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Hydroxylation of Phenol over (Fe, Co)/Zeolite Catalysts for the Selective Synthesis of Catechol  

Park, Jung-Nam (Advanced Chemical Technology Division, Korea Research Institute of Chemical Technology)
Shin, Chae-Ho (Department of Chemical Engineering, Chungbuk National University)
Baeg, Jin-Ook (Advanced Chemical Technology Division, Korea Research Institute of Chemical Technology)
Lee, Chul Wee (Advanced Chemical Technology Division, Korea Research Institute of Chemical Technology)
Publication Information
Korean Chemical Engineering Research / v.44, no.4, 2006 , pp. 387-392 More about this Journal
Abstract
(Fe, Co)/zeolite catalysts such as (Fe, Co)/NaY, (Fe, Co)/NaBeta and (Fe, Co)/HUSY were prepared by ion-exchange method and their catalytic performance was examined in the hydroxylation of phenol with $H_2O_2$ for the production of catechol. The (Fe, Co)/NaBeta catalyst showed its best performance at reaction temperature=$70^{\circ}C$, molar ratio of phenol/$H_2O_2=3$, weight ratio of phenol/catalyst=50 and weight ratio of solvent (water)/phenol=6 as 20％ of phenol conversion, 77％ of the selectivity for the hydroxylation, 70％ of the selectivity for catechol, and 2.5 of the formation ratio of catechol/hydroquinone. The (Fe, Co)/zeolite catalysts showed the reproducible activities without deactivation after repeated regeneration. The fresh and used(Fe, Co)/zeolites were characterized by XRD, UV-VIS DRS, and XPS and their catalytic performance was discussed based on these characterization results.
Keywords
Phenol Hydroxylation; $H_2O_2$; Catechol; (Fe, Co)/Zeolite Catalyst;
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