• Journal of Korean Society of Water and Wastewater
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• v.23 no.5
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• pp.669-678
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• 2009

The reduction of excess activated sludge from petrochemical plant was investigated by the electro fenton (E-Fenton) process using electrogenerated hydroxyl radicals which lead to mineralization of activated sludge to $CO_2$, water and inorganic ions. Factors affecting the disintegration efficiency of excess activated sludge in E-Fenton process were examined in terms of five criteria: pH, $H_2O_2/Fe^{2+}$ molar ratio, current density, initial MLSS (mixed liquid suspended solids) concentration, $H_2O_2$ feeding mode. TSS total suspended solid and $TCOD_{cr}$ reduction rate increased with the increasing $H_2O_2/Fe^{2+}$ molar ratio and current density until 42 and $6.7 mA/cm^2$, respectively but further increase of $H_2O_2/Fe^{2+}$ molar ratio and current density would reduce the reduction rate. On the other hand, as expected, increasing pH and initial MLSS concentration of activated sludge decreas TSS and $TCOD_{cr}$ reduction rate. The E-Fenton process was gradually increased during first 30 minutes and then linearly proceed till 120 minutes. The optimal E-Fenton condition showed TSS reduction rate of 62~63% and $TCOD_{cr}$ (total chemical oxygen demand) reduction rate of 55~56%. Molar ratio $H_2O_2/Fe^{2+} = 42$ was determined as optimal E-Fenton condition with initial $Fe^{2+}$ dose of 5.4 mM and current density of $6.7{\sim}13.3 mA/cm^2$, initial MLSS of 7,600 mg/L and pH 2 were chosen as the most efficient E-Fenton condition.

• Journal of Environmental Health Sciences
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• v.32 no.5 s.92
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• pp.446-450
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• 2006

In order to treat the wastewater containing organic compound, pre-treatment system connected with MSP(molecular separation process) was investigated. With the aim of selecting an optimum process of Fenton's oxidation, removal efficiency of each process in the optimum reaction condition was recommended. The $Fe/H_{2}O_{2}$(ferric sulfate to hydrogen peroxide)reagent is referred to as the Fenton's regent, which produces hydroxyl radicals by the interaction of Fe with $H_{2}O_{2}$. The powerful oxidizing ability and extreme kinetic reactively of the hydroxyl radical was well established. Increasing dosage of $Fe/H_{2}O_{2}$ increased removal efficiency as molar ratio of $Fe/H_{2}O_{2}$ between 0.2 and 2.5. Optimum dosage of molar ratio was 1. The removal efficiency for reaction condition was increased as pH decreased when the molar ratio of $Fe/H_{2}O_{2}$ was 1.7. Fenton's oxidation was most efficient in the reaction time 35 min for complex wastewater. Also, coagulation aid experiments using kaolin resulted in 3% of kaolin dosage.

• Journal of the Korean Institute of Electrical and Electronic Material Engineers
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• v.30 no.12
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• pp.812-816
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• 2017

$Fe_3O_4$ was prepared on the $TiO_2-coated$ natural mica substrate. The natural mica has an average particle size of $22{\mu}m$. The substrate was coated on $TiO_2$ thin films using hydrothermal synthesis at pH 1.5-2.5 at $75^{\circ}C$. The Fe precursor solution was prepared by mixing $FeSO_4$ (for $Fe^{2+}$ ion) and $FeCl_3$ (for $Fe^{3+}$ ions) with different molar ratios such as 1/2, 1/1, 2/1, 3/0, and $Fe_3O_4$ only. X-ray diffraction analysis shows that the crystal structure depends on the $FeCl_3-to-FeSO_4$ molar ratio. $Fe_3O_4$ crystal phase could be obtained at higher $FeSO_4$ contents.

• Journal of Korean Society on Water Environment
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• v.30 no.6
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• pp.653-657
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• 2014

Effects of $H_2O_2$ addition for fenton oxidation on iron coagulation for treatment of phosphorus species, such as orthophosphate, metaphosphate, pyrophosphate, organic phosphate, were investigated. The effects of coagulant dosage, hydrogen peroxide dosage and the combined sequence ferric coagulation and $H_2O_2$ addition for fenton oxidation and coagulation were studied. The characteristics of floc growth rate were monitored using the PDA. The removal efficiencies of phosphorus species by iron coagulation were increased as Fe/P molar ratio increased. However, the removal efficiencies of metaphosphate, pyrophosphate, organic phosphate by a ferric coagulation were not increased as Fe/P molar ratio increased. The removal efficiency of metaphosphate, pyrophosphate, organic phosphate was increased by using iron coagulation and $H_2O_2$ addition for fenton oxidation. The result indicated that non-reactive phosphorus after iron coagulation was changed to reactive phosphorus by $H_2O_2$ addition for fenton oxidation and the oxidized iron enhanced the coagulation efficiencies.

• Korean Chemical Engineering Research
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• v.44 no.4
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• pp.387-392
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• 2006

(Fe, Co)/zeolite catalysts such as (Fe, Co)/NaY, (Fe, Co)/NaBeta and (Fe, Co)/HUSY were prepared by ion-exchange method and their catalytic performance was examined in the hydroxylation of phenol with $H_2O_2$ for the production of catechol. The (Fe, Co)/NaBeta catalyst showed its best performance at reaction temperature=$70^{\circ}C$, molar ratio of phenol/$H_2O_2=3$, weight ratio of phenol/catalyst=50 and weight ratio of solvent (water)/phenol=6 as 20％ of phenol conversion, 77％ of the selectivity for the hydroxylation, 70％ of the selectivity for catechol, and 2.5 of the formation ratio of catechol/hydroquinone. The (Fe, Co)/zeolite catalysts showed the reproducible activities without deactivation after repeated regeneration. The fresh and used(Fe, Co)/zeolites were characterized by XRD, UV-VIS DRS, and XPS and their catalytic performance was discussed based on these characterization results.

• Korean Journal of Materials Research
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• v.25 no.2
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• pp.95-99
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• 2015

$NiAl_2O_4$ nanoparticle was synthesized by a reverse micelle processing for inorganic pigment. $Ni(NO_3)_2{\cdot}6H_2O$ and $Al(NO_3)_3{\cdot}9H_2O$ were used for the precursor in order to synthesize $NiAl_2O_4$ nanoparticles. The aqueous solution, which consisted of a mixing molar ratio of Ni/Al, was 1:2 and heat treated at $800{\sim}1100^{\circ}C$ for 2h. The average size and distribution of synthesized $NiAl_2O_4$ powders are in the range of 10-20 nm and narrow, respectively. The average size of the synthesized $NiAl_2O_4$ powders increased with an increasing water-to-surfactant molar ratio and heating temperature. The crystallinity of synthesized $NiAl_2O_4$ powder increased with an increasing heating temperature. The synthesized $NiAl_2O_4$ powders were characterized by X-ray diffraction analysis(XRD), a field emission scanning electron microscopy(FE-SEM), and a color spectrophotometer. The properties of synthesized powders were affected as a function such as a molar ratio and heating temperature. Results indicate that synthesis using a reverse miclle processing is a favorable process to obtain $NiAl_2O_4$ spinels at low temperatures. The procedure performed suggests that this new synthesis route for producing these oxides has the advantage of being fast and simple. Colorimetric coordinates indicate that the pigments obtained exhibit blue colors.

• Korean Chemical Engineering Research
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• v.52 no.5
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• pp.638-646
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• 2014

The effect of in-organic chelating agents with Fe(II) and Fe(III) in modified Fenton was evaluated to degradation BTEX (benzene, toluene, ethylbenzene, xylene). Citric acid and pyrophosphate were used in experimentals and an optimum chelating agent for BTEX degradation was determined. In $H_2O_2$/Fe(III)/citric acid, degradation of BTEX was decreased when concentration of citric acid was increased. In $H_2O_2$/Fe(III)/pyrophosphate, degradation of BTEX was increased when concentration of pyrophosphate was increased and degradation for BTEX was relatively high compared with $H_2O_2$/Fe(III)/citric acid. In $H_2O_2$/Fe(II)/chelating agents, degradation for BTEX was high and pH variation was minimized when molar ratio of Fe(II) and citric acid was 1:1. Optimum molar concentration of Fe(II), citric acid and $H_2O_2$ were 7 mM, 7mM and 500 mM for degradation of 100 mg/L of benzene to obtain best efficiency of $H_2O_2$, least precipitation of iron and best degradation.

• Journal of Korean Society of Water and Wastewater
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• v.26 no.6
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• pp.779-786
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• 2012

The degradation of 2-chlorophenol(2-CP) by various AOPs(Advanced Oxidation Processes) including the photo-Fenton process has been examined. In sole $Fe^{2+}$, UV or $H_2O_2$ process without combination, low removal efficiencies have been achieved. But the photo-Fenton process showed higher removal efficiency for degradation of 2-chlorophenol than those of other AOPs including the Fenton process and the UV processes. In the photo-Fenton process, the optimal experimental conditions of 2-chlorophenol degradation were obtained at pH 3 and the $Fe^{2+}/H_2O_2$molar ratio of 1. Also the 2-chlorophenol removal efficiency increased with decreasing of the initial 2-chlorophenol concentration. 3-chlorocatechol and chlorohydroquinone were identified as photo-Fenton reaction intermediates, and a degradation pathway of 2-chlorophenol in the aqueous phase during the photo-Fenton reaction was proposed.

• Korean Chemical Engineering Research
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• v.49 no.5
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• pp.530-534
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• 2011

The synthesis of dimethyl carbonate by liquid phase oxidative carbonylation of methanol was studied under batch reaction system. Reaction factors such as effect on various metals, anion containing in copper catalyst, temperature, carbon monoxide and oxygen molar ratio and copper content were investigated. In particular $CuCl_2{\cdot}2H_2O$ showed the excellent of the methanol conversion 65.2%, DMC selectivity 96.6% reaction condition under 1.0 g, $150^{\circ}C$, MeOH/CO/$O_2$=0.2/0.215/0.05 (molar ratio). $CuCl_2$ led to corrosion of the reactor. Thus, a new catalyst system using supports was investigated to resolve these corrosion problem. Influence on various supports were examined and copper catalyst supported on zeolite Y showed the most excellent activity on the formation of dimethyl carbonate. The amount of Fe dissolved during the reaction using ICP-AES (Inductively Coupled Plasma-Atomic Emission Spectrometer) was compared with catalysts, calcined Cu/zeolite Y showed the lower value below 5% than $CuCl_2-2H_2O$.

• Environmental Engineering Research
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• v.23 no.1
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• pp.114-119
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• 2018

Yarn dyed wastewater has to be treated prior to disposal into the water bodies due to its high content of harmful organic compounds. In this study, the performance of Chemical Oxygen Demand (COD) removal and kinetic rate constant are investigated via hybrid electrocoagulation-Fenton in a continuous system using wastewater discharged from a yarn dyed industry in Surabaya city. The wastewater was treated in a batch mode using electrocoagulation to reduce Total Suspended Solid, followed by Fenton method in a continuous system to reduce COD level. Various Fe(II) feeding modes, molar ratio of $Fe(II)/H_2O_2$, initial pH of wastewater, and flow rate are used in this study. The results show that COD removal process obeys a pseudo-first order kinetics. At $Fe(II)/H_2O_2$ ratio of 1:10, initial wastewater pH of 3.0, and feed flow rate of 30 mL/min, the COD removal efficiency was observed to be 80%, and the kinetic rate constant is $0.07046min^{-1}$. The chemical cost for the treatment estimated to be IDR 160 per L wastewater, which is cheaper than the previously reported batch system of IDR 256/L.