• 제목/요약/키워드: ‘D3E’

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COMPOSITE HURWITZ RINGS AS ARCHIMEDEAN RINGS

  • Lim, Jung Wook
    • East Asian mathematical journal
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    • 제33권3호
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    • pp.317-322
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    • 2017
  • Let $D{\subseteq}E$ be an extension of integral domains with characteristic zero, I be a nonzero proper ideal of D, and let H(D, E) and H(D, I) (resp., h(D, E) and h(D, I)) be composite Hurwitz series rings (resp., composite Hurwitz polynomial rings). In this article, we show that H(D, E) is an Archimedean ring if and only if h(D, E) is an Archimedean ring, if and only if ${\bigcap}_{n{\geq}1}d^nE=(0)$ for each nonzero nonunit d in D. We also prove that H(D, I) is an Archimedean ring if and only if h(D, I) is an Archimedean ring, if and only if D is an Archimedean ring.

알릴아민 항진균제의 합성과 생물학적 평가 (Synthesis and Biological Evaluation as a Potential Allylamine Type Antimycotics)

  • 정병호;조원제;천승훈;정순영;유진철
    • 약학회지
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    • 제47권5호
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    • pp.293-299
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    • 2003
  • Structure-activity relationship studies of allylamine type of antimycotics were carried out to evaluate the effect of naphthyl and methyl portion of naftifine. Compounds with 4-fluorophenyl(2a-5a), 2-fluorophenyl(2b-5b), 2,4-dichlorophenyl(2c-5c), 2,6-dichlorophenyl(2d-5d), 4-nitrophenyl(2e-5e), and 2,3-dihydro-benzo[1,4]dioxan-6-yl( 2f-5f) instead of naphthyl group with hydrogen(3a-3f), methyl(4a-4f), and ethyl(5a-5f) in the place of methyl in naftifine were synthesized and tested their in vitro anti-fungal activity against five different fungi. Eight compounds(3a, 5a, 3c, 4c, 4d, 5d, 5e, and 4f) showed significant antifungal activity against T. mentagrophytes. (E)-N-Ethyl-(3-phenyl-2-propenyl)-4-nitro-benzenemethaneamine(5e) displayed moderate antifungal activity against all five different fungi.

Triterpenoid Saponins from Vaccaria segetalis

  • Sang, Shengmin;Lao, Aina;Wang, Hongcheng;Chen, Zhongliang;Uzawa, Jun;Fujimoto, Yasuo
    • Natural Product Sciences
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    • 제4권4호
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    • pp.268-273
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    • 1998
  • Two new triterpenoid saponins, named segetoside D and E, have been isolated from the seeds of Vaccaria segetalis. On the basis of chemical reactions and spectral data, structures of segetoside D and E have been established as: $28-O-[{\beta}-D-xylopyranosyl-(1{\rightarrow}4)-{\alpha}-L-rhamnopyranosyl-(1{\rightarrow}2)]-[5-O-acetyl-{\alpha}-arabinofuranosyl(1{\rightarrow}3)]-[4-O-acetyl-{\beta}-D-fucopyranosyl]-quillaic\;acid-3-O-[{\beta}-D-galactopyranosyl(1{\rightarrow}2)]6-O-methyl\;ester-{\beta}-D-glucuronopyranoside$ and $28-O-[{\beta}-D-xylopyranosyl-(1{\rightarrow}4)-{\alpha}-L-rhamnopyranosyl-(1{\rightarrow}2)]-[5-O-acetyl-{\alpha}-arabinofuranosyl(1{\rightarrow}3)]-[4-O-acetyl-{\beta}-D-fucopyranosyl]-quillaic\;acid\;-3-O-[{\beta}-D-galactopyranosyl(1{\rightarrow}2)]-6-O-n-butyl\;ester-{\beta}-D-glucuronopyranoside$, respectively.

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Cu 3d 와 4p 궤도함수의 혼성과 리간드의 Spin-Orbit Coupling 이 Tetragonally 일그러진 $CuCl_4^{2-}$ 착물의 Zero-Field Splitting에 미치는 영향 (The Effect of Ligand's Spin-Orbit Coupling and the Intermixing of │3d 〉 and │4p 〉 Cu Atomic Orbitals on Zero-Field Splitting in the Tetragonally Distorted Tetrahedral $CuCl_4^{2-}\;Complex^\ast$)

  • 이왕노;최우성;백우현;김동희;최창진;이기계
    • 대한화학회지
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    • 제34권1호
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    • pp.37-43
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    • 1990
  • $D_{2d}$ 점군에 속하는 강결정장의 tetragonally 일그러진 사면체 3$d^9$전자계 착물의 바닥상태에 대한 리간드 궤도함수의 spin-orbit coupling과 중심 금속의 3d와 4p궤도함수의 intermixing이 미치는 영향에 대하여 중첩 섭동론을 사용하여 연구하였다. 단결정 $Cs_2CuCl_4$의 tetragonally 일그러진 $CuCl_4^{2-}$에 대한 d-d전이의 실험값을 사용한 LCAO-MO분석은 구리이온과 리간드 사이의 공유결합성은 Cu 4p orbital의 기여가 증가하므로서 급격히 감소하고 리간드 Cl 3p궤도함수의 spin-orbit coupling 상호작용에 의한 바닥상태의 에너지 준위 분리에 대한 효과는 $\Gamma_7(E)\;\to\;\Gamma_6(E)\; >\;\Gamma_7(B_2)\;\to\;\Gamma_6(E)\; >\;\Gamma_7(B_2)\;\to\;\Gamma_7(E)$의 순서로 감소하였다.

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해석모델링 방법에 따른 선체거더의 수중폭발 휘핑응답 비교 (Comparison of UNDEX Whipping Response of Hull Girder according to Modeling Methods)

  • 권정일;정정훈;이상갑
    • 대한조선학회논문집
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    • 제42권6호
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    • pp.631-636
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    • 2005
  • One and three dimensional whipping response analyses of a naval surface combatant subjected to an underwater explosion bubble pulse were carried out to compare the efficiency and accuracy according to the modeling methods. In 1-D analysis, program UNDEXWHIP developed by KIMM was used, which is based on the thin-walled Timoshenko's beam theory and on the modal analysis method using wetted vibratory modes of the hull girder. In 3-D analysis, three finite element models were suggested using LS-DYNA/USA code, such as 3-D beam model considering geometric shape of wetted side shell, coarse and fine 3-D F.E. models. Through the comparison of results from the 1-D and 3-D analyses, it could be confirmed that 1-D analysis result is in good agreement with 3-D analysis ones, and that fine 3-D F.E. model, shock analysis one, is also used both in the shock response and whipping response analyses for the analyst effort and time savings.

니켈 치환된 스피넬 LiMn2O4 박막의 구조적, 광학적 성질 (Structural and optical properties of Ni-substituted spinel $LiMn_2O_4$ thin films)

  • 이중한;김광주
    • 한국진공학회지
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    • 제15권5호
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    • pp.527-533
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    • 2006
  • 졸-겔(sol-gel) 방법을 이용하여 스피넬(spinel) 구조를 가지는 $LiNi_xMn_{2-x}O_4$ 박막을 x = 0.9까지 합성하였다. 니켈 치환된 박막은 작은 x 값에서는 cubic 구조가 유지되지만, $x{\geq}0.6$ 범위에서는 tetragonal 구조로 상전이가 일어남이 발견되었다. 이와 같은 cubic-tetragonal 상전이는 low-spin $(t_{2g}^6,e_g^1)$ 상태를 가지는 $N^{3+}(d^7)$ 이온이 팔면체 자리를 차지하게 됨으로써 나타나는 Jahn-Teller 효과에 의한 것으로 해석된다. 이와 같은 Ni 이온들은 +3 및 +2의 원자가를 가지고 존재함이 X-ray photoelectron spectroscopy 분석을 통하여 확인되었다. $LiNi_xMn_{2-x}O_4$ 박막들에 대하여 가시광선-자외선 영역에서 spectroscopic ellipsometry(SE)를 이용하여 광학적 성질을 조사하였고, 그 결과 분석을 통하여 화합물 전자구조에 대하여 고찰하였다. SE 측정된 유전함수 스펙트럼은 주로 전하이동(charge-transfer, CT) 전이(transition)에 의한 넓은 에너지 영역을 가지는 1.9, 2.3, $2.8{\sim}3.0$, $3.4{sim}3.6eV$ 근처의 흡수구조 들로 이루어져 있는데, $O^{2-}$에서 $Mn^{4+}$ 이온의 $t_{2g}$ (1.9 eV)와 $e_g$ $(2.8{\sim}3.0\;eV)$로의 전이 즉, $O^{2-}(2p){\rightarrow}Mn^{4+}(3d)$$O^{2-}$에서 $Mn^{3+}$ 이온의 $t_{2g}$ (2.3 eV)와 $e_g$ ($3.4{\sim}3.6$ eV)로의 전이 즉, $O^{2-}(2p){\rightarrow}Mn^{3+}(3d)$ 등에 의한 것으로 해석된다. 또한, 1.6, 1.8, 1.9 eV 부근에서 관측된 좁은 에너지 영역의 흡수구조 들은 팔면체 $Mn^{3+}$ 이온 내에서의 d-d 결정장(crystal-field) 전이에 의한 것으로 해석된다. 이러한 흡수구조는 Ni 치환량이 증가함에 따라 그 강도가 감소한다. x = 0.6의 경우 $e_g$ 상태와 관련된 CT 전이구조 들이 $t_{2g}$ 상태와 관련된 전이구조 들에 비하여 큰 폭으로 감소하는데 이것은 Jahn-Teller 효과에 의해서 격자상수가 tetragonal 구조로 확장됨에 따라 $e_g$ 상태와 $O^{2-}(2p)$ 상태 간의 파동함수 중첩이 감소한 것에 기인하는 것으로 해석된다.

Anti-Proliferative Activity of Ethanol Extracts from Taxilli Ramulus (Taxillus chinensis (DC.) Danser) Through Cyclin D1 Proteasomal Degradation in Human Colorectal Cancer Cells

  • Park, Gwang Hun;Song, Hun Min;Park, Su Bin;Park, Ji Hye;Shin, Myeong Su;Son, Ho-Jun;Um, Yurry;Jeong, Jin Boo
    • 한국자원식물학회지
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    • 제30권6호
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    • pp.640-646
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    • 2017
  • In this study, we elucidated anti-cancer activity and potential molecular mechanism of 70% ethanol extracts from Taxilli Ramulus (Taxillus chinensis (DC.) Danser) (TR-E70) against human colorectal cancer cells. Anti-cell proliferative effect of TR-E70 was evaluated by MTT assay. The effect of TR-E70 on the expression of cyclin D1 in the protein and mRNA level was evaluated by Western blot and RT-PCR, respectively. TR-E70 suppressed the proliferation of human colorectal cancer cell lines, HCT116 and SW480. Although TR-E70 decreased cyclin D1 expression in protein and mRNA level, decreased level of cyclin D1 protein by TR-E70 more dramatically occurred than that of cyclin D1 mRNA. Cyclin D1 downregulation by TR-E70 was attenuated in presence of MG132. In addition, TR-E70 phosphorylated threonine-286 (T286) of cyclin D1. TR-E70-mediated cyclin D1 degradation was blocked in presence of LiCl as an inhibitor $GSK3{\beta}$ but not PD98059 as an ERK1/2 inhibitor and SB203580 as a p38 inhibitor. Our results suggest that TR-E70 may downregulate cyclin D1 as one of the potential anti-cancer targets through $GSK3{\beta}$-dependent cyclin D1 degradation. From these findings, TR-E70 has potential to be a candidate for the development of chemoprevention or therapeutic agents for human colorectal cancer.

디지털 영사식 무아레를 이용한 3차원 형상 측정과 응용에 관한 연구( I ) (A Study on 3-D Shape Measurement and Application by using Digital Projection $Moir\acute{e}$ ( I ))

  • 유원재;노형민;이동환;강영준
    • 한국정밀공학회지
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    • 제22권7호
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    • pp.88-93
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    • 2005
  • $Moir\acute{e}$ topography method is a well-known non-contacting 3-D measurement method. Recently, the automatic 3-D measurement by $Moir\acute{e}$ topography has been required, since the method was frequently applied to the engineering and medical fields. The 3-D measurement using projection $Moir\acute{e}$ topography is very attractive because of its high measuring speed and high sensitivity. In this paper, using two-wavelength method of projection $Moir\acute{e}$ topography was tested to measuring object with $2\pi-ambiguity$ problems. The experimental results prove that the proposed scheme is capable of finding absolute fringe orders, so that the $2\pi-ambiguity$ problems can be effectively overcome so as to treat large step discontinuities in measured objects.

Effects of Consumers' Technology Readiness on Telepresence and E-loyalty toward 3D Online Shopping Mall

  • Yang, Hee-Soon;Jung, Hye-Jung;Youn, Cho-Rong;Choi, Yun-Jung;Lee, Yu-Ri
    • 한국의류학회지
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    • 제35권6호
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    • pp.659-669
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    • 2011
  • Consumer responses to 3D online shopping malls are influenced by their attitudes toward technology. This study examines the consumer differentiation according to technology readiness, compares customers with different technology readiness in terms of their perceived telepresence and e-loyalty, and examines the effect of their perceived telepresence on their e-loyalty. Samples from 300 females aged 21 to 39 were used for the final analysis. The results are as follows. First, consumers were classified into three groups, Explorers (N=72), Pioneers (N=105), and Skeptics (N=123), through factor analysis and k-means cluster analysis. Second, the Explorers evaluated the telepresence of the 3D online shopping mall higher than any other group. The Skeptics presented lower e-loyalty and perceived less telepresence in the 3D online shopping mall than the other two groups. Finally, telepresence had a significant influence on e-loyalty, as identified by the regression analysis. This verifies the effectiveness of 3D technology adopted or to be adopted by online shopping malls and demonstrates that 3D shopping malls can be a strategic alternative in the online shopping sector where competition is fierce. The results show that online shopping malls should focus on establishing 3D shopping environments with further effort to utilize the technology.