• Title/Summary/Keyword: $SmI_2$

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Luminescent Properties and Anti-Counterfeiting Applications of SrWO4:RE3+ (RE=Dy, Sm, Dy/Sm) Phosphors Doped with Several Activator Ions (다양한 활성제 이온이 도핑된 SrWO4:RE3+ (RE=Dy, Sm, Dy/Sm) 형광체의 특성과 위조 방지 응용)

  • Yoon, Soohwan;Cho, Shinho
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.33 no.5
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    • pp.393-399
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    • 2020
  • A series of phosphors, SrWO4:5 mol% Dy3+, SrWO4:5 mol% Sm3+, and SrWO4:5 mol% Dy3+:x Sm3+ (x=1~15 mol%), were prepared using a facile co-precipitation. The crystal structure, morphology, photoluminescence properties, and application in anti-counterfeiting fields were investigated. The crystalline structures of the prepared phosphors were found to be tetragonal systems with the dominant peak occurring at the (112) plane. The excitation spectra of the Dy3+ singly-doped SrWO4 phosphors were composed of an intense charge-transfer band centered at 246 nm in the range of 210~270 nm and two weak peaks at 351 nm and 387 nm due to the 6H15/26P7/2 and 6H15/24I13/2 transitions of Dy3+ ions, respectively. The wavelength of 246 nm was optimum for exciting the luminescence of Dy3+ and Sm3+ co-doped SrWO4 phosphors. The emission spectra consisted of two intense blue and yellow emission bands at 480 nm and 573 nm corresponding to the 4F9/26H15/2 and 4F9/26H13/2 transitions of Dy3+, and two strong emission peaks at 599 nm and 643 nm originating from the 4G5/26H7/2 and 4G5/26H9/2 transitions of Sm3+, respectively. As the concentration of Sm3+ ions increased, the emission intensities of Dy3+ rapidly decreased, while the emission intensities of Sm3+ gradually increased. These results suggest that the color of the emission light can be tuned from yellow to white by changing the concentration of Sm3+ ions at a fixed 5 mol% Dy3+. Furthermore, the fluorescent security inks were synthesized for use in anti-counterfeiting applications.

Adventitial Fibroblast Abormality in Thoracic Aortic Aneurysms and Aortic Dissections

  • Suh, Jong-Hui;Yoon, Jeong-Seob;Kim, Hwan-Wook;Jo, Keon-Hyon
    • Journal of Chest Surgery
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    • v.44 no.6
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    • pp.406-412
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    • 2011
  • Background: Development of thoracic aortic aneurysms and aortic dissections (TAAD) is attributed to unbearable wall tension superimposed on defective aortic wall integrity and impaired aortic repair mechanisms. Central to this repair mechanisms are well-balanced and adequately functional cellular components of the aortic wall, including endothelial cells, smooth muscle cells (SMCs), inflammatory cells, and adventitial fibroblasts. Adventitial fibroblasts naturally produce aortic extracellular matrix (ECM), and, when aortic wall is injured, they can be transformed into SMCs, which in turn are involved in aortic remodeling. We postulated the hypothesis that adventitial fibroblasts in patients with TAAD may have defects in ECM production and SMC transformation. Materials and Methods: Adventitial fibroblasts were procured from the adventitial layer of fresh aortic tissues of patients with TAAD (Group I) and of multi-organ donors (Group II), and 4-passage cell culture was performed prior to the experiment. To assess ECM production, cells were treated with TNF-${\alpha}$ (50 pM) and the expression of MMP-2/MMP-3 was analyzed using western blot technique. To assess SMC transformation capacity, cells were treated with TGF-${\beta}1$ and expression of SM ${\alpha}$-actin, SM-MHC, Ki-67 and SM calponin was evaluated using western blot technique. Fibroblasts were then treated with TGF-${\beta}1$ (10 pM) for up to 10 days with TGF-${\beta}1$ supplementation every 2 days, and the proportion of transformed SMC in the cell line was measured using immunofluorescence assay for fibroblast surface antigen every 2 days. Results: MMP-3 expression was significantly lower in group I than in group II. TGF-${\beta}1$-stimulated adventitial fibroblasts in group I expressed less SM ${\alpha}$-actin, SM-MHC, and Ki-67 than in group II. SM-calponin expression was not different between the two groups. Presence of fibroblast was observed on immunofluorescence assay after more than 6 days of TGF-${\beta}1$ treatment in group I, while most fibroblasts were transformed to SMC within 4 days in group II. Conclusion: ECM production and SMC transformation are compromised in adventitial fibroblasts from patients with TAAD. This result suggests that functional restoration of adventitial fibroblasts could well be a novel approach for the prevention and treatment of TAAD.

Kinetic Study of the Anaerobic Digestion of Swine Manure at Mesophilic Temperature: A Lab Scale Batch Operation

  • Kafle, Gopi Krishna;Kim, Sang-Hun
    • Journal of Biosystems Engineering
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    • v.37 no.4
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    • pp.233-244
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    • 2012
  • Purpose: The kinetic evaluation was performed for swine manure (SM) degradation and biogas generation. Methods: The SM was anaerobically digested using batch digesters at feed to inoculum ratio (F/I) of 1.0 under mesophilic conditions ($36.5^{\circ}C$). The specific gas yield was expressed in terms of gram total chemical oxygen demand (mL/g TCOD added) and gram volatile solids added (mL/g VS added) and their effectiveness was discussed. The biogas and methane production were predicted using first order kinetic model and the modified Gompertz model. The critical hydraulic retention time for biomass washout was determined using Chen and Hashimoto model. Results: The biogas and methane yield from SM was 346 and 274 mL/ TCOD added, respectively after 100 days of digestion. The average methane content in the biogas produced from SM was 79% and $H_2S$ concentration was in the range of 3000-4108 ppm. It took around 32-47 days for 80-90% of biogas recovery and the TCOD removal from SM was calculated to be 85%. When the specific biogas and methane yield from SM (with very high TVFA concentration) was expressed in terms of oven dried volatile solids (VS) basis, the gas yield was found to be over estimated. The difference in the measured and predicted gas yield was in the range of 1.2-1.5% when using first order kinetic model and 0.1% when using modified Gompertz model. The effective time for biogas production ($T_{Ef}$) from SM was calculated to be in the range of 30-45 days and the critical hydraulic retention time ($HRT_{Critical}$) for biomass wash out was found to be 9.5 days. Conclusions: The modified Gompertz model could be better in predicting biogas and methane production from SM. The HRT greater than 10 days is recommended for continuous digesters using SM as feedstock.

Electrical Conductivities of [(CeO2)1-x(ZrO2)x]0.8(SmO1.5)0.2 Solid Solution ([(CeO2)1-x(ZrO2)x]0.8(SmO1.5)0.2 고용체의 전기전도도)

  • 이충연;김영식;김남철
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.16 no.9
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    • pp.775-782
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    • 2003
  • In the study, the total conductivies in [(Ce $O_2$)$_{1-x}$ (Zr $O_2$)$_{x}$]$_{0.8}$(Sm $O_{1.5}$)$_{0.2}$ (x- 0, 0.05, 0.1, 0.2) solid solution were measured as a function of temperature and oxygen partial pressure between 80$0^{\circ}C$ and 1,00$0^{\circ}C$ using 4-probe d.c method. Under pure oxygen atmospere, the oxygen ionic conductivity of [(Ce $O_2$)$_{1-x}$ (Zr $O_2$)$_{x}$]$_{0.8}$(Sm $O_{1.5}$)$_{0.2}$ decreased with the concentration of Zr $O_2$At high oxygen partial pressure, the electrical conductivity is almost independent of oxygen partial pressure and decreased with the increase in Zr content. However, the electrical conductivity increase with decreasing oxygen partial pressure and is almost independent of Zr content at low oxygen partial pressure. Empirically, Total conductivity( $\sigma$ ) was expressed by the p$o_{2}$ -independent conductivity as $\sigma$$_{i}$, and the $p_{-1/4}$ $o_{2}$sup -dependent part as $\sigma$$_{e}$. Total, ionic and electronic conductivities fitted by data enabled to determine the transference number. The ionic transference number( $t_{i}$ ) decreased while the electronic transference( $t_{e}$ ) increase with the increase in Zr content and p$o_{2}$.

Evaluation of Forming Performance of TMC Steel Pipes & Tubes for Building Structure (건축구조용 TMC 강관의 가공성능 평가)

  • Im, Sung Woo;Kim, Jong Seong;Chang, In Hwa
    • Journal of Korean Society of Steel Construction
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    • v.16 no.1 s.68
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    • pp.43-49
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    • 2004
  • With building structures becoming higher and having longer spans, new structural steel with better strength, thicker plate, and performance may be required rather than conventional structural steel. TMC steel is widely used in building structures largely due to its excellent seismic performance, superior weldability, and design strength that is not affected by plate thickness. To make use of TMC steel in pipe structures with large diameter and heavy wall, however, the this study, the degradation of material properties in submerged are welded SM520TMC steel pipes and tubes was evaluated using variable fabrication process and material change. Degradation test results showed that the yield and ultimate strength increased and elongation decreased regardless of the mode of fabrication, i.e., through roll bending or press forming, or steel used, i.e., domestic SM520TMC steel or SM520TMC steel from Japan.

Effect of Corrosion Environment on the Fretting Wear Corrosion of a Hinge Material( I ) (힌지재료의 찰과마멸부식에 미치는 부식환경의 영향( I ))

  • Kwak Nam-In;Lim Uh-Joh;Lee Jong-Rark
    • Journal of the Korean Institute of Gas
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    • v.4 no.1 s.9
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    • pp.26-32
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    • 2000
  • The fretting wear corrosion characteristics between the SM20C and the SM20C, the YBsC3 and the STC4H was experimented by using radical type friction experimental device under the corrosion environment of atmosphere, neutral solution, acid solution and chemical factors of the sea water. The affection of underground water that affect fretting wear corrosion of the SM20C which is moving specimen was more sensitive at the STC4H and more insensible at the YBsC3. The affection of underground water that affect fretting wear corrosion of the STC4H was less, but in the $0.5\%\;H_2SO_4$ and $0.5\%\;HNO_3$ solutions the fretting wear corrosion of the STC4H was more large. The fretting wear corrosion of the SM20C which is moving specimen in the underground water was less than in the $3.5\%\;NaCl$, $0.5\%\;H_2SO_4$ and $0.5\%\;HNO_3$ solutions. As time passed, the fretting wear corrosion is increased in the $HNO_3$ solution and dull in the $0.5\%\;H_2SO_4$ solution.

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Synthesis and Mesomorphic Properties of New Achiral Liquid Crystals with 3-Alkoxy-2-(alkoxymethyl)-1-propoxy Swallow-Tails

  • Kang, Kyung-Tae;Kim, Jeong-Tak;Hwang, Ryeo-Yun;Park, Song-Ju;Lee, Seng-Kue;Lee, Jong-Gun;Kim, Yong-Bae
    • Bulletin of the Korean Chemical Society
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    • v.28 no.11
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    • pp.1939-1944
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    • 2007
  • New liquid crystalline (biphenylcarbonyloxy)benzoates with an achiral swallow-tail derived from 3-alkoxy-2- (alkoxymethyl)-1-propanol [(ROCH2)2CHCH2OH, R = Me, Et, Pr, Bu] were prepared. These liquid crystals exhibited the phase sequence (I-SmA-SmCalt-(SmCX)-Cr) and showed antiferroelectric-like Smectic C phase (SmCalt) at temperature lower, and temperature range broader than do the compounds containing a branched alkyl group as a swallow-tail. The temperature ranges of antiferroelectric phase were found to be 30-90 oC and crystallization temperatures were 4-60 oC. The binary mixture of an achiral swallow-tailed liquid crystal and a chiral antiferroelectric liquid crystal, (S)-MHPOBC showed antiferroelectric smectic C phase at temperature much lower than the single chiral antiferroelectric liquid crystal does.

Genetic properties of R plasmids in Salmonella isolates of swine and bovine origin in Korea I. Distribution and drug resistance of Salmonella isolated from dairy cow (우(牛), 돈(豚)에서 분리(分離)한 Salmonella유래(由來) R plasmid의 유전학적(遺傳學的) 및 분자생물학적(分子生物學的) 성상(性狀)에 관한 연구(硏究) I. 유우(乳牛)에서 Salmonella속균(屬菌)의 분포상황(分布狀況) 및 약제내성(藥劑耐性))

  • Choi, Won-pil;Lee, Hi-suk;Yeo, San-geon;Lee, Hun-jun;Chae, Tae-chul
    • Korean Journal of Veterinary Research
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    • v.28 no.2
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    • pp.331-337
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    • 1988
  • This paper dealt with the distribution of Salmonella (S) infection on 4 herds in Kyungju and Taegu during the period from May to October 1986. Isolated Salmonella were examined for serotypes, antimicrobial drug resistance and detection of R plasmid. The results obtained were summarised as followings: 1. Of total 4.622 samples from 4 herds, 67 Salmonella were isolated from 51 samples(1.1%), and their serovar strains were S typhimurium 6, S derby 5, S infantis 4, S bareilly 4, S dublin 3, S anatum 2, S montevideo 2 and untypable 41. 2. The isolation rate of Salmonella was higher in summer and autumn. 3. Of the 67 strains examined, 45 (67.2%) were resistant to one or more antibiotics, such as ampicillin (Am), cephalothin (Ce), chloramphenicol (Cm), rifampicin (Rf), sulfadimethoxine (Su), and tetracycline (Tc), and higher resistant to Sm (40.2%), Ce (31.3%), Am (23.9%). 4. Of the 45 resistant Salmonella strains, 44 (97.8%) harbored conjugative R plasmids and the transfer frequency of Sm (100%), Ce (95.2%), Tc (91.0%) and Su (80.0%) resistance was much higher than that of the other drug resistance. 5. The most common resistant patterns were Sm, Ce, AmCeCmSmSuTc, and AmCe. 6. In 4 herds, the incidience of drug resistance was 57.7%~100% and transfer frequency of conjugative R plasmid was 96.1%~100%.

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Survey of Sedimentary Environment and Sediment at the West-Northern Site of Chagwi-do nearby Jeju Island (제주도 차귀도 서북쪽 해역 내 퇴적 환경 및 퇴적물 조사)

  • Kim, Hansoo;Hyeon, Jong-Wu;Jin, Changzhu;Kim, Jeongrok;Cho, Il-Hyoung
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.19 no.2
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    • pp.137-143
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    • 2016
  • The sedimentary environment and sediment were surveyed at the West-Northern site of Chagwi-do nearby Jeju Island for the design of the embedded suction anchor system of 10 MW-class floating wave-offshore wind hybrid power generation system. According to the classification scheme of Chough et al.[2002], the echo type of the seismic profiles using the chirp III was classified. As a results, the center and west-northern area of survey site were proved to be type I-3 where subbottom layer with thickness 5~15 m exists under the flat seafloor. On the other hands, the east-southern area were regarded to be type I-1, I-2 and III-1 where seafloor reflection is much stronger than type I-3. Also, the physical tests (unit weight, moisture content, grain size, liquid limit, specific gravity) were performed with samples taken from 8 fixed locations. It is found that the sand (SP), the sand blended with silt (SM) and the mixture of SP-SM are distributed uniformly on the survey area.

Cytogenetic Analysis of Reciprocal Hybrids Reveals a Robertsonian Translocation between Mud Loach ($Misgurnus$ $mizolepis$) and Cyprinid Loach ($M.$ $anguillicaudatus$) (미꾸라지($Misgurnus$ $mizolepis$)와 미꾸리($M.$ $anguillicaudatus$) 및 유도된 종간 잡종의 세포유전학적 연구)

  • Lee, Seung-Ki;Kim, Dong-Soo
    • Korean Journal of Ichthyology
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    • v.24 no.1
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    • pp.1-10
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    • 2012
  • Reciprocal hybrids between the mud loach ($Misgurnus$ $mizolepis$) and cyprinid loach ($M.$ $anguillicaudatus$) were produced by artificial fertilization. The chromosome number of mud loach was 2n=48, consisting of 12M+4SM+32A chromosomes. The cyprinid loach has 2n=50, consisting of 10M+4SM+36A chromosomes. The chromosome numbers of the diploid reciprocal hybrids were 2n=49, consisting of 11M+4SM+34A chromosomes. All the karyotypes documented in this study had the same arm number of 64. There was no evidence of chromosomal polymorphisms or sex-related heteromorphism. The cytogenetic traits of the hybrid genotypes were intermediate between those of the parent species. In all genotypes, the chromosomal NORs localized to the terminal short arms of the same metacentric chromosome pair. These results suggest that Robertsonian translocation occurred between metacentric chromosome 1 of mud loach and acrocentric chromosome of cyprinid loach.