• Title/Summary/Keyword: $NO_2$ gas sensor

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Synthesis and Low-concentration (50 ppm) NO2 Sensing Properties of Bare and ZnO (n) Decorated TeO2 (p) Nanowires (ZnO가 첨가된 TeO2 나노와이어의 합성 및 저농도(50 ppm) 이산화질소 가스 센싱 특성)

  • Yu, Dong Jae;Shin, Ka Yoon;Oum, Wansik;Kang, Suk Woo;Kim, Eun Bi;Kim, Hyeong Min;Kim, Hyoun Woo
    • Korean Journal of Materials Research
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    • v.32 no.10
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    • pp.435-441
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    • 2022
  • We report the synthesis and gas sensing properties of bare and ZnO decorated TeO2 nanowires (NWs). A catalyst assisted-vapor-liquid-solid (VLS) growth method was used to synthesize TeO2 NWs and ZnO decoration was performed using an Au-catalyst assisted-VLS growth method followed by a subsequent heat treatment. Structural and morphological analyses using X-ray diffraction (XRD) and scanning/transmission electron microscopies, respectively, demonstrated the formation of bare and ZnO decorated TeO2 NWs with desired phase and morphology. NO2 gas sensing studies were performed at different temperatures ranging from 50 to 400 ℃ towards 50 ppm NO2 gas. The results obtained showed that both sensors had their best optimal sensing temperature at 350 ℃, while ZnO decorated TeO2 NWs sensor showed much better sensitivity towards NO2 relative to a bare TeO2 NWs gas sensor. The reason for the enhanced sensing performance of the ZnO decorated TeO2 NWs sensor was attributed to the formation of ZnO (n)/ TeO2 (p) heterojunctions and the high intrinsic gas sensing properties of ZnO.

[ $NO_2$ ] Gas Sensing Characteristics of Carbon Nanotubes (탄소 나노튜브를 이용한 이산화질소 감지 센서의 특성)

  • Lee R. Y.
    • Journal of the Microelectronics and Packaging Society
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    • v.12 no.3 s.36
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    • pp.227-233
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    • 2005
  • Carbon nanotubes (CNT) which were grown, on the alumina substrate with a pair of comb-type Au electrodes, by plasma enhanced chemical vapor deposition have been investigated for $NO_2$ gas sensor. The electrical resistance of CNT film decreased with temperature, indicating a semiconductor type of CNT, and also the resistance of CNT sensor decreased with increasing $NO_2$ concentration. Upon exposure to $NO_2$ gas, the electrical resistance of CNT film sensor rapidly decreased within 3 minutes, and then showed a constant value after $20\~30$ minutes. It is found that the sensitivity of CNT sensor has been improved by air oxidation. The CNT sensor oxidized at $450^{\circ}C$ for 30 minutes showed higher sensitivity value than that without oxidation by $27\%$, even for a low 250 ppb $NO_2$ concentration at operating temperature of $200^{\circ}C$. But it needs a recovery time more than 20 minutes for reuse after detection of $NO_2$ gas.

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NDIR Multi-Gas Measurement System for Air Quality based on Wireless Sensor Network (무선센서네트워크 기반 공기질 측정을 위한 비분산적외선 복합가스측정시스템)

  • Paik, Seung Hyun;Lee, Jun Yeong;Jung, Sang Woo;Park, Hong Bae
    • IEMEK Journal of Embedded Systems and Applications
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    • v.11 no.5
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    • pp.299-304
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    • 2016
  • As public interest in air quality and environment problem is increasing, many researches are being carried out the gas measurement system. Especially, Non-dispersive infrared (NDIR) measurements using Beer-Lambert gas sensing principle with very high selectivity and long life time are noted for reliable method. It is possible to detect various gases such as carbon dioxide (CO2), carbon monoxide (CO), and nitrogen dioxide (NO2), but many researches are mostly concentrated on CO2 sensor. The multi-gas measuring instrument is high price and unwieldy, therefore it is not suitable for wide area required numerous instrument. So we study the NDIR multi-gas measurement system for air quality based on wireless sensor network, and experiment the realized measurement system.

$NO_2$ Gas Sensor Utilizing Pt-$WO_3-Si_3N_4-SiO_2$-Si-Al Capacitor (Pt-$WO_3-Si_3N_4-SiO_2$-Si-Al 캐패시터를 이용한 $NO_2$ 가스 센서)

  • 김창교;이주헌;이영환;유광수;김영호
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.11a
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    • pp.105-108
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    • 1998
  • Pt-WO$_3$-Si$_3$N$_4$-SiO$_2$-Si-Al 캐패시터를 이용한 NO$_2$ 가스 센서를 개발하였다. 표준 실리콘 MNOS구조에 촉매 게이트로 Pt와 가스 흡착층으로 WO$_3$를 이용함으로서 전통적인 세라믹 가스 센서보다 낮은 온도에서 NO$_2$ 가스를 감지할 수 있었다. 은도 변화와 NO$_2$ 가스 농도의 변화에 따라서 디바이스의 NO$_2$ 가스 감도를 조사하였다. Pt-WO$_3$ 계면에서 NO$_2$ 이온농도의 변화에 기초로 한 가스 감지 모델을 제시하였다. 제시된 가스 감지 모델을 계면에서의 가스 반응 속도론에 의하여 분석함으로서 확인하였다.

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Failure Case Studies of Sensors for Electronic Controlled Engine in LPG Vehicle (LPG 자동차에서 전자제어엔진용 센서의 고장사례에 관한 연구)

  • Kim, Chung-Kyun;Lee, Il-Kwon
    • Journal of the Korean Institute of Gas
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    • v.14 no.4
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    • pp.56-62
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    • 2010
  • The purpose of this paper analyzes and investigates the failure case studies of electronic control sensors for a LP gas engine. The malfunction of crank angle sensor, which controls a fuel injection volume of LP gas, displays an irregular and non-uniform pulse wave form. The pulse form, which is related to the noise of the crank angle sensor, displays at the rectangular peak with a saw-toothed shape and is intermittently generated with a level of 2.46V noise signal. The malfunction of No. 1 TDC sensor in which is caused from the internal disorder affects to the reduction of engine power and engine stop suddenly. If the malfunction of oxygen sensor is occurred due to a wiring problem of a sensor connector, the LP gas vehicle may produce a shaking and disharmony of an engine because of no signal supply from the oxygen sensor. The air cleaner replica produces the clogging of continuous supply of fresh air. This may cause the retardation of vehicle acceleration and engine disharmony intermittently.

A Study of Thermal Performances for Micro Gas Sensor (마이크로 가스센서의 열적 성능에 관한 연구)

  • Joo Young-Cheol;Kim Chang-Kyo
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.30 no.6 s.249
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    • pp.531-537
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    • 2006
  • A lever type $NO_2$ micro gas sensor was fabricated by MEMS technology. In order to heat up the gas sensing material to a target temperature, a micro heater was built on the gas sensor. The sensing material laid on the heater and electrodes and did not contact with the silicon base to minimize the heat loss to the silicon base. The electric power to heat up the gas sensor to a target temperature was measured. The temperature distribution of micro gas sensor was analyzed by a CFD program. The predicted electric power of micro heater to heat up the sensing material to the target temperature showed a good agreement with the measured data. The design of micro gas sensor could be modified to show more uniform temperature distribution and to consume less electric power by optimizing the layout of micro heater and electrodes.

Preparation of Gas Sensor from Pitch-based Activated Carbon Fibers and Its Toxic Gas Sensing Characteristics (피치계 활성탄소섬유기반 가스센서 제조 및 유해가스 감응 특성)

  • Kim, Min Il;Lee, Young-Seak
    • Applied Chemistry for Engineering
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    • v.25 no.2
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    • pp.193-197
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    • 2014
  • The electrode for gas sensor was prepared by using pitch-based activated carbon fibers and polyvinyl alcohol (PVA) to investigate the toxic gas sensing characteristics. The physicochemical properties of activated carbon fibers electrode for gas sensor were analyzed with SEM and BET. Toxic gases sensing property of the electrode was also identified by different toxic gases such as $NH_3$, NO and $CO_2$. The specific surface area of activated carbon fibers electrode for gas sensor was decreased by 33% owing to PVA used as a binder compared with the activated carbon fibers. However, its pore size distribution of the ACF electrode was not greatly influenced by PVA. The activated carbon fibers electrode for gas sensor responded to toxic gases by electron hopping unlike semiconductor based gas sensors. In this study, activated carbon fibers electrode was decreased to 7.5% in resistance for the NH3 gas of the 100 ppm concentration and its $NH_3$ gas sensing property was confirmed the most excellent compared with other toxic gases.

NO Gas Sensing Properties of ZnO-SWCNT Composites (산화아연-단일벽탄소나노튜브복합체의 일산화질소 감지 특성)

  • Jang, Dong-Mi;Ahn, Se-Yong;Jung, Hyuck;Kim, Do-Jin
    • Korean Journal of Materials Research
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    • v.20 no.11
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    • pp.623-627
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    • 2010
  • Semiconducting metal oxides have been frequently used as gas sensing materials. While zinc oxide is a popular material for such applications, structures such as nanowires, nanorods and nanotubes, due to their large surface area, are natural candidates for use as gas sensors of higher sensitivity. The compound ZnO has been studied, due to its chemical and thermal stability, for use as an n-type semiconducting gas sensor. ZnO has a large exciton binding energy and a large bandgap energy at room temperature. Also, ZnO is sensitive to toxic and combustible gases. The NO gas properties of zinc oxide-single wall carbon nanotube (ZnO-SWCNT) composites were investigated. Fabrication includes the deposition of porous SWCNTs on thermally oxidized $SiO_2$ substrates followed by sputter deposition of Zn and thermal oxidation at $400^{\circ}C$ in oxygen. The Zn films were controlled to 50 nm thicknesses. The effects of microstructure and gas sensing properties were studied for process optimization through comparison of ZnO-SWCNT composites with ZnO film. The basic sensor response behavior to 10 ppm NO gas were checked at different operation temperatures in the range of $150-300^{\circ}C$. The highest sensor responses were observed at $300^{\circ}C$ in ZnO film and $250^{\circ}C$ in ZnO-SWCNT composites. The ZnO-SWCNT composite sensor showed a sensor response (~1300%) five times higher than that of pure ZnO thin film sensors at an operation temperature of $250^{\circ}C$.

Evaluation of Metal Oxide Semiconductor and Electrochemical Gas Sensor Array Characterization for Measuring Wastewater Odor (폐수의 악취측정을 위한 금속산화물 반도체 및 전기화학식 가스센서 어레이 특성 평가)

  • Yim, Bongbeen;Lee, Seok-Jun;Kim, Sun-Tae
    • Journal of Sensor Science and Technology
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    • v.24 no.1
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    • pp.29-34
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    • 2015
  • This study aimed to evaluate the characterization of a metal oxide semiconductor and electrochemical gas sensor array for measuring wastewater odor. The sensitivity of all gas sensors observed in sampling method by stripping was 6.7 to 20.6 times higher than that by no stripping, except sensor D (electrochemical gas sensor). The average reduction ratio of sensor signal as a function of initial dilution rate of wastewater was in the order of food plant > food waste reutilization facility > plating plant. The sensitivity of gas sensors was dependent on both the type of wastewater and the dilution rate. The sensor signals observed by the gas sensor array were correlated with the dilution factor (OU) calculated by the air dilution sensory test with several wastewater ($r^2=0.920{\sim}0.997$), except the sensor signals of sensor D measured in the plating plant wastewater. It seems likely that the gas sensor array plays a role in the evaluation of odor in wastewater and is useful tool for on-site odor monitoring in the wastewater facilities.