• 한국건축시공학회지
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• 제24권3호
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• pp.285-295
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• 2024

본 연구에서는 500℃·hr의 증기양생을 실시한 OPC 페이스트에 대하여 1atm 20% 농도의 CO₂와 5atm 99% 농도의 고농도 CO₂ 조건 하의 촉진 탄산화의 영향평가를 수행하였다. 이를 위하여 XRD, FT-IR을 통한 화학적 분석과 SEM, 압축강도 측정을 통한 물리적 특성 분석을 실시하였다. 그 결과 CO₂ 20% 농도의 상압 탄산화를 수행하는 경우 뚜렷한 내부 조직구조 치밀화 및 압축강도 증진 효과를 관찰할 수 있었고, CO₂ 99% 농도의 5atm 가압 탄산화를 실시할 경우 표면조직구조가 빠르게 치밀해지며 CO₂ 확산침투율이 크게 떨어지게 되어 압축강도 등 유의미한 수준의 물리적 특성 개선이 일어날 정도의 탄산화를 진행할 수 없었다.

• 한국수소및신에너지학회논문집
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• 제17권1호
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• pp.109-116
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• 2006

The heat treatment characteristics of natural talc sample was investigated in diverse analytical view point. The mass decrease comes to heat treatment was resulted by the continuous and the discontinuous process and the obtained result show very similar two step profiles with 8.9 % mass decrease. The dehydroxylation of -OH groups contained talc crystal was analyzed by spectroscopic method and the crystallographic variations was also observed after heat treatment. According to XPS result, the magnesium hydroxide($Mg(OH)_2$) of untreated talc powder changed to magnesium oxides(MgO) after heat treatment.

• 지구물리와물리탐사
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• 제9권1호
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• pp.44-49
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• 2006

이 연구에서는 $CO_2$ 주입 모니터링에서의 전기비저항 토모그래피(ERT)의 분해능에 대해 조사한다. $CO_2$ 주입체 양쪽의 케이싱 없는 시추공에서 단극자 및 양극자 전극 배열이 사용된다. 주입 전 및 주입에 따른 3단계 모델에 대한 반응이 계산되고, 잡음이 더해진 후의 이론 값들이 L1 과 L2 norm을 사용해 역산된다. 역산결과는 어느 정도 수준이상의 $CO_2$ 부피가 확실히 감지됨을 보여준다. 대부분의 경우에 L1 norm의 경우가 L2에 비해 우월함이 판명되었다. 역산 결과를 주입 전 모델의 역산결과로 정규화하면 전기비저항이 변화하는 부분의 훌륭한 영상을 보여주며, 비저항의 전체적인 변화를 통합해서 판단하면 전체 주입된 부피에 대한 타당한 측정이 이루어짐이 입증된다.

• 설비공학논문집
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• 제15권9호
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• pp.718-726
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• 2003

Carbon dioxide ocean disposal is one of the promising options to reduce carbon dioxide concentration in the atmosphere because the ocean has vast capacity for carbon dioxide sequestration. However, the dissolution rate of liquid carbon dioxide in seawater must be known in advance in order to estimate the amount of carbon dioxide sequestration in the ocean. Therefore, in the present study, calculations of the solubility, the surface concentration and the dissolution behavior of carbon dioxide when liquid carbon dioxide is released at 1,000m and 1,500m in depth are peformed. The results show that the droplet is completely dissolved below 500 m in depth if the carbon dioxide droplet is released both at 1,000m in depth with the initial droplet diameter of 0.011m or less and at 1,500m in depth with the diameter of 0.016 or less. Also, the surface concentration of carbon dioxide droplet with the hydrate film is about 50% of carbon dioxide solubility at 1,500 m in depth and about 60% of carbon dioxide solubility at 1,000 m in depth.

• Fisheries and Aquatic Sciences
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• 제12권4호
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• pp.350-353
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• 2009

As a result of human industrial development, carbon dioxide ($CO_2$) is currently accumulating in the atmosphere and dissolving into the oceans. Sequestration into the deep sea has been proposed as a possible solution to this increasing atmospheric $CO_2$, although the impact of such a program on marine ecosystems is unknown. We examined the effects of increased $CO_2$ levels on the growth of the olive flounder, Paralichthys olivaceus. Juvenile olive flounder 40 days post hatching were exposed to two levels of $CO_2$ (3.60-7.55 and 4.05-11.46 kPa) in running seawater for 26 days. During the exposure period, the pH and $CO_2$ levels of the water were measured, and the numbers of dead individuals were counted in each aquarium. Following the exposure period, the total lengths (mm) and body weights (mg) of the juvenile fish were measured. Both $CO_2$ treatments significantly increased fish mortality compared to controls ($19.87\pm4.53%$ vs. 7.14% and $75.96\pm1.36%$ vs. 7.14% for high and low doses, respectively). After the high $CO_2$ treatment, total length ($14.98\pm6.58$ mm vs. $19.52\pm1.83$ mm) and body weight ($28.92\pm13.85$ mg vs. $67.35\pm18.32$ mg) of the exposed flounder were reduced compared to the control fish; however, no significant differences in these values were observed after the low $CO_2$ dose. These results suggested that $CO_2$ exposure inhibits growth in the juvenile stage and that $CO_2$-enriched seawater is toxic in the early life stages of olive flounder.

• 한국지하수토양환경학회지:지하수토양환경
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• 제20권4호
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• pp.73-82
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• 2015

Despite significant effects on macroscopic migration and distribution of CO₂ injected during geological sequestration, only limited information is available on wettability in microscopic scCO₂-brine-mineral systems due to difficulties in pore-scale observation. In this study, a micromodel had been developed to improve our understanding of how scCO₂ flooding and residual characteristics of porewater are affected by the wettability in scCO₂-water-glass bead systems. The micromodel (a transparent pore structure made of glass beads and glass plates) in a pressurized chamber provided the opportunity to visualize scCO₂ spreading and porewater displacement. CO₂ flooding followed by fingering migration and dewatering followed by formation of residual water were observed through an imaging system. Measurement of contact angles of residual porewater in micromodels were conducted to estimate wettability in a scCO₂-water-glass bead system. The measurement revealed that the brine-3M NaCl solution-is a wetting fluid and the surface of glass beads is water-wet. It is also found that the contact angle at equilibrium decreases as the pressure decreases, whereas it increases as the salinity increases. Such changes in wettability may significantly affect the patterns of scCO₂ migration and porewater residence during the process of CO₂ injection into a saline aquifer at high pressures.

• 한국수자원학회:학술대회논문집
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• 한국수자원학회 2022년도 학술발표회
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• pp.462-462
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• 2022

Wetlands are one of the most vital natural habitats on the planet. India is incredibly blessed to have a number of multifunctional wetland ecosystems. Wetlands, in addition to their functional importance, can act as sources or sinks for greenhouse gases (GHGs) depending on their intrinsic factors. Carbon (CO2) and Methane (CH4) are the major greenhouse gases (GHG's) emitted in wetlands. It is demonstrated that, despite having 4.6 percent of its area covered by natural or man-made wetlands, being home to a large number of wetlands, and being the world's second largest cultivator of paddy, India's wetlands, including paddy fields that are intermittently flooded as typical wetlands, have been very poorly studied in terms of GHG emissions. The purpose of this paper is to examine the status of Indian wetlands and wetlands in terms of CH4 and CO2 emissions. The present study also reviews various literature to provide the equations, parameters that are required for estimating carbon and methane and some of the best strategies for conserving carbon in wetlands. The findings suggest that both non-manipulative and manipulative measures can be used to improve Carbon Sequestration (CS). Non-manipulative measures aim to improve CS by increasing the spatial extent of wetlands, whereas manipulative measures aim to change the characteristics of specific wetland components that influence CS. Uncertainty in carbon dynamics projections under changing environmental conditions is caused by a number of Knowledge gaps: i) There is a lack of knowledge on how organic matter mineralizes and partitions into carbon dioxide, methane, and dissolved organic carbon, ii) With the notable exception of methane dynamics, models that represent the dynamic interaction of processes and their controls have yet to be established. As a result, more research is needed to fully understand the importance of wetlands in terms of GHG emissions and carbon sequestration in India.

• 환경생물
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• 제34권4호
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• pp.257-263
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• 2016

본 연구는 영년생 작물 중 배 재배지의 탄소수지 평가를 위하여 전남 나주 욱곡리 배 재배지에서 토양호흡, 초본류의 생태계순생산량 그리고 배 과수의 바이오매스와 배 재배지에서의 생태계순교환량을 측정하였다. 2015년 배 재배지의 연간 토양호흡량은 약 $25.6ton\;CO_2\;ha^{-1}$이었다. 바이오매스 측정을 통해 측정된 배나무 수체에 저장된 $CO_2$ 양은 $(-)27.9ton\;CO_2\;ha^{-1}$이었으며, 전정된 가지에 저장된 $CO_2$ 양은 약 $(-)12.6ton\;CO_2\;ha^{-1}\;yr^{-1}$이었다. 배 재배지 임상 하부에 자생하는 초본류 광합성에 의해 흡수된 $CO_2$ 양은 $(-)5.2ton\;CO_2\;ha^{-1}\;yr^{-1}$이었다. 이를 배 재배지 단위에서의 $CO_2$ 배출량과 흡수량으로 구분하여 보면, 연간 1 ha당 약 25.6 ton이 대기 중으로 배출되었으며 대기로부터 흡수된 $CO_2$는 약 (-)45.7 ton이었다. 이를 합산하면 연간 약 (-)20.1 ton의 $CO_2$가 대기 중으로부터 배 재배지로 흡수되는 것을 확인할 수 있었다. 이는 미기상학적인 방법을 이용하여 측정한 배 재배지 대기와 작물 및 토양권 간의 연간 $CO_2$ 교환량 $(-)17.8ton\;ha^{-1}$와 큰 차이를 보이지 않았다. 이러한 다양한 접근 방법을 이용한 연구는 배 재배지뿐만 아니라 영년생 작물 재배지 단위에서 농업생태계 구성요소들 간의 $CO_2$ 흐름을 파악하여 보다 효율적인 탄소수지 평가 연구를 위한 방법론을 제시하고 향후 농업생태계가 탄소 흡수원으로서 인정받기 위한 후속 연구의 기초 데이터로 사용될 수 있을 것으로 예상된다.

• Bulletin of the Korean Chemical Society
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• 제33권7호
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• pp.2325-2332
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• 2012

A series $[C_3Omim]$[X] of imidazolium cation-based ILs, with ether functional group on the alkyl side-chain have been synthesized and structure of the materials were confirmed by various techniques like $^1H$, $^{13}C$ NMR spectroscopy, MS-ESI, FTIR spectroscopy and EA. More specifically, the influence of changing the anion with same cation is carried out. The absorption capacity of $CO_2$ for ILs were evaluated at 30 and $50^{\circ}C$ at ambient pressure (0-1.6 bar). Ether functionalized ILs shows significantly high absorption capacity for $CO_2$. In general, the $CO_2$ absorption capacity of ILs increased with a rise in pressure and decreased when temperature was raised. The obtained results showed that absorption capacity reached about 0.9 mol $CO_2$ per mol of IL at $30^{\circ}C$. The most probable mechanism of interaction of $CO_2$ with ILs were investigated using FTIR spectroscopy, $^{13}C$ NMR spectroscopy and result shows that the absorption of $CO_2$ in ether functionalized ILs is a chemical process. The $CO_2$ absorption results and detailed study indicates the predominance of 1:1 mechanism, where the $CO_2$ reacts with one IL to form a carbamic acid. The $CO_2$ absorption capacity of ILs for different anions follows the trend: $BF_4$ < DCA < $PF_6$ < TfO < $Tf_2N$. Moreover, the as-synthesized ILs is selective, thermally stable, long life operational and can be recycled at a temperature of $70^{\circ}C$ or under vacuum and can be used repeatedly.

• IMMUNE NETWORK
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• 제9권1호
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• pp.12-19
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• 2009

Heme oxygenase (HO)-1 is an inducible enzyme that catalyzes the first and rate-limiting step in the oxidative degradation of free heme into ferrous iron, carbon monoxide (CO), and biliverdin (BV), the latter being subsequently converted into bilirubin (BR). HO-1, once expressed during inflammation, forms high concentrations of its enzymatic by-products that can influence various biological events, and this expression is proven to be associated with the resolution of inflammation. The degradation of heme by HO-1 itself, the signaling actions of CO, the antioxidant properties of BV/BR, and the sequestration of ferrous iron by ferritin all concertedly contribute to the anti-inflammatory effects of HO-1. This review focuses on the anti-inflammatory mechanisms of HO-1 actions and its roles in inflammatory diseases.