• Title/Summary/Keyword: $Ca^{++}$uptake

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Usable Capacity for CO2 capture and storage in MOFs (금속 유기 골격체를 활용한 사용 가능한(Usable capacity) 이산화탄소 포집 연구)

  • Park, Seoha;Oh, Hyunchul;Jang, Haenam
    • Journal of Energy Engineering
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    • v.27 no.4
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    • pp.80-85
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    • 2018
  • Usable capacity is one of the most important parameters for evaluating the performance of an adsorbent for $CO_2$ capture from flue gas streams. In the pressure swing adsorption (PSA) process, the usable capacity is calculated as the difference between the quantity adsorbed in flue gas at high pressure (ca. 20 bar) and the quantity adsorbed at lower purge pressure (ca. 2 bar). In this paper, two stereo-types of metal-organic framework (MOF) were evaluated as an promising adsorbent for $CO_2$ capture: flexible structured MOF (MIL-53) and MOF possessing strong binding sites (MOF-74). The results showed that a total $CO_2$ capture capacity is strongly related to the specific surface area and heat of adsorption, revealing high uptake in MOF-74. However, the usable capacity was more pronounced in MIL-53 due to a structural transition.

Effect of Cigarette Filter on Cytotoxicity Potential of Mainstream Smoke (담배주류연의 세포독성에 대한 담배필터의 영향)

  • Shin Han-Jae;Sohn Hyung-Ok;Han Jung-Ho;Park Chul-Hoon;Hur Jae-Yeon;Lee Dong-Wook;Hwang Keon-Joong;Hyun Hak-Chul
    • Journal of the Korean Society of Tobacco Science
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    • v.27 no.1 s.53
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    • pp.51-58
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    • 2005
  • The objective of this study was to evaluate the effect of cigarette filter on in vitro cytotoxicity of cigarette mainstream smoke from the cigarette. In this work, we used 3 types of cigarettes included non-filtered 2R4F cigarette, cellulose acetate-filtered 2R4F cigarette, and carbon dual-filtered 2R4F cigarette which was made from original 2R4F by replacing with an acetate filter containing carbon. The cytotoxicity of both the cigarette smoke condensate (CSC), which was collected in Cambridge filter pad, and the gas/vapor phase (GVP), which was bubbled through in phosphate-buffered saline in a gas-washing bottle, was determined using a neutral red uptake assay with CHO-K1 cells. With regard to cytotoxicity when calculated on an equal puff basis, the cytotoxicity of CSC from the filtered cigarettes was lower than that of the non filtered cigarette. Also, $EC_{50}$ vlaue of GVP from carbon filter cigarette was 40.9 puff/L, indicating the cytotoxicity to be $20\%$ lower than that of the CA filter cigarette. The cytotoxicity of the GVP was correlated to the several vapor phase components (formaldehyde, acetaldehyde, acetone, acrolein, crotonaldehyde and MEK). In conclusion, carbon filter, which significantly reduced the amount of carbonyl compounds in mainstream cigarette smoke, results in significant reductions in the cytotoxicity potential of the smoke.

Solute patterns of four halophytic plant species at Suncheon Bay in Korea

  • Choi, Sung-Chul;Choi, Deok-Gyun;Hwang, Jeong-Sook;Kim, Jong-Guk;Choo, Yeon-Sik
    • Journal of Ecology and Environment
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    • v.37 no.3
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    • pp.131-137
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    • 2014
  • To investigate the solute pattern of salt marsh plants in Suncheon Bay in Korea, plants and soil samples were collected at three sites from July to September 2011. The soil pH around the investigated species was weakly alkaline, 6.9-8.1. The total ion and Cl- content of site 1 gradually increased, while those of site 2 and site 3 were lowest in August and highest in September. The exchangeable $Ca^{2+}$, $Mg^{2+}$ and $K^+$ in the soil were relatively constant during the study period, but the soil exchangeable $Na^+$ content was variable. Carex scabrifolia and Phragmites communis had constant leaf water content and very high concentrations of soluble carbohydrates during the study period. However, Suaeda malacosperma and S. japonica had high leaf water content and constant very low soluble carbohydrate concentrations. Carex scabrifolia accumulated similar amounts of $Na^+$ and $K^+$ ions in its leaves. Phragmites communis contained a high concentration of $K^+$ ions. Suada japonica and S. malacosperma had more $Na^+$ and $Cl^-$ ions than $K^+$ ions in their leaves. Suaeda japonica had higher levels of glycine betaine in its leaves under saline conditions than C. scabrifolia and P. communis. Consequently, the physiological characteristics of salt marsh chenopodiaceous plants (S. japonica and S. malacosperma) were the high storage capacity for inorganic ions (especially alkali cations and chloride) and accumulation of glycine betaine, but monocotyledonous plant species (C. scabrifolia and P. communis) showed high $K^+$concentrations, efficient regulation of ionic uptake, and accumulation of soluble carbohydrates. These characteristics might enable salt marsh plants to grow in saline habitats.

Studies on nickel uptake in transgenic Arabidopsis thaliana introduced with TgMTP1 gene encoding metal tolerance protein (TgMTP1 과발현 애기장대에서 Nickel 흡수 연구)

  • Kim, Donggiun
    • Journal of Plant Biotechnology
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    • v.42 no.4
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    • pp.409-413
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    • 2015
  • To enhance phytoremediation, which removes heavy metal from soil, transgenic plants were applied to contaminated soil. We constructed a transformation vector expressing both $TgMTP_1$ (T. goesingense metal tolerance protein):HA and TgMTP:GFP genes. Transgenic plants were generated using an Agrobacterium-mediated transformation system that expressed the two vectors. Screening and analysis confirmed the incorporation of foreign genes into the Arabidopsis thaliana genome. Callus was induced in the 116 T3 line. These transgenic plants and calli were used for further analyses on the accumulation of Ni. The 116 T3-line plants and calli from selected lines were resistant to heavy metals and accumulated Ni in their leaves. The expression level of TgMTP RNA was equal in all leaves, but protein stability increased in the leaves with Ni treatment. According to these results, we suggest that $TgMTP_1$-overexpressing plants may be useful for phytoremediation of soil.

Enhancement of the Strength of MgO-Based Binder by Accelerated Carbonation (촉진탄산염화에 의한 마그네슘계 고화제의 강도 향상 특성)

  • Yun, Do Youn;Ahn, Jun-Young;Kim, Cheolyong;Kim, Tae Yoo;Hwang, Inseong
    • Journal of Soil and Groundwater Environment
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    • v.21 no.6
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    • pp.135-145
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    • 2016
  • MgO recently has been regarded as the alternative material for replacement of cement. The aim of this study is to investigate the effects of accelerated carbonation on the strength development of MgO-based binder which is binary mixtures of magnesium oxide (MgO) with portland cement (PC) or ground granulated blast furnace slag (GGBS) or fly ash (FA). The compressive strengths of all binders were higher in the 20% $CO_2$ condition and for longer curing time. The strength were generally higher as the following order: MgO/PC > MgO/GGBS > MgO/FA system. The binder composed of 20% MgO and 80% PC showed highest compressive strength (38.0MPa) which was higher than PC. The correlation analysis of the porosity and compressive strength showed that compressive strength was higher when porosity was lower. The hydration and carbonation products of MgO including brucite ($Ca(OH)_2$), magnesite ($MgCO_3$) and nesquehonite ($MgCO_3{\cdot}3H_2O$) presumably filled the pores and contributed to strength development. Thermogravimetric analyses elucidated that 0.34 kg of $CO_2$ could be stored the 50% MgO/50% PC binder which performed the maximum $CO_2$ uptake at 20% $CO_2$ condition.

Loss of Heterozygosity at the Calcium Regulation Gene Locus on Chromosome 10q in Human Pancreatic Cancer

  • Long, Jin;Zhang, Zhong-Bo;Liu, Zhe;Xu, Yuan-Hong;Ge, Chun-Lin
    • Asian Pacific Journal of Cancer Prevention
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    • v.16 no.6
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    • pp.2489-2493
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    • 2015
  • Background: Loss of heterozygosity (LOH) on chromosomal regions is crucial in tumor progression and this study aimed to identify genome-wide LOH in pancreatic cancer. Materials and Methods: Single-nucleotide polymorphism (SNP) profiling data GSE32682 of human pancreatic samples snap-frozen during surgery were downloaded from Gene Expression Omnibus database. Genotype console software was used to perform data processing. Candidate genes with LOH were screened based on the genotype calls, SNP loci of LOH and dbSNP database. Gene annotation was performed to identify the functions of candidate genes using NCBI (the National Center for Biotechnology Information) database, followed by Gene Ontology, INTERPRO, PFAM and SMART annotation and UCSC Genome Browser track to the unannotated genes using DAVID (the Database for Annotation, Visualization and Integration Discovery). Results: The candidate genes with LOH identified in this study were MCU, MICU1 and OIT3 on chromosome 10. MCU was found to encode a calcium transporter and MICU1 could encode an essential regulator of mitochondrial $Ca^{2+}$ uptake. OIT3 possibly correlated with calcium binding revealed by the annotation analyses and was regulated by a large number of transcription factors including STAT, SOX9, CREB, NF-kB, PPARG and p53. Conclusions: Global genomic analysis of SNPs identified MICU1, MCU and OIT3 with LOH on chromosome 10, implying involvement of these genes in progression of pancreatic cancer.

Effects of Artificial Zeolite and Various ion Exchangers Supplemented in Rockwool on the Ion Exchangability of Muskmelon (암면배지내 인공 zeolite 형 각종 이온교환제 처리가 온실멜론의 이온교환능에 미치는 영향)

  • 장홍기;정순주
    • Journal of Bio-Environment Control
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    • v.5 no.1
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    • pp.43-49
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    • 1996
  • This study was conducted to investigate the effects of artificial zeolite and various ion exchangers supplemented in rockwool on the ion exchangability of muskmelon. The results obtained were as follows ; Plant height was higher in the treatment of Ca type artificial zeolite as of 131.2cm than that of control as of 124cm, and same trends were shown in fresh weight of leaf and stem. Fruit weight was increased by supplement of artificial zeolite, but there were no significant differences in the sugar degree and external appearance as influenced by supplementing artificial zeolite. Supplement of artificial zeolite stabilized the pH and increased the ion exchange capacity of nutrient solution. Nutrient absorption was more favorable and led to growth promotion. This study was demonstrated that supplement of artificial zeolite in rockwool slab was improved the stabilization of root environment and increased ion uptake of muskmelon plant.

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Effect of Calcium Cyanamide on Control of Clubroot of Chinese Cabbage Caused by Plasmodiophora brassicae (석회질소에 의한 배추뿌리혹병 방제효과)

  • Kim, Jeom-Soon;Lee, Jeong-Tae;Lee, Gye-Jun
    • Research in Plant Disease
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    • v.12 no.3
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    • pp.278-283
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    • 2006
  • The effect of calcium cyanamide($CaCN_2$) on suppression of clubroot of Chinese cabbage was evaluated in the fields infested with Plasmodiophora brassicae at National Institute of Highland Agriculture, Pyeongchang, Korea, from 2002 to 2003. Calcium cyanamide was found to be more effective in reducing disease severity than flusulfamide dust powder. The optimal dosage of calcium cyanamide for control of clubroot of Chinese cabbage was 61 kg/10a. When calcium cyanamide was incorporated into soil at 5, 10, 15 and 20 days before planting(DBP), maximum disease suppression was obtained in the plot with calcium cyanamide, applied 5DBP. The fertilizer property of calcium cyanamide as a nitrogen fertilizer was also investigated by comparing with urea on cv. CR Gangta, a resistant variety of Chinese cabbage. The nitrogen uptake in calcium cyanamide treatment(17.6 kg/10a), was not significantly different from that of urea(17.8 kg/10a). These results indicated that calcium cyanamide could be used as a soil disinfectant as well as a nitrogen fertilizer.

Effect of Artificial Light Sources on the Growth of Crisphead Lettuce in Plant Factory (식물공장에서 인공광원이 결구상추의 생육에 미치는 영향)

  • 조영렬;한동욱;이용범
    • Journal of Bio-Environment Control
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    • v.7 no.1
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    • pp.35-41
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    • 1998
  • This experiment was conducted to find out the effect of artificial light sources(high-pressure sodium lamp, metal halide lamp and fluorescent lamp) on growth of crisphead lettuce(Lactuca sativa L.) in a plant factory. No significant differences in leaf fresh and dry weight were presented among them. Lettuce plants grown under fluorescent lamp showed the lowest growth. Considering the growth of lettuce and efficiency of lamps, it is worth using HPS(high-pressure sodium) lamp in plant factories. The leaves of lettuce plants grown under artificial light sources showed tipburn symptoms at 14th day after transplanting. The beginning of tipburn symptom have been seen on the ninth to tenth leaves from the cotyledons. It is estimated that the occurrence of tipburn was related to rapid growth and K uptake of the lettuce Plants. The Ca, Mg. Cu and Zn elements tended to be accumulated in the nutrient solutions but the T-N, P, Fe and Mn elements keep in balance in them.

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Antioxidant Effects of Serotonin and L-DOPA on Oxidative Damages of Brain Synaptosomes

  • Ham, Sang-Soo;Kim, Dong-Hyun;Lee, Suk-Ha;Kim, Yun-Sang;Lee, Chung-Soo
    • The Korean Journal of Physiology and Pharmacology
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    • v.3 no.2
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    • pp.147-155
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    • 1999
  • Antioxidant effects of serotonin and L-DOPA on neuronal tissues were examined by studying the oxidative damages of brain synaptosomal components. The study further explored the mechanism by which they exert protective actions. Serotonin and L-DOPA (1 ${\mu}M$ to 1 mM) significantly inhibited lipid peroxidation of brain tissues by either $Fe^{2+}$ and ascorbate or t-butyl hydroperoxide in a dose dependent fashion. Protective effect of serotonin on the peroxidative actions of both systems was greater than that of L-DOPA. Protein oxidation of synaptosomes caused by $Fe^{2+}$ and ascorbate was attenuated by serotonin and L-DOPA. Protein oxidation more sensitively responded to L-DOPA rather than serotonin. Serotonin and L-DOPA (100 ${\mu}M$) decreased effectively the oxidation of synaptosomal sulfhydryl groups caused by $Fe^{2+}$ and ascorbate. The production of hydroxyl radical caused by either $Fe^{3+},$ EDTA, H_2O_2$ and ascorbate or xanthine and xanthine oxidase was significantly decreased by serotonin and L-DOPA (1 mM). Equal concentrations of serotonin and L-DOPA restored synaptosomal $Ca^{2+}$ uptake decreased by $Fe^{2+}$ and ascorbate, which is responsible for SOD and catalase. Protective effects of serotonin and L-DOPA on brain synaptosomes may be attributed to their removing action on reactive oxidants, hydroxyl radicals and probably iron-oxygen complex, without chelating action on iron.

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