• Title/Summary/Keyword: $NO_x$ production

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A Study on the Enviromental Impact of District Heating System (지역난방의 환경개선효과 측정에 관한 연구)

  • Sonn, Yang-Hoon;Park, Joo Heon;Cho, Jun-Hyuk
    • Environmental and Resource Economics Review
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    • v.10 no.3
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    • pp.367-386
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    • 2001
  • In this paper we analyze the environmental advantages of district heating system. We construct three econometric models to analyze the energy consumption and economic cost as well as the emission of the major pollutants like $SO_x$, $NO_x$, DUST, and $CO_2$. As the size of heating supply is larger, the district heating system is evaluated to be better than other heating systems environmentally and costly in the long run. Especially, the district heating reduces $SO_x$ emission significantly when the size of heat production is large. But the advantages of district heating system are very sensitive to the fuel mix and heat source.

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Ga doped ZnO Thin Films for Gas Sensor Application (Ga이 첨가된 ZnO 박막의 가스센서로의 응용 연구)

  • Hwang, Hyun-Suk;Yeo, Dong-Hun;Kim, Jong-Hee;Song, Joon-Tae
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.21 no.6
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    • pp.499-502
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    • 2008
  • In this work, Ga-doped ZnO (GZO) thin films for gas sensor application were deposited on low temperature co-fired ceramics (LTCC) substrates, by RF magnetron sputtering method. The LTCC substrate is one of promising materials for this application since it has many advantages (e.g., low cost production, high manufacturing yields and easy realizing 3D structure etc.). The LTCC substrates with thickness of $400\;{\mu}m$ were fabricated by laminating 12 green tapes which consist of alumina and glass particle in an organic binder. The structural properties of the fabricated GZO thin film with thickness of 50 nm is analyzed by X-ray diffraction method (XRD) and field emission scanning electron microscope (FESEM). The film shows good adhesion to the substrate. The GZO gas sensors are tested by gas measurement system and show fast response and recovery characteristics to $NO_x$ gas that is 27.2 and 27.9 sec, recpectively.

Preparation of equine blood typing reagents by isoimmunization (동종면역(同種免疫)에 의한 말항혈청(抗血淸)제조에 관한 연구)

  • Han, Bang-keun;Matsumoto, Hiroshi;Chang, Duk-gi
    • Korean Journal of Veterinary Research
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    • v.30 no.2
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    • pp.145-156
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    • 1990
  • This study was purposed to produce blood typing reagents for classifing Cheju horse's blood group factors. The blood typing reagents were prepared by immunization of sixteen pairs out of fourty eight heads of Cheju horses, and seventeen different blood typing reagents (anti-$A_1$, A', H, Z, $ZZ_2$, C, J, K, $P_1$, Q, R, S, $T_1$, $N_1$, $U_2$, X and $E_2$) were prepared from equine isoimmunization. The result for the reagent production and the variation of agglutinin and hemolysin titer are as follows: 1. Anti-K, R, S, $N_1$, $U_2$ and X acted exclusively as hemolysins whereas anti-J, $P_1$, $T_1$ and $E_2$ acted exclusively as agglutinins, however, Anti-$A_1$, A', H, Z, $ZZ_2$, C and Q reacted both as hemolysins and agglutinins. 2. Among the antibodies in most of the reagents reacted both as hemolysins and agglutinins, But anti-$A_1$, H, Z, $ZZ_2$ and Q elevated higher agglutin titers than hemolysin titers, Anti-A' and anti-C elevated higher hemolysin titers than agglutinin titers. 3. Complex antibody $A_1U_2$ was adsorbed $U_2$ and unified to $A_1$, while complex antibody X $N_1$ went through an adsorption process and produced simple antibody X and $N_1$, respectively. 4. In the hemolytic reaction, anti-K and anti-R showed the highest titer, In the agglutination reaction, anti-Z and anti-$ZZ_2$ showed the highest titer. 5. In the case of No.138~No.140 horse immunization combination and No.133~No.146 horse immunization combination, Although production of complex antibody $CE_2$ and $JP_1$ were expected, only anti-$E_2$ and anti-J were produced respectively. 6. The degree of elevation of antibody titer was varied by the blood types and by the types of donor and recipient combination. The fast elevating types, slow elevating types and types that never elevate the antibody titer were identified.

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A Study on NOx Reduction Mechanism in a Closed Vessel with Opposed Dual Pre-chambers (대향 부연소실이 있는 밀폐연소실 내의 $NO_x$ 저감기구에 대한 연구)

  • Kim, Jae-Heon;Lee, Soo-Gab;Jeung, In-Seuck
    • Journal of the Korean Society of Combustion
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    • v.2 no.1
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    • pp.17-27
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    • 1997
  • It is well known that NOx formation has a strong dependence on the maximum temperature and correspondingly with the maximum chamber pressure of a closed combustion system. However, in a case of impinging-jet-flame (IJF hereafter) combustion with opposed dual pre-chambers, low $NO_x$ formation with high pressure could be achieved, but its mechanism has not been clearly understood so far. In this study, a three-dimensional analysis is adopted to resolve time-variant local properties that might indicate the mechanism of IJF combustion. Numerical results are verified by comparing them with experiments. The IJF combustion in a vessel with no pre-chamber, with single pre-chamber, and with dual pre-chambers is studied. The orifice diameter and the volumetric ratio of pre-chamber are used as geometric parameters. The effects of main-chamber ignition delay time and combustion time of main-chamber, orifice exit velocity, orifice exit temperature, turbulent kinetic energy of main-chamber and spatial distribution of temperature in the latter stage of combustion are investigated. A longer main-chamber ignition delay and a shorter main-chamber combustion time suppress the formation of high temperature region with respect to mean temperature, which consequently results in less NO production.

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NOx Reduction Characteristics of Ship Power Generator Engine SCR Catalysts according to Cell Density Difference (선박 발전기관용 SCR 촉매의 셀 밀도차에 따른 NOx 저감 특성)

  • Kyung-Sun Lim;Myeong-Hwan Im
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.28 no.7
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    • pp.1209-1215
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    • 2022
  • The selective catalytic reduction (SCR) is known as a very efficient method to reduce nitrogen oxides (NOx) and the catalyst performs reduction from nitrogen oxides (NOx) to nitrogen (N2) and water vapor (H2O). The catalyst, which is one of the factors determining the performance of the nitrogen oxide (NOx) ruduction method, is known to increase catalyst efficiency as cell density increases. In this study, the reduction characteristics of nitrogen oxides (NOx) under various engine loads investigated. A 100CPSI(60Cell) catalysts was studied through a laboratory-sized simulating device that can simulate the exhaust gas conditions from the power generation engine installed in the training ship SEGERO. The effect of 100CPSI(60Cell) cell density was compared with that of 25.8CPSI(30Cell) cell density that already had NOx reduction data from the SCR manufacturing. The experimental catalysts were honeycomb type and its compositions and materials of V2O5-WO3-TiO2 were retained, with only change on cell density. As a result, the NOx concentration reduction rate from 100CPSI(60Cell) catalyst was 88.5%, and IMO specific NOx emission was 0.99g/kwh satisfying the IMO Tier III NOx emission requirement. The NOx concentration reduction rate from 25.8CPSI(30Cell) was 78%, and IMO specific NOx emission was 2.00g/kwh. Comparing the NOx concentration reduction rate and emission of 100CPSI(60Cell) and 25.8CPSI(30Cell) catalysts, notably, the NOx concentration reduction rate of 100CPSI(60Cell) catalyst was 10.5% higher and its IMO specific NOx emission was about twice less than that of the 25.8CPSI(30Cell) catalysts. Therefore, an efficient NOx reduction effect can be expected by increasing the cell density of catalysts. In other words, effects to production cost reduction, efficient arrangement of engine room and cargo space can be estimated from the reduced catalyst volume.

Effects of Transplanting Time and Vinyl-film Mulching Treatment on the Biomass Production of Artemisia annua L. in the Saemangeum Reclaimed Tidal Lands in Korea

  • Song, Jae-Do;Sohn, Yong-Man;Lee, Myung-Hi;Jeon, Geon-Yeong;Kim, Doo-Hwan;Park, Moo-Eon
    • Korean Journal of Soil Science and Fertilizer
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    • v.44 no.1
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    • pp.29-37
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    • 2011
  • The experiment was carried out to find the effects of transplanting time and vinyl-film mulching treatment on the growth of artemisia by randomized block design with three replications. The experiment site ($100{\times}130$ m) was temporally established in the south-eastern part of Saemangeum reclaimed tidal land (near Gwanghwal myun, Gimjae-gun, Jellabukdo). Artemisia plants had been partly suffered from salt injury, because soil salinities in some area during growing period had been measured higher than 10 dS $m^{-1}$. Growth of plant height and survival ratio of transplanted plants had been significantly correlated with soil salinity and then the regression equations between plant height (y) and soil EC (x) and between survival ratio (y) and soil EC (x) were expressed as y=-16.59ln(x)+43.852 and $y=0.6453x^2-17.566x+103.99$, respectively. It was concluded that early transplanting and vinyl mulching was more beneficial for biomass production of artemisia, because biomass was 6.41 times more in the early transplanting than in the late transplanting, and 2.63 times more in the vinyl-film mulching than in the no mulching treatment.

A Study on the Comparison of Emission Factor Method and CEMS (Continuous Emission Monitoring System) (배출계수법과 연속자동측정법에 의한 배출량 비교 연구)

  • Jang, Kee-Won;Lee, Ju-Hyoung;Jung, Sung-Woon;Kang, Kyoung-Hee;Hong, Ji-Hyung
    • Journal of Korean Society for Atmospheric Environment
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    • v.25 no.5
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    • pp.410-419
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    • 2009
  • Generally, air pollutant emission at workplace is estimated by two methods: indirect methods using emission factors and direct methods based on CEMS (Continuous Emission Monitoring System). CAPSS (Clean Air Policy Support System) is a representative indirect method and the national air pollutant database of Korea. However, characteristics of some workplaces may create a gap between CAPSS and CEMS data. For improving of emission data accuracy, emission data of CEMS (named CleanSYS) equipped at 138 target workplaces were compared with those of CAPSS. As a result, $SO_x$ and $PM_{10}$ emission levels obtained by CAPSS were lower than those of CleanSYS. $SO_x$ and $PM_{10}$emission ratios were 61.5% and 71.2% lower respectively, showing the biggest gaps. On the other hand, $NO_x$ emission of CAPSS was higher by 10.4%. $SO_x$ showed the biggest difference in 'Energy industry combustion' and $NO_x$ did in 'Production Process' within the SCC category. $PM_{10}$ presented a large gap in 'Manufacturing industry combustion.' The differences in $SO_x$ between the two systems occurred because some large-size facilities lack pollution controllers or efficient pollution controllers. Based on this study, CAPSS emission database of Korea will improve accuracy through adopting CEMS emission system, which enables more efficient national atmospheric policies and workplace management.

Synthesis of Iron-loaded Zeolites for Removal of Ammonium and Phosphate from Aqueous Solutions

  • Kim, Kwang Soo;Park, Jung O;Nam, Sang Chul
    • Environmental Engineering Research
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    • v.18 no.4
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    • pp.267-276
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    • 2013
  • This study presents a comparison of different protocols for the synthesis of iron-loaded zeolites, and the results of their application, as well as that of zeolite-A (Z-A), to the removal of ammonium and phosphate from aqueous media. Zeolites prepared by three methods were evaluated: iron-incorporated zeolites (IIZ), iron-exchanged zeolites (IEZ), and iron-calcined zeolites (ICZ). The optimal iron content for preparing of IIZ, as determined via scanning electron microscopy and X-ray photoelectron spectroscopy analyses, expressed as molar ratio of $SiO_2:Al_2O_3:Fe$, was below 0.05. Ammonia removal revealed that the iron-loaded zeolites have a higher removal capacity than that of Z-A due, not only to ion-exchange phenomena, but also via adsorption. Greater phosphate removal was achieved with IEZ than with ICZ; additionally, no sludge production was observed in this heterogeneous reaction, even though the coagulation process is generally accompanied by the production of a large amount of undesired chemical sludge. This study demonstrates that the developed synthetic iron-loaded zeolites can be applied as a heterogeneous nutrient-removal materials with no sludge production.

Desulfurization of Sulfur Compounds in City-gas using Metal Salt Impregnated Zeolite (금속이온이 담지 된 제올라이트를 이용한 도시가스 내 부취제 제거)

  • Song, Hirn-Ill;Ko, Chang Hyun;Kim, Jae Chang;Kim, Jong-Nam
    • Korean Chemical Engineering Research
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    • v.45 no.2
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    • pp.143-148
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    • 2007
  • In hydrogen production for fuel cell by reforming city-gas, sulfur compounds, odorant in city-gas, are detrimental to reforming catalyst and fuel cell electrodes. We prepared metal salt impregnated ${\beta}-zeolite(BEA)$ to remove sulfur compound in city-gas by adsorption. The sulfur breakthrough adsorption capacity was changed depending on the concentration and species of metal salt. $AgNO_3$ impregnated BEA showed the highest sulfur breakthrough capacity among adsorbents used in this experiment(41.1 mg/g). But metal salt impregnated BEA such as $Ni(NO_3)_2/BEA$, $Fe(NO_3_)_3/BEA$, $Co(NO_3)_2/BEA$ showed a certain amount of sulfur adsorption capacity comparable to $AgNO_3/BEA$. Adsorption temperature effect, desorption study, and x-ray photoelectron spectroscopy analysis revealed that the dominant interaction between metal impregnated adsorbent and sulfur compounds was not chemisorption but physisorption.

Effects of Three Feeding Systems on Production Performance, Rumen Fermentation and Rumen Digesta Particle Structure of Beef Cattle

  • Liu, Y.F.;Sun, F.F.;Wan, F.C.;Zhao, H.B.;Liu, X.M.;You, W.;Cheng, H.J.;Liu, G.F.;Tan, X.W.;Song, E.L.
    • Asian-Australasian Journal of Animal Sciences
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    • v.29 no.5
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    • pp.659-665
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    • 2016
  • The effects of three different feeding systems on beef cattle production performance, rumen fermentation, and rumen digesta particle structure were investigated by using 18 Limousin (steers) with a similar body weight ($575{\pm}10kg$) in a 80-d experiment. The animals were equally and randomly divided into three treatment groups, namely, total mixed ration group (cattle fed TMR), SI1 group (cattle fed concentrate firstly then roughage), and SI2 group (cattle fed roughage firstly then concentrate). The results showed that the average daily gain was significantly higher in cattle receiving TMR than in those receiving SI1 and SI2 (p<0.05). Consumption per kg weight gain of concentrate, silage, and combined net energy (NEmf) were significantly decreased when cattle received TMR, unlike when they received SI1 and SI2 (p<0.05), indicating that the feed efficiency of TMR was the highest. Blood urea nitrogen (BUN) was significantly decreased when cattle received TMR compared with that in cattle receiving SI1 (p<0.05), whereas there was no difference compared with that in cattle receiving SI2. Ammonia nitrogen concentration was significantly lower in cattle receiving TMR than in those receiving SI1 and SI2 (p<0.05). The rumen area of cattle that received TMR was significantly larger than that of cattle receiving SI1 (p<0.05), but there was no difference compared with that of cattle receiving SI2. Although there was no significant difference among the three feeding systems in rumen digesta particle distribution, the TMR group trended to have fewer large- and medium-sized particles and more small-sized particles than those in the SI1 and SI2 groups. In conclusion, cattle with dietary TMR showed increased weight gain and ruminal development and decreased BUN. This indicated that TMR feeding was more conducive toward improving the production performance and rumen fermentation of beef cattle.