• 한국대기환경학회지
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• 제27권5호
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• pp.504-522
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• 2011

Simulations of CMAQ with the High-order Decoupled Direct Method (HDDM) for a 2010 June episode are applied to estimate the influence of local and neighborhood emissions on ozone concentrations in the Kwang-Yang Bay (KYB) area. In order to examine ozone response to reductions in $NO_x$ and VOC emissions from KYB and Gyeongsang, ozone isopleths are generated with the first and second-order sensitivity coefficients from HDDM simulations at three sites; Taein, Samil, and Gwangmoo. Simulations show that reduction in KYB $NO_x$ may increase ozone over the sites. On the contrary, $NO_x$ reduction from Gyeongsang may decrease ozone at the sites when transport of ozone and its precursors from upwind Gyeongsang is potentially high. However, VOC reductions from KYB and Gyeongsang are favorable to lower ozone over KYB. The study implies that emission reductions for both local and neighboring areas are likely more effective to bring KYB to ozone attainment.

• 대한기계학회논문집B
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• 제30권9호
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• pp.842-849
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• 2006

An experimental study has been conducted to investigate the effects of a multi air-staged burner on NOx formation and heat transfer in a 15kW large-scale laboratory furnace adopted the reburning process. The reburn fuel as well as burnout air was injected from each nozzle attached at the wall of the cylindrical furnace. Fuel in both main burner and reburn nozzle was LPG (Liquefied Petroleum Gas). The paper reports the influences on NOx reduction of reburn fuel fraction in reburning zone. Temperature distribution inside the overall region as well as total heat flux at the wall of the furnace has been measured to examine the heat transfer characteristics due to the reburning process. For comparison, the reburning effects were examined for a combustor with two types of burner; a regular single staged burner and a multi-air staged burner. A gas analysis was also performed to evaluate an appropriate condition for NOx emission in a primary zone for the excess air ratio of 1.1. As a result, combustion efficiency expected to become more efficient due to the reduction of heat loss in burnout zone decrease when multi air-staged burner in furnace adopted reburning technology was used.

• 대한화학회지
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• 제30권2호
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• pp.207-215
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• 1986

본 연구는 대기중의 질소산화물($NO_x$)을 효율적으로 제거하기 위하여 기존의 방법을 개선한 것으로서, $NH_3$를 이용한 환원법을 개량하였다. 상대습도 60%에서 50 ppm의 $NO_x$는 1% hr-1의 분해율을 나타낸 반면 5배 이상의 $NH_3$를 첨가함으로써 50 ppm $NO_x$인 경우에는 6% $hr^{-1}$, 20ppm인 경우는 10% $hr^{-1}$의 제거율을 나타내었다. 그러나 실제 배기기체에서는 과량의 수분과 탄화수소나 일산화탄소같은 환원성 기체가 포함되고 미량의 금속이온들이 공존되므로 최고 15% $hr^{-1}$까지 $NO_x$의 제거가 촉진되었다. 또한 SO_2와 같은 산성기체의 공존은 분해율을 감소시켰다. 이 $NO_x$의 분해현상은 주로 계에 가해진 수증기의 응축으로 생긴 수막에 NO_x가 용해되는 동시에 염기성인 $NH_3$기체도 용해되어 이루어진 이들 이온들의 환원반응에 기인된다고 생각된다.

• 한국수소및신에너지학회논문집
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• 제21권6호
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• pp.519-525
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• 2010

Ethanol was used as reductant to remove $NO_x$ over Ag/$Al_2O_3$ catalyst via SCR from stationary emission source. Among the tested hydrocarbon reductants, ethanol showed highest de-$NO_x$ performance over the Ag/$Al_2O_3$ catalyst. De-$NO_x$ efficiency of about 83% was obtained in the condition of GHSV 20,000 $hr^{-1}$, $NO_x$ 200 ppm, CO 200 ppm, $O_2$ 13%, $H_2O$ 5% and mole ratio of ethanol/$NO_x$ = 2 between temperature of $300^{\circ}C$ and $400^{\circ}C$. While $SO_2$ presence in the $NO_x$ exhaust suppressed the catalytic activity, catalyst with acid (0.7% $H_2SO_4$) treatment of catalyst showed higher catalytic activity, where In-Situ DRIFT showed S presence over catalyst surface was increased after acid treatment of catalyst. From in-situ DRIFT and SCR results, it was concluded that sulfur presence over the surface of Ag/$Al_2O_3$ catalyst was the dominant factor to control the de-$NO_x$ reaction yield via HC-SCR from the exhausted gas including $SO_2$.

• 한국수소및신에너지학회논문집
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• 제19권6호
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• pp.474-481
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• 2008

수소 기관에서 역화없이 고성능과 저$NO_x$를 실현시키기 위하여 밸브 타이밍 변화에 따른 흡기관 분사식 수소 기관의 성능을 파악하고 가솔린의 경우와 비교하였다. 그 결과 흡기밸브 타이밍은 역화억제와 성능향상에 큰 영향을 미치는 것을 확인하였다. 흡기밸브타이밍의 진각은 역화를 억제하며 효율과 출력을 동시에 향상된다. 비록 흡기밸브 타이밍 변화에 의해 NOx는 증가하지만, 희박영역인 출 ${\Phi}=0.5$에서 현저히 감소된다. 또한 열효율은 ${\Phi}=0.5$ 토크는 ${\Phi}=1.0$에서 가장 높게 나타난다. 흡기밸브 타이밍을 $ATDC20^{\circ}$에서 TDC로 변화시켰을 때, ${\Phi}=1.0$에서 토크는 약 28% 증가되고, ${\Phi}=0.5$에서 효율은 약 7%향상된다.

• 한국대기환경학회:학술대회논문집
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• 한국대기환경학회 1999년도 추계학술대회 논문집
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• pp.209-210
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• 1999

오존 precursor인 NOx의 배출기준은 점차 강화되고 있고 NOx의 처리기술로는 선택적 촉매환원법 (Selective Catalytic Reduction; SCR)이 가장 널리 사용되고 있다. 국내 SCR 적용공정의 경우, 100% 수입에 의존하고 있어 support 촉매의 국산화가 절실히 요구되고있다. 이에 본 연구에서는 support로 섬유형 세라믹 필터를 사용하여 CuO, V$_2$O$_{5}$ 촉매를 담지시켜 NOx의 제거실험을 수행하였다.(중략)

• 한국세라믹학회지
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• 제43권4호
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• pp.224-229
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• 2006

Ag-Pd alloy nanoparticles were prepared by a chemical reduction method using hydrazine $(N_2H_4)$ as a reductant in $AgNO_3\;and\;Pd(NO_3)_2$ aqueous solutions. Characterization of these particles by X-ray powder diffraction revealed a bimetallic and crystalline silver-palladium alloy. The average size of the particles was influenced not by the reductant $(N_2H_4)$ concentration, but the concentration of the starting materials $(AgNO_3\;and\;Pd(NO_3)_2)$.

• 산업기술연구
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• 제19권
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• pp.331-341
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• 1999

We analyzed theoretically the removal efficiency and the particle growth inside the pulse corona discharge reactor to remove $NO_x$ and investigated the effects of process variables such as the NO and $NH_3$ input concentrations. Most of NO is converted into $NO_2$ and $HNO_3$ and the $HNO_3$ reacts with $NH_3$ to form the $NH_4NO_3$ particles. About 6.4% of NO is converted into $HNO_2$ which form the $NH_4NO_2$ particles by reaction with $NH_3$. Some of $NO_2$ follows the reaction pathway to form $NO_3$ and $N_2O_5$. The amount of particles formed inside the reactor is basically determined by the input $NH_3$ concentration. The ratio of NO to $NH_3$ affects the reactor length for particle formation significantly. The higher the input concentrations of NO and $NH_3$ are, the faster the particles grow.

• 한국안전학회지
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• 제14권1호
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• pp.73-77
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• 1999

In this study, $SO_2$ and $NO_2$ reduction have been investigated by using coil type plasma reactor. The experiments have been carried out changing discharge power, gas flow rate frequency and electrode style to obtain the decomposition rate. Decomposition rates of $SO_2$ and $NO_2$ were obtained 20~98% at gas flow rate 100ml/min~1,000ml/min and discharge power 5~25w respectively. The energy efficiency is very good at the high frequency power. The decomposition rate of $SO_2$ for 5kHz power supply is only 90%, but for 10kHz power supply is very high, more than 98% for 15w. The decomposition rate is increasing according to the residence time or the power consumption of the discharge. About 15W discharge power for 17$cm^2$ reactor is necessary to obtain the decomposition rate of $SO_2$ and $NO_2$ of more than 85% or 98%. From these experiments, the consumption power of the decomposition rate of 98% in 300ppm $NO_2$ gas in nitrogen gas proved to be 18W and 300ppm $SO_2$ gas to be 15w.

• 한국철도학회:학술대회논문집
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• 한국철도학회 2006년도 추계학술대회 논문집
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• pp.152-157
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• 2006

The air pollutant emission from the railroad diesel locomotive is still a significant environmental concern in many countries including Korea and Unites States. The emission characteristics of the railroad diesel locomotive were extensively studied in this study. Particulate matter (PM) and nitrogen oxides ($NO_x$) emitted from a large locomotive engine (2-cycle, 16-cylinder, and 3,000-horsepower) under various engine-rating conditions was analyzed with a scanning mobility particle sizer and a gas stack sampler by using a dilution tunnel. We could gain the emission values of 2.1 g/horsepower-hour for PM and 42.7 g/horsepower-hour for $NO_x$. We proposed the emission reduction goal of the railroad diesel locomotive for Korea in comparison with the regulation of United States.