• Title/Summary/Keyword: $Y_2O_3$ additive

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Dielectric and Piezoelectric Properties of MnO2-doped PSN-PNN-PT Ceramics (MnO2가 첨가된 PSN-PNN-PT 세라믹스의 유전 및 압전특성)

  • Lee, Jong-Deok
    • Journal of Sensor Science and Technology
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    • v.13 no.2
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    • pp.152-156
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    • 2004
  • The dielectric and piezoelectric properties of 0.36Pb($Sc_{1/2}Nb_{1/2}$)$O_{3}$-0.25Pb($Ni_{1/3}Nb_{2/3}$)$O_{3}$-0.39Pb$TiO_{3}$ (hereafter PSNNT) at the morphotropic phase boundary (MPB) composition were investigated with $0{\sim}2.5$ mot% $MnO_{2}$ doping. Bulk density, dielectric loss and tetragonality of crystal structure were all improved with increasing $MnO_{2}$ additive content. With increasing $MnO_{2}$ additive content, the electromechanical coupling factor and quality factor were also increased: Electromechanical coupling $k_{p}$ and quality factor $Q_{m}$ at 2.0 mol% $MnO_{2}$ doping with were showed highest values of 55.6 % and 252, respectively.

The Effect of Sb2O3 Additive on the Electrical Properties of ZnO Varistor (Sb2O3 첨가제가 ZnO 배리스터의 전기적 특성에 미치는 영향)

  • Kim, Yong-Hyuk
    • The Transactions of The Korean Institute of Electrical Engineers
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    • v.65 no.10
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    • pp.1697-1701
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    • 2016
  • The leakage conduction and critical voltage characteristic of ZnO ceramic were investigated as a function of $Sb_2O_3$ concentration. Leakage conduction in the ohmic region increased with increasing $Sb_2O_3$ concentration and was attributed to the potential barrier height. The nonlinear coefficient increased with an increasing amount of $Sb_2O_3$. It was found that increases in the apparent critical voltages were associated with the lowered donor concentration in the grain boundary of between two ZnO grains. And the decrease of donor concentration on doping with $Sb_2O_3$ additive was attributed to the lowered capacitance in the grain boundary layer.

HYERS-ULAM STABILITY OF AN ADDITIVE TYPE FUNCTIONAL EQUATION

  • Lee, Don-O
    • Journal of applied mathematics & informatics
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    • v.13 no.1_2
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    • pp.471-477
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    • 2003
  • In this paper we invstigate the new additive type functional equation f(2x - y) + f(x-2y) = 3f(x)-3f(y) and prove the stability problem for this equation in the spirit of Hyers, Ulam, Rassias and Gavruta.

Dependences on Heating Conditions and Applicabilities as an Additive for ECIA of Sr1-xBaxFe3+1-ΤFe4+ ΤO3-y Ferrite System

  • Lee, Eun-Seok
    • Bulletin of the Korean Chemical Society
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    • v.25 no.6
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    • pp.859-864
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    • 2004
  • The solid solutions of the $Sr_{1-x}Ba_xFeO_{3-y)$ system (x = 0.0, 0.1, 0.2 and 0.3) having a perovskite structure were prepared in air at 1423 K and then heat-treated in air (A), $O_2(O)\;and\;N_2(N)$ to examine possibility of controlling the nonstoichiometry and applicability as an additive for electrical conducting inorganic adhesives (ECIA). In the samples heated in $N_2$ stream, there existed almost no $Fe^{4+}$ ions, and at constant temperature their electrical conductivities were considerably lower than those of the samples heat-treated in air or $O_2.\; Sr_{0.8}Ba_{0.2}Fe^{3+}_{0.49}Fe^{4+}_{0.51}O_{2.76}$ (SB2-A) whose $Fe^{3+}/Fe^{4+}$ ratio was nearly 1 (0.96) and whose conductivity values (1.04 $ohm^{-1}cm^{-1}$ at 283 K and 1.88 $ohm^{-1}cm^{-1}$ at 673 K) were higher than any other samples, was found to be the best additive for ECIA.

Composite Effect of Ag and Au in the $Bi_{1.84}\;Pb_{0.34}\;Sr_{1.91}\;Ca_{2.03}\;Cu_{3.06}\;O_{10+\delta}$(110K Phase) High-Tc Superconductor (Ag와 Au가 혼합된 $Bi_{1.84}\;Pb_{0.34}\;Sr_{1.91}\;Ca_{2.03}\;Cu_{3.06}\;O_{10+\delta}$ 산화물 고온초전도체의 초전도특성)

  • 이민수
    • The Transactions of the Korean Institute of Electrical Engineers C
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    • v.52 no.6
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    • pp.241-248
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    • 2003
  • $Bi_{1.84}Pb_{0.34}Sr_{1.91}Ca_{2.03}Cu_{3.06}O_{10+\delta}$ high $T_{c}$ superconductors containing Ag as an additive were fabricated by a solid-state reaction method. The superconducting properties, such as the structural characteristics, the critical temperatures, the grain size and the image of mapping on the surface were investigated. Samples with Ag and Au of 50 wt% each were sintered at various temperature(820~$850^{\circ}C$). The structural characteristics, the microstructure of surface and the critical temperature with respect to the each samples were analyzed by XRD and SEM, EDS and four-prove methode respectively. The critical temperature showed the result which the Ag additive samples are higher than Au additive samples. The microstructure of the surface showed the tendency which the Ag additive samples become more minuteness than Au additive samples.

Fabrication and Characteristics of $Al_2O_{3p}$/AC8A Composites by Pressureless Infiltration Process (무가압함침법에 의한 $Al_2O_{3p}$/AC8A 복합재료의 제조 및 특성)

  • 김재동;고성위;정해용
    • Composites Research
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    • v.13 no.6
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    • pp.1-8
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    • 2000
  • The fabrication Process of $Al_2O_{3p}$/AC8A composites by pressureless infiltration technique and the effects of additive Mg content and volume fraction of particulate reinforcement on mechanical and wear properties were investigated. It was found that the bending strength decreased with increasing volume fraction of $Al_2O_{3p}$ particles. Whereas hardness increased with volume fraction of $Al_2O_{3p}$ particles. The decrement of strength in case of high volume fraction of $Al_2O_{3p}$ particles was attributed to high porosity level. In terms of additive Mg content, $Al_2O_{3p}$/AC8A composites containing around 5~7wt% of additive Mg indicated the highest strength, and hardness values increased with additive Mg contents. Wear resistance of AC8A alloy were improved by reinforcement of $Al_2O_{3p}$ particles especially at high sliding velocity. Wear property of $Al_2O_{3p}$/AC8A composites and AC8A alloy exhibited different aspects. $Al_2O_{3p}$/AC8A composites indicated more wear loss than AC8A alloy at slow velocity region. However a transition point of wear loss was found at middle velocity region which shows the minimum wear loss and wear loss at high velocity region exhibited almost same value as at slow velocity region, whereas wear loss of AC8A alloy almost linearly increased with sliding velocity. It was found that $Al_2O_{3p}$/AC8A composites containing $Al_2O_{3p}$ volume fraction of 20% exhibited abrasive wear surface regardless of sliding velocity and $Al_2O_{3p}$/AC8A composites containing $Al_2O_{3p}$ volume fraction of 40% showed slightly adhesive wear surface at low sliding velocity, and it progressed to severe wear as increasing the sliding velocity.

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Effect of $Dy_2O_3$ Additive on the Nonohmic Characteristics of ZnO-$Pr_6O_{11}$-CoO-Based Ceramic Varistor (ZnO-$Pr_6O_{11}$-CoO계 세라믹 바리스터의 비옴성 특성에 $Dy_2O_3$ 첨가제의 영향)

  • Park, Choon-Hyun;Yoon, Han-Soo;Nahm, Choon-Woo
    • Proceedings of the KIEE Conference
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    • 1999.07d
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    • pp.1692-1695
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    • 1999
  • The nonohmic characteristics of ZnO-$Pr_6O_{11}$-CoO-based ceramic varistor doped with $Dy_2O_3$ in the range $0.0\sim2.0mol%$ sintered at $1300^{\circ}C$ and $1350^{\circ}C$ were investigated. 98.5 ZnO-$0.5Pr_6O_{11}$-1.0CoO varistor sintered at $130^{\circ}C$ exhibited higher nonlinear coefficient of 36 than the established Pr-based varistor. The four-component-system varistor such as 96.5 ZnO-$0.5Pr_6O_{11}$-1.0CoO-$2.0Dy_2O_3$ exhibited very highly nonohmic characteristics, which has nonlinear coefficient of 53.9. 98.5ZnO-$0.5Pr_6O_{11}$-1.0CoO varistor sintered at $1350^{\circ}C$, in contrast with that of $1300^{\circ}C$, exhibited approximately ohmic characteristics but nonlinear coefficient of varistor doped with 0.5mol% $Dy_2O_3$ showed higher nonlinear coefficient of probably 35. Consequently, it can be confirmed that $Dy_2O_3$ acted as additive of improvement on nonlinear coefficient. It is estimated that $Dy_2O_3$ will be used as additive of improvement on nonlinear coefficient to develop a goof ZnO varistor.

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Microstructure and Superconducting Properties of (Bi,Pb)-Sr-Ca-Cu-O-(Ag, Au, Mg) Composites ((Bi,Pb)-Sr-Ca-Cu-O-(Ag, Au, Mg) 복합체의 미세구조와 초전도 특성)

  • 이민수
    • Journal of the Korean Ceramic Society
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    • v.40 no.5
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    • pp.447-454
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    • 2003
  • Samples were prepared by the solid-state reaction method. The nominal composition of the samples was B $i_{1.84}$P $b_{0.34}$S $r_{1.91}$C $a_{2.03}$C $u_{3.06}$ $O_{10+{delta}$ prepared from powder of B $i_2$ $O_3$, PbO, SrC $O_3$, CaC $O_3$, and CuO. They were pulverized, mixed with AgO, A $u_2$ $O_3$and MgO of 50 wt%. Finally, they were sintered at 820 to 85$0^{\circ}C$ in air. The structural characteristics, the microstructure of surface and the critical temperature with respect to the each samples were analyzed by XRD, $T_{c}$, SEM and EDS respectively. It was found that the the critical temperature of the silver oxide additive samples (99.58 K) is higher than those of gold or magnesium oxides additive samples, but all those values are lower than that of pure Bi-2223 phase. The microstructure of surface showed the tendency which the AgO additive samples become more minuteness than A $u_2$ $O_3$ and MgO additive samples.s.samples.s.

The Microstructure and Electrical Characteristics of High Voltage ZnO Varistors with $Sb_2O_3$Additive ($Sb_2O_3$가 첨가된 고전압 ZnO 바리스터의 미세 구조 및 전기적 특성)

  • Oh, Soo-Hong;Jung, Woo-Sung;Hong, Kyung-Jin;Lee, Jin;Kim, Tae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2000.07a
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    • pp.369-372
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    • 2000
  • ZnO varistor is studied to sintering condition and mixing condition for the improvement to non linear of electrical characteristics. In this paper, ZnO varistor, ZnO-Bi$_2$O$_3$-Y$_2$O$_3$-MnO-Cr$_2$O$_3$-Sb$_2$O$_3$series, is fabricated with Sb$_2$O$_3$mol ratio(0.5~4[mol%]) and sintered at 1250[$^{\circ}C$] for 2 hours. The grain size to Sb$_2$O$_3$moi ratio was measured by fractal mathematics. The ZnO varistors that Sb$_2$O$_3$mot ratio is 1[mol%] were shown small grain size because of spinel phase. The fractal dimension were increased with increasing of Sb$_2$O$_3$mo ratios. The capacitance of ZnO varistors with increasing of Sb$_2$O$_3$additive in voltage-capacitance characteristics was decreased by small grain size.

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Effect of Additives and Cooling Rates on the Electrical Resistivity of BaTiO3 Ceramics (I) (BaTiO$_3$ 세라믹스의 전기저항에 미치는 첨가제와 냉각속도의 영향(I) - TiO$_2$, SiO$_2$ 및 Al2O$_3$ 단미첨가 -)

  • 염희남;하명수;이재춘;정윤중
    • Journal of the Korean Ceramic Society
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    • v.28 no.9
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    • pp.661-666
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    • 1991
  • Microstructure, room temperature resistivity and temperature coefficient of resistance of BaTiO3 ceramics were studied by varying cooling rates and additives such as TiO2, SiO2 and Al2O3. The basic composition of the BaTiO3 ceramics was formed by adding 0.25 mol% Dy2O3 and 0.07 mol% MnO2 to the BaTiO3 composition. Unlike the additives of SiO2 and Al2O3, an addition of 2 mol% TiO2 to the basic composition was effective to control the grain size of the fired specimens. The room temperature resistivity and the temperature coefficient of resistance for the specimen of this particular compostion were measured as about 102 ohm.cm and 16.5%/$^{\circ}C$, respectively. The observed grain boundary phase of the sample with Al2O3 additive was BaTi3O7, while that of the samples with SiO2 additive was confirmed as BaTiSiO5.

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