• Proceedings of the Korean Institute of Surface Engineering Conference
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• 2011.05a
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• pp.77-78
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• 2011

저비용, 고효율, 안정적 수급이 가능한 전력 에너지원이 요구되면서 석탄이 새로운 에너지원으로 급부상하게 됨에 따라 차세대 친환경 석탄화력 발전기술인 IGCC (Integrated Gasification Combined Cycle) 발전 시스템 의 개발이 필요하게 되었다. 석탄가스화 공정(IGCC: integrated coal gasification combined cycle)은 석탄을 가스화한 후 이를 이용하여 복합발전소를 운전하는 발전기술로서 석탄을 고온, 고압아래에서 수소와 일산화탄소를 주성분으로 한 합성가스로 전환한 뒤 합성가스 중에 포함 된 분진과 황 화합물 등 유해물질을 제거하고 천연가스와 유사한 수준으로 정제하여 전기를 생산하는 친환경 발전 기술이다.

• The Journal of Korea Institute of Information, Electronics, and Communication Technology
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• v.13 no.5
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• pp.412-418
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• 2020

This paper produced an automatic fluid management system that can accurately control the specific gravity of etching solution(FeCl₃), and produced a SUS MASK applied to OLED. The target was set at 0.4 mm in diameter of the hole. As a result of this misconception, the etching speed increased when the specific gravity(S.G) value of FeCl₃ was changed from 1.43 to 1.49. And when the weight was 1.49, it was found that the vertical diameter was 0.405 mm, approaching the target. When pressure injection was varied from 2.0kg/cm2 to 3.5kg/cm2, the hole diameter at 3.0 kg/cm2 averaged 0.4mm, matching the target. The characteristics of the change in gravity were analyzed by applying the additive 1.2% and setting the weight at 1.430 by mixing HCl and H2O in FeCl₃ and fixing the injection pressure at 3.0 kg/cm2. When the weight changed from 1.460 to 1.469 the etching speed increased from 0.564 to 0.540. When the weight was 1.467, the hole diameter was measured at 0.4 mm and the target was reached.

• KSBB Journal
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• v.23 no.1
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• pp.83-89
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• 2008

Food wastewater derived from the three-stage methane fermentation system developed in this lab contained high concentration organic substances. The organic wastewater should be treated through advanced wastewater treatment system to satisfy the "Permissible Pollutant Discharge Standard of Korea". In order to treat the organic wastewater efficiently, several optimum operation conditions of a modified $UV/TiO_{2}$ photocatalytic system have been investigated. In the first process, wastewater was pre-treated with $FeCl_{3}$. The optimum pH and coagulant concentration were 4.0 and 2000mg/L, respectively. Through this process, 52.6% of CODcr was removed. The second process was $UV-TiO_{2}$ photocatalytic reaction. The optimum operation conditions for the system were as follows: UV lamp wavelength, 254 nm; wastewater temperature, $40^{\circ}C$; pH 8.0; and air flow rate, 40L/min, respectively. Through the above two combined processes, 69.7% of T-N and 70.9% of CODcr contained in the wastewater were removed.

• 한국생물공학회:학술대회논문집
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• 2005.04a
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• pp.272-276
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• 2005

Food wastewater derived from three-stages methane fermentation system showed high concentrations of sCOD, T-N and $NH_{3}-N$. To treat the organic wastewater, the optimal operating conditions for high efficiency $UV/TiO_{2}$ photocotalytic system have been investigated. In the first process, wastewater was pre-treated with $FeCl_{3}. The optimum pH and concentration for coagulation were 4.0 and 2000 mg/L, respectively. Through this process, 52.6% of $COD_{cr}$ was removed. The second process was $UV/TiO_{2}$ photocatalytic reaction. The optimum conditions for the operation of $UV/TiO_{2}$ photocatalytic system developed in this lab have been studied. In this process, CODcr was removed from 2890 to 184 mg/L and T-N was removed from 2496 to 914 for 24 hours, respectively.

• Clean Technology
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• v.20 no.3
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• pp.269-276
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• 2014

This study was aimed to develop catalytic system for the dry-based reduction of oxidized mercury ($Hg^{2+}$) to elemental mercury ($Hg^0$) which is one of the most important components comprising mercury continuous emission monitoring system (Hg-CEMS). Based on the standard potential in oxidation-reduction reaction, transition metals including Fe, Cu, Ni and Co were selected as possible candidates for catalyst proceeding spontaneous reduction of $Hg^{2+}$ into $Hg^0$. These transition metal catalysts revealed high activity for reduction of $Hg^{2+}$ into $Hg^0$ in the absence of oxygen in reactant gases. However, their activities were greatly decreased in the presence of oxygen, which was attributed to the transformation of transition metals by oxygen to the corresponding transition metal oxides with less catalytic activity for the reduction of oxidized mercury. Hydrogen supplied to the reactant gases significantly enhanced $Hg^{2+}$ reduction activity even in the presence of oxygen. It might be due to occurrence of combustion reaction between $H_2$ and $O_2$ causing the consumption of $O_2$ at such high reaction temperature at which oxidized mercury reduction reaction took place. Because the system showed high activity for $Hg^{2+}$ reduction to $Hg^0$, which was compatible to that of wet-chemistry technology using $SnCl_2$ solution, the catalytic reduction system of Fe catalyst with the supply of $H_2$ could be employed as a commercial system for the reduction of oxidized mercury to elemental mercury.

• Journal of Environmental Science International
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• v.28 no.5
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• pp.511-520
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• 2019

This study was investigated to improve the phosphorus release and water quality by transformation of sedimentary P fraction for application of $CaO_2$. For the experiment, 0.5% (w/w) of $CaO_2$ was homogenized in the sediment and incubated with the control for 20 days. The analytical results showed that pH increased with $CaO_2$ and redox potential (ORP) was improved in the sediment of the reactor. The growth rate of chlorophyll-a was lower in the $CaO_2$ reactor and Dissolved Oxygen (DO) of overlying water maintained higher than that of the control. Total phosphorus (T-P) concentration in the overlying water increased from the initial concentration to 0.304mg/L in the control at 20 days. The reactor of $CaO_2$ was lowered by 29.3%. Ex-P, Fe-P and Ca-P in sediment P fraction were increased with the $CaO_2$. The formation of bound Fe-P and Ca-P in the sediments seemed to control the release of P by removing the Soluble Reactive Phosphorus (SRP) presented in the pore water. From the result, this indicated that the reduction of P release from the sediments seems to be effective in suppressing the eutrophication of P and improving the oxygen condition in the water quality with the application of $CaO_2$.

• Korean Chemical Engineering Research
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• v.49 no.5
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• pp.530-534
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• 2011

The synthesis of dimethyl carbonate by liquid phase oxidative carbonylation of methanol was studied under batch reaction system. Reaction factors such as effect on various metals, anion containing in copper catalyst, temperature, carbon monoxide and oxygen molar ratio and copper content were investigated. In particular $CuCl_2{\cdot}2H_2O$ showed the excellent of the methanol conversion 65.2%, DMC selectivity 96.6% reaction condition under 1.0 g, $150^{\circ}C$, MeOH/CO/$O_2$=0.2/0.215/0.05 (molar ratio). $CuCl_2$ led to corrosion of the reactor. Thus, a new catalyst system using supports was investigated to resolve these corrosion problem. Influence on various supports were examined and copper catalyst supported on zeolite Y showed the most excellent activity on the formation of dimethyl carbonate. The amount of Fe dissolved during the reaction using ICP-AES (Inductively Coupled Plasma-Atomic Emission Spectrometer) was compared with catalysts, calcined Cu/zeolite Y showed the lower value below 5% than $CuCl_2-2H_2O$.

• Economic and Environmental Geology
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• v.43 no.6
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• pp.589-601
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• 2010

Recently it has been frequently reported arsenic contamination of geologic origin in groundwater. The iron-impregnated ranular activated carbon (Fe-GAC) was developed for effective removal of arsenic from groundwater n the study. Fe-GACs were prepared by impregnating iron compounds into a supporting medium (GAC) with 0.05 M iron nitrate solution. The materials were used in arsenic adsorption isotherm tests to know the effect of iron impregnation time, batch kinetic tests to understand the influence of pH, and column tests to evaluate for the preliminary operation of water treatment system. The results showed that the minimum twelve hours of impregnation time were required for making the Fe-GAC with sufficient iron content for arsenic removal, confirmed by a high arsenic adsorption capacity evaluated in the isotherm tests. Most of the impregnated iron compounds were iron hydroxynitrate $Fe_4(OH)_{11}NO_3{\cdot}2H_2O$ but a mall quantity of hematite was also identified in X-ray diffraction(XRD) analysis. The batch isotherms of Fe-GAC for arsenic adsorption were well explained by Langmuir than Freundlich model and the iron contents of Fe-GAC have positive linear correlations on logarithmic plots with Freundlich distribution coefficients ($K_F$ and Langmuir maximum adsorption capacities ($Q_m$. The results of kinetic experiments suggested hat Fe-GAC had he excellent arsenic adsorption capacities regardless of all pH conditions except for pH 11 and could be used a promising adsorbents for groundwater arsenic removal considering the general groundwater pH range of 6-8. The pseudo-second order model, based on the assumption that the ate-limiting step might be chemisorption, provided the best correlation of the kinetic experimental data and explained the arsenic adsorption system f Fe-GAC. The column test was conducted to valuate the feasibility of Fe-GAC use and the operation parameters in arsenic groundwater treatment system. The parameters obtained from the column test were the retardation actor of 482.4 and the distribution coefficient of 581.1 L/mg which were similar values of 511.5-592.5 L/mg acquired from Freundlich batch isotherm model. The results of this study suggested that Fe-GAC could be used as promising adsorbent of arsenic removal in a small groundwater supply system with water treatment facility.

• Applied Chemistry for Engineering
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• v.10 no.1
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• pp.24-29
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• 1999

Naturally-occurring iron minerals, goethite, magnetite, and hydrogen peroxide were used to catalyze and initiate Fenton-like oxidation of silica sand contaminated with mixture of diesel and kerosene in batch system. Optimal reaction conditions were investigated by varying pH(3, 7), $H_2O_2$ concentration(0%, 1%, 7%, 15%, 35%), initial contaminant concentration(0.2, 0.5, 1.0 g-mixture of diesel and kerosene/ kg-soil), and iron mineral contents(1, 5, and 10 wt % magnetite or goethite). Contaminant degradations in silica sand-iron mineral-$H_2O_2$ systems were identified by determining total petroleum hydrocarbon(TPH) concentration. The optimal pH of the system was 3. The system which iron minerals were the only iron source was more efficient than the system with $FeSO_4$ solution due to lower $H_2O_2$ consumption. In case of initial contaminant concentration of 1g-contaminant/kg-soil with 5 wt % magnetite, addition of 0%, 1%, 7%, 15%, and 35% of $H_2O_2$ showed 0%, 24.5%, 44%, 52%, and 70% of TPH reduction in 8 days, respectively. When the mineral contents were varied 0, 1, 5, and 10wt%, removal of contaminants were 0%, 33.5%, 50%, and 60% for magnetite and 0%, 29%, 41%, and 53% for goethite, respectively. Reaction of magnetite system showed higher degradation than that of goethite system due to dissolution of iron and mixed presence of iron(II) and iron(III); however, dissolved iron precipitated on the surface of iron mineral and seemed to cause reducing electron transfer activity on the surface and quenching $H_2O_2$. The system using goethite has better treatment efficiency due to less $H_2O_2$ consumption. When cach system was mixed by shaker, removal of contaminants increased by 41% for magnetite and 30% for goethite. Results of this study showed catalyzed $H_2O_2$ system made in-situ treatment of soil contaminated with petroleum possible without addition of iron source since natural soils generally contain iron minerals such as magnetite and goethite.

• Proceedings of the Korean Vacuum Society Conference
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• 2010.02a
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• pp.400-400
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• 2010

우리는 기본 진공 $10^{-11}\;Torr$의 UHV surface magneto-optical Kerr effect (SMOKE) 시스템을 quarter-wave plate를 사용하였던 기존의 방식에서 PEM (photo elastic modulator)를 사용하는 방식으로 장비의 기능을 향상시켰다. 기존 quarter-wave plate를 사용하는 방식의 경우 Kerr signal을 구하기 위해 편광자와 검광자를 수직으로 두어 광량을 0으로 만들어야 한다. 그러나 금속의 경우 대부분 가시광선 영역에서 큰 반사율 때문에 측정되는 광량이 편광자와 검광자를 거치면서 넓은 각도 범위에서 최소값을 갖기 때문에 정확한 영점을 잡는 데 한계가 있다. 이러한 단점을 해결하기 위하여 우리는 PEM을 이용한 위상변조방식을 사용하였다. 위상변조 방식은 Kerr signal과 관계된 양을 PEM을 이용하여 50 kH ($1{\omega}$)와 100 kH ($2{\omega}$)의 진동 주파수에 공조시키고 이를 Lock-in-amplifier를 사용하여 탐지하기 때문에 좋은 sensitivity를 얻을 수 있을 뿐 아니라 Kerr ellipticity와 Kerr rotation을 동시에 측정할 수 있다. 자화에 필요한 전자석은 순철로 된 코어를 제작하여 챔버에 부착하였고 10 A에서 최대 7 kOe의 고자장을 얻을 수 있어 포화자화가 큰 물질에 대해서도 필요한 자성영역까지 측정이 가능하게 하였다. 또 저온 측정을 위해 SMOKE 샘플 홀더를 개조하여 액체 질소를 이용하여 100 K 근방의 영역에서 온도를 제어할 수 있도록 저온 장치를 구성하였다. 여기에서 샘플 근처에 위차한 e-beam heater가 장착된 고온 부분과 액체 질소 냉각, 온도감지를 위한 센서, cartridge heater가 장착된 저온 부분을 sapphire plate로 분리하여 저온용 cartridge heater의 파손을 최소화하였다. 이러한 SMOKE 시스템을 구성한 후에 우리는 Fe/Cr(001)시스템의 자성특성에 대해 연구하였다. Fe/Cr 시스템은 Fe/Cr/Fe의 exchange coupling이나 bulk Cr의 복잡한 자성 특성 때문에 주목을 받아왔다. 이 연구에서 우리는 저온 및 상온에서 Cr(001) 단결정 위에 증착된 Fe 박막의 자성 특성을 보고한다.