• Proceedings of the Korean Vacuum Society Conference
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• 2012.02a
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• pp.267-267
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• 2012

$TiO_2$-Ni inverse catalysts were prepared using atomic layer deposition (ALD) process and catalytic $CO_2$ reforming of methane (CRM) reaction over catalysts (either bare Ni or $TiO_2$ coated-Ni particles) were performed using a continuous flow reactor at $800^{\circ}C$. $TiO_2$-Ni inverse catalyst showed higher catalytic reactivity at initial stage of CRM reactions at $800^{\circ}C$ comparing to bare Ni catalysts. Moreover, catalytic activity of $TiO_2$/Ni catalyst was kept high during 13 hrs of the CRM reactions at $800^{\circ}C$, whereas deactivation of bare Ni surface was started within 1hr under same conditions. The results of surface analysis using SEM, XPS, and Raman showed that deposition of graphitic carbon was effectively suppressed in a presence of $TiO_2$ nanoparticles on Ni surface, thereby improving catalytic reactivity and stability of $TiO_2$/Ni catalytic systems. We suggest that utilizing decoration effect of metal catalyst with oxide nanoaprticles is of great potential to develop metal-based catalysts with high stability and reactivity.

• Bulletin of the Korean Chemical Society
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• v.34 no.12
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• pp.3811-3816
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• 2013

Nucleophilic substitution reactions of ethyl methyl (2), ethyl propyl (4) and diisopropyl (7) chlorothiophosphates with substituted anilines and deuterated anilines are investigated kinetically in acetonitrile at $55.0^{\circ}C$. A concerted mechanism is proposed based on the selectivity parameters. The deuterium kinetic isotope effects (DKIEs; $k_H/k_D$) are secondary inverse ($k_H/k_D=0.66-0.99$) with 2, primary normal and secondary inverse ($k_H/k_D=0.78-1.19$) with 4, and primary normal ($k_H/k_D=1.06-1.21$) with 7. The primary normal and secondary inverse DKIEs are rationalized by frontside attack involving hydrogen bonded, four-center-type transition state, and backside attack involving in-line-type transition state, respectively. The anilinolyses of ten chlorothiophosphates are examined based on the reactivity, steric effect of the two ligands, thio effect, reaction mechanism, DKIE and activation parameter.

• Korean Journal of Applied Biomechanics
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• v.15 no.2
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• pp.57-67
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• 2005

The purpose of this study was to analyze the kinetic factors of the golf driver swing using the Inverse Dynamics function. For this purpose, joint force were calculated. In order to test the possibility of Inverse Dynamics function(motion-dependent interaction), a triple segmental system was set for wrist, left shoulder and lumbar and joint force working on the anatomical joint region was estimated. For this study, 7 professional golfers were sampled, and then, their driver swings were recorded with two high-speed digital video cameras (180 frames/sec.) to be synthesized into 3-dimensional images and coordinated. Then, Eular's equation was used to produce some kinematic data, which were used to calculate joint force and torque with Newton's function. All data were calculated using LabVIEW 6.1 graphic program. The results of this study can be summarized as follows; It was found that the joint force was generated on wrist, shoulder and lumbar joints in the direction of the target, and that the joint force was stronger in the direction of target immediately before impact. The joint force was generated towards the target to activate the nodes, and then, it was generated in the reverse direction to increase the speed during impact.

• Applied Chemistry for Engineering
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• v.28 no.2
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• pp.141-152
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• 2017

Inverse electron-demand Diels-Alder reactions (IEDDA) between tetrazine derivatives and strained dienophiles have attracted a lot of attention for the efficient conjugation of biomolecules, polymers, and nanomaterials. Excellent specificity, exceptionally fast reaction rate, and biocompatibility are key features of IEDDA. Therefore, it has also been applied to the development of new labeling methods using several radioisotopes and development of radiotracers to carry out various nuclear imaging as well as therapeutic studies. The purpose of this review is to introduce the reader to the recent advances and applications of IEDDA in the fields of radiochemistry and nuclear medicine.

• Journal of applied mathematics & informatics
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• v.20 no.1_2
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• pp.17-34
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• 2006

Inverse coefficient identification problems associated with the fourth-order Sturm-Liouville operator in the steady state Euler-Bernoulli beam equation are investigated. Unlike previous studies in which spectral data are used as additional information, in this paper only boundary information is used, hence non-destructive tests can be employed in practical applications.

• Journal of applied mathematics & informatics
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• v.15 no.1_2
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• pp.485-493
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• 2004

This paper presents the interesting properties of a certain patterned matrix that plays an significant role in the statistical analysis. The necessary and sufficient condition on the existence of the inverse of the patterned matrix and its determinant are derived. In special cases of the patterned matrix, explicit formulas for its inverse, determinant and the characteristic equation are obtained.

• Clean Technology
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• v.18 no.1
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• pp.38-42
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• 2012

Photonic crystals (PCs) are highly ordered porous materials which have been much attention because of its potential for controlling the light sauces. There are many methods for synthesizing this kind of materials among them we chose the supercritical deposition. With this method the reactants can easily infiltrate into the complex structure. In this paper, supercritical carbon dioxide ($scCO_2$) was used as a reaction medium, which is known as a sustainable solvent due to its nontoxic and noninflammable characteristics. We coated the colloidal template with metal alkoxide by using $scCO_2$ and then obtained macro-porous inverse opals. The reaction was carried out at $40^{\circ}C$ and 80 bar. We synthesized two different inverse opals which called silica and titania inverse opals by use of tetraethyl orthosilicate (TEOS) and titanium isopropoxide (TTIP) as a precursor, respectively.

• Journal of the Korean Mathematical Society
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• v.48 no.2
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• pp.311-327
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• 2011

This paper is devoted to simplified Tikhonov regularization for two kinds of parabolic equations, i.e., a sideways parabolic equation, and a two-dimensional inverse heat conduction problem. The measured data are assumed to be known approximately. We concentrate on the convergence rates of the simplified Tikhonov approximation of u(x, t) and its derivative $u_x$(x, t) of sideways parabolic equations at 0 $\leq$ x < 1, and that of two-dimensional inverse heat conduction problem at 0 < x $\leq$ 1, respectively.

• The Korean Journal of Applied Statistics
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• v.10 no.2
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• pp.293-308
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• 1997

Sliced inverse regression is a method for reducing the dimension of the explanatory variable X without going through any parametric or nonparametric model fitting process. This method explores the simplicity of the inverse view of regression; that is, instead of regressing the univariate output varable y against the multivariate X, we regress X against y. In this article, we propose bivariate sliced inverse regression, whose method regress the multivariate X against the bivariate output variables $y_1, Y_2$. Bivariate sliced inverse regression estimates the e.d.r. directions of satisfying two generalized regression model simultaneously. For the application of bivariate sliced inverse regression, we decompose the output variable y into two variables, one variable y gained by projecting the output variable y onto the column space of X and the other variable r through projecting the output variable y onto the space orthogonal to the column space of X, respectively and then estimate the e.d.r. directions of the generalized regression model by utilize two variables simultaneously. As a result, bivariate sliced inverse regression of considering the variable y and r simultaneously estimates the e.d.r. directions efficiently and steadily when the regression model is linear, quadratic and nonlinear, respectively.

• Journal of Korean Association for Spatial Structures
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• v.2 no.1 s.3
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• pp.75-84
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• 2002

In this study, the 'force density method' for shape finding of cable net structures is presented. This concept is based on the force-length ratios or force densities which are defined for each branch of the net structures. This method renders a simple linear 'analytical form finding' possible. If the free choice of the force densities is restricted by further condition, the linear method is extended to a nonlinear one. The nonlinear one can be applied to the detailed computation of networks. In this paper, the general inverse matrix is introduced to solve the nonlinear equilibrium equation including Jacobian matrix which is rectangular matrix. Several examples for linear and nonlinear analysis applied additional constraints are presented. It is shown that the force density method is suitable for form finding of cable net and the general inverse matrix can be applied to solve the nonlinear equation without Lagrangian factors.