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Hydrogen Production from hydrocarbon by carbon black decomposition (탄화수소류로부터 카본블랙에 의한 수소생산)

  • Yoon, Suk-Hoon;Han, Gi-Bo;Lee, Jong-Dae;Park, No-Kuk;Ryu, Si-Ok;Lee, Tae-Jin;Yoon, Ki-June
    • 한국신재생에너지학회:학술대회논문집
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    • 2005.11a
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    • pp.638-641
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    • 2005
  • 수소는 자원이 무한하고 청결한 에너지이다. 수소는 무공해 청정 대체연료로 사용될 수 있을 뿐만 아니라 풍부한 자원으로부터 얻을 수 있다. 수소에너지는 물을 분해하여 얻거나 화석연료를 수증기개질 또는 부분산화 시킴으로써 얻을 수가 있다. 수소에너지는 1차 에너지를 변환시켜 얻을 수 있는 2차 에너지로서 환경에 대한 부하가 거의 없어 향후 화석연료를 대체할 수 있는 가장 가능성이 높은 에너지이며, 연료전지의 상용화를 앞두고 있어 중요성이 더욱 증대되고 있다. 수소를 생산하는 방법 중 가장 이상적인 방법으로는 물분해함으로써 수소를 제조하는 방법이 있다. 그러나 물분해에 의한 수소생산은 제조비용이 비싸 경제성이 떨어진다는 점과 수소의 대량생산에 필요한 기술확보가 여의치 않아 어렵다. 그러므로 수소를 저 비용으로 대량 생산할 수 있는 수소 제조 기술의 확보가 선행되어야 할 것이다. 현재 상용화되어 있는 수소제조방법은 거의 석유나 천연가스의 수증기 개질에 의한 수소 제조 방법이다. 그러나 이러한 방법은 유해 환경 물질인 CO나 $CO_2$를 배출하는 단점을 지니고 있다. 이러한 단점을 보완키 위한 수소 제조공정의 대안 중 하나는 탄화수소연료의 수소와 탄소로의 직접분해에 의한 수소생산이다. 이 중 원하는 생성물인 수소 외에 부산물이 카본이 동시에 얻을 수 있는 메탄분해에 의한 수소생산방법은 생산된 수소의 약 15%만 연소시킴으로서 필요한 에너지를 공급할 수 있으며, 동시에 지구온난화의 주범인 CO 또는 $CO_2$가 생성되지 않는 장점이 있다. 하지만 메탄을 분해하기 위해서는 매우 높은 에너지가 필요로 하게 된다. 이에 반해 프로판은 메탄보다 낮은 열원에서 분해할 수 있는 장점을 지니고 있다. 본 연구에서는 메탄보다 분해하기 쉬운 프로판을 직접 분해하여 수소를 생산하고자 하였다. 프로판 직접분해반응는 $500\sim750^{\circ}C$의 온도 범위에서 이루어 졌으며, 촉매로서는 국내에서 생산되는 상용촉매인 카본블랙을 이용하였다.

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Study on manufacturing and operating characteristics of Magnetic cores for Flat TR (Flat TR용 핵심 쿄아의 제조와 동작 특성 안정화 연구)

  • Han, Se-Won;Cho, Han-Goo;Yu, Dong-Uk;Ryu, Mung-Ho;Choi, Kwang-Bo;Kim, Sung-Ba
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2003.05e
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    • pp.23-26
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    • 2003
  • The flat transformer, typically, has a number of parallel single turn secondary windings. Each secondary winding is coupled to the same primary winding. Therefore, the current in each secondary winding is equal to the ampere-turns in the primary winding, and to each other. These characteristics are particularly advantageous where parallel rectifiers are used. The windings share the current equally, with no need for ballast resistors or other added components. In this study, the ferrite magnetic core samples of Mn-Zn system for the Flat transformer are manufactured and the electrical and magnetic characteristics of its tested. The density of sample FO2-2 sintered at $1350^{\circ}C$ is $4.00kg/m^3$, which shows the good microstructural state. The initial permeability and saturation flux density of FO2 at room temperature is 2700 and 510mT, individually. The power loss of FO2 samples at 250kHz have been ranged $350kW/m^3$ to $80kW/m^3$ with temperature. And the minimum power loss of sample FO2-2 showed at $70^{\circ}C$, which property seems very positive to apply for a flat transformer.

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Influence of Superficial Heat and Deep Heat for Lumbo-sacral Segment on H-Reflex (흉요추부의 표재열 및 심부열 적용이 H 반사의 변화에 미치는 영향)

  • Yoon, Se-Won;Lim, Young-Eun;Lee, Jeong-Woo
    • Journal of the Korean Academy of Clinical Electrophysiology
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    • v.5 no.2
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    • pp.1-9
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    • 2007
  • Purpose: The purpose of this study was to investigate influence of superficial heat and deep heat for lumbo-sacral segment on H-reflex. Methods: Subjects of this research were 12 normal men and women (6 men and 6 women) and they were assigned to superficial heat group (6) and deep heat group (6). Heat treatment was applied between Th12-L2 by placing them at prone posture. superficial heat was applied for 20 min at 30 cm height with infrared lamp. Deep heat was applied for 20 mm at 5 cm height with 100 watt of microwave diathermy. H-reflex used diagnostic electromyography, active electrode was placed at muscle belly of medial gastrocnemius muscle at prone posture and electrical stimulation was given to posterior tibial nerve. Measurement was made before and after experiment and 10 min. and 20 min. after experiment. All data were analyzed with window 12.0 program, comparison of differences among measured items of groups according to repeated measurement was made with repeated measures ANOVA and significance level a was 0.05. Results: M latency at latency analysis showed little changes at two groups. H latency was reduced a little immediately after experiment and recovered to original state, there was significant difference. In analysis of amplitude, Mmax amplitude showed rise a little immediately after.

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A Study on a Method of Identifying a Block Cipher Algorithm to Increase Ransomware Detection Rate (랜섬웨어 탐지율을 높이기 위한 블록암호 알고리즘 식별 방법에 관한 연구)

  • Yoon, Se-won;Jun, Moon-seog
    • Journal of the Korea Institute of Information Security & Cryptology
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    • v.28 no.2
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    • pp.347-355
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    • 2018
  • Ransomware uses symmetric-key algorithm such as a block cipher to encrypt users' files illegally. If we find the traces of a block cipher algorithm in a certain program in advance, the ransomware will be detected in increased rate. The inclusion of a block cipher can consider the encryption function will be enabled potentially. This paper proposes a way to determine whether a particular program contains a block cipher. We have studied the implementation characteristics of various block ciphers, as well as the AES used by ransomware. Based on those characteristics, we are able to find what kind of block ciphers have been contained in a particular program. The methods proposed in this paper will be able to detect ransomware with high probability by complementing the previous detection methods.

A study on applying of the ITC-Hulls & ISM Code for the Accident of Foundering Ship (선박침몰사고에 따른 ITC약관 및 ISM Code 적용에 관한 연구)

  • Kim, Dae-Hae;Kim, Se-Won
    • Proceedings of the Korean Institute of Navigation and Port Research Conference
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    • 2007.12a
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    • pp.117-118
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    • 2007
  • This paper was provided to apply the ITC-Hulls Clauses & ISM Code for the accident of sunken ship which was occurred by seamen's barratry. For the causes of the sunken accident, the underwriter insisted that shipowner submerged the vessel intentionally for the purpose of the insured amounts, while shipowner protests that the ship was submerged because of crews faults. In this connection, the judge sentenced that this accident was caused by humans errors as the Provisions of 6.2.4 of ITC-Hulls, however shipowner is responsible for hiring onboard qualified seafarers and carrying out the due diligence for performing ISM Code for ensuring ship's safety and seaworthiness.

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Behavior of Reduction and Carburization of EAF Dust and Mill Scale (전기로 분진과 압연 Scale의 환원 및 탄화거동)

  • Hwang Ho-Sun;Chung Uoo-Chang;Chung Won-Sub;Chung Won-Bae
    • Resources Recycling
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    • v.12 no.5
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    • pp.50-56
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    • 2003
  • To be recycled iron and heat source in EAF, EAF dust and mill scale generated from steelmaking plant should be made to iron carbide. Behavior of reduction and carburization in EAF dust and mill scale is studied to get fundamental data. EAF dust and mill scale are carburized at $650^{\circ}C$ by 100% CO gas. The carbon content of iron carbide(about 9 wt,% C) is higher than that of cementite without free carbon. The 1.2 times of calculated carbon content is suitable for reduction of EAF dust. The reduction temperature is appropriate to $900^{\circ}C$ in EAF dust and $1000^{\circ}C$ in mill scale. The carburization rate of mill scale are faster than those of EAF dust. The composition of super iron carbide is almost $Fe_2$C.

A case of Rothmund-Thomson syndrome (Rothmund-Thomson 증후군 1례)

  • Kim, Seung Hyo;Shin, Choong Ho;Yang, Sei Won
    • Clinical and Experimental Pediatrics
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    • v.49 no.5
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    • pp.565-569
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    • 2006
  • Rothmund-Thomson syndrome (RTS), is a rare autosomal recessive disorder, characterized by : skin photosensitivity, poikiloderma, sparse hair, sparse eyebrows/lashes, short stature, skeletal abnormalities, cataracts, and an increased risk of malignancy. Skeletal abnormalities include : dysplasia, absent or malformed bones, such as absent radii, osteopenia, and delayed bone formation. RTS is thought to result from chromosomal instability, and children with RTS are at risk of cancer. Reported cancers in children with RTS include : basal cell carcinoma, squamous cell carcinoma of the skin and osteosarcoma of bone. We report an 11 year-old boy, who presented to our institution with poikilodermatous skin change with telangiectasia and hyperpigmentation, absence of radius and thumb, and the development of osteosarcoma of the left tibia. The patient is now receiving supportive care and is receiving maintenance chemotherapy after surgery for osteosarcoma.

Investigation of Structural Reliability on Solder Joint According to Heater Set-point of the Lunar Lander (달 착륙선의 히터 작동온도 설정에 따른 솔더 접합부의 구조적 신뢰성 분석)

  • Jeon, Young-Hyeon;Park, Tae-Yong;Lee, Jang-Joon;Kim, Jung-Hoon;Oh, Hyun-Ung
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.46 no.2
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    • pp.167-174
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    • 2018
  • The heater is applied to the lunar lander for securing its survivability under severe lunar thermal environment during 14 days of night time. For this, the heater on/off set-points shall be determined to minimize the power consumption due to the limited power generation of lunar lander during night time. In addition, the temperature changes of the lander according to the heater set-point is also an important factor because it is related to thermo-mechanical reliability on solder joint of on-board electronics. In this study, we investigated thermo-mechanical reliability on solder joint according to the heater set-point by using commercial reliability and a life prediction tool of Sherlock based on the thermal analysis results of lunar lander that is a year of the mission lifetime.

No Association between the 5-HT6 Receptor C267T Polymorphism and Response to Citalopram Treatment in Patient with Major Depressive Disorder (주요우울증 환자에서 세로토닌 6(5-HT6) 수용체 C267T 다형성과 Citalopram 치료반응에 대한 연구)

  • Hahn, Sang-Woo;Lim, Se-Won;Oh, Kang-Seob;Kang, Rhee-Hun;Lee, Min-Soo
    • Korean Journal of Biological Psychiatry
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    • v.14 no.4
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    • pp.262-267
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    • 2007
  • The serotonin 6(5-HT6) receptor gene is a candidate gene for influencing the clinical response to treatment with antidepressants. The purpose of this study was to determine the relationship between the C267T polymorphism in the 5-HT6 receptor gene and the treatment response to citalopram in a Korean population with major depressive disorder(MDD). Methods : Citalopram was administered for 8 weeks to the 90 patients who completed study. 21-item Hamilton depression rating scale(HAMD-21) was used as a outcome measure. Results : We found that the genotype, allele, and allele-carrier distributions did not differ significantly between MDD patients and normal controls. A main effect of an interaction of genotype with time on the decrease in the HAMD-21 score during the 8 weeks study period was not found. ANOVA revealed no significant effects of the C825T polymorphism on the decrease in the HAMD-21 score at each time period. Conclusions : These results suggest that the C267T polymorphism in the 5-HT6 receptor gene is not associated with the treatment response to citalopram.

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A Study on Hardening Characteristics of High Carbon Steel by using High Power Diode Laser (고출력 다이오드 레이저를 이용한 고탄소강의 경화특성에 관한 연구)

  • Hwang, Hyun-Tae;Kim, Jong-Do;So, Sang-Woo
    • Journal of Advanced Marine Engineering and Technology
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    • v.35 no.5
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    • pp.600-607
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    • 2011
  • Recently, high carbon steel has become essential not only for shipbuilding parts, but also mass production. Its surface has been treated by carburizing, nitriding and induction hardening, but these existing treatments cause considerable deformation and increase the expense of postprocessing after treatment; furthermore, these treatments cannot be easily applied to parts that requiring the hardening of only a certain section. This is because the treatment cannot heat the material homogeneously, nor can it heat all of it. Laser surface treatment was developed to overcome these disadvantages, and when the laser beam is irradiated on the surface and laser speed is appropriate, the laser focal position is rapidly heated and the thermal energy of surface penetrates the material after irradiation, finally imbuing it with a new mechanical characteristic by the process of self-quenching. This research estimates the material characteristic after efficient and functional surface treatment using HPDL, which is more efficient than the existing CW Nd:YAG laser heat source. To estimate, microstructural changes and hardness characteristics of two parts (the surface treatment part, and parental material) are observed with the change of laser beam speed and surface temperature.