• Title/Summary/Keyword: $Ca^{2+}$ flux

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Study on the Reaction Characteristics of Self-reducing $Nb_2O_5$ Briquettes (자기 환원성 $Nb_2O_5$ 브리켓의 반응특성 연구)

  • Kim M. S.;You B. D.;Wi C. H.;Yun D. J.;Choi S. O.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2005.05a
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    • pp.333-336
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    • 2005
  • The reduction behavior of $Nb_2O_5$ in aluminum containing self-reducing briquettes(SRNB) was investigated. The time required for slag/metal equilibrium was estimated as about 20 minutes from the addition of SRNB on to the surface of molten steel. The maximum yield of Nb was expected with the slag composition of $60\%CaO-40\%Al_2O_3$. When $CaCO_3$ was used as a flux, the oxidation loss of Al by $CO_2$ should be compensated, and the chemical equivalent ratio of Al to $Nb_2O_5$ of about 1.43 was required to maximize the yield of Nb.

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Coherent motion of fluxons in stacked intrinsic Josephson junctions of $Bi_2$$Sr_2$Ca$Cu_2$$O_{8+x}$ single crystals ($Bi_2Sr_2CaCu_2O_{8+x}$ 단결정 선천성 조셉슨 접합에서의 플럭손 결맞음 운동)

  • Doh, Yong-Joo;Chang, Hyun-Sik;Chang, Dong-In;Lee, Hu-Jong;Kim, Jinhee;Kim, Kyu-Tae;Lee, Woo;Choy, Jin-Ho
    • Progress in Superconductivity
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    • v.3 no.1
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    • pp.28-30
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    • 2001
  • We studied the flux-flow current-voltage characteristics of microwave-generated fluxons formed in serially stacked intrinsic Josephson junctions fabricated on$ HgI_2$-intercalated $Bi_2$$Sr_2$$CaCu_2$O/8+x/(Bi2212) single crystals. With increasing the irradiation power of 73$\square$76 GHz microwave, the supercurrent branch became resistive and split into multiple sub -branches. Each sub-branch represented a specific mode of collective motion of Josephson fluxons. We also observed similar branch splitting In a mesa prepared on an underdoped Bi2212 single crystal in a static magnetic field.

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An experimental study of magnetic diffusion in Bi-2212 High-Tc supercondutor tube (Bi-2212 고온초전도체 튜브의 자기확산에 관한 연구)

  • 정성기;설승윤
    • Progress in Superconductivity and Cryogenics
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    • v.5 no.2
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    • pp.66-70
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    • 2003
  • Transient magnetic diffusion process in a melt-cast Bi2Sr2CaCu20X(Bi-2212) tube was studied by experimental and numerical analyses. The transient diffusion partial differential equation is transformed into an ordinary differential equation by integral method. The penetration depth of magnetic field into a superconducting tube is obtained by solving the differential equation numerically. The results show that the penetration depth as a function of time which is somewhat different from the results by Bean's critical state model. The reason of the difference between the present results and that of Bean's model is discussed and compared in this paper. This experiment measure the magnetic flux density in the supercondutor after supply direct-current of Bi-2212 rounded by copper coil. This study was discussed of valid of a previous numerical solution which is compared by the penetrate time and the magnetic flux density difference of between the present results and the numerical solution.

Effects of polymeric Al and hydrolysis products of PAC at different pH on performance of nanofiltration with PAC coagulation pretreatment (PAC 전처리 시 수소이온 농도에 따라 발생 가능한 알루미늄 종에 의한 나노여과막 성능 연구)

  • Choi, Yang-Hun;Kweon, Ji-Hyang
    • Journal of Korean Society of Water and Wastewater
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    • v.24 no.1
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    • pp.15-24
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    • 2010
  • Coagulation can be used for pretreatment of NF membrane filtration. Foulants such as organic matter and particulate can be removed effectively with the process while high flux recovery is maintained. Recently various types of polyaluminium coagulants including polyaluminium chloride(PAC) are commercially available for water treatment. This study examines effects of polymeric Al and hydrolysis products of PAC on nanofiltration membrane performance. Dominant hydrolysis products were polymeric Al, $Al(OH)_3$, and ${Al(OH)_4}^{-1}$ at acidic, neutral, and alkaline pH conditions, respectively. Under acidic pH condition, flux decline was increased with increasing PAC concentrations, possibly due to polymeric Al adsorption on membrane pore and/or surfaces. For neutral and alkaline pH conditions, little flux decline was observed with increasing PAC concentrations except the highest ${Al(OH)_4}^{-1}$ concentration, with which rapid flux decline was shown. Removal of ionic matters was also varied with pH conditions in this study. Especially, conductivity removal was substantially low and $Ca^{2+}$ concentration in the permeate was quite high at neutral pH condition.

Fly Ash Application Effects on CH4 and CO2 Emission in an Incubation Experiment with a Paddy Soil (항온 배양 논토양 조건에서 비산재 처리에 따른 CH4와 CO2 방출 특성)

  • Lim, Sang-Sun;Choi, Woo-Jung;Kim, Han-Yong;Jung, Jae-Woon;Yoon, Kwang-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.5
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    • pp.853-860
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    • 2012
  • To estimate potential use of fly ash in reducing $CH_4$ and $CO_2$ emission from soil, $CH_4$ and $CO_2$ fluxes from a paddy soil mixed with fly ash at different rate (w/w; 0, 5, and 10%) in the presence and absence of fertilizer N ($(NH_4)_2SO_4$) addition were investigated in a laboratory incubation for 60 days under changing water regime from wetting to drying via transition. The mean $CH_4$ flux during the entire incubation period ranged from 0.59 to $1.68mg\;CH_4\;m^{-2}day^{-1}$ with a lower rate in the soil treated with N fertilizer due to suppression of $CH_4$ production by $SO_4^{2-}$ that acts as an electron acceptor, leading to decreases in electron availability for methanogen. Fly ash application reduced $CH_4$ flux by 37.5 and 33.0% in soils without and with N addition, respectively, probably due to retardation of $CH_4$ diffusion through soil pores by addition of fine-textured fly ash. In addition, as fly ash has a potential for $CO_2$ removal via carbonation (formation of carbonate precipitates) that decreases $CO_2$ availability that is a substrate for $CO_2$ reduction reaction (one of $CH_4$ generation pathways) is likely to be another mechanisms of $CH_4$ flux reduction by fly ash. Meanwhile, the mean $CO_2$ flux during the entire incubation period was between 0.64 and $0.90g\;CO_2\;m^{-2}day^{-1}$, and that of N treated soil was lower than that without N addition. Because N addition is likely to increase soil respiration, it is not straightforward to explain the results. However, it may be possible that our experiment did not account for the substantial amount of $CO_2$ produced by heterotrophs that were activated by N addition in earlier period than the measurement was initiated. Fly ash application also lowered $CO_2$ flux by up to 20% in the soil mixed with fly ash at 10% through $CO_2$ removal by the carbonation. At the whole picture, fly ash application at 10% decreased global warming potential of emitted $CH_4$ and $CO_2$ by about 20%. Therefore, our results suggest that fly ash application can be a soil management practice to reduce green house gas emission from paddy soils. Further studies under field conditions with rice cultivation are necessary to verify our findings.

The Influence of Several Drugs Affecting $Ca^{2+}$ Influx on Frequency-tension Curve of Rat Left Atrium (쥐의 좌심방에서 세포막을 통한 $Ca^{2+}\;Flux$에 영향을 주는 약물이 자극빈도-장력 곡선에 미치는 영향)

  • Kim, Chan-Yun;Ahn, Sok-Kyun;Suh, Chang-Kook;Kang, Doo-Hee
    • The Korean Journal of Physiology
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    • v.23 no.2
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    • pp.329-337
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    • 1989
  • Cardiac muscles show stimulation frequency-dependent tension changes i.e. Bowditch phenomenon and Woodworth phenomenon, the former is an increase of tension with the increase of stimulation frequency, whereas the latter is an increase of tension with a decrease of stimulation frequency. Bowditch phenomenon is seen in the range of frequency 1.0 cps and above, and Woodworth phenomenon below the frequency 1.0 cps in the most of mammalian cardiac atrium. To throw some light on the possible mechanism of both phenomena in rat atrium, influences of drugs affecting $Ca^{2+}$ influx through the plasma membrane $(verapamil,\;La^{3+},\;norepinephrine)$ and $Ca^{2+}$ release from sarcoplasmic reticulum (SR) on frequency-tension curve were studied. The results obtained are summarized as follows: 1) At low temperature $(27.5^{\circ}C)$, both Bowditch and Woodworth phenomenon were demonstrated. But Bowditch phenomenon disappeared at the temperature above $(32.5^{\circ}C)$. 2) At $(27.5^{\circ}C)$, in the presence of verapamil, a $Ca^{2+}$ channel blocker, a time course of change in the frequency-tension was studied. It was found that Bowditch phenomenon was affected before the Woodworth phenomenon, then the former was completely disappeared. At $(32.5^{\circ}C)$, where no Bow-ditch is seen in normal atrial muscle, Bowditch phenomenon was reappeared by an administration of norepinephrine suggesting again that slow inward current of such as $Ca^{2+}$ channel is closely related to Bowditch phenomenon. 3) At $27.5^{\circ}C$, in the presence of $La^{3+}$, although tensions were decreased at all stimulation frequencies, Bowditch and Woodworth phenomenon were still demonstrated. However in the presence of both $La^{3+}$ and verapamil, Bowditch phenomena was disappeared suggesting that $La^{3+}$ is less effective in blocking $Ca^{2+}$ channel than verapamil. 4) At $27.5^{\circ}C$, in the presence of ryanodine, an inhibitor of calcium release from SR, Woodworth phenomenon was disappeared, which was consistent with previous reports of others, suggesting that $Ca^{2+}$ release from SR is closely related to Woodworth phenomenon. From the above findings, it may be concluded that Bowditch phenomenon is dependent on the magnitude of $Ca^{2+}$ influx through slow channel and Woodworth phenomenon is dependent on the amount of $Ca^{2+}$ stored in SR.

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Inorganic Nutrient Inputs from Precipitation, Throughfall, and Stemflow in Pinus densiflora and Quercus mongolica Stands in an Urban Forest Ecosystem

  • Kim, Kee Dae
    • Journal of Environmental Science International
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    • v.28 no.10
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    • pp.813-829
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    • 2019
  • We measured the amount of precipitation, stemflow, and throughfall and concentrations of nine major inorganic nutrients ($H^+$, ${NH_4}^+$, $Ca^{2+}$, $Mg^{2+}$, $K^+$, $Na^+$, $Cl^-$, ${NO_3}^-$, and ${SO_4}^{2-}$) to investigate the nutrient inputs into soil from precipitation in Pinus densiflora and Quercus mongolica stands from September 2015 to August 2016. The precipitation inputs of $H^+$, ${NH_4}^+$, $Ca^{2+}$, $Mg^{2+}$, $K^+$, $Na^+$, $Cl^-$, ${NO_3}^-$, and ${SO_4}^{2-}$ into soil were 0.170, 15.124, 42.227, 19.218, 14.050, 15.887, 22.391, 5.431, and $129.440kg{\cdot}ha^{-1}{\cdot}yr^{-1}$, respectively. The P. densiflora stemflow inputs were 0.008, 0.784, 1.652, 1.044, 0.476, 0.651, 1.509, 0.278, and $9.098kg{\cdot}ha^{-1}{\cdot}yr^{-1}$, and those for Q. mongolica were 0.008, 0.684, 2.429, 2.417, 2.941, 1.398, 2.407, 0.436, and $13.504kg{\cdot}ha^{-1}{\cdot}yr^{-1}$, respectively. The P. densiflora throughfall inputs were 0.042, 21.518, 52.207 27.694, 20.060, 24.049, 37.229, 10.241, and $153.790kg{\cdot}ha^{-1}{\cdot}yr^{-1}$, and those for Q. mongolica were 0.032, 15.068, 42.834, 21.219, 20.294, 20.237, 24.288, 5.647, and $119.134kg{\cdot}ha^{-1}{\cdot}yr^{-1}$, respectively. Of the total throughfall flux (i.e., stemflow + throughfall flux) of the nine ions for the two species, ${SO_4}^{2-}$ had the greatest total throughfall flux and $H^+$ had the lowest. The net throughfall fluxes of the ions for the two species had various correlations with the precedent dry period, rainfall intensity, rainfall amount, and pH of precipitation. The soil pH under the Q. mongolica canopy (4.88) was higher than that under the P. densiflora canopy (4.34). The difference in the soil pH between the two stands was significant (P < 0.01), but the difference in soil pH by the distance from the stems of the two species was not (P > 0.01). This study shows the enrichments of inorganic nutrients by two representative urban forests in temperate regions and the roles of urban forests during rainfall events in a year.

Development of Iron and Steelmaking Processes by Slag Engineering Technology (슬래그 엔지니어링에 의한 製銃 및 제강조업의 효율향상에 관한 연구)

  • 박주현;민동준;송효석
    • Resources Recycling
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    • v.10 no.3
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    • pp.37-42
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    • 2001
  • Current iron and steelmaking operation was re-evaluated on the basis of slag engineering technology to optimize slag operations. In blast furnace process, increase in the basicity of slags (C/S) could obtain progressed fluidity and hot metal quality. COREX process would be stabilized in view of slag fluidity and hot metal quality by reducing input content of $SiO_2$and $A1_2$$O_3$In STS-AOD process, addition of small amount of lime could improve refining capacity of the slag; also calcium aluminate flux could be taken into account as a potential substitute for fluorspar, without degradation of operation efficiency and steel quality.

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Garnet-Orthopyroxene Geothermometer and Geological Applications (석류석-사방휘석 지질온도계와 지질학적 응용)

  • Lee, Han Yeang
    • Economic and Environmental Geology
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    • v.21 no.1
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    • pp.29-44
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    • 1988
  • Equilibrium relations between garnet and orthopyroxene have been investigated by reversal experiments in the range of 20-45Kb and $975-1400^{\circ}C$ in the $FeO-MgO-Al_2O_3-SiO_2$(FMAS) system. A mixture of PbO with about 55 mol per cent $PbF_2$ was used as a flux and proved very effective. The Fe-Mg exchange reaction seems to have little or no compositional dependence at these conditions. Combination of the experimental results with the garnet mixing model of Ganguly and Saxena(1984) yields the following geothermometric expression for the common natural assemblages that can be represented essentially within the system $FeO-MgO-CaO-MnO-Al_2O_3-SiO_2$. $$T^{\circ}C=(1971+11.91P(Kb)+1510(X_{Ca}+X_{Mn})^{Gt}/(lnK_D+0.96)-273$$.

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Phase Transformation and Luminescent Properties of Ca1-xSrxAl2O4:Eu2+ Phosphors ([Ca1-xSrxAl2O4:Eu2+] 형광체의 상전이 및 발광특성에 관한 연구)

  • Park, Yun-Jin;Song, Hyun-Don;Jung, Sang-Hyun;Lee, Jee-Hee;Hwang, Min-Ha;Kim, Young-Jin
    • Korean Journal of Materials Research
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    • v.18 no.1
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    • pp.1-4
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    • 2008
  • The phase transformations and luminescent properties of Eu-doped $Ca_{1-x}Sr_xAl_2O_4$ phosphors were investigated. $Ca_{1-x}Sr_xAl_2O_4:Eu^{2+}$ phosphors were synthesized by a solid-state reaction with a flux, $H_3BO_3$. A phase transformation from monoclinic $CaAl_2O_4$ to monoclinic $SrAl_2O_4$ was observed as the x values increased. A high-temperature hexagonal phase of $SrAl_2O_4$ was formed during this transformation as an intermediate phase under an $H_2$ atmosphere due to oxygen vacancies; this did not occur in an air atmosphere. Accordingly, the emission spectra shifted from a blue region to a green region as x increased.