• Title/Summary/Keyword: $SO_2$ absorption

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Investigation of SO2 effect on OMI-TOMS and OMI-DOAS O3 in volcanic areas with OMI satellite data (OMI 위성자료를 이용한 화산지역 고농도 이산화황 환경에서의 TOMS 오존과 DOAS 오존의 비교연구)

  • Choi, Wonei;Hong, Hyunkee;Park, Junsung;Kim, Daewon;Yeo, Jaeho;Lee, Hanlim
    • Korean Journal of Remote Sensing
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    • v.31 no.6
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    • pp.599-608
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    • 2015
  • In this present study, we quantified the $SO_2$ effect on $O_3$ retrieval from the Ozone Monitoring Instrument (OMI) measurement. The difference between OMI-Total Ozone Mapping Spectrometer (TOMS) and OMI-Differential Optical Absorption Spectrometer (DOAS) total $O_3$ is calculated in high $SO_2$ volcanic plume on several volcanic eruptions (Anatahan, La Cumbre, Sierra Negra, and Piton) from 2005 through 2008. There is a certain correlation ($R{\geq}0.5$) between the difference and $OMI-SO_2$ in volcanic plumes and the significant difference close to 100 DU. The high $SO_2$ condition found to affect TOMS $O_3$ retrieval significantly due to a strong $SO_2$ absorption at the TOMS $O_3$ retrieval wavelengths. Besides, we calculated the difference against various $SO_2$ levels. There is the considerable difference (average = 32.9 DU; standard deviation = 13.5 DU) in the high $OMI-SO_2$ condition ($OMI-SO_2{\geq}7.0DU$). We also found that the rate of change in the difference per 1.0 DU change in middle troposphere (TRM) and upper troposphere and stratosphere (STL) $SO_2$ columns are 3.9 DU and 4.9 DU, respectively.

A Study on Hydraulic Behavior and Mass Transfer by Absorption in Packing Tower (충전탑에서 흡수에 따른 물질전달과 수력학적 거동에 관한 연구)

  • 김석택
    • Journal of Environmental Science International
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    • v.9 no.5
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    • pp.393-396
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    • 2000
  • Packing tower has been used in the chemical industry and the protection of environment for a long time. In the view of environmental protection purification of exhaust gas can be performance effective by gas absorption in counter-current packing tower. In this study characteristics of hydraulic and mass transfer were investigated in D. $0.3m {\times} H. 1.4m$ packing tower with 50mn plastic Hiflow-ring. This study was carried out "Test systems were experimented in conditions of Air, $Air/H_2O. NH_3-Air/H_2O, NH_3-Air/H_2O-H_2SO_4$ and $SO_2-Air/H_2O-NaOH$ under steady state" The extent of test included dry and wetting pressure drop physical law separation efficiency and hold-up as function of gas and liquid load.quid load.

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Interaction of SO2 with Oxygen on Ni(100) Studied by XPS and NEXAFS

  • Kim, Chang-Min
    • Bulletin of the Korean Chemical Society
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    • v.27 no.12
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    • pp.2037-2039
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    • 2006
  • The adsorption and surface reactions of $SO_2$ on Ni(100), c($2{\times}2$)_O/Ni (100) and NiO(111)/Ni(100) surfaces have been investigated using X-ray photoelectron spectroscopy (XPS) and near-edge X-ray absorption fine structure (NEXAFS) technique. On Ni(100), chemisorbed $SO_2$ is formed at 160 K. When $SO_2$ is adsorbed on c($2{\times}2$)_O/Ni(100) at 160 K, $SO_2$ reacts with oxygen to form $SO_3$ and trace amount of $SO_4$ species. $SO_3$ is adsorbed on this surface with its $C_3$ axis perpendicular to the surface. On a NiO(111)/Ni(100) surface, both $SO_3$ and $SO_4$ species are formed at 160 K from adsorbed $SO_2$.

Combustion Diagnostics Method Using Diode Laser Absorption Spectroscopy (다이오드 레이저를 이용한 연소진단기법)

  • Cha, Hak-Joo;Kim, Min-Soo;Shin, Myung-Chul;Kim, Se-Won;Kim, Hyuck-Joo;Han, Jae-Won
    • 한국연소학회:학술대회논문집
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    • 2003.05a
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    • pp.75-83
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    • 2003
  • Diode laser absorption system is advantageous of their non-invasive nature, fast response time, high sensitivity and real-time measurement capability. Furthermore, recent advances in room-temperature, near-IR and visible diode laser sources for telecommunication, optical data storage applications are enabling combustion diagnostics system based on diode laser absorption spectroscopy. So, combined with fiber-optics and high sensitive detection strategies, compact and portable sensor system are now appearing for a variety of applications. The objective of this research is to take advantage of distributed feed-back diode laser and develope new gas sensing system. It experimentally found out that the wavelength, power characteristics as a function of injection current and temperature. In addition to direct absorption and wavelength modulation spectroscopy have been demonstrated in these experiments and have a bright prospect to this diode laser system.

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Shapes and Deformation of the Hydrogen Absorption Metal (수소저장금속의 형상과 변형)

  • 정영관;박규섭;이근진;김경훈;김세웅
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2003.06a
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    • pp.1382-1385
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    • 2003
  • Deformation on shapes of the hydrogen absorption metal in this paper was investigated on hydrogen absorption-desorption cycling. In order to study this problem, the cold rolled palladium plate and the cold extrusion palladium bar as specimens had been used. By using the electrochemical method, the palladium specimens were cyclically hydrogenated in the 0.1 mol H$_2$SO$_4$ electrolyte. As results, it is noted that the thickness of the plate specimen gradually increased in increasing hydrogenation cycles whereas the width and the length decreased. But both the diameter and the length of the bar specimen increased with increasing hydrogenation cycles. Also, grains in the plate specimen were greatly deformed after hydrogenation cycling whereas internal grains in the bar specimen were pulverized. And deterioration of the hydrogen absorption rate of the bar specimen was lager than the plate specimen.

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Analysis of the Light Environment in Model Greenhouse using Infrared Absorption Film as Shading Screen (적외선 흡수필름을 차광재로 사용한 모형 온실의 광환경 분석(농업시설))

  • 권혁진;김기성;김문기
    • Proceedings of the Korean Society of Agricultural Engineers Conference
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    • 2000.10a
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    • pp.340-345
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    • 2000
  • This study was carried out to analyze the light and thermal environment in model greenhouse using infrared absorption film as shading screen and to compare with the case of no shading and using general shading screen such as aluminum foil-backed film, black polyethylene film and thermal blanket. PPFD(photosynthetic photon flux density) of inside the model greenhouse under infrared absorption film was increased by 22% than under general shading screen on the average. And temperature of inside air under infrared absorption film was 2$^{\circ}C$ lower than under general shading screen on the average. So, it is expected that infrared absorption film is useful as shading screen.

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Simulation of a two-stage absorption heat pump cycle using treated sewage (하수처리수 이용 흡수식 열펌프 사이클의 시뮬레이션)

  • 이용화;신현준;최국광
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.11 no.3
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    • pp.422-430
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    • 1999
  • This paper concerns the study of a two-stage absorption heat pump cycle to utilize treated sewage. This two-stage cycle consists of coupling double-effect with parallel or series flow type and single effect cycle so that the first stage absorber and condenser produces hot water to evaporate refrigerant in the evaporator of the second stage. The effects of operating variables such as absorber temperature on the coefficient of performance have been studied for two-stage absorption heat pump cycle. The working fluid is lithium bromide and water solution. The efficiency of the two-stage absorption heat pump cycle has been studied and simulation results show that higher coefficient of performance could be obtained for the first stage with parallel flow type. The optimum ratio of solution distribution can be shown by considering the COP, the crystallization of solution and the generator temperature.

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The Concentration Measurements of Toxic Exhaust Gas by Tunable Diode Laser Absorption Spectroscopy System (TDLAS 시스템을 이용한 유해 배기가스의 농도 계측)

  • Cha, Hak-Joo;Kim, Min-Soo;Shin, Myung-Chul;Kim, Se-Won;Chun, Kwang-Min
    • Proceedings of the KSME Conference
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    • 2003.11a
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    • pp.222-227
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    • 2003
  • Recent advances in room-temperature, visible and near-IR diode laser sources for telecommunication, optical data storage applications are enabling combustion diagnostics system based on diode laser absorption spectroscopy. In contrast to some traditional sampling-based gas-sensing instruments, tunable diode laser absorption spectroscopy system is advantageous because of their non-invasive nature, high sensitivity, fast response time and real-time measurement capability. So, combined with fiber-optics and high sensitive detection strategies, compact and portable sensor system arc now appearing for a variety of applications. The objective of this research is to take advantage of distributed feed-back diode laser and measure the $CO_{2}$ concentration (by using direct absorption and wavelength modulation spectroscopy methods). In addition to survey spectra of $CO_{2}$ bands and spectroscopic parameters between 1565 and 1579 run were computed at temperatures between 296 and 1200 K (by using HITRAN 2000 database). It experimentally found out that the features of direct absorption and wavelength modulation spectroscopy methods.

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Studies on the Releasing Effect of Cerium in Calcium Analysis by Atomic Absorption Spectrometry (원자흡수 분광법에 의한 칼슘분석에서 세륨의 해방효과에 관한 연구)

  • Kee Chae Park;Hee Seon Choi;Soo Han Kwon
    • Journal of the Korean Chemical Society
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    • v.29 no.2
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    • pp.129-136
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    • 1985
  • In the atomic absorption spectrometry using an air-acetylene flame, the interferences of Zr, Sn, Al, Sb, $SO_4^{2-},\;VO_3^-,\;and\;SiO_3^{2-}$, on the calcium absorption and the repression of this interference by the addition of cerium have been studied. The interference by Zr, Sn, Al, Sb, $SO_4^{2-},\;VO_3^-,\;and\;SiO_3^{2-}$ existed as the same concentration as calciurn ($3.0 {\times} 10^{-4}$M) in the sample solution are completely released by the addition of cerium twice as much as interfering cation. The interferences by the mixed interfering cations (Zr, Sn, Al and Sb) and by the mixed interfering anions ($SO_4^{2-},\;VO_3^-,\;and\;SiO_3^{2-}$) are larger than by each interfering cation and anion, and the releasing effect by cerium ($1.5 {\times} 10^{-2}$M) is effective up to some degree of the concentration of mixed interfering cations and of mixed interfering anions. The releasing effect by cerium to the mixed solution of interfering cations and anions is applicable to quite wide range of concentration.

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Heating and Cooling System using the Sewage Source Absorption Refrigeration and Heat Pump Cycle (하수열을 이용한 냉난방시스템에 관한 연구)

  • Lee, Yong-Hwa;Shin, Hyun-Joon;Yoon, Hee-Chul;Park, Hyun-Gun
    • Journal of the Korean Solar Energy Society
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    • v.27 no.4
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    • pp.19-26
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    • 2007
  • This paper concerns the study of absorption refrigeration and heat pump cycle to use sewage. Simulation analysis on the double-effect absorption refrigeration cycle with parallel and two-stage heat pump cycle has been performed. The working fluid is Lithium Bromide and water solution. The absorption refrigeration cycle use sewage as a cooling water for the absorber and condenser, and absorption refrigeration cycle does that as a chilled water for the evaporator of the first stage cycle. And the two-stage cycle consists of coupling double-effect with parallel and single effect cycle so that the first stage absorber and condenser produces heating water to evaporate refrigerant in the evaporator of the second stage. The effects of operating variables such as a absorber temperature on the coefficient of performance have been studied for absorption refrigeration and heat pump cycle.