• Journal of Environmental Science International
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• v.17 no.4
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• pp.423-437
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• 2008

Until comparatively lately, the annual time series of the $SO_2$ concentration had been shown in a decreasing trend in Ulsan as well as other Korean cities. However, the high concentration of $SO_2$ was frequently found in the specific countermeasure region including the national industrial complex such as Mipo and Onsan in the Ulsan city for the period of $2001{\sim}2004$. There are many conditions that can influence the high concentration of $SO_2$ at monitoring sites in Ulsan, such as: First, annual usage of the fuel including sulfur increased in comparison with the year before in spite of the fuel conversion policy which wants to use low sulfur oil less than 3% and LNG. Second, point source, such as the power plants and the petroleum and chemistry stacks, was the biggest contributor in $SO_2$ emission, as a analyzed result of both the air quality modeling and the stack tole-monitoring system (TMS) data. And third, the air pollutants that occurred in processes of homing and manufacturing of the fuel including sulfur were transported slow into a special monitoring site by accumulating along the frontal area of see-breeze. It was concluded that Ulsan's current environmental policy together with control methods should be changed into the regulation on total amount of emission, including a market-based emission trading with calculating of atmospheric environmental critical loads, for the $SO_2$ reduction like the specific countermeasure for the $O_3$ and PM10 reduction in the Seoul metropolitan area. And this change should be started in the big point sources of $1{\sim}3$ species because they are big contributors of Ulsan's $SO_2$ pollution. Especially it is necessary to revitalize of the self-regulation environmental management. Other control methods for sustaining the $SO_2$ reduction are as follows: maintenance of the fuel conversion policy, reinforcement of the regional stationary source emission standard, and enlargement of the stack TMS.

• Journal of Electrochemical Science and Technology
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• v.8 no.3
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• pp.197-205
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• 2017

Lead dioxide thin films were electrodeposited on nickel substrate from acidic lead nitrate solution. Current efficiency and thickness measurements, cyclic voltammetry, AFM, SEM, and X-ray diffraction experiments were conducted on $PbO_2$ surface to elucidate the effect of lead nitrate concentration, current density, temperature on the morphology, chemical behavior, and crystal structure. Experimental results showed that deposition efficiency was affected by the current density and solution concentration. The film thickness was independent of current density when deposition from high $Pb(NO_3)_2$ concentration, while it decreased for low concentration and high current density deposition. On the other hand, deposition temperature had negative effect on current efficiency more for lower current density deposition. Cyclic voltammetric study revealed that comparatively more ${\beta}-PbO_2$ produced compact deposits when deposition was carried out from high $Pb(NO_3)_2$ concentration. Such compact films gave lower charge discharge current density during cycling. SEM and AFM studies showed that deposition of regular-size sharp-edge grains occurred for all deposition conditions. The grain size for high temperature and low concentration $Pb(NO_3)_2$ deposition was bigger than from low temperature and high concentration deposition conditions. While cycling converted all grains into loosely adhered flappy deposit with numerous pores. X-ray diffraction measurement indicates that high concentration, high temperature, and high current density favored ${\beta}-PbO_2$ deposition while ${\alpha}-PbO_2$ converted to ${\beta}-PbO_2$ together with some unconverted $PbSO_4$ during cycling in $H_2SO_4$.

• Journal of the Korean Chemical Society
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• v.28 no.5
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• pp.309-314
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• 1984

The species and equilibria of uranium and vanadium have been investigated in the various concentration of perchloric, hydrochloric and sulfuric acid by anion exchange chromatography. In the concentration range of $0.01\;{\sim}\;0.5M$ hydrochloric and $0.01\;{\sim}\;0.5M$ perchloric acid, uranium seems to be $UO_2^{2+}$species and in higher concentration than 0.5M hydrochloric acid $UO_2^{2+}$seems to form the chloride complex ion as $UO_2Cl^+$, $UO_2Cl_2$, $UO_2Cl_3^-$ and $UO_2Cl_4^{2-}$ according to the increase of the hydrochloric acid concentration. In the dilute(0.01N) sulfuric acid the adsorbability of uranium on anion exchange resin is strong and then decreases with increasing the sulfuric acid concentration. From this result we conclude that $UO_26{2+}$ formed the complex ion as $UO_2(SO_4)_2^{2-}$. In the perchloric acid of $0.01\;{\sim}\;0.5N$ concentration the existing equilibrium of vanadium and its constant calculated at $20^{\circ}C$ is $1.9{\times}108$ for $H_2V_{10}O_{28}^{4-}$ + $14H^+$ = $10VO_2^+ + 8H_2O$. The elution behaviors of vanadium in the hydrochloric and sulfuric acid are smiliar to those in perchloric acid.

• Membrane and Water Treatment
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• v.10 no.4
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• pp.307-311
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• 2019

The ejector type microbubble generator, which is the method to supply air to water by using cavitation in the nozzle, does not require any air supplier so it is an effective and economical. Also, the distribution of the size of bubbles is diverse. Especially, the size of bubbles is smaller than the bubbles from a conventional air diffuser and bigger than the bubbles from a pressurized dissolution type microbubble generator so it could be applied to the aeration tank for wastewater treatment. However, the performance of the ejector type microbubble generator was affected by hydraulic pressure and MLSS(Mixed Liquor Suspended Solid) concentration so many factors should be considered to apply the generator to aeration tank. Therefore, this study was performed to verify effects of hydraulic pressure and MLSS concentration on oxygen transfer of the ejector type microbubble generator. In the tests, the quantity of sucked air in the nozzle, dissolved oxygen(DO) concentration, oxygen uptake rate(OUR), oxygen transfer coefficient were measured and calculated by using experimental results. In case of the MLSS, the experiments were performed in the condition of MLSS concentration of 0, 2,000, 4,000, 8,000 mg/L. The hydraulic pressure was considered up to $2.0mH_2O$. In the results of experiments, oxygen transfer coefficient was decreased with the increase of MLSS concentration and hydraulic pressure due to the increased viscosity and density of wastewater and decreased air flow rate. Also, by using statistical analysis, when the ejector type microbubble generator was used to supply air to wasterwater, the model equation of DO concentration was suggested to predict DO concentration in wastewater.

• Resources Recycling
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• v.17 no.5
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• pp.37-43
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• 2008

Stripping experiments of iron from the loaded Alamine336 by sulfurous, chloric and sulfuric acid solutions have been performed by varying the concentration of acid and stripping conditions. The stripping percentage of iron decreased with the increase of HCl and $H_{2}SO_4$ concentration, while that increased with the increase of $H_{2}SO_3$ concentration up to 3 M. Stripping temperature had adverse effect on the stripping percentage of iron in the stripping by $H_{2}SO_3$ solution, while the stripping percentage of iron by HCl solution increased with the increase of temperature. Stripping isotherm of iron by 0.1 M HCl and 0.1 M $H_{2}SO_4$ solution indicated that three and four stripping stages could result in a solution containing 0.05 M iron at an O/A ratio of 1/10 from the loaded Alamine336 phase where iron concentration was 0.5 M.

• 보존과학연구
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• s.23
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• pp.95-112
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• 2002

Seoul City built a facility for conservation of the Wongaksajisipcheungseoktap (Ten storied stone pagoda of Wongaksa Temple site, National treasure No. 2). It has speciality glass(thickness 21.5㎜) between steel-frames(8.4m, length 8.4m, height 15.4m). So we investigated the inside of facility to know whether the environment alvariation exists. We measured continuously the temperature and relative humidity, twice for the particulate, once for the $SO_2$(sulfur dioxide), $NO_2$(nitrogen dioxide)and $O_3$(ozone) from September $1_st$, 2000 to August $31_st$, 2001.The temperature and relative humidity, have a tendency to vary, and they have no difference between the inside and the outside. As dewy phenomenon doesn appear on the surface of the Pagoda and facility we know that the inside air is moving. As a result of the particulate is $64\mug$/$m_3$ of average concentration, the particulate fluxed inside don’t flow out because air-velocity of the outside is faster than that of the inside. The air pollutants are 0.036ppm/hr of SO$_2$average concentration, 0.028ppm/hr of $NO_2$ average concentration and 0.008ppm/hr of $O_3$ average concentration which are lower than the Environmental Air Quality Standards($SO_2$ : 0.15ppm/hr, $NO_2$ : 0.25ppm/hr,O3 : 0.1ppm/hr).

• Journal of Korea Technical Association of The Pulp and Paper Industry
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• v.44 no.6
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• pp.15-20
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• 2012

The effects of sulfur dioxide on paper were investigated since these sulfur compounds could cause damages on cellulose and organic materials in papers. For the reason, exposure ageing tests were performed on traditional Korean paper (Hanji) and two different types of modern paper (acid-free and acid paper) to determine the damage with regard to the optical as well as physicochemical properties according to the varying $SO_2$ concentration. As a result, optical properties were not changed while physical and chemical peoperties were remarkably changed with the exposure period. In the case of pH, $SO_2$ had little impact on the pH of the Hanji and acid-free paper while the pH of acid paper was remarkably decreased. The decrease of the folding endurance of the Hanji was relatively smaller than those of the acid-free and acid paper. The results prove Hanji was more resistant to $SO_2$ than the modern paper in terms of optical, physical and chemical properties. In addition, it was also suggested that $SO_2$ concentration should be kept below 0.01 ppm for the preservation of paper objects.

• Journal of Environmental Health Sciences
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• v.39 no.1
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• pp.99-103
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• 2013

Objectives: This paper was prepared in memory of Jerry Sherwood, who provided a significant contribution to the Korean environmental and occupational health fields. Methods: Rare air quality data in Seoul were gathered by Jerry Sherwood when he visited Korea in the early 1980s. $SO_2$ and TPM concentrations were measured. These air quality measurements were based on ambient stationary monitoring and indoor air quality monitoring in various locations. Measurement during transportation was also applied. Results: Ambient $SO_2$ and TPM concentrations in Seoul were very high in the early 1980s. Ambient $SO_2$ concentrations were higher at nighttime. While ambient $SO_2$ concentrations varied by location, the Guro industrial area showed high levels. When indoor sources were presented, indoor $SO_2$ concentration was higher than outdoor level. Coal briquettes were closely associated with high indoor $SO_2$ concentration. Conclusion: This paper provided valuable historical information of air quality in Seoul.

• Journal of Environmental Science International
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• v.18 no.2
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• pp.129-139
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• 2009

Development of an artificial neural network model was presented to predict the daily maximum $SO_2$ concentration in the urban-industrial area of Ulsan. The network model was trained during April through September for 2000-2005 using $SO_2$ potential parameters estimated from meteorological and air quality data which are closely related to daily maximum $SO_2$ concentrations. Meteorological data were obtained from regional modeling results, upper air soundings and surface field measurements and were then used to create the $SO_2$ potential parameters such as synoptic conditions, mixing heights, atmospheric stabilities, and surface conditions. In particular, two-stage clustering techniques were used to identify potential index representing major synoptic conditions associated with high $SO_2$ concentration. Two neural network models were developed and tested in different conditions for prediction: the first model was set up to predict daily maximum $SO_2$ at 5 PM on the previous day, and the second was 10 AM for a given forecast day using an additional potential factors related with urban emissions in the early morning. The results showed that the developed models can predict the daily maximum $SO_2$ concentrations with good simulation accuracy of 87% and 96% for the first and second model. respectively, but the limitation of predictive capability was found at a higher or lower concentrations. The increased accuracy for the second model demonstrates that improvements can be made by utilizing more recent air quality data for initialization of the model.

• Journal of the Korean Society of Clothing and Textiles
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• v.23 no.6
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• pp.800-808
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• 1999

The demand for PU coated synthetic leather is increasing as a high fashion material. But it has some faults of water vapor permeability surface tacky property and static electricity. Therefore the purpose of this study was the produce of PU coated fabric added collagen with hydrophilic property and soft touch. In the PU coated fabric water vapor permeability water vaper absorption and frictional electronic voltage were investigated surface bending and compression properties were also examined by the use of KES-FB System. The followings were the results of this study. 1. There was no Cr in the collagen so that Cr was not treated in the collagen. 2. The surface and cross sectional layer of PU coated fabric with collagen were highly developed by micro porous structure. 3. The water vapor permeability of PU coated fabric was increased as collagen concentration increased. 4. The water vapor absorption of PU coated fabric was increased as collagen concentration increased. 5. The frictional electronic voltage of PU coated fabric was decreased in accordance with the increase of collagen concentration. Especially it effectively decreased by the use of only 5% collagen concentration. 6,. The bending and compression properties of PU coated fabric were increased in accordance with the increase of collagen concentration so that it became stiff. 7. The Value of MIU, SMD was decreased in accordance with the increase of collagen concentration so that the PU coated fabric became smooth.