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γ-C2S 혼입 시멘트 모르타르의 공극구조 및 Fractal특성 (Pore Structure and Fractal Characters of Cement Mortar Containing γ-C2S)

  • 진정심;이한승
    • 한국건축시공학회:학술대회논문집
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    • 한국건축시공학회 2017년도 추계 학술논문 발표대회
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    • pp.24-25
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    • 2017
  • Gamma-C2S (γ-C2S) is a substance that is difficult to react with water under normal temperature but can absorb a large amount of CO2 in the air. The addition of γ-C2S to cementitious materials through the curing of CO2 can improve the pore structure and improve the durability of the material. In this study, three kind of Ca-bearing materials : CaO, Ca(OH)2, CaCO3, were calcined 2.5h at 1450℃ to synthesize γ-C2S after mixing with SiO2 respectively. Among them, Ca(OH)2 mixed with SiO2 after calcining shows highest content. Synthesized γ-C2S was added to the cement mortar, after water curing for 1 month, accelerated carbonation test was experimented. After 28d accelerated carbonation test, pore structure will be detectived by MIP. Based on the MIP result, following the calculation method of Fractal theory, the pore structure will be quantitative described.

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A UNIFORM LAW OF LARGE MUNBERS FOR PRODUCT RANDOM MEASURES

  • Kil, Byung-Mun;Kwon, Joong-Sung
    • 대한수학회보
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    • 제32권2호
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    • pp.221-231
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    • 1995
  • Let $Z_1, Z_2, \ldots, Z_l$ be random set functions or intergrals. Then it is possible to discuss their products. In the case of random integrals, $Z_i$ is a random set function indexed y a family, $G_i$ say, of real valued functions g on $S_i$ for which the integrals $Z_i(g) = \smallint gdZ_i$ are well defined. If $g_i = \in g_i (i = 1, 2, \ldots, l) and g_1 \otimes \cdots \otimes g_l$ denotes the tensor product $g(s) = g_1(s_1)g_2(s_2) \cdots g_l(s_l) for s = (s_1, s_2, \ldots, s_l) and s_i \in S_i$, then we can defined $Z(g) = (Z_1 \times Z_2 \times \cdots \times Z_l)(g) = Z_1(g_1)Z_2(g_2) \cdots Z_l(g_l)$.

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광발광 측정법에 의한 $AgGaS_2$ 단결정 박막의 점결함 연구 (Study on Point Defect for $AgGaS_2$ Single Crystal Thin film Obtained by Photoluminescience Measurement Method)

  • 홍광준;김경석
    • 비파괴검사학회지
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    • 제25권2호
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    • pp.117-126
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    • 2005
  • [ $AgGaS_2$ ] 단결정 박막을 수평 전기로에서 합성한 $AgGaS_2$ 다결정을 증발원으로하여, hot wall epitaxy(HWE) 방법으로 증발원과 기판 (반절연성 -GaAs (100))의 온도를 각각 $590^{\circ}C,\;440^{\circ}C$로 고정하여 성장하였다. 이때 단결정 박막의 결정성은 광발광 스펙트럼과 이중결정 X-선 요동곡선 (DCRC)으로 부터 구하였다. $AgGaS_2$의 광흡수 스펙트럼으로부터 구한 온도에 의존하는 에너지 밴드갭 $E_g(T)$는 Varshni. 공식에 fitting한 결과 $E_g(T)=2.7284 eV-(8.695{\times}10^{-4}eV/K)T^2/T(T+332K)$를 잘 만족하였다. 성장된 $AgGaS_2$, 단결정 박막을 Ag, Ga, S분위기에서 각각 열처리하여 10K에서 photoluminescience(PL) spectrum을 측정하여 점 결함의 기원을 알아보았다. PL 측정으로부터 얻어진 $V_{Ag},\;V_s,\;Ag_{int}$, 그리고 $S_{int}$는 주개와 받개로 분류되어졌다. $AgGaS_2$ 단결정 박막을 Ag분위기에서 열처리하면 n형으로 변환됨을 알 수 있었다. 또한, Ca 분위기에서 열처리하면 열처리 이전의 PL스펙트럼을 보이고 있어서, $AgGaS_2$ 단결정 박막에서 Ga은 안정된 결합의 형태로 있기 때문에 자연 결함의 형성에는 관련이 없음을 알았다.

Molecular Characterization and Expression Analysis of Clathrin-Associated Adaptor Protein 3-δ Subunit 2 (AP3S2) in Chicken

  • Oh, Jae-Don;Bigirwa, Godfrey;Lee, Seokhyun;Song, Ki-Duk
    • 한국가금학회지
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    • 제46권1호
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    • pp.31-37
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    • 2019
  • 닭의 clathrin-associated adaptor protein $3-{\delta}$ subunit 2(AP3S2)는 clathrin-coated vesicle를 가진 표적 세포막으로 암 배양 단백질 수송에 관여한다. AP3S2는 C형 간염 바이러스 감염으로 간 섬유화를 매개하고, 2형 당뇨병과 관련이 있는 것으로 알려져 있다. 또한, AP3S2는 clathrin-dependent endocytosis를 통해 숙주 세포로의 바이러스 유입에 관련된 역할을 하는 것으로 알려져 있다. 본 연구는 기존 연구에서 닭 신장조직에서 차별 발현 유전자로 발굴된 닭 AP3S2 유전자의 분자유전학적 특성을 구명하고, 닭의 조직에서의 유전자 발현 양상을 조사하며, 톨-유사수용체 3 (Toll-like receptor 3; TLR3) 자극에 의한 전사 조절을 연구하였다. 닭 AP3S2 유전자가 코딩하는 단백질의 구조는 다른 종과 매우 보존적이고 진화적으로 제브라 피쉬와 가장 가깝고, 포유류와 가장 먼 것으로 추정되었다. 닭의 다양한 조직에서 닭 AP3S2 유전자의 전사 수준을 조사한 결과, 폐에서 가장 높게 발현되었으며, 그 다음은 비장 순이었다. 닭의 배아 섬유아세포 주인 DF-1세포에서 조사한 결과, AP3S2 유전자의 발현은 TLR3 신호자극에 의해 감소하였다. 전사조절인자인 $NF{\kappa}B$나 AP-1의 억제제를 이용하여 조사한 결과, $NF{\kappa}B$나 AP-1의 억제에 의해 유전자 발현이 영향을 받지 않았다. 이 결과는 DF-1 세포에서 닭 AP3S2 유전자의 발현은 적어도 이 두 전사조절인자와는 독립적인 경로에 의해 조절됨을 시사한다. 본 연구의 결과는 닭 AP3S2가 바이러스 감염에 역할을 하고, TLR3 신호에 관여함을 제시한다. 추가연구를 통해 닭 AP3S2의 전사 조절과 바이러스 침입 메커니즘을 구명할 필요가 있다고 사료된다.

s-cis-$[Co(eee)Cl_2$]^+ 및 s-cis-$[Co(eee)Br_2]^+ $착이온의 수화반응에 미치는 압력의 영향 (Pressure Dependence on the Aquation of s-cis-[Co(ee)$Cl_2$]+ and s-cis-[Co(eee)$Br_2$]+ ions)

  • 정종재;백성오
    • 대한화학회지
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    • 제32권4호
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    • pp.318-322
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    • 1988
  • s-cis-$[Co(eee)Cl_2]^+$ 와 s-cis-$[Co(eee)Br_2]^+$ 착이온의 수화반응을 여러가지 온도와 압력하에서 분광광도법으로 연구하였다. 여기서 eee는 $NH_2-CH_2CH_2-S-CH_2CH_2-NH_2이다. 두가지 착물의 수화반응은 속도법칙 Rate = $k_{obsd}$[Co(III)]를 따르고, 속도상수$(k_{obsd})$)는 0.1M $HClO_4,\;40^{\circ}C$에서 s-cis-$[Co(eee)Cl_2]^+$와 s-cis-$[Co(eee)Br_2]^+$가 각각 $0.687{\times}10^{-4}$ $sec^{-1}$$4.10{\times}10^{-4}$$sec^{-1}$이다. 같은 조건에서$[Co(eee)Cl_2]^+$ 와 s-cis-$[Co(eee)Br_2]^+$착이온의 활성화엔트로피$({\Delta}S^{\neq})$는 각각 -15.5eu와 -7.54eu 이고 활성화부피$({\Delta}V^{\neq})$는 각각 $-4.6cm^3mole^{-1}$$-4.2cm^3mole^{-1}$이다. 이들 데이타로부터 수화반응의 메카니즘은 교환해리(Id)메카니즘으로 추론할 수 있다.

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TiO2/ZnS/Ag/ZnS/TiO2 다층막의 PDP 필터용 전극 특성 (Transparent Electrode Performance of TiO2/ZnS/Ag/ZnS/TiO2 Multi-Layer for PDP Filter)

  • 오원석;이서희;장건익;박성완
    • 한국전기전자재료학회논문지
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    • 제23권9호
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    • pp.681-684
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    • 2010
  • The $TiO_2$/ZnS/Ag/ZnS/$TiO_2$ multilayered structure for the transparent electrodes in plasma display panel was designed by essential macleod program (EMP) and the multilayered film was deposited on a glass substrate by direct-current (DC)/radio-frequency (RF) magnetron sputtering system. During film deposition process, the Ag layer in $TiO_2$/Ag/$TiO_2$ structure became oxidized and the filter characteristic was degraded easily. In this study, ZnS layer was adopted as a diffusion blocking layer between $TiO_2$ and Ag to prevent the oxidation of Ag layer efficiently in $TiO_2$/ZnS/Ag/ZnS/$TiO_2$ structure. Based on the AES depth profiling analysis, the Ag layer was effectively protected by the ZnS layer as compared with the $TiO_2$/Ag/$TiO_2$ multilayered films without ZnS as an antioxidant layer. The 3 times stacked $TiO_2$/ZnS/Ag/ZnS/$TiO_2$ films have low sheet resistance of $1.22{\Omega}/{\square}$ and luminous transmittance was as high as 62% in the visible ranges.

작업환경에서 오는 시력분포 및 고찰 (A study of Frequency Distributions by the Action styles)

  • 강향녀;김성태
    • 한국안광학회지
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    • 제5권2호
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    • pp.99-105
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    • 2000
  • 작업환경에서 시력저하가 나타나는 굴절이상의 종류별 분포는 안경사 100명, 사진기사 100명, 대학생 100명중 단성근시 35% 근시성 단난시 2% 근시성 복난시 30.6% 혼합난시 6.26% 원시성 복난시 3.74% 정시 22.4%의 순으로 나타났다. 양안 굴절이상의 근시도수 분포는 -0.50~-2.00 Dptr가 전체 대상자중 14%, -2.00~-6.00 Dptr 이상이 16% -6.00 Dptr 이상이 5%로 나타났으며, 근시성 단난시의 분포는 C-0.25(90, 180)~C-2.00 Dptr Axis(90, 180) 2%, 근시성 복난시의 분포는 S-0.25 C-0.25 Dptr Axis(90, 180)~S-1.00 C-1.00 Dptr Axis(90, 180)이 22.6%, S-1.00 C-1.00 Dptr Axis(90, 180)~S-2.00 C-2.00 Dptr Axis(90, 180)이 8%로 나타났다. 혼합난시의 분포는 S+0.25 C-0.25 Axis(90, 180)~S+2.00 C-2.00 Axis(90, 180)가 6.26%, 원시성 복난시의 분포는 S+0.25 C+0.25 Axis(90, 180)~S+1.00 Dptr Axis(90, 180)가 3.4%, S+1.00 C+1.00 Axis(90, 180)~S+2.00 C+2.00 Dptr Axis(90, 180)가 0.34%의 순으로 나타났다.

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사상체질음성분석기(四象體質音聲分析機)(PSSC)를 통한 한국인 성인여성(成人女性)의 체질별(體質別) 음향특성연구(音響特性硏究) - 단문(短文)을 중심으로 - (A Study on the Charateristics of the Korean Adult Female Sound According to Sasang Constitution Using PSSC with a Sentence)

  • 윤지영;윤우영;조성언;왕향란;전종원;김달래;유준상
    • 사상체질의학회지
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    • 제18권3호
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    • pp.75-93
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    • 2006
  • 1. Objectives and Methods Sasang Constitutional Medicine is the original Korean Medicine. The purpose of this study was to objectify the diagnosis of Sasang Constitution. 212 Women's sentences were analyzed into 228 factors like Pitch, APQ, Shimmer, Octave and Energy, etc. Women's sentences were classified into 3 categories: total group, under 54 years old group and over 55 years old group. 2. Results 1) In Total group Soyangin's Center feq.(3) was significantly high compared with Taeyangin and Taeumin groups. Taeumin's Pitch2 was significantly high compared with Soeumin and Taeyangin groups. Taeyangin's Pitch S.D. was significantly high compared with Soyangin group. Taeyangin's Octave6 was significantly high compared with Soeumin group. There were no significant differences among constitutional groups in APQ and Shimmer segment. On the point of Energy, Taeyangin's G Tot E(1), G# Tot E(1), G dev.(1), G# dev.(1), G Tot E(2), G# Tot E(2), G dev.(4) and G# dev.(4) were significantly high compared with other groups. Soyangin's A#S.D.(2) was significantly high compared with Taeyangin group. Taeyangin's A#S.D.(3) was significantly high compared with Taeumin group. Taeyangin's F S.D.(5), F# S.D.(5) and Max Average were significantly high compared with Soeumin group. Taeumin's Peak3 and Peak4 were significantly high compared with Taeyangin group. Taeumin's PeakValue1 was significantly high compared with Soeumin group. Taeyangin's PeakValue2 was significantly high compared with Soeumin group. Taeyangin's PeakValue3 and PeakValue5 were significantly high compared with Other groups. 2) In Under 54 years old group, there were no significant differences among constitutional groups in APQ, Shimmer and Octave segment. Taeumin's Center freq.(2) was significantly high compared with Taeyangin and Soyangin groups. Taeumin's Pitch(2) and Pitch(3) were significantly high compared with Taeyangin and Soeumin groups. Taeyangin's and Taeumin's Pitch S.D. were significantly high compared with Soyangin group. Taeyangin's and Soyangin's Octave2 were significantly high compared with Taeumin group. On the point of Energy, Taeyangin's and Soyangin's A# S.D.(2) were significantly high compared with Soeumin group. Taeyangin's and Soyangin's G# dev.(1), G# dev.(2) were significantly high compared with Taeumin group. Taeyangin's and Taeumin's F# S.D.(3) were significantly high compared with Soeumin group. Taeyangin's and Soyangin's Max Average were significantly high compared with Soeumin group. Taeumin's Peak3 was significantly high compared with Taeyangin and Soeumin groups. Taeyangin's and Taeumin's PeakValue2 were significantly high compared with Soeumin group. Taeyangin's and Soeumin's PeakValue3 were significantly high compared with Taeumin group. Taeyangin's and Soyangin's PeakValue5 were significantly high compared with Soeumin group. Taeyangin's and Soyangin's PeakValue9 were significantly high compared with Taeumin group 3) In Over 55 years old group, there were no significant differences among constitutional groups in Pitch, APQ, and Peak segment. Soeumin's F Shimmer(1) and F Shimmer(2) were significantly high compared with Taeyangin and Taeumin groups. Soeumin's G# Shimmer(1) and G# Shimmer(2) were significantly high compared with Soyangin group. Taeyangin's Octave5 and Octave6 were significantly high compared with Soeumin group. On the point of Energy, Soyangin's C S.D., F# S.D.(1), F# S.D.(2) and G dev.(2) were significantly high compared with other groups. Soyangin's F# S.D.(3) was significantly high compared with Taeumin and Soeumin groups. Taeyangin's and Taeumin's G# S.D.(2) and G# S.D.(3) were significantly high compared with Soyangin group 3. Conclusions From above result, there is the possibility of efficient standard guide for constitution diagnosis by analysis of voice

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Studies of Sulphate in Portland Cement Clinker (Cement Technology 1971.9)

  • Gutt W.;Smith M. A.
    • 시멘트
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    • 통권51호
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    • pp.20-30
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    • 1973
  • 1) electron-microprobe를 응용하여 $CaO-SiO_2-Al_2O_3$ 계에서 생성한 $C_2S$, $C_3S$ 에 존재하는 sulfate의 solid, solution을 정량적으로 구할 수 있었으며 이 결과로 $C_2S$$Al_2O_3$, $SO_3$ 등이 solid soln 등으로 침적되고 이들이 $C_3S$의 생성을 억제한다는 mechanism이 확인되었다. 2) phase equilibrium(상평형)에 의하면 $Na_2SO_4$, $K_2SO_4$는 mineralizer로서 작용하며 $C_3S$ 의 생성을 돕는다. 그러나 $K_2SO_4$$Al_2SO_3$ 가 결합상태로 존재할 경우는 1,400 $^{\circ}C$에서 광범위한 liquid를 생성하며 quenching하면 glass질과 $\beta-C_2S$ 만이 얻어지고 $C_3S$ 는 생성되지 않는다. 또 이를 1,250 $^{\circ}C$ 까지 서냉하면 $C_2S$ 와 Ca, K, Al, S, 등을 함유한 새로운 물질이 생성된다. 3) $CaO-SiO_2-Al_2O_3-Fe_2O_3$ 계에서 $C_3S$ 의 생성에 미치는 $Na_2SO_4$, $K_2SO_4$ 의 영향을 실험실적으로 검토한 결과 complex interaction이 확인되었으며 $Na_2SO_4$ 는 어떤 경우에는 mineralizing effect를 상실한다는 재미 있는 사실이 발견되었다.

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$CdAl_2S_4 : Co_{2+}$ 단결정의 광학적 특성 (Optical Properties of $CdAl_2S_4 : Co_{2+}$ Single Crystal)

  • 김형곤;김남오;손경춘
    • 대한전기학회논문지:전기물성ㆍ응용부문C
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    • 제49권7호
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    • pp.382-387
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    • 2000
  • The $CdAl_2S_4 and CdAl_2S_4 : Co^{2+}$ single crystals were grown by the chemical transport reaction method using iodine as a transport agent. The $CdAl_2S_4 and CdAl_2S_4 : Co^{2+}$single crystals were crystallized into a defect chalcopyrite structure. The optical energy gap of the $CdAl_2S_4 and CdAl_2S_4 : Co^{2+}$ single crystals was found to be 3.377 eV and 2.924 eV, respectively, at 300 K. Blue emission with peaks in 456nm~466nm at 280K was observed in the $CdAl_2S_4$ single crystal. Optical absorption and emission peaks due to impurities in the $CdAl_2S_4 Co^{2+}$ single crystal were observed and described as originating from the electron transition between energy levels of the $Co^{2+} ion sited at the Td symmetry point.

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