• 한국자기학회지
• /
• 제22권3호
• /
• pp.85-90
• /
• 2012

$Nd_2Fe_{14}B$ 화합물 결정의 산화 및 미세 $Nd_2Fe_{14}B$ 결정입자의 보자력에 미치는 산화의 영향을 조사하였다. $Nd_2Fe_{14}B$ 화합물 결정의 산화속도는 $Nd_{15}Fe_{77}B_8$ 합금 잉곳 중의 과잉 성장시킨 $Nd_2Fe_{14}B$ 결정립을 이용하여 조사하였다. $Nd_2Fe_{14}B$ 화합물 결정의 산화는 이 결정상의 ${\alpha}$-Fe, $Fe_3B$, 및 Nd 산화물 복합상으로의 분해에 의해 일어 났다. $Nd_2Fe_{14}B$ 화합물 결정의 산화속도는 결정 방위와는 무관하였다. 산화반응 속도 식은 단순한 직선관계로 나타났다. $Nd_2Fe_{14}B$ 화합물 결정의 산화에 대한 활성화에너지는 약 26.8 kJ/mol로 계산되었다. HDDR 처리한 $Nd_{15}Fe_{77}B_8$ 합금을 볼밀링하여 임계단자구 크기에 유사한 미세한 $Nd_2Fe_{14}B$ 결정입자를 제조하고, 이 입자들을 이용하여 보자력에 미치는 산화의 영향을 조사하였다. 임계단자구 크기에 유사한 미세한 $Nd_2Fe_{14}B$ 결정입자(${\fallingdotseq}0.3\;{\mu}m$)는 9 kOe 이상의 높은 보자력을 가졌다. 그러나, 이 보자력은 공기 중에서 온도 상승에 따라 급격하게 저하하였다($200^{\circ}C$에서 2 kOe 이하). 이러한 급격한 보자력의 감소는 산화에 의해 미세 입자의 표면에 형성된 연자성 ${\alpha}$-Fe 및 $Fe_3B$ 상 때문으로 판단되었다.

• 한국결정성장학회지
• /
• 제8권4호
• /
• pp.655-659
• /
• 1998

과냉각된 melt-spun $Nd_{14.73}Fe_{78.67}B_{6.60}$리본의 급속응고속도 및 열처리에 따른 보자력의 변화를 조사하였으며, 이 결과를 분석하기 위하여 비정질로 부터의 결정화 거동을 연구하였다. 리본 제조시 급속응고속도가 증가함에 따라 결정화 후의 고유 보자력은 감소하였다. $Nd_{14.73}Fe_{78.67}B_{6.60}$ 비정질은 안정한 $Nd_2Fe_{14}B$ 상으로 결정화하는 과정에서 $\alpha$-Fe와 $Fe_3B$ 상이 생성된다. $Fe_3B$ 상은 $Nd_2Fe_{14}B$ 상이 결정화됨과 동시에 사라지나 $\alpha$-Fe 상은 완전히 결정화된 이후에도 기지상인 $Nd_2Fe_{14}B$ 상과 함께 잔류한다. 열처리된 리본내에 잔류하는 연자성상인 $\alpha$-Fe에 의해 고유 보자력의 특성이 저하하였다.

• 한국자기학회지
• /
• 제8권3호
• /
• pp.144-149
• /
• 1998

자장중에서 정렬시킨 다결정 분말의 자화곡선을 이용하여 콘이방성의 스핀재배열각을 결정할 수 있는 새로운 방법을 제시하였다. 이방법을 이용하여 Nd2Fe14B 다결정시료의 스핀재배열각을 구한 결과 단결정과 일치하는 결과를 얻었다. 4.2K에서의 Nd2Fe14B의 스핀재배열각을 결정함에 있어서 저면이방성효과가 무시될 경우 약 9%의 낮은 값이 얻어질 것으로 예상된다.

• 한국결정성장학회:학술대회논문집
• /
• 한국결정성장학회 1997년도 Proceedings of the 13th KACG Technical Meeting `97 Industrial Crystallization Symposium(ICS)-Doosan Resort, Chunchon, October 30-31, 1997
• /
• pp.63-67
• /
• 1997

환원확산법은 저렴한 Nd 산화물을 환원제를 이용하여 환원시키고 환원된 Nd가 Fe, FeB와 확산하여 주상인 Nd$_2$Fe14B가 만들어지는 공정으로 환원제로 사용된 CaO나 미반응 Ca 및 잔존 산소함량을 조절하는데 어려움이 있어 아직까지는 상업되지 못하고 있는 실정이다. 본 연구에서는 환원확산법을 이용하여 Nd-Fe-B계 영구자석에 사용될 미세분말을 제조하고 그 자기적 특성을 관찰하였다.

• Journal of Magnetics
• /
• 제9권2호
• /
• pp.27-33
• /
• 2004

Magnetic properties of $Nd_4Fe_{77.5}B_{18.5}$ compound in term of exchange coupling between $Nd_2Fe_{14}B$ and $Fe_3B$ magnetic nano crystals in melt spun powders were characterized by varying the quenching speed in mass production line. The exchange coupled phenomenon was characterized as functions of nano crystal size and volume fraction of each magnetic phase which was possible by employing Henkel plot (${\delta}M$) and refined Mossbauer spectroscopy. The optimized magnetic properties obtained from the present volume production line were: $B_r= 11.73 kG,{_i}H_c/ = 3.082 kOe$, and $(BH)_{max} = 12.28 MGOe.$ The volume fraction of each magnetic phase for those conditions giving the grain size of 10 nm were ${\alpha}-Fe; 4.2%, Fe_3B; 60.1 %$, and $Nd_2Fe_{14}B; 35.7%$. The superior magnetic properties in the $Nd_2Fe_{14}Fe_3B$ based nanocomposites were confirmed to be dependant on the volume fraction of $Fe_3B$.

• Bulletin of the Korean Chemical Society
• /
• 제35권3호
• /
• pp.886-890
• /
• 2014

The properties of magnetic material of Nd-Fe-B are highly affected by various factors such as particle size, magnetic anisotropy, phase purity and crystal structure. Incorporation of excess neodymium was carried out in various percentages so that it will adjust the proportion of neodymium in the host crystal after reduction treatment and finally help to improve magnetic property of a material. The interdiffusion of Nd-Fe and boron was studied for various compositions and their effect on magnetic property was understood with theoretical concepts. The factors such as amount of hard and soft phase in the reduction treated product is also responsible for the possible exchange coupling between hard and soft phase magnets for better magnetic properties.

• Journal of Magnetics
• /
• 제10권1호
• /
• pp.14-22
• /
• 2005

Precisely refined Mossbauer study and nano structure observation revealed that intergranular phase formed between a-Fe and Nd₂Fe₁₄B phase in NdFeNbB alloys plays a significant role on the magnetic properties. The intergranular interaction was characterized in term of Henkel Plot (δM plot), and hyperfine field, quardrupole splitting and isomer shift were refined to predict the presence and role of the intergranular phase. By the addition of Nb into Nd₈Fe₈₆B₆ composition, coercivity was found to increase by 25% due to the refinement of average grain size of both the soft and hard magnetic phases which was decreased from 50 nm of virgin Nd/sub 8/Fe/sub 86/B/sub 6/ to 25 nm in Nd₈Fe ₈₅Nb₁B₆ alloys. The role of Nb addition was confirmed to stabilize the Nd₂Fe₁₄B lattice preventing from thermal vibration of the corresponding sites substituted Fe by Nb atoms in all sites in the Nd₂Fe₁₄B lattice. The enhanced coercivity was originated from the exchange hardening of soft and amorphous phases surrounding the hard magnetic Nd₂Fe₁₄B crystal.

• 한국자기학회:학술대회 개요집
• /
• 한국자기학회 2011년도 자성 및 자성재료 국제학술대회
• /
• pp.144-145
• /
• 2011

• 한국분말야금학회:학술대회논문집
• /
• 한국분말야금학회 2006년도 Extended Abstracts of 2006 POWDER METALLURGY World Congress Part2
• /
• pp.790-791
• /
• 2006

The fracture behavior and mechanical characteristics of sintered rare-earth magnets were investigated. It shows that the fracture behavior and bending strength of the magnets obviously exhibit anisotropy. Sm-Co magnets tend to cleavage fracture in the close-packed (0001) plane or in the ($10\bar{1}1$) plane. The fracture mechanism of $Nd_2Fe_{14}B$ magnet mainly appears to be intergranular fracture. The anisotropy of fracture behavior and mechanical strength of sintered rare-earth magnets is caused mainly by the strong crystal-structure anisotropy and the grain alignment texture. The effects of Nd content, and Pr, Dy substitution on the impact stability of $Nd_2Fe_{14}B$ magnets were also reported.

• Journal of Magnetics
• /
• 제18권3호
• /
• pp.235-239
• /
• 2013

The effect of Dy addition on the microstructure and magnetic properties of the sintered NdFeB magnets was investigated. The results of the microstructure analysis showed that Dy-free and Dy-doped samples are composed of $Nd_2Fe_{14}B$ (P42/mnm) and a trace of Nd-rich phase. Dy addition reduces significantly the pole density factor of (004), (006) and (008) crystal faces as estimated by the Horta formula. Accordingly, the coercivity of the Dy-doped sample increases from 2038 $kA{\cdot}m^{-1}$ up to 2288 $kA{\cdot}m^{-1}$. The $H_{cj}(T)/M_s(T)$ versus $H^{min}_N/M_s(T)$ (Kronm$\ddot{u}$ller-plot) behavior shows that the nucleation is the dominating mechanism for the magnetization reversal in these two kinds of magnets, and two microstructural parameters of ${\alpha}_k$ and $N_{eff}$ are obtained. The Kronm$\ddot{u}$ller-Plot gives evidence for an increase of the ${\alpha}_k$ responsible for an increase of the coercivity as the result of the increase of the magnetic field as the magnetic domain reversed.