• Title/Summary/Keyword: $Ca^{2+}$ flux

검색결과 213건 처리시간 0.028초

Tiny Pores Observed by New Solar Telescope and Hinode

  • 조경석;봉수찬;채종철;김연한;박영득
    • 천문학회보
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    • 제36권1호
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    • pp.37.2-37.2
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    • 2011
  • Our previous study on tiny pores (R < 2") observed by HINODE/Solar Optical Telescope (SOT) revealed that the plasma in the pores at the photosphere is always moving down and the pores are surrounded by the strong downward motions (highly red-shifted) of neighboring granulations. From this study, we speculated that the flow motions above the pore should be related with the motions at the photosphere, since the pore is strong magnetic field region. Meanwhile, SNU and KASI installed Fast Imaging Solar Spectrograph (FISS) in the Cude room of the 1.6 m New Solar Telescope (NST) at Big Bear Solar Observatory. FISS is a unique system that can do imaging of H-alpha and Ca II 8542 band simultaneously, which is quite suitable for studying of dynamics of chromosphere. To get some clue on the relationship between the photospheric and low-chromospheric motions at the pore region, we took a coordinate observation with NST/FISS and Hinode/SOT for new emerging active region (AR11117) on October 26, 2010. In the observed region, we could find two tiny pores and two small magnetic islands (SMIs), which have similar magnetic flux with the pores but does not look dark. Magnetic flux density and Doppler velocities at the photosphere are estimated by applying the center-of-gravity (COG) method to the HINODE/spectropolarimeter (SP) data. The line-of-sight motions above the photosphere are determined by adopting the bisector method to the wing spectra of Ha and CaII 8542 lines. As results, we found the followings. (1) There are upflow motion on the pores and downflow motion on the SMIs. (2) Towards the CaII 8542 line center, upflow motion decrease and turn to downward motion in pores, while the speed of down flow motion increases in the SMIs. (3) There is oscillating motion above pores and the SMIs, and this motion keep its pattern along the height. (4) As height increase, there is a general tendency of the speed shift to downward on pores and the SMIs. This is more clearly seen on the other regions of stronger magnetic field. In this talk, we will present preliminary understanding of the coupling of pore dynamics between the photosphere and the low-chromosphere.

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Investigation of Al-hydroxide Precipitate Fouling on the Nanofiltration Membrane System with Coagulation Pretreatment: Effect of Inorganic Compound, Organic Compound, and Their Combination

  • Choi, Yang-Hun;Kweon, Ji-Hyang
    • Environmental Engineering Research
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    • 제16권3호
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    • pp.149-157
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    • 2011
  • Nanofiltration (NF) experiments were conducted to investigate fouling of Al-hydroxide precipitate and the influence of organic compound, inorganic compound, and their combination, i.e., multiple foulants. $CaCl_2$ and $MgSO_4$ were employed as surrogates of inorganic compounds while humic acid was used as surrogate of organic compound. The flux attained from NF experiments was fitted with the mathematical fouling model to evaluate the potential fouling mechanisms. Al-hydroxide fouling with a cake formation mechanism had little effect on the NF membrane fouling regardless of the Al concentration. The NF fouling by Al-hydroxide precipitate was deteriorated in presence of inorganic matter. The effect of Mg was more critical in increasing the fouling than Ca. This is because the Mg ions enhanced the resistances of the cake layer accumulated by the Al-hydroxide precipitate on the membrane surfaces. However, the fouling with Mg was dramatically mitigated by adding humic acid. It is interesting to observe that the removal of the conductivity was enhanced to 61.2% in presence of Mg and humic acid from 30.9% with Al-hydroxide alone. The influence of dissolved matter (i.e., colloids) was more negative than particulate matter on the NF fouling for Al-hydroxide precipitate in presence of inorganic and organic matter.

Luminescent Properties of Two-Ions Doped Phosphors for LED Application

  • Kim, Tae-Gon;Kim, Young-Sic;Im, Seoung-Jae
    • 한국정보디스플레이학회:학술대회논문집
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    • 한국정보디스플레이학회 2009년도 9th International Meeting on Information Display
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    • pp.52-55
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    • 2009
  • A red phosphor, $(Sr,Ca)_2P_2O_7:Eu^{2+},Mn^{2+}$, for UV-LED was synthesized under a reducing atmosphere, and its luminescent properties were investigated. The phosphor absorbs ultraviolet light at around 400 nm and efficiently emits red light at approximately 610 nm through an energy transfer from $Eu^{2+}$ to $Mn^{2+}$. Using the varied input current test for the phosphor-loaded LED lamps, it was found that the luminescent efficiency of the phosphor decreased with increasing light flux. This might be due to an increased probability of excited-state absorption and the consequent non-radiative relaxation in $Mn^{2+}$ ions in the condition of high photon influx.

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한국 포타쉬 유리구슬의 조성 분류에 따른 특성 비교 (Characteristic Comparison of the Composition Classification on Potash Glass Beads Excavated in Korea)

  • 김나영;김규호
    • 보존과학회지
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    • 제31권3호
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    • pp.255-265
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    • 2015
  • 본 연구에서는 지금까지 자연과학적 분석을 통해 확인된 30개 유적의 281점 포타쉬유리에 대하여 화학 조성에 따라 유형을 분류하고 색상, 크기, 제작 기법 그리고 유통 시기를 비교하였다. 한국의 포타쉬유리는 안정제 함량에 따라 3가지 유형으로 구분된다. I, II형은 CaO와 $Al_2O_3$ 함량이 모두 5% 미만으로 상대적으로 I형은 CaO 함량이 높고 II형은 $Al_2O_3$ 함량이 높다. 이와 달리 III형은 CaO를 5% 이상 포함한다. 이들은 융제를 첨가하기 위해 I, II형이 초석, III형이 식물 재를 원료로 사용한 것으로 추정된다. 유형별 특성에서, I형은 감청색, 벽색 및 청록색, 자색을 띠고 외경이 1.4~7.4mm까지 다양한 크기가 확인된다. 늘인 기법에 의해 제작되었으며 가장 빠른 BC 1C경 출현하여 AD 6C까지 지속적으로 유통된 것으로 나타났다. 반면 II형은 벽색 및 청록색을 띠며, 외경이 1.9~3.6mm 정도의 소형 구슬이다. 제작 기법은 I형과 동일하며 AD 1C경 나타나 4C경 단절되는 양상을 보인다. 마지막으로 III형은 갈색, 무색, 황색을 띠며 외경이 대략 10mm 전후에 달하는 대형 구슬이다. 말은 기법에 의해 성형되었으며 고려 및 조선시대 민묘에서 등장한다. 이상의 결과에서 한국에서 유통된 3가지 유형의 포타쉬유리는 각기 다른 생산지에서 다양한 교역 루트를 통해 유입된 것으로 판단된다.

탄소피막 저항기용 자기소체 제조에 있어 Barite 활용에 관한 연구 (Study on the Utilization of Barite in Making Carbon Film Ceramic Resistor)

  • 박정현;전병세;배원태
    • 한국세라믹학회지
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    • 제19권2호
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    • pp.95-100
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    • 1982
  • Instead of barium carbonate, domestic barite was used as the flux in manufacturing theinsulating porcelain. To avoid the problems arising from the decomposition of barite in the body during firing, BaO.$Al_2O_3$ was synthesized at $1300^{\circ}C$ for 5 hours. synthetic BaO.$Al_2O_3$ was mixed with other materials such as kaoline, alumina, clay, dolomite. The RO content (CaO. MgO. BaO) of the batches was varied from range of 4 to 14wt. % at 2wt. % - intervals, and firing temperature was varied from 1280 to 140$0^{\circ}C$-at 4$0^{\circ}C$ intervals The properties such as water absorption, bulk density. mechnical strength, specific resistance, and linear shrinkage were measured. The body containing 12 wt.% of RO content showed the satisfactory for the application in the Fixed Carbon Film Resistor.

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질산은을 산소 캐리어로 하는 CA막의 제조 (Preparation of Cellulose Acetate Containing Silver Nitrate as Oxygen Carrier)

  • 안필성;이우태
    • 한국산업융합학회 논문집
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    • 제2권2호
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    • pp.83-90
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    • 1999
  • A cellulose acetate membrane containing silver nitrate was prepared by gelatinizing in water at $2^{\circ}C$ after evaporating solvent from the casting solution on a glass plate. Permeation experiments for oxygen and nitrogen were conducted in the ranges of temperature, $5-40^{\circ}C$ and pressure difference, $1-5kg/cm^2$ in order to investigate the effects of temperature and pressure difference on permeation characteristics of the membrane. When the evaporation time was increased, the permeability of oxygen decreased but the separation factor of oxygen against nitrogen increased since a more dense layer was formed on the membrane surface. When the silver nitrate was added, the permeation flux was doubled and the separation factor was improved from 3.0 to 3.3. This implies that silver nitrate acts as an oxygen carrier in the membrane.

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한국에서 분진 및 금속원소의 건식 침착속도 추정에 관한 연구 (Studies on Estimating Dry Deposition Velocities for Atmospheric Aerosol and Metal Elements in Korea)

  • 김성천;김동술
    • 한국대기환경학회지
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    • 제12권1호
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    • pp.101-112
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    • 1996
  • Dry and wet deposition is an impertant removal mechanism of the amobient aerosol in the atmospheric environment. Since the deposition flut provides adverse impacts on various encironmental media including aquatic and ecological system as well as human health, it is essential to quantitatively estimate the removal fluxes of many air pollutants. Thus, the purposes of this experimental study are to investigate seasonal deposition flux variations of the total dustfall and various inorganic elements in the local ambient air and then to finally estimate their dry deposition velocities. To perform the study, the total of 90 dustfall samples were collected from January, 1994 thru February, 1995 in 5 different cities of Korea including Seoul, Suwon, Daejon, Kwangju, and Kangrung. Each sample was analyzed by an AAS and an ICP to determine the quantities of the 11 inorganic elements, such as Zn, Cd, Cr, K, Na, Pb, Ca, Fe, Mn, Mi, and Cu. As results, deposition fluxes, soluble/insoluble fractions, and deposition velocities for each element were extensively investigated. The resulting dry deposition velocities of some elements in Suwon were estimated by ranges of 0.57 .sim. 0.87 cm/sec for Zn, 0.35 .sim. 0.45 cm/sec for Pb, 1.25 .sim. 3.52 cm/sec for Ca, 0.21 .sim. 0.48 cm/sec for Fe, 0.95 .sim. 9.31 cm/sec for Mn, and 2.08 cm/sec for Cu.

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남해안 통영지역 가두리양식장 해수-퇴적물 경계면에서의 chemical fluxes (Chemical Fluxes at the Sediment-Water Interface Below Marine Fish Cages on the Coastal Waters off Tong-Young, South Coast of Korea)

  • 심정희;강영철;최진우
    • 한국해양학회지:바다
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    • 제2권2호
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    • pp.151-159
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    • 1997
  • 1995년 6월, 남해안 통영지역 가두리양식장 해수-퇴적물 경계면에서 입자상유기물의 수직유입량과 용존산소의 소모량, 영양염류의 용출량을 관측하였다. 입자상유기물의 수직유입량은 저층고정식 sediment trap을 이용하였으며, 용존산소의 소모량과 영양염류의 용출량은 benthic chamber method로 측정하였다. 가두리양식이 연안부영양화에 미치는 영향과 가두리에서 유출된 입자상유기물의 확산강도를 정량하기 위해, 가두리 아래(수심 약 18 m, Cage Site)와 가두리에서 수평으로 약 100 m 가량 떨어진 곳(수심 약 32 m, Control Site)의 해수-퇴적물 경계면에서, 암모니아와 인산염, 규산염의 용출량을 비교하고, 탄소와 질소와 인의 mass balances를 추정하였다. 관측결과, 가두리정점(Cage Site)으로는 6400 mg C $m^{-2}d^{-1}$의 입자상유기물이 유입되었고, 동시에 230 mmol $O_2\;m^{-2}d^{-1}$ 이상의 용존산소가 소모되었다. 따라서 탄소의 경우, 가두리 아래 해저면으로 공급되는 유기 입자의 약 40%에 달하는 양이 해수-퇴적물 경계면에서 분해되며 (ca. 2400 mg C $m^{-2}d^{-1}$), 나머지 약 60%는 퇴적되어 매몰되는 것으로 보인다. (ca. 4000 mg C $m^{-2}d^{-1}$) 그러나 대비정점(Control Site)에서는 가두리정점에 비해 상대적으로 적은 양의 유기물유입과(ca. 4000 mg C $m^{-2}d^{-1}$), 낮은 용존산소소모율이 관측되었다(75 mmol $O_2\;m^{-2}d^{-1}$). 관측결과는 가두리에서 투기되는 대부분의 입자상유기물이 가두리 아래 해저면에 집중적으로 퇴적되고 있음을 보여주며, 가두리 부근 해저면으로 확산되는 입자상유기물의 양은 가두리에서 멀어질수록 급속히 감소함을 시사한다.

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투과증발공정을 이용한 물-알코올계에 대한 금속이온이 치환된 이온교환막의 염효과 연구 (Salt Effect of Metal Ion Substituted Membranes for Water-Alcohol Systems Using Pervaporation Processes)

  • 임지원;전지현
    • 멤브레인
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    • 제11권3호
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    • pp.133-139
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    • 2001
  • PVA/SSA-$H^{+}$으로 제조된 막은 1가 이온 $Li^{+}$, $Na^{+}$, $K^{+}$, 2가 이온 $Mg^{2+}$, $Ca^{2+}$, $Ba^{2+}$, 3가 이온 $Al^{+}$로 치환되었다. 각 금속이온이 치환된 막의 금속이온의 효과를 알아보기 위하여 물-에탄올 및 물-메탄올 혼합용액에 대하여 팽윤도 및 투과증발 실험을 수행하였다. 또한 이들의 치환정도를 알아보기 위해 부분적으로 ESCA 실험을 통하여 알아보았다. 물-에탄올 및 물-메탄올 혼합용액에 대한 팽윤도는 $Li^{+}$> $Na^{+}$>$K^{+}$의 순으로 감소하였는데 이는 금속이온의 `salting-out'효과에 기인하는 것으로 사료되었으며, 2가 및 3가이온의 경우의 팽윤도 결과는 `salting-out' 효과뿐만 아니라 electrostatic 가교 및 금속이온의 반응성에 의해 좌우되는 것으로 사료되었다. 투과증발실험을 통한 투과도면에서는 물-에탄올 용액에 대해 PVA/SSA-$Na^{+}$막에서 최소치를 보였다가 PVA/SSA-$K^{+}$막에서 다시 증가하는 결과를 얻은 반면에 선택도는 반대의 경향을 얻었다. 대표적 분리 결과는 $50^{\circ}C$에서 90%에탄올 수용액에 대하여 투과도는 59 g/$m^{2}$hr, 선택도는 44의 값을 얻었다. 물-메탄올 용액에 대해서는 1가이온의 경우 에탄올 용액과 같은 경향의 결과를 얻었으나 2가 및 3가 이온의 경우 팽윤도 실험 결과와 마찬가지로 `salting-out' 효과 그리고 electrostatic 가교 등에 의해 영향을 받는다고 할 수 있다.

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이가 양이온 금속 친환 및 유기 첨가제를 이용하여 분무열분해법으로 제조된 Y2O3:Eu3+ 적색 형광체의 휘도 개선 (Photoluminescence Enhancement of Y2O3:Eu3+ Red Phosphor Prepared by Spray Pyrolysis using Aliovalent Cation Substitution and Organic Additives)

  • 민병호;정경열
    • 한국분말재료학회지
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    • 제27권2호
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    • pp.146-153
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    • 2020
  • The co-doping effect of aliovalent metal ions such as Mg2+, Ca2+, Sr2+, Ba2+, and Zn2+ on the photoluminescence of the Y2O3:Eu3+ red phosphor, prepared by spray pyrolysis, is analyzed. Mg2+ metal doping is found to be helpful for enhancing the luminescence of Y2O3:Eu3+. When comparing the luminescence intensity at the optimum doping level of each Mg2+ ion, the emission enhancement shows the order of Zn2+ ≈ Ba2+ > Ca2+ > Sr3+ > Mg2+. The highest emission occurs when doping approximately 1.3% Zn2+, which is approximately 127% of the luminescence intensity of pure Y2O3:Eu3+. The highest emission was about 127% of the luminescence intensity of pure Y2O3:Eu3+ when doping about 1.3% Zn2+. It is determined that the reason (Y, M)2O3:Eu3+ has improved luminescence compared to that of Y2O3:Eu3+ is because the crystallinity of the matrix is improved and the non-luminous defects are reduced, even though local lattice strain is formed by the doping of aliovalent metal. Further improvement of the luminescence is achieved while reducing the particle size by using Li2CO3 as a flux with organic additives.