• Bulletin of the Korean Chemical Society
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• v.32 no.3
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• pp.964-972
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• 2011

This work investigated the difference between $Fe^{2+}$ autoxidation-induced and Fenton-type cleavage of pBR322 plasmid DNA. $^{\cdot}OH$ generation reactions in the absence and presence of $H_2O_2$ under various conditions were also investigated. Although both the $Fe^{2+}$ autoxidation and Fenton-type reactions showed DNA cleavage and $^{\cdot}OH$ generation, there were significant differences in their efficiencies and reaction rates. The rate and efficiency of the cleavage reaction were higher in the absence of 1.0 mM of $H_2O_2$ than in its presence in 20 mM phosphate buffer. In contrast, the $^{\cdot}OH$ generation reaction was more prominent in the presence of $H_2O_2$ and showed a pH-independent, fast initial reaction rate, but the rate was decreased in the absence of $H_2O_2$ at across the entire tested pH range. Studies using radical scavengers on DNA cleavage and $^{\cdot}OH$ generation reactions in both the absence and presence of $H_2O_2$ confirmed that both reactions spontaneously involved the active oxygen species $^{\cdot}OH$, ${O_2}^{\cdot-}$, $^1O_2$ and $H_2O_2$, indicating that a similar process may participate in both reactions. Based on the above observations, a new mechanism for the $Fe^{2+}$ autoxidation-induced DNA cleavage reaction is proposed.

• Rapid Communication in Photoscience
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• v.1 no.2
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• pp.35-37
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• 2012

Photoinduced electron-transfer process of 1,8-naphthalimide-linker-trimethylsilane (NI-O3-TMS, O3 = 3,6,9-trioxaundecyl) and NI-O3 has been investigated using the transient absorption measurements in $CH_3CN$ and $CH_3CN/H_2O$. The excitation of NI-O3-TMS in $CH_3CN$ produced the NI radical anion ($NI^{{\cdot}-}$) with a transient absorption band around 413 nm, via the intermolecular electron-transfer between NI moieties in the excited singlet state. In contrast, in a protic polar solvent mixture of $CH_3CN/H_2O$, a proton abstraction process occurred from $NI^{{\cdot}-}$ to generate the NI ketyl radical ($NIH^{\cdot}$), which showed a transient absorption band around 405 nm. The decay time constants of $NIH^{\cdot}$ were quite long compared to those of $NI^{{\cdot}-}$ in $CH_3CN$.

• Journal of Korean Society on Water Environment
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• v.30 no.4
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• pp.394-402
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• 2014

High-voltage dielectric discharges are an emerging technique in environmental pollutant degradation, which are characterized by the production of hydroxyl radicals as the primary degradation species. The initiation and propagation of the electrical discharges depends on several physical, chemical, and electrical parameters such as 1st and 2nd voltage of power, gas supply, conductivity and pH. These parameters also influence the physical and chemical characteristics of the discharges, including the production of reactive species such as OH, $H_2O_2$ and $O_3$. The experimental results showed that the optimum 1st voltage and oxygen flow rate for RNO (N-Dimethyl-4-nitrosoaniline, indicator of the generation of OH radical) degradation were 160 V (2nd voltage of is 15 kV) and 4 L/min, respectively. As the 2nd voltage (4 kV to 15 kV) was increase, RNO degradation was increased and, generated $H_2O_2$ and $O_3$ concentration were increased. The conductivity of the solution was not influencing the RNO degradation, $H_2O_2$ and $O_3$ generation. The pH effect on RNO degradation was not high. However, the lower pH and the conductivity, the higher $H_2O_2$ and $O_3$ generation were observed.

• The Transactions of the Korean Institute of Power Electronics
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• v.22 no.3
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• pp.199-206
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• 2017

Maximum Power Point Tracking (MPPT) control needs to generate the maximum power of a tidal current turbine. A tidal current speed sensor is required to achieve effective generated power in a tidal current generation system. The most common methods used to achieve such power is the tip speed ratio of turbine and tidal current information. However, these methods have disadvantages, such as expensive installation of the tidal current sensor, parameter errors in turbine design, and different information according to the installed position of the tidal current sensor. This paper proposes a maximum power control scheme using perturb-and-observe (P&O) for tidal current generation system. The proposed P&O MPPT scheme can achieve the maximum power without tidal current sensors and turbine design parameters. The reliability and suitability of the proposed control scheme are proven through simulation and experiment results at the tidal current generation laboratory.

• Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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• v.20 no.7
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• pp.58-64
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• 2006

Recently deep interests have been paid on the effective generation of ozone, which has been widely used for water treatment, deodorization, color removal, and chemical processing of exhausted smoke. The silent discharge reaction has been proposed as the most effective one in the many ozone generation methods, because the silent discharge can be generated under the conditions of lower applied voltage and power consumption, compared other ones. In this paper, in order to improve the ozone generation and ozone generation efficiency, the conventional silent discharge chamber with $Al_2O_3$ dielectric layer and tubular ferroelectric bed discharge reactor packed with $Al_2O_3$ pellets were made, and the silent discharge of the reactors were studied experimentally. The ozone generation characteristics are also discussed based on the discharge characteristics, especially on the wall charge accumulation properties and power consumption. The results show that the electric charges of discharge tube with bead are around 2.5 times as large as those without bead. In the discharge chamber packed with dielectric beads, the ozone concentration and the energy yield characteristics were also improved, compared with those in the conventional silent discharge reactor.

• KOREAN JOURNAL OF CROP SCIENCE
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• v.33 no.4
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• pp.370-374
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• 1988

The study was objected to compare the differential responses in photosynthesis and resipiration by selected cultivars as tolerant or susceptible to oxyfluorfen and bensulfuron-methyl. Clark-typed oxygen elect rude system (Rank Brothers Co., Bottisham. UK.) was used to detect the releasing oxygen from the leaf disks. By increasing oxyfluorfen concentrations. both cultivars were disposed to decrease in photosynthetic O$_2$ generation and increase in respiratory O$_2$ generation. Comparing of both rice cultivars. cv. Mushakdanti (selected at 10$\^$-3/M as the susceptible) failed down in photosynthetic O$_2$ generation as lower as 43% of the control but cv. Aichiasahi to 55%, respectively. However. no significant difference in respiratory O$_2$ generation were detected between both cultivars. As for bensulfuron-methyl. almost same tendency was conferable with general responses on O$_2$ generation between both selected cultivars, namely cv. IR 1846 failed down in photosynthetic O$_2$ generation as lower as 55% of the control but cv. Chinsurah Boro II to 77%. respectively.

• Journal of the Optical Society of Korea
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• v.19 no.3
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• pp.297-302
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• 2015

Terahertz (THz) wave generation from bulk and periodically poled $LiTaO_3$ (PPLT) with a Cherenkov phase matching scheme is numerically investigated. It is shown that by using the crystal birefringence of bulk $LiTaO_3$ and a grating vector of PPLT, THz waves can be efficiently generated by difference frequency generation (DFG) with a Cherenkov phase matching scheme. The frequency tuning characteristics of the THz wave via varying wavelength of difference frequency waves, phase matching angle, poling period of PPLT and working temperature are theoretically analyzed. The parametric gain coefficient in the low-loss limit and the absorption coefficient of the THz wave during the DFG process in the vicinity of polariton resonances are numerically analyzed. A THz wave can be efficiently generated by utilizing the giant second order nonlinearities of $LiTaO_3$ in the vicinity of polariton resonances.

• Nuclear Engineering and Technology
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• v.45 no.5
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• pp.683-688
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• 2013

Candidate coating materials for re-usable metallic nuclear fuel crucibles, TaC, TiC, ZrC, $ZrO_2$, and $Y_2O_3$, were plasmasprayed onto a niobium substrate. The microstructure of the plasma-sprayed coatings and thermal cycling behavior were characterized, and U-Zr melt interaction studies were carried out. The TaC and $Y_2O_3$ coating layers had a uniform thickness, and high density with only a few small closed pores showing good consolidation, while the ZrC, TiC, and $ZrO_2$ coatings were not well consolidated with a considerable amount of porosity. Thermal cycling tests showed that the adhesion of the TiC, ZrC, and $ZrO_2$ coating layers with niobium was relatively weak compared to the TaC and $Y_2O_3$ coatings. The TaC and $Y_2O_3$ coatings had better cycling characteristics with no interconnected cracks. In the interaction studies, ZrC and $ZrO_2$ coated rods showed significant degradations after exposure to U-10 wt.% Zr melt at $1600^{\circ}C$ for 15 min., but TaC, TiC, and $Y_2O_3$ coatings showed good compatibility with U-Zr melt.

• Current Optics and Photonics
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• v.2 no.2
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• pp.179-184
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• 2018

Terahertz (THz) wave generation by periodically poled $BaTiO_3$ (PPBT) with a quasi-phase-matching (QPM) scheme based on cascaded difference-frequency generation (DFG) is theoretically analyzed. The cascaded DFG processes comprise cascaded Stokes and anti-Stokes processes. The calculated results indicate that the cascaded Stokes processes are stronger than the cascaded anti-Stokes processes. Compared to a noncascaded Stokes process, THz intensities from $20^{th}$-order cascaded Stokes processes increase by a factor of 30. THz waves with a maximum intensity of $0.37MW/mm^2$ can be generated by $20^{th}$-order cascaded DFG processes when the optical intensity is $10MW/mm^2$, corresponding to a quantum conversion efficiency of 1033%. The high quantum conversion efficiency of 1033% exceeds the Manley-Rowe limit, which indicates that PPBT is an excellent crystal for THz wave generation via cascaded DFG.

• Current Optics and Photonics
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• v.2 no.3
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• pp.261-268
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• 2018

Stimulated polariton scattering (SPS) from the $A_1$ transverse optical (TO) modes of $BaTiO_3$ bulk crystal generating a terahertz (THz) wave with the noncollinear phase-matching (NPM) condition is theoretically investigated. To our best knowledge, this is the first report on THz wave generation from $BaTiO_3$ bulk crystal via SPS. Phase-matching (PM) characteristics in the NPM configuration are analyzed. Effective parametric gain lengths for the Stokes and THz waves in the NPM configuration are calculated. The effective parametric gain coefficient and absorption coefficient of the THz wave in $BaTiO_3$ are theoretically simulated. The THz phonon flux densities generated via SPS in $BaTiO_3$ are theoretically calculated by solving the coupled wave equations under the NPM condition. The PM characteristics and THz-wave parametric gain characteristics in $BaTiO_3$ are compared to those in $MgO:LiNbO_3$. The results of the analysis indicate that $BaTiO_3$ is an attractive optical crystal for efficient THz wave generation via SPS.