• Title/Summary/Keyword: $CrO_2$

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Effects of Paper Sludge Application on the Chemical Properties of Paddy Soil and Growth of Paddy Rice.;III. Effects of Paper Sludge Application in the Growth of Paddy Rice. (제지(製紙)슬러지의 시용(施用)이 논 토양(土壤)의 화학성(化學性)과 수도생육(水稻生育)에 미치는 영향(影響);III. 슬러지시용(施用)이 수도생육(水稻生育)에 미치는 영향(影響))

  • Heo, Jong-Soo;Kim, Kwang-Sik;Ha, Ho-Sung
    • Korean Journal of Environmental Agriculture
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    • v.7 no.1
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    • pp.26-33
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    • 1988
  • To investigate the effects of paper sludge on the growth response of paddy rice, paper sludge was applied to pots at the rate of either 300, 600, 900 or 1,200 kg/l0a which was either preadjusted at a C/N ratio of 30 : 1 or not adjusted. The effects were compared with those of the control. 1. Plant heights, number of tillers and dry weight were significantly reduced with the increasing application of paper sludge in the early stages of rice growth, whereas opposite results were observed after the heading stage when treated with C/N ratio preadjusted paper sludge. 2. The uptake of $N,P_2O_5,K_2O$ and $SiO_2$ by rice plants grown in paper sludge treated soil was significantly reduced in the early stages of rice growth. Conversely, uptake was enhanced in the C/N ratio preadjusted plot in the young panicle formation stage. 3. Zn, Cu and Cd content in rice straw was in the range of $39{\sim}101$, $0{\sim}0.11$ and $0.03{\sim}0.14ppm$, respectively, and Pb and Cr in rice straw were not detected at all. However, there was no difference in the content of all these heavy metals in rice straw irrespective of treatment.

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Miniature Ultrasonic and Tactile Sensors for Dexterous Robot

  • Okuyama, Masanori;Yamashita, Kaoru;Noda, Minoru;Sohgawa, Masayuki;Kanashima, Takeshi;Noma, Haruo
    • Transactions on Electrical and Electronic Materials
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    • v.13 no.5
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    • pp.215-220
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    • 2012
  • Miniature ultrasonic and tactile sensors on Si substrate have been proposed, fabricated and characterized to detect objects for a dexterous robot. The ultrasonic sensor consists of piezoelectric PZT thin film on a Pt/Ti/$SiO_2$ and/or Si diaphragm fabricated using a micromachining technique; the ultrasonic sensor detects the piezoelectric voltage as an ultrasonic wave. The sensitivity has been enhanced by improving the device structure, and the resonant frequency in the array sensor has been equalized. Position detection has been carried out by using a sensor array with high sensitivity and uniform resonant frequency. The tactile sensor consists of four or three warped cantilevers which have NiCr or $Si:B^+$ piezoresistive layer for stress detection. Normal and shear stresses can be estimated by calculation using resistance changes of the piezoresitive layers on the cantilevers. Gripping state has been identified by using the tactile sensor which is installed on finger of a robot hand, and friction of objects has been measured by slipping the sensor.

A Study on the Regulatory Technology for Lightning Protection and Grounding System in Nuclear Power Plants (원전낙뢰보호 및 접지계통에 대한 규제기술연구)

  • Lee, J.D.;Zhu, O.P.;Lee, S.K.;Kim, D.S.
    • Proceedings of the KIEE Conference
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    • 2007.11b
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    • pp.66-68
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    • 2007
  • The regulatory guide, RG-1.204 and its underlying or confirmatory research, NUREG/CR-6866 were studied for Korean application to LPGS of NPPs. However they excluded the application to that of NPPs. So US-NRC approved selectively industrial standards to that of NPPs on Nov 2005. It is necessary to understand the basis of regulatory technology related regulatory positions on LPGS and important to implement the guidance on LPGS as a resonable standard. The paper is examined what and how state of the art of relevant technology applied to the LPGS as well as the trip-out events related to electrical system were involved with LPGS. We reviewed the relevant standards applicable to Korean NPPs. Following are concluded to recommend. (1) IEEE 510-1050 is recommended as a guide for I&C grounding against EMI and lighting transients (2) IEEE Std-665, 510-666, Std-C62.23 for electrical grounding against voltage surges and lighting transients (3) Inspection should be thoroughly be implemented a frequency of 3-5 year period according to NFPA780 or KSC-IEC 61024.

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Quantitative Analysis of Heavy Metals in Packaging Papers

  • Jo, Byoung-Muk;Jeong, Myung-Joon
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.39 no.5
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    • pp.45-51
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    • 2007
  • This study was carried out to investigate various heavy metal contents in packaging papers by pre-treatments for ICP-ES (Inductively Coupled Plasma Emission Spectrometry) analysis. Pre-treatment methods of heavy metals in this study include extraction, migration and decomposition methods (dry ashing, $HNO_3-HClO_4-HF,\;HNO_3,\;and\;H_2SO_4-HNO_3$). Test results were compared with conventional extraction (water) and migration (3% acetic acid) methods. The five representative heavy metals (Cd, As, Pb, Cr and Hg) were analyzed. For Cd, Hg, and As, the results were below detection limit of the instrumental technique. It was considered that the migration test was a better method compared to extraction test, but all the decomposition methods showed much higher detection values than the extraction or migration test. In case of recycled corrugated containers, 3% acetic acid solution extracted about 25% of chromium and 30% of lead compared to the content by decomposition methods. Among all decomposition methods, the nitric acid - perchloric acid - hydrofluoric acid treatment brought a slightly higher detection value than others, but there was no significant difference among them except sulfuric acid - nitric acid method.

INFLUENCE OF MECHANICAL ALLOYING ATMOSPHERES ON THE MICROSTRUCTURES AND MECHANICAL PROPERTIES OF 15Cr ODS STEELS

  • Noh, Sanghoon;Choi, Byoung-Kwon;Kang, Suk Hoon;Kim, Tae Kyu
    • Nuclear Engineering and Technology
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    • v.46 no.6
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    • pp.857-862
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    • 2014
  • Mechanical alloying under various gas atmospheres such as Ar, an Ar-$H_2$ mixture, and He gases were carried out, and its effects on the powder properties, microstructure and mechanical properties of ODS ferritic steels were investigated. Hot isostatic pressing and hot rolling processes were employed to consolidate the ODS steel plates. While the mechanical alloyed powder in He had a high oxygen concentration, a milling in Ar showed fine particle diameters with comparably low oxygen concentration. The microstructural observation revealed that low oxygen concentration contributed to the formation of fine grains and homogeneous oxide particle distribution by the Y-Ti-O complex oxides. A milling in Ar was sufficient to lower the oxygen concentration, and this led a high tensile strength and fracture elongation at a high temperature. It is concluded that the mechanical alloying atmosphere affects oxygen concentration as well as powder particle properties. This leads to a homogeneous grain and oxide particle distribution with excellent creep strength at high temperature.

The Influence of Temperature, Ultrasonication and Chiral Mobile Phase Additives on Chiral Separation: Predominant Influence of β-Cyclodextrin Chiral Mobile Phase Additive Under Ultrasonic Irradiation

  • Lee, Jae Hwan;Ryoo, Jae Jeong
    • Bulletin of the Korean Chemical Society
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    • v.33 no.12
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    • pp.4141-4144
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    • 2012
  • This paper introduces a technique for resolving amino acids that combines the advantages of the conventional CSP (chiral stationary phase) method with the CMPA (chiral mobile phase additive) method. A commercially available chiral crown ether column, CROWNPAK CR(+), was used as the CSP and three cyclodextrins (${\beta}$-CD, ${\gamma}$-CD, HP-${\beta}$-CD) were used as the mobile phase additives. Chromatographic resolution was performed at $25^{\circ}C$ and $50^{\circ}C$ with or without sonication. A comparison of the chromatographic results under ultrasonic conditions with those under non-ultrasonic conditions showed that ultrasound decreased the elution time and enantioselectivity at all temperatures. In the case of the ${\beta}$-CD mobile phase additive, the elution time and enantioselectivity under ultrasonic condition were significantly higher than under non-sonic condition at all temperatures. Commercially available Chiralpak AD, Whelk-O2 and Pirkle 1-J columns were used as CSPs to examine more meticulously the effects of ultrasonication and temperature on the optical resolution. The optical resolution of some chiral samples analyzed at $25^{\circ}C$ and $50^{\circ}C$ with or without sonication was compared. As in the previous case, the enantioselectivity was lower at $25^{\circ}C$ but similar enantioselectivity was observed at $50^{\circ}C$.

Patterning of poly(3,4-ethylenedioxythiophene)(PEDOT) Thin Films by Using Self-assembled Monolayers(SAMs) Patterns Formed by Ultra-violet(UV) Lithography (UV를 사용한 SAMs 패터닝과 PEDOT의 선택적 증착에 관한 연구)

  • Kwon, T.W.;Lee, J.;Lee, J.G.
    • Korean Journal of Materials Research
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    • v.16 no.10
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    • pp.619-623
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    • 2006
  • Selective vapor deposition of conductive poly(3,4-ethylenedioxythiophene) (PEDOT), thin films has been carried out on self assembled monolayers patterned oxide substrate. Since the 3,4-ethylenedioxythiophene(EDOT) monomer can be polymerized only in the presence of oxidant such as $FeCl_3$, the PEDOT thin film is selectively deposited on patterned $FeCl_3$, which only adsorbs on the partly removed SAMs region due to the inability of $FeCl_3$ to adsorb on SAMs. Therefore, the partly removed SAMs can act as an adsorption layer for the $FeCl_3$ and also as a glue layer for the deposition of PEDOT, resulting in the significantly increased adhesion of PEDOT to $SiO_2$ substrate. The use of UV lithography and Cr patterned quartz mask provided the formation of SAMs patterns on oxide substrates, which allowed for the selective deposition of conductive PEDOT thin films.$^{oo}The$ new process was successfully developed for the selective deposition of PEDOT thin films on SAMs patterned oxide substrate, providing a new way for the patterning of vapor phase deposition of PEDOT thin films with accurate alignment and addressing the inherent adhesion issues between PEDOT and dielectrics.

Microfabrication of Micro-Conductive patterns on Insulating Substrate by Electroless Nickel Plating (무전해 니켈 도금을 이용한 절연기판상의 미세전도성 패턴 제조)

  • Lee, Bong-Gu;Moon, Jun Hee
    • Korean Journal of Metals and Materials
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    • v.48 no.1
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    • pp.90-100
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    • 2010
  • Micro-conductive patterns were microfabricated on an insulating substrate ($SiO_2$) surface by a selective electroless nickel plating process in order to investigate the formation of seed layers. To fabricate micro-conductive patterns, a thin layer of metal (Cu.Cr) was deposited in the desired micropattern using laser-induced forward transfer (LIFT). and above this layer, a second layer was plated by selective electroless plating. The LIFT process. which was carried out in multi-scan mode, was used to fabricate micro-conductive patterns via electroless nickel plating. This method helps to improve the deposition process for forming seed patterns on the insulating substrate surface and the electrical conductivity of the resulting patterns. This study analyzes the effect of seed pattern formation by LIFT and key parameters in electroless nickel plating during micro-conductive pattern fabrication. The effects of the process variables on the cross-sectional shape and surface quality of the deposited patterns are examined using field emission scanning electron microscopy (FE-SEM) and an optical microscope.

A novel approach for manufacturing oxide dispersion strengthened (ODS) steel cladding tubes using cold spray technology

  • Maier, Benjamin;Lenling, Mia;Yeom, Hwasung;Johnson, Greg;Maloy, Stuart;Sridharan, Kumar
    • Nuclear Engineering and Technology
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    • v.51 no.4
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    • pp.1069-1074
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    • 2019
  • A novel fabrication method of oxide dispersion strengthened (ODS) steel cladding tubes for advanced fast reactors has been investigated using the cold spray powder-based materials deposition process. Cold spraying has the potential advantage for rapidly fabricating ODS cladding tubes in comparison with the conventional multi-step extrusion process. A gas atomized spherical 14YWT (Fe-14%Cr, 3%W, 0.4%Ti, 0.2% Y, 0.01%O) powder was sprayed on a rotating cylindrical 6061-T6 aluminum mandrel using nitrogen as the propellant gas. The powder lacked the oxygen content needed to precipitate the nanoclusters in ODS steel, therefore this work was intended to serve as a proof-of-concept study to demonstrate that free-standing steel cladding tubes with prototypical ODS composition could be manufactured using the cold spray process. The spray process produced an approximately 1-mm thick, dense 14YWT deposit on the aluminum-alloy tube. After surface polishing of the 14YWT deposit to obtain desired cladding thickness and surface roughness, the aluminum-alloy mandrel was dissolved in an alkaline medium to leave behind a free-standing ODS tube. The as-fabricated cladding tube was annealed at $1000^{\circ}C$ for 1 h in an argon atmosphere to improve the overall mechanical properties of the cladding.

Chemical Components and Physiological Activities of Thinned Apple, Pear and Peach (솎은 과실의 화학성분 및 생리활성)

  • Jung, Gi-Tai;Ju, In-Ok;Ryu, Jeong;Choi, Joung-Sik;Choi, Yeong-Geun
    • Food Science and Preservation
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    • v.9 no.4
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    • pp.391-395
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    • 2002
  • Thinned fruits, apple, pear and peach were investigated into chemical components and physiological activities. On proximate compositions, crude protein, crude fat and ash of thinned fruits were higher than those of ripe fruits, showing lower carbohydrate in thinned fruits. The contents of inorganic substance were Ca, Mg, P, Na, K and B in order. On heavy metals, As, Cd, Cr and Hg were not detected and Ge, Mo, Ni and Pb were trace. Organic acid in thinned apple and peach were detected as tartaric acid, citric acid, malic acid and succinic acid, but thinned pear did not contain citric acid. Free sugars in thinned pear and peach were composed of glucose, fructose and sucrose but sucrose was not detected in thinned apple. Contents of insoluble dietary fiber in thinned fruits were higher than soluble dietary fiber. The thinned apple extracts showed high antioxidant activity. Nitrite scavenging activity of thinned apple and pear extracts were 71∼80 e/o and 61∼63% at pH 1.2, respectively. Tyrosinase inhibitory activity of thinned pear extracts was 61.0∼89.4 %, however peach extinct showed no activity.