• Title/Summary/Keyword: $H_T$

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The ab Initio Quantum Mechanical Investigation for the Weakly Bound $H^+_{2n+1}$(n=1-6) Complexes (약한 결합을 갖는 $H^+_{2n+1}$(n=1-6) complex들에 대한 순 이론 양자역학적 연구)

  • In, Eun Jeong;Seo, Hyeon Il;Kim, Seung Jun
    • Journal of the Korean Chemical Society
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    • v.45 no.5
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    • pp.401-412
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    • 2001
  • The geometrical parameters, vibrational frequencies, and dissociation energies for $H_{2n+1}^+$ (n=1~6) clusters have been investigated using high level ab initio quantum mechanical techniques with large basis sets. The equilibrium geometries have been optimized at the self-consistent field (SCF), the single and double excitation configuration interaction (CISD), the coupled cluster with single and double excitation (CCSD), and the CCSD with connected triple excitations [CCSD(T)] levels of theory. The highest levels of theory employed in this study are TZ2P+d CCSD(T) up to $H^+_g$ and TZ2P CCSD(T) for $H_{11}^+$ and $H_{13}^+$. Harmonic vibrational frequencies are also determined at the SCF level of theory with various basis sets and confirm that all the optimized geometries are true minima. The dissociation energies, $D_e$, for $H_{2n+1}^+$ (n=26) have been predicted using energy differences at each optimized geometry and zero-point vibrational energies(ZPVEs) have been considered to compare with experimental dissociation energies, $D_0$.

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Effects of Caprylic Acid and Cyclodextrin Complex on In vitro Fermentation Characteristics and Methane Production (Caprylic Acid와 Cyclodextrin 복합물이 In vitro 반추위 발효성상 및 메탄 생성에 미치는 영향)

  • Kim, K.H.;Seol, Y.J.;Lee, S.S.;Oh, Y.G.;Nam, I.S.;Kim, D.H.;Choi, C.W.
    • Journal of Animal Science and Technology
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    • v.49 no.5
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    • pp.657-666
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    • 2007
  • This study was conducted to evaluate the effects of dietary addition of caprylic acid(CA)-cyclodextrin (CD) complex on in vitro fermentation characteristics, total gas and methane production. Experiment was done with six treatment groups; 1) no CA-CD complex(control), 2) CA 20 mg(T1), 3) CD 830 mg(T2), 4) CA-CD complex 425 mg(T3), CA-CD complex 850mg(T4), CA-CD complex 1,700 mg(T5). Ruminal pH, ammonia and total VFA concentrations of T2, T3, T4 and T5 were lower(P<0.05) than those of control and T1 for the 12h incubation. The increase in molar percentage of propionate was observed in T4 and T5 compared with control and T2 for the 8h incubation(P<0.05), however, the ratio of acetate to propionate was unchanged in all treatments. Total gas of T1 was lower than that of control, but T2, T3, T4 and T5 were higher compared with control for 12h incubation(P<0.05). If the methane ratio (as %) to total gas for all treatments was compared, T3, T4 and T5(CA-CD supplemented groups) averaged 2.7% whereas control, T1 and T2 showed 3.4, 2.8 and 5.1%, respectively. Therefore, according to these results, it might be concluded that supplementation of CA-CD complex could reduce methane production without disrupting ruminal fermentation.

Middle distillate production by the hydrocracking of F-T wax (F-T wax의 수소첨가분해반응에 의한 middle distillate 제조)

  • Jeong, Heon-Do;Jung, Heon
    • 한국신재생에너지학회:학술대회논문집
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    • 2009.06a
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    • pp.873-875
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    • 2009
  • Middle distillate was produced by the hydrocracking of F-T wax on the zeolite catalysts. Novel metal loaded zeolite catalysts had good performance for hydrocracking of F-T wax. 2 wt.% Platinum loaded H-Y zeolite catalyst showed the highest selectivity of middle distillate and conversion of F-T wax. H-Y zeolite had more strong acidity site and large pore than that of another zeolite catalyst. So, H-Y zeolilte catalyst showed the best activity for hydrocracking of F-T wax.

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Effect of Full-Fat Flax, $\alpha$-Tocopherol and Selenium on Phagocytes Chemiluminescence of Broiler Chickens (아마종실과 $\alpha$-Tocopherol, 셀레늄 급여가 육계 혈액의 탐식세포로부터 생성되는 $O_{2}$-와 $H_{2}$ $O_{2}$ 에 의해 유도된 화학발광(chemiluminescence) 생성)

  • 안종남;채현석;김동운;권명상;박병성
    • Korean Journal of Poultry Science
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    • v.28 no.3
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    • pp.239-244
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    • 2001
  • To examine the effects of feed additives on the expression of Perpheral blood cell surface molecules, phagocytosis and antigen specific antibody formation, broilers were randomly assigned to T$_1$, T$_2$, T$_3$, and T$_4$ groups. T$_1$ group was fed diet without any additives for 13 weeks, T$_2$ was fed diet with full fat flax, T$_3$ was fed diet with full fat flax containing $\alpha$-tocopherol, and T$_4$ was fed diet with full-fat flax containing $\alpha$-tocopherol and selenium. Since 5 weeks feeding the data were examined by luminometer. After 2 weeks adminstration of different feeding, although all treated groups (T$_2$, T$_3$, and T$_4$,) showed slightly increased chemiluminescence (CL) responses than T$_1$, this result was not significant. After 4 weeks feeding there was no significant increase of CL in the Phagocytes like neutrophils and macrophages of T$_2$ group compared to T$_1$. But phagocytes from T$_3$ and T$_4$ group showed in creased $O_2$- (6%, 18% respectively) as well as $H_2O$$_2$ (9.5% and 10.9%, respectively) induced CL responses. After 8 weeks feeding there was more than 50% increase $O_2$- induced CL in T$_3$ and T$_4$ group, but $H_2O$$_2$ induced CL responses in T$_3$ and T$_4$ group was slightly increased (6.6% and 9.3%, respectively).

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Effects of Nitrogen Fertilization on Forage Production and Nutritive Nalue of Geukdong 6, Teosinte Hybrid [Zea mays L. subsp. mexicana (Schrad.) H. H. Iltis]

  • Wang, Chengyu;Lee, Sang Moo
    • Journal of The Korean Society of Grassland and Forage Science
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    • v.40 no.1
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    • pp.37-43
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    • 2020
  • This study was conducted to evaluate the effects of different nitrogen levels on the yield and nutrient quality of a newly developed domestic hybrid of Teosinte, Geukdong 6〔Zea mays L. subsp. mexicana (Schrad.) H. H. Iltis〕. The field experiment was conducted in a randomized block design with three replicates and consisted of four nitrogen (N) application rates, T1 (200 kg/ha), T2 (300 kg/ha), T3 (400 kg/ha), and T4 (500 kg/ha). No differences were found in plant length, leaf length, leaf width, leaf number, dead leaves, stem hardness, tiller number, and fresh yield (p>0.05). The T3 showed significantly greater dry matter yield at harvest (heading stage) compared to the other treatments (p<0.05). The crude protein content of T4 (10.49%) was higher than those of T1 and T2 (p<0.05). However, there was no significant difference between T4 (10.49%) and T3 (9.63%). The effects on crude fat, crude ash, neutral detergent fiber (NDF), acid detergent fiber (ADF), and crude fiber were not significant (p>0.05). The sugar content was higher in the T2 treatment than the other treatments (p<0.05). For Ca, T3 showed significantly greater content (p<0.05). However, no significant effects were found in the contents of Cu, Fe, K, Mg, Mn, Mo, and Zn (p>0.05). Na content was higher in order of T2 > T4 > T3 > T1 (p<0.05). Total mineral contents were not significantly different among the treatments (p>0.05). Given these results, we recommend the amount of nitrogen fertilization necessary for "Geukdong 6" to be around 400 kg per ha (T3), when considering, high fresh yield, dry matter yield, number of leaves and content of crude protein.

An Implementation of H.283 Remote Device Control in H.323 (H.323에서 운용되는 H.283 원격기기제어의 구현)

  • 성동수;이건배
    • Journal of Korea Multimedia Society
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    • v.5 no.3
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    • pp.239-248
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    • 2002
  • International Standard Organizations such as ITU(International Telecommunication Union) and IETF (Internet Engineering Task Force) are proceeding standardization for various applications and protocols to provide video-conference and multimedia conference services on a variety of networks. Remote device control among these protocols is provided with various capabilities as well as device control to multimedia conference. This protocol for remote device control is standardizing as H.282 recommendation which is specified as core service for the configuration and control of remote device to multimedia conference. The H.282 recommendation does not specify the use of a particular transport protocol. That is, T.120 multimedia conference uses T.136 and H.323 video conference uses H.283 for the transport of H.282 protocol. The introduced system in this paper is based on H.282 and is implemented to be capable of remote device control within the framework of H.323 using H.283. Also, it is shown that a variety of services in the specification of the standard are satisfied through experiments.

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Homolytic Reactions of Isonitriles (이소니트릴의 자유라디칼반응)

  • Sung Soo Kim
    • Journal of the Korean Chemical Society
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    • v.24 no.3
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    • pp.250-258
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    • 1980
  • Various radicals may add to isonitriles to give imidoyl radcals RN=CR'. This may be also generated via abstraction of imidoyl hydrogen from imine in the following manner: RN=CR' + R"${\cdot}{\rightarrow}$ RN=CR' + R"-H Imidoyl radicals would be stabilized via two pathways, ${\beta}$-cleavage and atom transfer reactions. ${\beta}$-Cleavage may occur in two directions depending upon structure of the radicals. Cyanide transfer and the "so-called" normal ${\beta}$-cleavage are the two modes of ${\beta}$-cleavage. Addition of t-butoxy radical to t-butyl isocyanide 7 generates an imidoyl radical t-Bu-N=C-O-Bu-t, which undergoes ${\beta}$-cleavage to give t-butyl isocyanate and t-butyl radical. Addition of phenyl radical to 7 forms the intermediate radical t-Bu-N=$C-C_6H_5$, which decomposes to give benzonitrile and t-butyl radical. The t-butyl radical generated from the ${\beta}$-cleavage adds to 7 giving the radical t-Bu-N=C-Bu-t, which cleaves only to pivalonitrile and t-butyl radical, inducing radical chain isomerization. Trimethylsilyl radical adds to 7 to give the intermediate t-Bu-N=$C-Si(CH_3)_3$, which collapses to $(CH_3)_3$SiCN and a t-butyl radical.

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RESULTS OF CERTAIN LOCAL COHOMOLOGY MODULES

  • Mafi, Amir;Talemi, Atiyeh Pour Eshmanan
    • Bulletin of the Korean Mathematical Society
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    • v.51 no.3
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    • pp.653-657
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    • 2014
  • Let R be a commutative Noetherian ring, I and J two ideals of R, and M a finitely generated R-module. We prove that $$Ext^i{_R}(R/I,H^t{_{I,J}}(M))$$ is finitely generated for i = 0, 1 where t=inf{$i{\in}\mathbb{N}_0:H^2{_{I,J}}(M)$ is not finitely generated}. Also, we prove that $H^i{_{I+J}}(H^t{_{I,J}}(M))$ is Artinian when dim(R/I + J) = 0 and i = 0, 1.

A REMARK ON SOME INEQUALITIES FOR THE SCHATTEN p-NORM

  • HEDAYATIAN, K.;BAHMANI, F.
    • Honam Mathematical Journal
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    • v.24 no.1
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    • pp.9-23
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    • 2002
  • For a closed densely defined linear operator T on a Hilbert space H, let ${\prod}$ denote the function which corresponds to T, the orthogonal projection from $H{\oplus}H$ onto the graph of T. We extend some ordinary norm ineqralites comparing ${\parallel}{\Pi}(A)-{\Pi}(B){\parallel}$ and ${\parallel}A-B{\parallel}$ to the Schatten p-norm where A and B are bounded operators on H.

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