized in groundwater purification and waste water treatment. But it have strong tendency of aggregation, rapid sedimentation and limited mobility. In this study, we focused on reduction of perchlorate ion using nZVI particles immobilized in alginate polymer bead for stabilization. The stabilized nZVI particles displayed much greater surface area, and much faster reaction rates of reduction of perchlorate ion. In this study, an efficient way to immobilize nZVI particles in a support material, alginate bead, was developed by using $Ca^{2+}$ as the cross-linking cations. The efficiency and reusability of the immobilized Fe-alginate beads on the reduction of perchlorate was tested at various temperature conditions.

• Applied Chemistry for Engineering
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• v.16 no.4
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• pp.496-501
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• 2005

The thermal degradation of ABS in the presence of iron-based metal catalysts has been studied by thermogravimetric analysis (TGA). The reaction of iron-based metal catalysts (ferric nitrate nonahydrate, ammonium ferric sulfate dodecahydrate, iron sulfate hydrate, ammonium ferric oxalate, iron(II) acetate, iron(II) acetylacetonate and ferric chloride) with ABS has been found to occur during the thermal degradation of ABS. In a nitrogen atmosphere, char formation was observed, and at $600^{\circ}C$ approximately 3~23 wt% of the reaction product was non-volatile char. The resulting enhancement of char formation in a nitrogen atmosphere has been primarily due to the catalytic crosslinking effect of iron-based metal catalysts. On the other hand, char formation of ABS in air at high temperature by iron-based metal catalyst was unsuccessful due to the oxidative degradation of the char.

• Applied Chemistry for Engineering
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• v.7 no.4
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• pp.787-793
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• 1996

In this paper, to investigate the effect of the offset ink formulation on deinking of Korean old newspaper, the samples printed with five different types of offset ink were aged naturally for 10, 30, 90, 180 days, and then yield, brightness, fiber length, physical properties(tensile, tear, burst index) were evaluated according to aging time. As the aging time increased, the yield and brightness of respective samples decreased. Particially, as the addition amounts of linseed oil increased, those of samples decreased. Therefore, linseed oil is thought to reduce the deinkability of ink. Also, containing rosin-modified phenolic resin and gilsonite seem to reduce brightness of samples according aging time. In physical properties, tensile index and burst index were roughly decreased, but tear index was increased according to aging time. However, the three indexes of the sample containing only linseed oil as the vehicle component were considerably reduced in comparison with those of other samples, as once crosslinked a strong bond between the ink and fibers was produced and made it difficult to defibrate in producing sheets.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.05c
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• pp.101-105
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• 2001

For high voltage XLPE power cables, semiconducting layers have been applied to prevent discharge at the interface between conductor and insulation, and/or insulation and external shielding layer. The semiconducting layers may be also effective to release electrical stress in the interface. The property of semiconducting layers are significantly related to the quality and reliability of power cables. Generally, these semiconducting layers are formed by extruding, the conductibility of the material is given by the carbon black mixed with base polymer. The life of power cables is depended on the smoothness of the interface between insulation and semiconducting layer. If the smoothness is no good, the life of power cables is shorter because the electrical stress and water tree is increased. The causes of no good smoothness are the void of the interface, the protrusions, the contaminants and impurities of the semiconducting layer. The selection and dispersion of the Carbon Black is the significant factor to determine the life of power cable in the manufacturing of semiconducting compound.

• Elastomers and Composites
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• v.35 no.2
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• pp.149-156
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• 2000

trans-octylene rubber(TOR) was melt-blended with an incompatible NBR/EPDM (70/30) blend. Mixing torque and temperature were reduced as TOR was added to the NBR/EPDM blend. Rheometer results indicated that TOR participated in vulcanization and became a part of network. A scanning electron micrograph demonstrated that EPDM was dispersed in NBR matrix in the blend and the addition of TOR led to a finer dispersion of EPDM particles. On the addition of TOR, the tensile strength, the tensile strain as well as the modulus of the blend vulcanizates increased. The ozone resistance of the blends determined in terms of critical stress-strain parameter was significantly enhanced in the blend as TOR was added. Improvements in the properties were believed to be associated with fine morphology and the increase in crosslink density due to the chain entanglement of the ternary blends.

• Journal of the Society of Cosmetic Scientists of Korea
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• v.43 no.2
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• pp.165-174
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• 2017

This study reports a synthesis of an amphiphilic linear block copolymer consisting of a hydrophobic poly (lactide) (PLA) block and a hydrophilic hyperbranched polyglycerol (hbPG) block, PLA-b-hbPG. Simple chemical modification of the hbPG block with 4-hydroxycinnamic acid (CA) led to a photo-crosslinkable block copolymer, PLA-b-hbPG-CA. Nanosized micelles of the block copolyemrs were used as drug carriers for sustainable release. The hbPG shell made of a small molecular weight hbPG block showed excellent hydrophilicity, which can minimize in vivo toxicity. The UV-crosslinked PLA-b-hbPG-CA micelles loaded with drugs colud be served as a drug delivery carrier for its biocompatibility and self-assembled structures.

• Polymer(Korea)
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• v.37 no.5
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• pp.571-578
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• 2013

Polyamide12 (PA12) is blended with ethylene propylene diene rubber (EPDM) at various compositions in the presence of maleated EPDM (mEPDM) to afford blend materials having the characteristics of thermoplastic elastomer (TPE). The EPDM/PA12 melt-blends are further irradiated with electron-beam (e-beam) at 0~100 kGy dosage, yielding selective crosslinking between EPDM chains while retaining melt-processibility originated from PA12 phase. mEPDM acts as a compatibilizer and affords additional improvements in mechanical properties of the EPDM/PA12 blend. With 25 kGy of e-beam irradiation and mEPDM, the EPDM/PA12 blends successfully exhibit TPE behaviors with reasonable elastomeric and mechanical properties.