• Title/Summary/Keyword: $H_2PO_4^-$

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A Comparative Study on the Effect of Fire Retardancy of the Plywood Treated by Ammonium Sulphate and Monoammonium Phosphate (황산암모늄과 제 1 암모늄처리(處理) 합판(合板)의 내화효과에 관(關)한 비교연구(比較硏究))

  • Lee, Phil-Woo;Kim, Cheol-San
    • Journal of the Korean Wood Science and Technology
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    • v.11 no.3
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    • pp.23-30
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    • 1983
  • This experiment was carried out for diminishing the material loss and the damage of human life due to the fire disaster by treating plywood with fire retardant chemical solution. At this study, we observed and measured chemical retention, burning point, maximum flame length, flame exausted time, carbonized area, and weight loss of plywood treated by each solution of ammonium sulphate [$(NH_4)_2SO_4$] and monoammonium phosphate [$NH_4H_2PO_4$]. Obtained results at the study may be summarized as follows: 1. In case of monoammonium phosphate-treated plywood, every tested item of fire retardancy was shown more excellent at the 25% chemical concentration and shown also at 9 hours treatment except maximum flame length compared with ammonium sulphate-treated plywood. 2. However in case of ammonium sulphate-treated plywood, 6 hours treatment of fire retardancy was better than 9 hours treating time. 3. Monoammonium phosphate was generally better than ammonium sulphate in every tested item.

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Development of n Hydroponic Technique for Fruit Vegetables Using Synthetic Fiber Medium (합성섬유 배지를 이용한 과채류 수경재배 기술 개발)

  • Hwang Yeon-Hyeon;Yoon Hae-Suk;An Chul-Geon;Hwang Hae-Jun;Rho Chi-Woong;Jeong Byoung-Ryong
    • Journal of Bio-Environment Control
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    • v.14 no.2
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    • pp.106-113
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    • 2005
  • This study was carried out to develop a novel hydroponic medium far fruit vegetable crops by using waste synthetic fibers. In physical analysis of the synthetic fiber medium (SFM), the bulk density and percent solid phase were lower, while the porosity and water content were greater in comparison with the rockwool slab. The SFM had pH of 6.5 and EC of $0.03dS{\cdot}m^{-1}$ both of which are similar to those of the rockwool slab. The CEC of 0.39me/100mL of the SFM was lower than compared with 3.29me/100mL of the rockwool slab. However, concentrations K, Ca, Mg and Na were slightly higher in the SFM than those in the rockwool slab. The 'Momotaro' tomato crop in the SFM gave comparable plant height, stem diameter, days to first flowering, fruit weight and percent marketable yield as the rockwool slab. In the SFM and in the rockwool slab, mean fiuit weight were 182g and 181g, percent marketable yield were $93.8\%$ and $92.0\%$, respectively. The marketable yield per 10a in the SFM was 12,799 kg, which was $97\%$ of that in the rockwool slab. Growth parameters such as leaf length and width, leaf number, stem diameter and chlorophyll content of an exportable cucumber crop grown in the SFM and the rockwool slab were not different. Fruit weight was greater in the rockwool slab, while percent marketable yield was greater in the SFM. The marketable fruit yield per 10a of 5,062kg in the SFM was $2\%$ greater than that in the rockwool slab. $NO_3$ concentration in nutrient solution during the crop cultivation was higher in the SFM than in the rockwool slab, while concentrations $NH_4$, K, Ca, Mg and $SO_4$ were not different between the two media.

Determination of Metal Elements in Mongolian Chromite (몽골산 크롬철광 중의 금속성분 분석)

  • Choi, Kwang Soon;Lee, Chang Heon;Pyo, Hyung Yeol;Park, Soon Dal;Joe, Kih Soo
    • Analytical Science and Technology
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    • v.13 no.6
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    • pp.766-774
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    • 2000
  • The major and trace constituents of Mongolian chromite were analyzed by ICP-AES. The dissolution procedures, mixed acid ($HClO_4+H_3PO_4$) digestion and fusion with $Na_2O_2$ flux, have been studied to dissolve the chromite. The optimum dissolution method was found to be a fusion with $Na_2O_2$ flux. The effect of large amount of Na on major and trace constituents was examined when these elements were determined by ICP-AES. There was no effect on major elements at a concentration of Na 250 mg/L solution. The emission intensity of trace constituents containing Na 1,250 mg/L decreased to 1.0-5.2% according to elements and wavelengths. The result of this method was compared with that of neutron activation analysis (NAA) to confirm the accuracy of this procedure. The results between two methods were in a good agreement within less than 5% for $Al_2O_3$, $Cr_2O_3$, MgO and -20 to 8% for Co, Mn, V, Zn, respectively.

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Phosphorus Modified Co/Al2O3 Fischer-Tropsch Catalyst for a Slurry Phase CSTR with Enhanced Hydrothermal and Mechanical Stability (수열특성 및 기계적 안정성의 개선으로 슬러리상 CSTR에 적합한 P 첨가 알루미나 기반의 Fischer-Tropsch 합성용 코발트 촉매)

  • Jung, Gyu-In;Ha, Kyoung-Su;Park, Seon-Ju;Kim, Du-Eil;Woo, Min-Hee;Jun, Ki-Won;Bae, Jong-Wook;Kang, Yong
    • Korean Chemical Engineering Research
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    • v.50 no.2
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    • pp.229-237
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    • 2012
  • Phosphorus was incorporated into Co/$Al_2O_3$ catalyst for FTS by impregnating an acidic precursor, phosphoric acid, in ${\gamma}-Al_2O_3$ support to improve the mechanical strength, the hydrothermal stability of the catalyst particle, and the catalytic performance as well. Surface characterization techniques such as FT-IR revealed that $AlPO_4$ phase was generated on the surface of the P-modified catalyst. The addition of phosphorus was found to alleviate the interaction between cobalt and alumina surface, and to increase reducibility of catalyst. The catalytic activity such as $C_{5+}$ productivity and turnover frequency (TOF) was calculated to evaluate catalytic performance. The influence of calcination temperature of the $Al_2O_3$ containing 2 wt.% P on the catalytic performance was also investigated. Through hydrothermal stability test and XRD analysis, the P-modified catalyst had strong resistant to the pressurized and hot $H_2O$. The mechanical strength of the P-modified catalyst was also examined through an in-house fluidized-bed vessel, and it was found that the catalyst fragmentation could be successfully suppressed with P. Taken as a whole, the best performance was shown to be at 1~2 wt.% P in alumina and at the calcination temperature of $500^{\circ}C$.

Hemipelvectomy in a Cat with Obstipation (심한 변비를 보이는 고양이에서 반골반절제술을 이용한 외과적 치료 증례)

  • Yoon, Hun-Young;Kim, Kyung-Hee;Jeong, Soon-Wuk
    • Journal of Veterinary Clinics
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    • v.30 no.2
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    • pp.119-122
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    • 2013
  • A 9-month-old female Korean short hair cat weighing 2.2 kg presented for evaluation of a two-week history of obstipation. The owner reported that the cat sustained pelvic fractures 4 months previous to the onset of fecal tenesmus. On physical examination, fecal tenesmus was observed and restriction of the movement of the right coxofemoral joint was evident. Rectal palpation revealed narrowing of the pelvic canal with a hard bony protuberance at the bilateral acetabulum and pubic bones. Radiographs revealed a distended colon with feces and narrowing of the pelvic canal with abnormal structure of the pelvic bone. Conservative management consisting of stool softeners and a warm water enema was instituted; however, there was no improvement in obstipation. Partial iliac, ischial, pubic, and acetabular ostectomies were performed. Postoperative radiographs and rectal palpation revealed the enlarged pelvic canal. Stool softeners (5 ml orally twice daily) was administered following surgery for 14 days and then tapered down to 2.5 ml for 14 days. A warm water enema was performed twice postoperatively. At examination 14 days postoperatively, no problems with defecation and gait were reported. There was no evidence of obstipation and lameness of the left pelvic limb 5 months postoperatively.

Water Quality Improvement of Pocheon Stream Using Freshwater Bivalves: Development and Operation of Continuous Removal of Organic Matter in Streams (S-CROM) (포천천 수질개선을 위한 패류의 이용 하천형 유기물 제어(S-CROM) 기술의 적용)

  • Kim, Baik-Ho;Lee, Ju-Hwan;Kim, Yong-Jae;Hwang, Su-Ok;Hwang, Soon-Jin
    • Korean Journal of Ecology and Environment
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    • v.42 no.3
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    • pp.317-330
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    • 2009
  • To diminish the levels of organic matters, a novel S-CROM (continuous removal of organic matters in the stream system using freshwater bivalve), was developed and applied to the polluted stream discharging from the wastewater treatment plant, Pocheon stream, Pocheon city (Korea). Major pollutants of the stream were human population and industrial wastewaters. The study was conducted at a small dam constructed within the stream, often called 'bo', and designed with four tanks; no mussels and no sediment (negative control), no mussels and sediment (positive control), 30 mussels and sediment (D1), and 60 mussels and sediment (D2). Physicochemical and biological parameters were measured at 12 hours interval (day and night) after mussel stocking. Results indicated that Anodonta woodiana Lea (D2) clearly removed approximately 72% of chl-$\alpha$ and 57% of suspended solids on second day, however, there were no differences in removal activities between animal densities (P>0.5). Dislike a laboratory CROM system, which previously developed, there were no huge release of nutrient ($NH_3$-N and SRP), due perhaps to the higher flow rate and the lower animal density. Therefore, we may suggest that if we can determine the relevant current and the animal density considering the stream state, an S-CROM system has a strong potential to water quality improvement of eutrophic streams. Some characteristics on both CROM and S-CROM were compared.

Evaluation of Freshness Prolonging Ability of Antibacterial Packaging Bags and Corrugated Boxes (항균포장지와 포장상자에 저장된 과채류의 선도평가)

  • Kim, Chul-Hwan;Kim, Jae-Ok;Park, Woo-Po;Jung, Jun-Ho;Cho, Sung-Hwan
    • Korean Journal of Food Science and Technology
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    • v.37 no.3
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    • pp.364-371
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    • 2005
  • Packaging bags and corrugated boxes prepared from newly developed antimicrobial packaging paper had greater ability to prolong freshness of packed fruits, and lower weight loss of fruits and microbial growth than non-treated bags and boxes. Addition of zeolite to paper greatly increased absorbance of aging hormone, $C_{2}H_{4}$, emitted from stored fruits, and contributed to decrease in putrefied fruits during storage. Water repellent agent such as alkyl ketone dimer played significant role in preventing functional paper from absorbing water from stored fruits, leading to preservation of fresh weight in stored fruits. Because rise in production cost of functional packaging paper could be offset by reduction of fruit and vegetable wastes, storing fruits and vegetables in functional paper containers was more economical than storing in non-treated containers.

Influence of Wet Chemistry Damage on the Electrical and Structural Properties in the Wet Chemistry-Assisted Nanopatterned Ohmic Electrode (Wet chemistry damage가 Nanopatterned p-ohmic electrode의 전기적/구조적 특성에 미치는 영향)

  • Lee, Young-Min;Nam, Hyo-Duk;Jang, Ja-Soon;Kim, Sang-Mook;Baek, Jong-Hyub
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.11a
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    • pp.150-150
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    • 2008
  • 본 연구에서는 Wet chemistry damage가 Nanopatterned p-ohmic electrode에 미치는 영향을 연구하였다. Nanopattern은 Metal clustering을 이용하여, P-GaN와 Ohmic형성에 유리한 Pd을 50$\AA$ 적층한 후 Rapid Thermal Annealing방법으로 $850^{\circ}C$, $N_2$분위기에서 3min열처리를 하여 Pd Clustering mask 를 제작하였다. Wet etching은 $85^{\circ}C$, $H_3PO_4$조건에서 시간에 따라 Sample을 Dipping하는 방법으로 시행하였다 Ohmic test를 위해서 Circular - Transmission line Model 방법을 이용하였으며, Atomic Force Microscopy과 Parameter Analyzer로 Nanopatterned GaN surface위에 형성된 Ni/ Au Contact에서의 전기적 분석과, 표면구조분석을 시행하였다. AFM결과 Wet처리시간에 따라서 Etching형상 및 Etch rate이 영향을 받는 것이 확인되었고, Ohmic test에서 Wet chemistry처리에 의한 Tunneling parameter와 Schottky Barrier Height가 크게 증/감함을 관찰하였다. 이러한 결과들은 Wet처리에 의해서 발생된 Defect가 GaN의 표면과 하부에서 발생되며, Deep acceptor trap 및 transfer거동과 밀접한 관련이 있음을 확인 할 수 있었다. 보다 자세한 Transport 및 Wet chemical처리영향에 관한 형성 Mechanism은 후에 I-V-T, I-V, C-V, AFM결과 들을 활용하여 발표할 예정이다.

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A Literature Study on the Yuk-mi-ji-hwang-tang-kakambang of Applying to Dementia (치매에 응용(應用)된 육미지황탕가감방(六味地黃湯加減方)에 대한 문헌적(文獻的) 고찰(考察))

  • Jeon, S.Y.;Kang, H.J.;Choi, J.B.;Cho, M.R.;Jin, C.S.;Hong, S.
    • The Journal of Internal Korean Medicine
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    • v.19 no.1
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    • pp.271-290
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    • 1998
  • As a result of investigating the cases of applying Yuk-mi-ji-hwang-tang-kakambang(六味地黃湯加減方) to treating dementia, the following results are obtained. 1. Yuk-mi-ji-hwang-tang-kakambang(六味地黃湯加減方)is applied to anapladementia. 2 Yuk-mi-ji-hwang-tang-kakambang(六味地黃湯加減方) is also applied to treating the dementia due to congenital weakness and defficiencies of the Liver and Kidney, the Spleen and Kidney. 3. To cure congenital weakness, Yuk-mi-ji-hwang-tang(六味地黃湯), Jwa-kwi-hwan(左歸丸), Bo-sin-ik-su-tang(補腎益髓湯) and Chil-bok-eum-kakam(七福飮加減) which can bo-sin-ik-jeong(補腎益精) sung-noi-ik-ji(醒腦益智), for the defficiencies of liver and kidney, Jwa-kwi-hwan-kakam(左歸丸加減), Woo- kwi-eum-kakam(左歸飮加減) and Ki-kuk-ji-hwang-tang-hap-jng-ji-tang-kakam(杞菊地黃湯合定智湯加減) which can bo-ik- kan-sin(補益肝腎) jeon-jeong-gun-noi(塡精健腦) and for the defficiencies of spleen and kidney, Hwan-so-dan-kakam(還少丹加減) and Kum-kwe-shin-ki-hwan-kakam(金궤腎氣丸加減) which can bo-sin-gun-bi(補腎健脾) ik-gi-sang-jeong(益氣生精) gun-noi-sang-su(健腦生髓) 4. Won-Ji(遠志) and Suk-chang-po(石菖蒲) which can sung-sin-ga-gu(醒神開竅) are added to yuk-mi-ji-hwang-tang(六味地黃湯).

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Use of hybrid materials in the trace determination of As(V) from aqueous solutions: An electrochemical study

  • Tiwari, Diwakar;Jamsheera, A.;Zirlianngura, Zirlianngura;Lee, Seung Mok
    • Environmental Engineering Research
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    • v.22 no.2
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    • pp.186-192
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    • 2017
  • The carbon paste electrode (CPE) was modified with the pristine bentonite and hybrid material (HDTMA-modified bentonite). The modified-CPEs are then employed as working electrode in an electrochemical detection of As(V) from aqueous solutions using the cyclic voltammetric measurements. Cyclic voltammograms revealed that As(V) showed reversible behavior onto the working electrode. The hybrid material-modified carbon paste electrode showed significantly enhanced electrochemical signal which was then utilized in the low level detection of As(V). Moreover, the studies were conducted at neutral pH conditions. The electrochemical studies were conducted with scan rates (20 to 200 mV/s) to deduce the mechanism of redox processes involved at the electrode surface. The anodic current was linearly increased, increasing the concentration of As(V) from 5.0 to $35.0{\mu}g/g$ using the hybrid material-modified electrode. This provided fairly a good calibration line for As(V) detection. The presence of varied concentrations of As(III) in the determination of total arsenic was studied. The influence of several cations and anions viz., Cu(II), Mn(II), Zn(II), Pb(II), Cd(II), Fe(III), $Cl^-$, $NO_3{^-}$, $PO_4{^{3-}}$, EDTA and glycine in the detection of As(V) from aqueous solution was also studied. Further, in an attempt to simulate the real matrix analysis, the tap water sample was spiked with As(V) and subjected for As(V) detection using the modified-CPE.