• Journal of the Korean Ceramic Society
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• v.24 no.5
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• pp.477-483
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• 1987

Cr2O3 doped Pb(Zr0.525 Ti0.475)O3 piezoelectric ceramics were prepared from reagent grade oxide mixture, PbO, ZrO2, TiO2 and Cr2O3. Piezoelectric and aging properties of specimens were measured for various additions of Cr2O3. Generally, it has been known that aging rate decreased with Cr2O3 addition by stabilizing the domain wall. But hysteresis loops showed that the domain destabilization was occurred at high electric field (larger than 10KV/cm). In smaller additions of Cr2O3 (0-0.2mol%), aging rate increased and microcracks were created with increasing poling filed due to increasing internal stress. In larger additions of Cr2O3(0.4∼0.6mol%), aging rate decreased with increasing poling field.

• Journal of the Korean Ceramic Society
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• v.32 no.3
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• pp.378-384
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• 1995

Effects of $La_2O_3$, $MnO_2$ on the dielectric and piezoelectric properties of $0.02Pb(Y_{2/3}W_{1/3}O_3-0.98Pb(Zr_{0.52}Ti_{0.48})O_3$ system were investigated. The addition of La2O3 to the system enhanced electromechanical coupling factor (kp), piezoelectric constant (d33), but hardly changed mechanical quality factor (Qm). On the other hand, the addition of $MnO_2$ increased Qm significantly, but did not degrade kp and d33 so much. The piezoelectric properties of $0.02Pb(Y_{2/3}W_{1/3}O_3-0.98Pb(Zr_{0.52}Ti_{0.48})O_3$ containing 0.1wt% $La_2O_3$, 0.4wt% $MnO_2$ were very good and kp, d33, Qm were 55%, 350$\times$10-12C/N, 780, respectively. The size of the grains was proportional to the change of c/a (tetragonality) ratio caused by the addition of $La_2O_3$ and $MnO_2$, and dielectric, piezoelectric properties were sensitive to the amountof pyrochrole phase.

• Journal of the Korean Ceramic Society
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• v.20 no.1
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• pp.19-24
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• 1983

Dielectrics used as capacitor was studied in the system of $Pb(MgW)_{0.5} O_3-PbTiO_3-PbZrO_3$ Curie tempera-tures of $PbTiO_3 PbZrO_3$ and $Pb[MgW]_{0.5} O_3$ were 49$0^{\circ}C$ 23$0^{\circ}C$ and 39$0^{\circ}C$ respectively. When these materials formed solid solution the more amount of $Pb(MgW)_{0.5}O_3$ was increased the more Curie temperature lowered and dielectric constant increased. Higher dielectric constants were measured in the solid solution of which X-Ray diffraction patterns were changed. Especially Curie temperature and dielectric constant were 85$^{\circ}C$ and 4159 respectively in the composition of 60 $Pb(MgW)_{0.5}O_3-30 PbTiO_3-10PbZrO_3$. Also in this composition ferroeletric material with thermal stability was obtained.

• Journal of the Korean Ceramic Society
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• v.23 no.3
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• pp.21-26
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• 1986

In this study the system of $Pb(Mn_{1/3} Nb_{2/3})O_3-PbTiO_3-PbZrO_3$ piexoelectric ceramics was made in the radial mode disk and attenuation characteristic of the desinged ladder type filter was investigated. What is more temperature dependance of resonant frequency and variation of resonant frequency was examined by chan-ging the electrode diameter of piezoelectric resonator. (A Group : De=11mm, B Group : De=7.5mm and C Gro-up : De=5.5mm) Upon investigation it was the following. The center frequency of A, B and c filter showed up in the 200KHz, 270KHz and 380KHz respectively. As the electrode diameter decreased center frequency in creased abruptly. As the Co_2/Co1 increased attenuation characteristics and selectivity was improved. As the x=50. resonant frequ-ency invaried with variation of temperature.

• Journal of the Korean Ceramic Society
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• v.25 no.5
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• pp.523-531
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• 1988

The dielectric and piezoelectric properties with compositions in Pb(Ni1/3Nb2/3)O3-PbTiO3-PbZrO3-(PNN-PT-PZ)solid solution ceramics were investigated. In this study, the compsition ranges were 30 PNN 45mole%, 20 PT 50mole% and 50 PZ5mole%. As PT fraction were increased the grain size was increased and the fired density was decreased, but the changes of PNN fraction had no effect on the grain size. The Curie temperature was increased when PT and PNN fraction were increased. The displacement was increased but had a great hysteresis loss when PT fraction was increased. In morphotropic phase boundary, the maximum piezoelectric and electromechanical coupling factor were indicated. Morphotropic phase boundary(MPB) was 34 PT 36mole% in chang of compositions.

• Journal of the Korean Ceramic Society
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• v.24 no.5
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• pp.470-476
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• 1987

The system of 0.1Pb(Mg1/3N2/3)O3-yPbTiO3-zPbZrO3 piezoelectric ceramics was made in the radial model disk and ring dot type filter. The resonant frequency(fr) variations were investigated for 100 hours and the temperature range from 20$^{\circ}C$ to 100$^{\circ}C$. As the results, the morphotropic phase boundary was supposed to be the composition of 45 y 50 and 40 z 45. The best characteristic of againg effect, after 10-hours, was composed of y, z=45. The stabilized characteristic of temperature varition, to become 0.1% up to 100$^{\circ}C$, was composed of y=50 and z=40. The bandwidth was broadened with increasing the electromechanical coefficient(kp), and the filter characteristics was approached ideal mode with increasing mechanical quality factor(Qm). Kp and Qm affected combinationally on filter characteristics.

• Electrical & Electronic Materials
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• v.5 no.1
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• pp.111-121
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• 1992

본 연구는 Pb( $Co_{1}$3/Nb$_{2}$3/) $O_{3}$-PbTi $O_{3}$-PbZr $O_{3}$계 압전세라믹스의 조성에 따른 착화소자특성과 기계적응력 인가시의 압전열화현상에 대하여 조사하였다. 그 결과 상경계 조성에서 소결밀도, $K_{33}$ 및 출력전압이 최고치를 나타내었으며 능방정계조성에서는 조성의 변화에 따른 소결 및 전기적특성의 변화는 정방정계조성에 비하여 작았다. 기계적 응력 인가시의 압전퇴화현상은 분역의 재배열로 설명할 수 있었다.

• Electrical & Electronic Materials
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• v.4 no.3
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• pp.220-228
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• 1991

본 연구에서는 핫프레스법으로 제작된 0.05Pb(Sn$_{1}$2/Sb$_{1}$2/)O$_{3}$-0.60PbZrO$_{3}$-0.35PbTiO$_{3}$+x[wt%]MnO$_{2}$ 세라믹스에 대해 구조적, 전기적 특성 및 탄성 표면파 특성을 조사하였다. x가 0.4인 조성을 1150[.deg.C]에서 45분간 소성한 시편의 경우 탄성표명파의 전기 기계 결합 계수 k$_{s}$ $^{2}$가 2.8[%], 기계적 품질 계수 Q$_{m}$ 이 1976으로 탄성 표면파 소자용 기판으로서 응용 가능함을 보였다.

• Particle and aerosol research
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• v.4 no.1
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• pp.21-25
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• 2008

$Pb(Zr_{0.53}Ti_{0.47})O_3$ (PZT) was synthesized by a multiple wet dry process. Precipitates prepared from reaction between $ZrOCl_2{\cdot}8H_2O$ and $TiOCl_2$ and $NH_4OH$ in an aqueous solution was dried at $100^{\circ}C$, and calcined at $500^{\circ}C$ and $700^{\circ}C$. The mixture mixed with PbO and as-dried or calcined $Zr_{0.53}Ti_{0.47}O_4$ (ZT) powders was calcined again at 700 and $800^{\circ}C$. Well crystallized ZT and PZT were formed at even $700^{\circ}C$. PZT piezoelectric ceramics of more than 98.5% in a relative density was obtained by sintering at as low as $900^{\circ}C$.

• Proceedings of the Materials Research Society of Korea Conference
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• 1997.10a
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• pp.136-136
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• 1997