Browse > Article
http://dx.doi.org/10.5012/bkcs.2014.35.3.886

Nd2Fe14B Synthesis: Effect of Excess Neodymium on Phase Purity and Magnetic Property  

Jadhav, Abhijit P. (Department of Chemistry, Sogang University)
Ma, Haoxuan (Department of Chemistry, Sogang University)
Kim, Dong Soo (Korea Institute of Material Science)
Baek, Youn Kyung (Korea Institute of Material Science)
Choi, Chul Jin (Korea Institute of Material Science)
Kang, Young Soo (Department of Chemistry, Sogang University)
Publication Information
Abstract
The properties of magnetic material of Nd-Fe-B are highly affected by various factors such as particle size, magnetic anisotropy, phase purity and crystal structure. Incorporation of excess neodymium was carried out in various percentages so that it will adjust the proportion of neodymium in the host crystal after reduction treatment and finally help to improve magnetic property of a material. The interdiffusion of Nd-Fe and boron was studied for various compositions and their effect on magnetic property was understood with theoretical concepts. The factors such as amount of hard and soft phase in the reduction treated product is also responsible for the possible exchange coupling between hard and soft phase magnets for better magnetic properties.
Keywords
Ferromagnetism; $Nd_2Fe_{14}B$; Reduction-diffusion;
Citations & Related Records
연도 인용수 순위
  • Reference
1 Herth, S.; Ye, F.; Eggersmann, M.; Gutfleisch, O.; Wurschum, R. Phys. Rev. Lett. 2004, 92, 095901.   DOI
2 Hyeon, T. Chem. Commun. 2003, 927.
3 Bhame, S. D.; Swaminathan, V.; Deheri, P. K.; Ramanujan, R. V. Adv. Sci. Lett. 2010, 3, 174.   DOI
4 Jadhav, A. P.; Hussain, A.; Lee, J. H.; Baek, Y. K.; Choi, C. J.; Kang, Y. S. New J. Chem. 2012, 36, 2405.   DOI
5 Herbst, J. F.; Croat, J. J.; Yelon, W. B. Phys. Rev. B 1984, 29, 4176.   DOI
6 Betancourt, R. J. I. Rev. Mex. Fis. 2002, 48, 283.
7 Berlin, J. Imaging & Microscopy magazine 2011, 13, 19.
8 Fischer, R.; Leineweber, T.; Kronmuller, H. Phys. Rev. B: Condens. Matter Mater. Phys. 1998, 57, 10723.   DOI
9 Deheri, P. K.; Shukla, S.; Ramanujan, R. V. J. Solid State Chem. 2012, 186, 224.   DOI
10 Zijlstra, H. In Permanent Magnets; Theory in Ferromagnetic Materials; Wohlfarth, E. P., Ed.; North Holland, 1982; Vol 3, p 37.
11 Sagawa, M.; Fujimura, S.; Togawa, N.; Yamamoto, H.; Matsuura, Y. J. Appl. Phys. 1984, 55, 6409.
12 Sprengel, W.; Herth, S.; Barbe, V.; Schaefer, H-E. J. Appl. Phys. 2005, 98, 0714314.
13 Grunberger, W.; Hinz, D.; Kirchner, A.; Muller, K. H.; Schultz, L. J. Alloys Compd. 1997, 257, 293.   DOI
14 Herth, S.; Ye, F.; Eggersmann, M.; Rosner, H.; Gutfleisch, O.; Wurschum, R. Zeitschrift Fur Metallkunde 2004, 95, 895.   DOI