• 한국재료학회지
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• 제26권10호
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• pp.561-569
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• 2016

$SrAl_2O_4$: $Eu^{2+}$ and $Dy^{3+}$ phosphorescent phosphors were synthesized using the polymerized complex method. Generally, phosphorescent phosphors synthesized by conventional solid state reaction show a micro-sized particle diameter; thus, this process is restricted to applications such as phosphorescent ink and paint. However, it is possible to synthesize homogeneous multi-component powders with fine particle diameter by wet process such as the polymerized complex method. The characteristics of $SrAl_2O_4$: $Eu^{2+}$ and $Dy^{3+}$ powders prepared by polymerized complex method with one and two step calcination processes were comparatively analyzed. Temperatures of organic material removal and crystallization were observed through TG-DTA analysis. The crystalline phase and crystallite size of the $SrAl_2O_4$: $Eu^{2+}$ and $Dy^{3+}$ phosphorescent phosphors were analyzed by XRD. Microstructures and afterglow characteristics of the $SrAl_2O_4$: $Eu^{2+}$ and $Dy^{3+}$ phosphors were measured by SEM and spectrofluorometry, respectively.

• 한국재료학회지
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• 제21권5호
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• pp.250-254
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• 2011

We have synthesized bluish-green, highly-efficient $BaSi_2O_2N_2:Eu^{2+}$ and $(Ba,Sr)Si_2O_2N_2:Eu^{2+}$ phosphors through a conventional solid state reaction method using metal carbonate, $Si_3N_4$, and $Eu_2O_3$ as raw materials. The X-ray diffraction (XRD) pattern of these phosphors revealed that a $BaSi_2O_2N_2$ single phase was obtained. The excitation and emission spectra showed typical broadband excitation and emission resulting from the 5d to 4f transition of $Eu^{2+}$. These phosphors absorb blue light at around 450 nm and emit bluish-green luminescence, with a peak wavelength at around 495 nm. From the results of an experiment involving Eu concentration quenching, the relative PL intensity was reduced dramatically for Eu = 0.033. A small substitution of Sr in place of Ba increased the relative emission intensity of the phosphor. We prepared several white LEDs through a combination of $BaSi_2O_2N_2:Eu^{2+}$, YAG:$Ce^{3+}$, and silicone resin with a blue InGaN-based LED. In the case of only the YAG:$Ce^{3+}$-converted LED, the color rendering index was 73.4 and the efficiency was 127 lm/W. In contrast, in the YAG:$Ce^{3+}$ and $BaSi_2O_2N_2:Eu^{2+}$-converted LED, two distinct emission bands from InGaN (450 nm) and the two phosphors (475-750 nm) are observed, and combine to give a spectrum that appears white to the naked eye. The range of the color rendering index and the efficiency were 79.7-81.2 and 117-128 lm/W, respectively. The increased values of the color rendering index indicate that the two phosphor-converted LEDs have improved bluish-green emission compared to the YAG:Ce-converted LED. As such, the $BaSi_2O_2N_2:Eu^{2+}$ phosphor is applicable to white high-rendered LEDs for solid state lighting.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2005년도 추계학술대회 논문집 Vol.18
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• pp.39-40
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• 2005

Ferroelectric Eu-substituted $Bi_4Ti_3O_{12}$ (BET) thin films with a thickness of 200 nm were deposited on Pt(111)/Ti/SiO$_2$/Si(100) substrate by means of the liquid delivery MOCVD system and annealed at several temperatures in an oxygen atmosphere. At annealing temperature above $600^{\circ}C$, the microstructure of layered perovskite phase was observed. The remanent polarization of these films increased with increase in annealing temperature. The remanent polarization values ($2P_r$) of the BET thin films annealed at $720^{\circ}C$ were $37.71{\mu}C/cm^2$ at an applied voltage of 5 V.

• 한국결정성장학회지
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• 제12권3호
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• pp.149-156
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• 2002

$Ga_2O_3$ : $Eu^{3+}$ 형광체 분말을 균일침전법에 의해 제조하여 TG/DTA, XRD, FT-IR, SEM 등으로 특성을 분석하였다. 결정질 GaOOH 와 비정질에 가까운 $\gamma$-$Ga_2O_3$ 등 두 종류의 분말이 얻어졌다. 요소 농노가 0.5 M 이하에서는 입자는 막대모양을 이루고, 열처리에 따라 $\alpha$-$Ga_2O_3$을 거쳐서 $\beta$-$Ga_2O_3$상으로 변태하였다. 한편 나노미터 크기를 갖는 $\gamma$-$Ga_2O_3$분말은 1.0 M 이상의 요소 농도에서 생성되며, 직접 $\beta$-$Ga_2O_3$으로 전이하였다. 실온에서 광 발광 특성을 비교한 결과 마이크로미터 크기의 분말에 비해 나노미터 크기의 분말이 610 nm에서의 발광 강도가 더 크게 나타났다.

• Korean Chemical Engineering Research
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• 제44권6호
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• pp.609-613
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• 2006

분무열분해법에 의해 장파장 UV 여기원 하에서 높은 발광세기를 가지는 $Ba_{2-x.}Sr_{x.}SiO_4:Eu^{2+}$ 형광체를 제조하였다. 분무열분해공정 의해 제조된 $Ba_{2-x.}Sr_{x.}SiO_4:Eu^{2+}$ 형광체의 발광특성, 분말 형태 및 결정성에 대해 조사하였다. 분무열분해 공정에 의해 제조된 $Ba_{2-x.}Sr_{x.}SiO_4:Eu^{2+}$ 형광체는 모체를 구성하는 바륨과 스트론튬의 비에 따라 청녹색에서 황색에 이르기까지 다양한 파장대의 색을 구현할 수 있었다. x = 0인 $Ba_2SiO_4:Eu^{2+}$ 형광체의 경우 발광 중심파장이 500 nm였으며, x = 2인 $Sr_2SiO_4:Eu^{2+}$ 형광체의 경우 발광중심 파장이 554 nm였다. 분무열분해 공정에 의해 제조된 $Ba_{2-x.}Sr_{x.}SiO_4:Eu^{2+}$ 형광체는 구형의 형상을 띄지만 중공성의 입자 특성을 가졌다. 반면에 후열처리 과정을 거친 $Ba_{2-x.}Sr_{x.}SiO_4:Eu^{2+}$ 형광체는 큰 입자 크기와 불규칙한 형태를 가졌다. $Ba_{1.488}Sr_{0.5}SiO_4:Eu_{0.012}{^{2+}}$ 형광체가 환원분위기 하에서 후열처리 온도 $1,200^{\circ}C$에서 3시간 동안 후열처리 과정을 거쳤을 때 최적의 발광 세기를 가졌다.

• 대한의용생체공학회:의공학회지
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• 제28권1호
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• pp.148-152
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• 2007

In this paper, we have synthesized $Gd_2O_3:Eu^{3+}$ nano phosphor particle using a low temperature solution-combustion method. We have investigated the structure and the luminescent characteristic as the sintering temperature and europium concentration. From XRD(X-ray diffraction) and SEM(scanning electron microscope) results, we have verified that the phosphor particle was fabricated a spherical shape with $30{\sim}40nm$ particle size. From the photoluminescence results, the strong peak exhibits at 611 um and the luminescent intensity depends on europium concentration. $Gd_2O_3:Eu$ fine phosphor particle has shown excellent luminescent efficiency at 5 wt% of europium concentration. The phosphors calcinated at $500^{\circ}C$ have possessed the x-ray peaks corresponding to the cubic phase of $Gd_2O_3$. As calcinations temperature increased to $700^{\circ}C$, the new monoclinic phase has identified except cubic patterns. From the luminescent decay time measurements, mean lifetimes were $2.3{\sim}2.6ms$ relatively higher than conventional bulk phosphors. These results indicate that $Gd_2O_3:Eu$ nano phosphor is possible for the operation at the low x-ray dose, therefore, the application as medical imaging detector.

• 한국전기전자재료학회:학술대회논문집
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• 한국전기전자재료학회 2002년도 추계학술대회 논문집 Vol.15
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• pp.116-119
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• 2002

A different route to the synthesis of $Eu^{3+}$ - activated matrices such as $YAlO_{3}$ and $GdAlO_{3}$ and luminiscent properties of these compounds, were studied. The new route (Combustion method) consist of the redox reactions between the respective metal nitrates and urea in a preheated furnace at ${500^{\circ}C}$. The Phosphor thus obtained were then heated at ${1000^{\circ}C}$ for 2-3 hours to get better luminiscent properties. The incorporation of $Eu^{3+}$ activator in these phosphors were checked by luminiscence investigations. Scanning electron microscopy (SEM) studies were carried out to understand surface morphological features and the particle size. X-ray energy dispersive analysis (EDAX) was also performed for the qualitative analysis of the phosphors.

• 한국표면공학회지
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• 제48권5호
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• pp.211-217
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• 2015

To fabricate white LED having a high color rendering index value, red color phosphor mixed with the green color phosphor together in the blue chip, namely the blue chips with RG phosphors packaging is most favorable for high power white LEDs. In our previous papers, we reported on successful syntheses of $Sr_{2-}$ $Si_5N_8:Eu^{2+}$ and $CaAlSiN_3$ phosphors for red phosphor. In this work, for high power green phosphor, greenemitting ternary nitride $Ba_3Si_6O_{12}N_2:Eu^{2+}$ phosphor was synthesized in a high frequency induction furnace under $N_2$ gas atmosphere at temperatures up to $1400^{\circ}C$ using $EuF_3$ as a raw material for $Eu^{2+}$ dopant. The effects of molar ratio of component and experimental conditions on luminescence property of prepared phosphors have been investigated. The structure and luminescence properties of prepared $Ba_3Si_6O_{12}N_2:Eu^{2+}$ phosphors were investigated by XRD and photoluminescence spectroscopy. The excitation spectra of $Ba_3Si_6O_{12}N_2:Eu^{2+}$ phosphors indicated broad excitation wavelength range of 250 - 500 nm, namely from UV to blue region with distinct enhanced emission spectrum peaking at ${\approx}530nm$.

• 한국정보디스플레이학회:학술대회논문집
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• 한국정보디스플레이학회 2003년도 International Meeting on Information Display
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• pp.791-794
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• 2003

To synthesize $Gd_{2}O_{3}:Eu$ phosphor powder of nano size and high luminescence efficiency under UV (ultraviolet) and VUV (vacuum ultraviolet) light, organic additives such as citric acid and ethylene glycol and $Na_{2}CO_{3}$ flux were introduced in large-scale spray pyrolysis and critical conditions for forming nano-sized particles were investigated. The $Gd_{2}O_{3}:Eu$ phosphor particles prepared from solutions with organic additives such as citric acid and ethylene glycol had micron size and spherical shape. However, the particles prepared from polymeric precursor solution with $Na_{2}CO_{3}$ flux had nano size and non-aggregation characteristics. The as-prepared spherical particles with micron size turned into nano-sized particles during post-treatment by recrystallization process. The nano-sized $Gd_{2}O_{3}:Eu$ phosphor particles showed higher brightness than the commercial $Y_2O_3:Eu$ phosphor product under both UV light of 254nm and VUV light of 147 nm.

• 한국진공학회지
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• 제22권2호
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• pp.79-85
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• 2013

희토류 이온 $Eu^{3+}$와 $Dy^{3+}$가 각각 도핑된 $CaMoO_4$ 광체 분말을 고상반응법으로 합성하였다. 모든 형광체 분말의 결정 구조는 활성제 이온의 종류와 농도비에 관계없이 주 회절 피크(112)를 갖는 정방 정계이었다. $Eu^{3+}$ 이온이 도핑된 형광체의 경우에, $Eu^{3+}$ 이온의 농도가 0.01~0.10 mol 영역에서 결정 입자의 크기는 전반적으로 증가하였고, 비교적 균일한 크기 분포를 가지면서 조약돌 형태를 나타내었으며, 흡광 스펙트럼은 311 nm를 정점으로 넓게 퍼져있는 전하 전달 밴드와 파장 영역 360~470nm에서 약한 피크를 갖는 다수의 흡수선이 관측되었으며, 주 발광 스펙트럼은 $Eu^{3+}$ 이온의 $^5D_0{\rightarrow}^7F_2$ 전이에 의한 618 nm에 피크를 갖는 강한 적색 발광이었다. $Dy^{3+}$ 이온이 도핑된 분말의 경우에, 흡광 스펙트럼은 303 nm에 피크를 갖는 전하 전달 밴드와 상대적으로 세기가 약한 다수의 $Dy^{3+}$ 이온의 전이 신호가 발생하였으며, 주 발광 스펙트럼은 $^4F_{9/2}{\rightarrow}^7H_{13/2}$ 전이에 의한 578 nm에 피크를 갖는 황색 발광 스펙트럼이 관측되었다.