• Title/Summary/Keyword: $N_2O-O_2$

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Application of Hybrid SNCR/SCR process for Improved N Ox Removals Efficiency of SNCR (SNCR의 N Ox 제거효율 향상을 위한 Hybrid SNCR/SCR 공정 응용)

  • 최상기;최성우
    • Journal of Environmental Science International
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    • v.12 no.9
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    • pp.997-1004
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    • 2003
  • The objective of this research was to test whether, under controlled laboratory conditions, hybrid SNCR/SCR process improves N $O_{x}$ removal efficiency in comparison with the SNCR only. The hybrid process is a combination of a redesigned existing SNCR with a new downstream SCR. N $O_{x}$ reduction experiments using a hybrid SNCR/SCR process have been conducted in simple NO/N $H_3$/ $O_2$ gas mixtures. Total gas flow rate was kept constant 4 liter/min throughout the SNCR and SCR reactors, where initial N $O_{x}$ concentration was 500 ppm in the presence of 5% or 15% $O_2$. Commercial catalysts, $V_2$ $O_{5}$ -W $O_3$-S $O_4$/Ti $O_2$, were used for SCR N $O_{x}$ reduction. The residence time and space velocity were around 1.67 seconds and 2,400 $h^{-1}$ or 6000 $h^{-1}$ in SNCR and SCR reactors, respectively. N $O_{x}$ reduction of the hybrid system was always higher than could be achieved by SNCR alone at a given value of N $H_{3SLIP}$. Optimization of the hybrid system performance requires maximizing N $O_{x}$ removal in the SNCR process. An analysis based on the hybrid system performance in this lab-scale work indicates that a equipment with N $O_{xi}$ =500 ppm will achieve a total N $O_{x}$ removal of about 90 percent with N $H_{3SLIP}$ $\leq$ 5 ppm only if the SNCR N $O_{x}$ reduction is at least 60 percent. A hybrid SNCR/SCR process has shown about 26∼37% more N $O_{x}$ reduction than a SNCR unit process in which a lower temperature of 85$0^{\circ}C$ turned out to be more effective.be more effective.

A Deterministic Resource Discovery Algorithm in Distributed Networks (분산 망에서 자원발견을 위한 결정 알고리즘)

  • Park, Hae-Kyeong;Ryu, Kwan-Woo
    • Journal of KIISE:Information Networking
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    • v.28 no.4
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    • pp.455-462
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    • 2001
  • In this paper, we propose a deterministic algorithm to solve the resource discovery problem, that is, some subset of machines to learn the existence of each other in a large distributed network. Harchol et al. proposed a randomized algorithm solving this problem within O($log^2\;n$) rounds with high probability, which requires O($nlog^2\;n$) connection communication complexity and O($n^2log^2\;n$) pointer communication complexity, where n is the number of machines in the network. His solution is based on randomization method and it is difficult to determine convergence time. We propose an efficient algorithm which improve performance and the non-deterministic characteristics. Our algorithm requires O(log n) rounds which shows O(mlog n) connection communication complexity and O($n^2log\;n$) pointer communication complexity, where m is the number of links in the network.

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Effect of Fertilizers on Yield and Storage Quality of Early Maturing Variety in Onion (조생종양파의 수량과 저장성에 미치는 비료의 영향)

  • 권병선
    • Korean Journal of Plant Resources
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    • v.10 no.2
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    • pp.145-150
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    • 1997
  • To find out the optimum fertilizer level for onion, early maturing cultivar Fechongjoseng, experiment with four fertilizer levels was conducted of the field of the paddy and upland in Muan and Changyeong from Sep.1993 to Feb.1995. The yield character of onion was higher and rate of the rottenness was lowest under the treatment of $N-P_2O_5-K_2O$=28-9.5-23Kg/10a in the soil of paddy and upland field of Muan area. But the onion yield was excellent and rate of the rottenness was lowest under the treatments, $N-P_2O_5-K_2O$=21-19-17.3Kg/10a, in the soil of paddy field and $N-P_2O_5-K_2O$=28-9.5-23Kg/10a, in the soil of upland field of Changyeong area.

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Review of Nitrous Oxide Emission by Denitrification in Subsurface Soil Environment (심층토에 있어서 탈질화에 의한 $N_2 O$ 방출의 평가)

  • Chung Doug-Young;Jin Hyun-O;Lee Chaang-Hwan
    • Korean Journal of Agricultural and Forest Meteorology
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    • v.1 no.2
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    • pp.160-164
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    • 1999
  • Subsurface environments, including the intermediate vadose zone and aquifers, may be contributing to increased atmospheric concentrations of $N_2$O. Denitrification appears to be the major source of $N_2$O in the subsurface environment. In the intermediate vadose zone, the level of denitrifying activity is dependent on the soil morphology, particularly stratified layers within the soil profile, which impede water and solute movement and create conditions favorable for denitrification. Movement of organic C from the soil surface appears to support denitrifying activity by providing an energy source and increasing the consumption of $O_2$. Denitrirication and $N_2$O production have been observed in aquifers but appear to be of greatest significance in shallow unconfined aquifers. The lack of organic C, N $O_2$, or anaerobiosis is often a limiting factor for activity but seems to be site specific. The presence of denitrifying bacteria does not appear to be a major limitation, based on published results, but the ubiquity of denitrifiers in subsurface environments needs to be confirmed. The fate of the $N_2$O produced in subsurface environments is unknown. Transport of $N_2$O by up ward diffusion, by outgassing at contacts with surface waters, and by ground water use need to be quantified to determine the contribution to atmospheric $N_2$O. Contamination of subsurface environment with N $O_3$$^{ }$ and organics has the potential for increasing the contribution to atmospheric $N_2$O by enhancing denitrification .

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Evaluation of Visible-light activation of Cu2O-TiO2 (P-N type) Semiconductor Nanomaterials prepared by Ultrasonic-assisted Synthesis (초음파 합성 적용 Cu2O-TiO2 (P-N 타입) 반도체 나노물질의 가시광 활성 평가)

  • Shin, Seung-ho;Choi, Jeong-Hak;Kim, Ji-hoon;Lee, Joon Yeob
    • Journal of Environmental Science International
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    • v.28 no.11
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    • pp.971-981
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    • 2019
  • This study evaluated the photocatalytic oxidation efficiency of volatile organic compounds by $Cu_2O-TiO_2$ under visible-light irradiation. $Cu_2O-TiO_2$ was synthesized by an ultrasonic-assisted method. The XRD result indicated successful p-n type photocatalysts. However, no diffraction peaks belonging to $TiO_2$ were observed for the $Cu_2O-TiO_2$. The Uv-vis spectra result revealed that the synthesized $Cu_2O-TiO_2$ can be activated under visible-light irradiation. The FE-TEM/EDS result showed the formation of synthesized nanocomposites in the commercial P25 $TiO_2$, the undoped $TiO_2$, and $Cu_2O-TiO_2$ and componential analysis in the undoped $TiO_2$ and $Cu_2O-TiO_2$. The photocatalytic oxidation efficiencies of benzene, toluene, ethylbenzene, and o-xylene with $Cu_2O-TiO_2$ were higher than those of P25 $TiO_2$ and undoped $TiO_2$. These results indicate that the prepared $Cu_2O-TiO_2$ photocatalyst can be applied effectively to control gaseous BTEX.

Syntheses and Mechanical Properties of Quaternary Cr-Si-O-N Coatings by Hybrid Coating System (하이브리드 코팅시스템에 의한 Cr-Si-O-N 코팅막 합성 및 기계적 성질)

  • Lee, Jeong-Doo;Wang, Qi Min;Kim, Kwang-Ho
    • Journal of the Korean institute of surface engineering
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    • v.43 no.5
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    • pp.238-242
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    • 2010
  • In the present work, the influence of oxide on the Cr-Si-N coatings was investigated for the Cr-Si-O-N coatings on AISI 304 and Si wafer deposited by hybrid system, which combines the DC magnetron sputtering technique and arc ion plating (AIP) using Cr and Si target in an $Ar/N_2/O_2$ gaseous mixture. As the O content in the Cr-Si-N coatings increased, the diffraction patterns of the Cr-Si-O-N coatings showed CrN and $Cr_2O_3$ phases. However, as the O content increased to 28.8 at.%, diffraction peak of $Cr_2O_3$ was disappeared in the Cr-Si-O-N coating. The $d_{200}$ value was decreased with increasing of O content. The average grain size increased from about 40 nm to 65 nm as the O content increased. The maximum micro-hardness of the Cr-Si-O-N coating was obtained 4507 Hk at the O content of 24.8 at.%. The average friction coefficient of the Cr-Si-O-N coatings was gradually decreased by increasing the O content and the average friction coefficient decreased from 0.37 to 0.25 by increasing the O content. These results indicated that amorphous phase was increased in the Cr-Si-O-N coatings by increasing of O content.

Effects of $N_2O$/$SiH_4$Flow Ratio and RF Power on Properties of $SiO_2$Thick Films Deposited by Plasma Enhanced Chemical Vapor Deposition (PECVD법에 의해 증착된 $SiO_2$후막 특성에서 $N_2O$/$SiH_4$Flow Ratio와 RF Power가 미치는 영향)

  • 조성민;김용탁;서용곤;임영민;윤대호
    • Journal of the Korean Ceramic Society
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    • v.38 no.11
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    • pp.1037-1041
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    • 2001
  • Silicon diosixde thick film using silica optical waveguide cladding was fabricated by Plasma Enhanced Chemical Vapor Deposition (PECVD) method, at a low temperature (32$0^{\circ}C$) and from (SiH$_4$+$N_2$O) gas mixtures. The effects of deposition parameters on properties of SiO$_2$thick films were investigated by variation of $N_2$O/SiH$_4$flow ratio and RF power. As the $N_2$O/SiH$_4$flow ratio decreased, deposition rate increased from 2.9${\mu}{\textrm}{m}$/h to maximum 10.1${\mu}{\textrm}{m}$/h. As the RF power increased from 60 W to 120 W, deposition rate increased (5.2~6.7 ${\mu}{\textrm}{m}$/h) and refractive index approached at thermally grown silicon dioxide (n=1.46).

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Studies on Photocatalytic Thin Films($TiO_2$, TiO-N) Manufactured by DC Magnetron Sputtering Method and it's Characteristics for Removal of Pollutants (DC 마그네트론 스퍼터링법을 이용한 광촉매박막($TiO_2$, TiO-N)제조 및 오염물질 제거에 관한 연구)

  • Jeong, Weon-Sang;Park, Sang-Weon
    • Journal of Korean Society of Environmental Engineers
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    • v.27 no.1
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    • pp.59-66
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    • 2005
  • [ $TiO_2$ ] was deposited by DC magnetron sputtering on glass surface under various sputtering parameters such as discharge power($0.6{\sim}5.2\;kW$, substrate temperature($R.T{\sim}350^{\circ}C$), Ar and $O_2$ flow ratio with $0{\sim}50\;sccm$($Ar+O_2$ 90 sccm) and about 1 mtorr of pressure. TiO-N thin film was prepared under same sputtering conditions for $TiO_2$ thin film except flow ratio($Ar+O_2+N_2$ 90 sccm). The sheet resistance of thin films deposited under these parameters was measured to analyze electronic characteristic and thin film's thickness(${\alpha}$-step), surface roughness(AFM) and formation construction(FE-SEM, XRD) were also measured to draw optimal sputtering parameters. In order to evaluate photo-activity of thin film($TiO_2$, TiO-N) made in optimal parameters for removal of pollutants, toluene among VOCs and Suncion Yellow among reactive dyes were chosen to probe organic compounds for photo-degradation. It was shown that the photo-catalytic thin films had a significant photo-activation for the chosen contaminants and especially TiO-N thin film showed maximum efficiency of 33% for toluene(5 ppm) removal in visible-light range.

$N_2O$ Emissions with Different Land-Use Patterns in a Basin (유역 내 토지이용도에 따른 $N_2O$ 배출양상)

  • Seo, Ju-Young;Kang, Ho-Jeong
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.2
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    • pp.86-90
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    • 2012
  • The gaseous product of nitrogen cycle, nitrous oxide ($N_2O$) is a potent greenhouse gas whose Global Warming Potential (GWP) is about 300 times greater than $CO_2$. The dynamics of $N_2O$ emission are controlled by such environments and soil conditions. The main aim of this study is to investigate variations of $N_2O$ emission and its controlling factors with different land-use patterns in Haean basin. A forest, a radish field and a rice paddy were selected as three different land-use patterns. Their $N_2O$ emissions were measured every month during a growing season. We also collected soil samples with seasons and analyzed soil characteristics including inorganic nitrogen content. $N_2O$ emission was greatest at the radish field likely due to anthropogenic nitrogen addition by fertilization. Soils of forest and rice paddy also contained inorganic nitrogen originated from organic matter. However, the spatial variation was great and it looks that nitrogen cycle and $N_2O$ production were slower than that of radish field. Intensive observation and control of fertilization would be requiredto adjust $N_2O$ emission from agriculture soils.

Study on the Characteristics of Thermal-resistance Catalyst for $N_2O$ Propellant Decomposition ($N_2O$ 추진제 분해 촉매의 고온 내열 특성 연구)

  • Baek, Jin-Oh;Kim, Tae-Gu
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2010.05a
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    • pp.373-376
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    • 2010
  • The characteristics of thermal-resistance catalyst for $N_2O$ propellant decomposition were studied in the present study. Si was added to the $Al_2O_3$ support to stabilize its surface area at high temperature (> $1000^{\circ}C$). Ru was used as a catalyst for $N_2O$ decomposition. The prepared catalysts were characterized using SEM, EDS and XRD analysis, and $N_2O$ conversion was measured as reaction temperatures. The Ru/$Al_2O_3$-Si catalyst showed better performance than Ru/$Al_2O_3$ catalyst.

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