• Journal of the Korean Society of Combustion
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• v.4 no.1
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• pp.27-38
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• 1999

We constructed a wire-cylinder type pulsed corona discharge system for $NO_x$ removal, which was operated in room temperature. A emission spectrometer was built with a boxcar averager and monochrometer equipped with photo-multiplier tube detector. The sensitivity of the emission spectrometer was greatly improved by synchronizing the emission spectrometer with pulsed corona discharge system using a triggered spark-gap switch. $N_2$ spectrum($c^3{\Pi}_u{\rightarrow}X^1{\Sigma}_g{^+}$) was measured in the range of 300 - 450 nm and oxidizing OH radical emission($A^2{\Sigma}^+{\rightarrow}X^2{\Pi}$) was measured in case $N_2$ was supplied with water bubbling. As wet gas composition of inlet $N_2$ supplied in the discharge system increased, the intensity of OH emission was increased and saturated at wet gas composition 50%. We also investigated additive effect of $C_2H_4,\;H_2O,\;H_2O_2$ on the intensity of OR emission and $NO/NO_2/NO_x$ reduction and analysed the related reaction mechanism in corona discharge process. $H_2O_2$ additive increased the intensity of OH emission and $NO/NO_x$ reduction.

• Proceedings of the Korea Air Pollution Research Association Conference
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• 2000.11a
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• pp.407-408
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• 2000

유전체 장벽 방전 반응기 (Dielectric Barrier Discharge (DBD) Reactor)를 이용한 비열 플라즈마(Non-thermal plasma) 공정에서 NO 제거 특성을 실험적으로 연구하였다. 질소 분위기에서 전자에 의한 NO 의 제거는 $N_2$ + e $\longrightarrow$ N + N + e 반응에 의한 질소의 전자충돌해리 (electron-impact dissociation)와 이 반응에 의하여 생성된 질소원자에 의한 NO 의 환원반응 N + NO $\longrightarrow$ $N_2$ + O 으로 설명될 수 있으며, 이로 인하여 $O_2$ 나 $H_2O$ 의 첨가에 따른 부산물(O, $O_3$, OH 등)에 의한 산화반응이 주로 일어나는 경우 (XO + NO $\longrightarrow$ X + NO$_2$) 와는 달리 NO 제거에 소모된 에너지를 평가하기에 용이한 장점이 있다(Penetrante et al., 1995). (중략)

• Geosystem Engineering
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• v.21 no.5
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• pp.243-250
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• 2018

This study investigated nitrite ($NO_2{^-}$) accumulation due to FA (Free Ammonia: $NH_3$) inhibition in an anaerobic-aerobic-anoxic (AOA) process reactor to mainly treat wastewater containing 302-610 mg/L of $NH_3/NH_4{^+}-N$. Based on an experimental operation focusing on the nitrification, it was observed that $NO_2{^-}$ was accumulated in the aerobic nitrification zone as pH increased, due to inhibition of $NO_2{^-}$ conversion to $NO_3{^-}$ by FA. This result implied FA inhibition to NOB ($NO_2{^-}$-Oxidizing Bacteria) for converting $NO_2{^-}$ to $NO_3{^-}$. The objective of this study is to develop a feasible monitoring procedure for early detection of the FA inhibition toward $NO_2{^-}$ accumulation and poor nitrification. Thus, in order to rapidly assess FA concentrations, an $NH_3$ probe was utilized to measure $NH_3$ concentrations together with applying a simple model prediction using the measured $NH_4{^+}$ concentrations, the Henry's law constant of $NH_3$ and measured pH. The predictive model $NH_3$ levels were verified by a good correlation (89%) with the corresponding measured data, but the model prediction underestimated FA concentrations at less than 7.4 and a little overestimated at pH above 7.5. Interestingly, accumulated $NO_2{^-}$ levels were roughly correlated with FA levels that were observed at delayed time points. This reflects the detected FA levels can be good indicators of $NO_2{^-}$ levels with some delayed time. $NO_2{^-}$ accumulation started at measured FA concentrations of higher than approximately 3 mg/L and ceased below that FA level.

• Transactions of the Korean Society of Automotive Engineers
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• v.16 no.3
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• pp.179-187
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• 2008

A mathematical modeling of $NO_x$ reduction in $NH_3$-SCR process is conducted. The present deterministic model solves one-dimensional conservation equations of mass and species concentrations for channel flows and the catalytic reaction. NO and NO_2$ reactions by the vanadium catalyst in the presence of $NH_3$ are calculated with the rate expressions of Langmuir-Hinshelwood scheme. The modeling was validated with extensive empirical data regarding $NO_x$ reduction efficiency. Analysis of De-$NO_x$ sensitivity conducted with regard to oxygen and water yielded highly accurate prediction over a wide range of $NO_2/NO_x$ ratios from 0 to 1 in a temperature range of $200^{\circ}C{\sim}550^{\circ}C$. The $NO_x$ reduction largely depends on $NO_2/NO_x$ ratio at temperatures lower than $300^{\circ}C$. NO reduction efficiency is significantly augmented with increasing in $NH_3$/NO ratio at higher temperatures, whereas rather insensitive to the $NH_3$/NO ratio at lower temperatures.

• Journal of ILASS-Korea
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• v.6 no.3
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• pp.1-7
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• 2001

In this study, quantitative measurement of nitric oxide concentration distributions visualization were investigated in the laminar $CH_4/O_2N_2$ nixed flame by Planar laser-induced fluorescence(PLIF). The NO A-X (0,0) vibrational band around 226nm was excited using a XeCl excimer-pumped dye laser. Selecting an appropriate NO transition minimizes interference from Rayleigh scattering and $O_2$ fluorescence. The measurements were taken in $CH_4/O_2N_2$ premixed flame with equivalence ratios varying from $1.0{\sim}1.6$, and a fixed flow rate of 3slpm. NO was found to produce primarily between an inner premixed and an outer nonpremixed flame front, and total NO concentration is raised when equivalence ratios increase. These results suggest that prompt NO is likely to contribute to MO formation in $CH_4/O_2N_2$ premixed flame. Furthermore, this trend was well matched with previous works.

• Applied Chemistry for Engineering
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• v.17 no.6
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• pp.653-657
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• 2006

The adsorption properties for $NO_{2}$ by hybrid ion exchange fiber with resins were investigated. The adsorption of $NO_{2}$ was increased with increasing of adsorption time and the initial concentration. At the initial $NO_{2}$ concentration of 900 ppm, approximately 40% of initial $NO_{2}$ was adsorbed around 20 min. And the adsorption of $NO_{2}$ was decreased with increasing of flow rate from 20 to 40 L/min. The maximum adsorbed amount of initial $NO_{2}$ was 45% at the flow rate of 10 L/min. The amount of adsorption was increased with increasing the water content.

• 한국연소학회:학술대회논문집
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• 2000.12a
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• pp.33-46
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• 2000

In the present study, a systematic chemical kinetic calculations were made to investigate the augmentation of NO-$NO_2$ conversion due to the addition of various hydrocarbons (methane, ethylene, ethane, propene, propane) in the nonthermal plasma treatment. It is included in the present conclusion that the reaction between hydrocarbon and oxygen radicals induced by electron collision, is believed to be a primarily process for triggering the overall NO oxidation and the eventual NOx reduction. Upon the completion of the initiating step, various radicals (OH, $NO_2$ etc.) successively produced by hydrocarbon decomposition form the primary path of NO-$NO_2$ conversion. When the initiating step is not activated, hydrocarbon consumption rate appeared to be very low, thereby the targeted level of NO conversion can only be achieved by the addition of more input energy. Present study showed ethylene and propene to have higher affinity with 0 radical under all conditions, thereby both of these hydrocarbons show very fast and efficient NO-$NO_2$ oxidation. It was also shown that propene is superior to ethylene in the aspect of NOx removal.

• Journal of Industrial Technology
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• v.19
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• pp.331-341
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• 1999

We analyzed theoretically the removal efficiency and the particle growth inside the pulse corona discharge reactor to remove $NO_x$ and investigated the effects of process variables such as the NO and $NH_3$ input concentrations. Most of NO is converted into $NO_2$ and $HNO_3$ and the $HNO_3$ reacts with $NH_3$ to form the $NH_4NO_3$ particles. About 6.4% of NO is converted into $HNO_2$ which form the $NH_4NO_2$ particles by reaction with $NH_3$. Some of $NO_2$ follows the reaction pathway to form $NO_3$ and $N_2O_5$. The amount of particles formed inside the reactor is basically determined by the input $NH_3$ concentration. The ratio of NO to $NH_3$ affects the reactor length for particle formation significantly. The higher the input concentrations of NO and $NH_3$ are, the faster the particles grow.

• KSBB Journal
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• v.25 no.1
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• pp.62-66
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• 2010

This study was carried out to get phosphorus uptake rate in aerobic condition with nitrate and nitrite. Nitrate and nitrite inhibited phosphorus accumulating organisms' (PAOs') luxury uptake in aerobic condition. Nitrite awfully decreased the phosphorus uptake rate in aerobic condition. At the influent of 10 mg ${NO_3}^-$-NL, the phosphorus uptake was decreased to 52% comparing that at no influent of nitrate. And at the influent of 10 mg ${NO_2}^-$-NL, the phosphorus uptake was decreased to 28% comparing that at no influent of nitrite. At the influent of 20 mg ${NO_3}^-$-NL, nitrite and nitrate were co-existed and the phosphorus uptake rate was decreased to 16% comparing that at no influent of nitrite and nitrate. Also, the denitrification was occurred by denitrifying glycogen accumulating organisms (DGAOs)/denitrifying phosphorus accumulating organisms (OPAOs) in spite of aerobic condition, and the phosphorus uptake rate was increased by the decrease of influent nitrate concentration at the aerobic condition. The inflection point in the phosphorus uptake rate was shown at the nitrite concentration of 1.5~2 mg/L.

• Journal of the Korean Ceramic Society
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• v.39 no.10
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• pp.988-993
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• 2002

Electrochemical cells for decomposing $NO_x$ were fabricated using a hydrothermally synthesized lanthanum stannate pyrochlore catalyst. Thick film of the catalyst on the YSZ electrolyte disk was produced by screen-printing a paste consisted of $La_2Sn_2O_7$ and YSZ powders. Direct current was applied to the electrochemical cell to promote an electrochemical catalytic decomposition of $NO_x$. $NO_x$ decomposition behavior of the rectant gas mixture ($NO_x$ 0.1%, $O_2$ 2%) was investigated at 700${\circ}C$ under atmosphere pressure using on-line gas chromatography and $NO_x$ analyzer. It was observed that microstructure of the catalyst layer significantly influences the electrocatalystic decomposition of $NO_x$.