• Title/Summary/Keyword: $C_60^-

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A Study on the Measurement of Moisture Content in the Organic Soils (유기질토의 함수비 측정에 관한 연구)

  • Park, Sung-Sik;Choi, Sun-Gyu;Ryu, Ju-Hyung
    • Journal of the Korean Geotechnical Society
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    • v.29 no.10
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    • pp.29-37
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    • 2013
  • Organic soils are widely distributed at Youngdong areas in Kangwon prefecture and Jeonbuk area. Such organic soils usually consist of undecomposed fiber materials. It is difficult to exactly measure the water content of such organic soils because some organic materials may decompose at $110^{\circ}C$ in drying oven. In this study, both drying oven and microwave oven methods are used to measure the water content of organic soils. Three different levels of oven temperature, $60^{\circ}C$, $80^{\circ}C$, and the standard temperature of $110^{\circ}C$, were used to measure the water content of organic soils in the 1st, 2nd, and 3rd day. The water content by microwave oven was measured for two different sample masses (30, 60 g) with five different measuring times (3, 6, 9, 12, 15 min.). As the temperature increased, the water content of organic soils increased due to the decomposition of organic materials in soils. The water content of some soils increased up to 2 times as the temperature was increased from $60^{\circ}C$ to $110^{\circ}C$. However, the water content was not changed after the 1st day, regardless of drying oven temperature and soil types. The water content by microwave oven became constant after 12 min. for the 30 g sample and 15 min. for the 60 g sample used. The measured water content by microwave oven was similar to that measured by drying oven at $60^{\circ}C$.

Fullerene derivatives for Polymer Bulk-heterojunction Solar Cells (고분자 태양전지용 플러렌 유도체)

  • Shin, Won-Suk;Hwang, Yong-Mook;Yoon, Sung-Cheol;Lee, Chang-Jin;Moon, Sang-Jin
    • 한국신재생에너지학회:학술대회논문집
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    • 2007.06a
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    • pp.246-249
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    • 2007
  • 현재까지 $P3HT:C_{60}-PCBM$계는 고분자 유기 태양전지에서 가장 좋은 효율을 보여주고 있다. 그러나 보다 고효율의 소자 제작을 위해 신재료에 대한 연구들이 활발히 진행되고 있으며, 본 연구에서는 $C_{60}-PCBM$ 대신 $C_{70}-PCBM$을 합성하여 소자를 제작하였다. $C_{70}-PCBM$$C_{60}-PCBM$에 비하여 가시광선 영역에서 상대적으로 높은 광흡수율을 보여 주었으며, 이것은 광전류의 향상을 가져왔다. 소자제작의 주요 변수로 $P3HT:C_{70}-PCBM$ 광활성층의 처리 조건, 즉, 용매, 조성비, 열처리 조건, 광활성층의 두께 등을 조절하였는데, buffer층(LiF 층) 등이 도입되지 않은 간단한 제작조건 하에서도 본 $C_{70}-PCBM$$C_{60}-PCBM$계에 버금가는 3.5% (AM 1.5G, 100 $mW/cm^{2}$ 조건) 이상의 효율을 나타내었다.

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Estimation of Combining Abilities for Traits of Mice from Diallel Crosses -II. Estimation of Combining Abilities for Baby Weights at Weaning and at the Age of 60 Days (양면교잡(兩面交雜)에 의(依)한 Mouse 주요(主要) 형질(形質)의 결합능력(結合能力) 추정(推定) -II. 이유시(離乳時) 체중(體重)과 60일령(日齡) 체중(體重)에 대한 결합능력(結合能力) 추정(推定))

  • Hyun, Byung Hwa;Choi, Kwang Soo
    • Current Research on Agriculture and Life Sciences
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    • v.4
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    • pp.119-123
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    • 1986
  • The study was conducted to find out the gene effects on body weights at weaning and at the age of 60 days in mice, with 343 progenies from full-dialell crosses of four lines of BALB/c, CBA, C3H and C57BL. The progenies were reared at the Experimental Animal Farm, College of Agriculture, Kyungpook National University from November, 1984 to February, 1985, and data collected from the progenies were analyzed into general combining ability, maternal effects, specific combining ability and reciprocal effects with Harvey's model. General combining ability effects estimated in line-crosses were -0.6033~0.5298 for weaning weights and -0.5086~1.0012 for body weights at the age of 60 days. General combining ability for BALB/c and C57BL were significantly better than general combining ability for CBA and C3H for both traits (P<0.05). Maternal effects for C3H were significantly larger than the maternal effects of BALB/c for both traits (P<0.05). The estimates of maternal effects were -0.9678~0.4609 for weaning weights and -1.1886~0.0729 for body weights at the age of 60 days. Specific combining ability effects were estimated to be significant (P<0.05), and the estimates were -0.1999~0.3380 for weaning weights and -0.4056~0.3317 for body weights at the age of 60 days. Reciprocal effects were found to be largest in BALB/c${\times}$C57BL and BALB/c${\times}$C3H. The estimates were -0.5049 from BALB/c${\times}$C57BL and 0.4972 from BALB/c${\times}$C3H form weaning weights, and -1.0336 from BALB/c${\times}$C57BL and 1.2793 from BALB/c${\times}$C3H for body weights at the age of 60 days.

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Temperature and the Interfacial Buffer Layer Effects on the Nanostructure in the Copper (II) Phthalocyanine: Fullerene Bulk Heterojunction

  • Kim, Hyo Jung;Kim, Jang-Joo;Jeon, Taeyeol;Kong, Ki Won;Lee, Hyun Hwi
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.275.1-275.1
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    • 2014
  • The effects of the interfacial buffer layer and temperature on the organic bulk heterojunction (BHJ) nanostructures of copper phthalocyanine (CuPc) and fullerene (C60) systems were investigated using real time in-situ x-ray scattering. In the CuPc:C60 BHJ structures, standing-on configured ${\gamma}$-CuPc phase was formed by co-deposition of CuPc and C60. Once formed ${\gamma}$-phase was thermally stable during the annealing upon $180^{\circ}C$. Meanwhile, the insertion of CuI buffer layer prior to deposition of the CuPc:C60 BHJ layer induced lying-down configured CuPc crystals in the BHJ layer. The lying CuPc peak intensity and the lattice parameter were increased by the thermal annealing. This increment of the intensity seemed to be related to the strain at the interface between CuPc:C60 and CuI, which was proportional to the enhancement of the power conversion efficiency of the device.

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Ferroelectric Properties of the PZT(40/60)/(60/40) Heterolayered Thin Film Prepared by Sol-Gel Method (Sol-Gel법으로 제작한 PZT(40/60)/(60/40) 이종층 박막의 강유전특성)

  • 김경균;정장호;박인길;이성갑;이영희
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 1998.06a
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    • pp.83-86
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    • 1998
  • Ferroelectric PZT(40/67)/PZT(60/40)heterolayered thin films were Prepared by the alkoxide-based Sol-Gel method. PZT(40/60) and PZT(60/40) stock solutions were made and spin-coated on the P7Ti/Si02/Si substrate alternately. These PZT(40/60) and PZT(60/40) films were dried at 300$^{\circ}C$ for 30min to remove organic materials and were sintered at 650$^{\circ}C$ for 1 hour to crystalize into a perovskite structure. The coating and heating procedure were repeated 6 times to form heterolayered films. Increasing the number of coating, coercive field was decreased. The relative dielectric constant, loss, remanent polarization and coercive field of the 4-coated PZT heterolayered were 1200, 4.1[%], 30.794[${\mu}$C/㎡] and 147.22[kV/cm], respectively.

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Studies On Thermal Diffusivity of Model Foods (모형식품의 열확산도에 관한 연구)

  • Chang, Kyu-Seob;Kim, Dong-Man;Kim, Jae-Uk
    • Korean Journal of Food Science and Technology
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    • v.18 no.1
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    • pp.24-30
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    • 1986
  • The model foods similar to general Korean foods were prepared by combining starch, protein and moisture, and relationship between their thermal diffusivities and components were investigated. Thermal diffusivity of the model foods tended to be proportional with the moisture content. Under the same level of moisture content of the model foods, thermal diffusivity of the starch foods was higher than that of the protein foods, but no interaction among components was found. The measured values was quite agreed upon with the calculated values with 3.60 residual percent. The regression equations between thermal diffusivity and moisture, protein and starch contents at $20^{\circ}C$ and $60^{\circ}C$ were ${\alpha}20^{\circ}C$ = 0.04911M+0.37355P+3.73072, ${\alpha}60^{\circ}C$ = 0.05353M-0.4766P+4.15136, respectively. The correlation coefficients obtained according to the above equation were $0.9650^{**}$ and $20^{\circ}C$ and $0.9002^{**}$ at $60^{\circ}C$.

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Enhancement of Photocurrent Generation by C60-encapsulated Single-walled Carbon Nanotubes in Ru-sensitized Photoelectrochemical Cell

  • Lee, Jung-Woo;Park, Tae-Hee;Lee, Jong-Taek;Jang, Mi-Ra;Lee, Seung-Jin;Kim, Hee-Su;Han, Sung-Hwan;Yi, Whi-Kun
    • Bulletin of the Korean Chemical Society
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    • v.33 no.8
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    • pp.2689-2693
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    • 2012
  • Single-walled carbon nanotubes (SWNTs) and $C_{60}$-encapsulated SWNTs ($C_{60}@SWNTs$) are introduced to Ru-sensitized photoelectrochemical cells (PECs), and photocurrents are compared between two cells, i.e., an $RuL_2(NCS)_2$/DAPV/SWNTs/ITO cell and an $RuL_2(NCS)_2$/DAPV/$C_{60}@SWNTs$/ITO cell. [L = 2,2'-bipyridine-4,4'-dicarboxylic acid, DAPV = di-(3-aminopropyl)-viologen, and ITO = indium-tin oxide] The photocurrents are increased by 70.6% in the presence of $C_{60}@SWNTs$. To explain the photocurrent increase, the reverse-field emission method is used, i.e., $RuL_2(NCS)_2$/DAPV/SWNTs/ITO cell (or $RuL_2(NCS)_2$/DAPV/$C_{60}@SWNTs$/ITO cell) as an anode and a counter electrode Pt as a cathode in the external electric field. The improved field emission properties, i.e., ${\beta}$ (field enhancement factor) and emission currents in the reverse-field emission with $C_{60}@SWNTs$ indicate the enhancement of the PEC electric field, which implies the improvement of the electron transfer rate along with the reduced charge recombination in the cell.

The effect of Fullerene (C60) nanoparticles on the surface of PVDF composite membrane

  • Kim, Kyung Hee;Lee, Ju Sung;Hong, Hyun Pyo;Han, Jun Young;Park, Jin-Won;Min, ByoungRyul
    • Membrane and Water Treatment
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    • v.6 no.5
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    • pp.423-437
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    • 2015
  • Polyvinylidene fluoride/fullerene nanoparticle (PVDF/$C_{60}$) composite microfiltration (MF) membranes were fabricated by a non-solvent induced phase separation (NIPS) using N, N-dimethylacetamide (DMAc) as solvent and deionized water (DI) as coagulation solution. Polyvinylpyrrolidone (PVP) was added to the casting solution to form membrane pores. $C_{60}$ was added in increments of 0.2% from 0.0% to 1.0% to produce six different membrane types: one pristine PVDF membrane type with no $C_{60}$ added as control, and five composite membrane types with varying $C_{60}$ concentrations of 0.2, 0.4, 0.6, 0.8 and 1.0%, respectively. The mechanical strength, morphology, pore size and distribution, hydrophilicity, surface property, permeation performance, and fouling resistance of the six membranes types were characterized using respective analytical methods. The results indicate that membranes containing $C_{60}$ have higher surface porosity and pore density than the pristine membrane. The presence of numerous pores on the membrane caused weaker mechanical strength, but the water flux of the composite membranes increased in spite of their smaller size. Initial flux and surface roughness reached the maximum point among the composite membranes when the $C_{60}$ concentration was 0.6 wt.%.

Effects of Pressure on Properties of SiC-$ZrB_2$ Composites through SPS (SPS법에 의한 SiC-$ZrB_2$ 복합체의 특성에 미치는 압력의 영향)

  • Shin, Yong-Deok;Lee, Jung-Hoon;Kim, Chul-Ho;Jin, Beom-Soo;Wu, Na
    • Proceedings of the KIEE Conference
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    • 2011.07a
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    • pp.1449-1450
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    • 2011
  • The SiC-$ZrB_2$ composites were produced by subjecting a 40:60 (vol.%) mixture of zirconium diboride($ZrB_2$) powder and ${\beta}$-silicon carbide (SiC) matrix to spark plasma sintering(SPS) under argon atmosphere at 50MPa(P50) and 60MPa(P60) pressure. The relative density, 94.13% of P60 sample was lower than that, 94.75% of P50 sample. Reactions between ${\beta}$-SiC and $ZrB_2$ were not observed via x-ray diffraction (hereafter, XRD) analysis. The trend of flexural strength of SiC-$ZrB_2$ composites were in accordance with the relative density. The properties of a SiC-$ZrB_2$ composites through SPS under argon atmosphere were positive temperature coefficient resistance in the temperature range from $25^{\circ}C$ to $500^{\circ}C$, and electrical resistivity of P50 and P60 sample were $6.75{\times}10^{-4}$ and $7.22{\times}10^{-4}{\Omega}{\cdot}cm$ at room temperature, respectively.

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Characteristic of Nutrient Release by Submerged Plants under Different Water Temperatures in Lake Reservoir (호소저수구역에서 침수식물체의 수온별 영양염류 용출 특성)

  • Lim, Byung-Jin;Lee, Sang-Gyu;Seo, Dong-Cheol;Choi, Ik-Won;Kang, Se-Won;Seo, Young-Jin;Lee, Dong-Jin;Kim, Sang-Don;Heo, Jong-Soo;Cho, Ju-Sik
    • Korean Journal of Soil Science and Fertilizer
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    • v.45 no.4
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    • pp.657-663
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    • 2012
  • To evaluate effects of water temperatures on nutrient releases of submerged plants in lake reservoir, COD, T-N and T-P releases of submerged plants were investigated for 60 days under different incubation temperatures ($5^{\circ}C$ and $25^{\circ}C$) in columns. The amounts of COD releases by Carex dimorpholepis were $60.4mg\;L^{-1}$ at $5^{\circ}C$ and $78.0mg\;L^{-1}$ at $25^{\circ}C$. In Miscanthus sacchariflorus, the amounts of COD releases were $62.5mg\;L^{-1}$ at $5^{\circ}C$ and $70.5mg\;L^{-1}$ at $25^{\circ}C$. The amounts of T-N releases in Carex dimorpholepis at $5^{\circ}C$ and $25^{\circ}C$ were 45.8 and $60mg\;L^{-1}$, respectively. In Miscanthus sacchariflorus, the amounts of T-N releases were $55.7mg\;L^{-1}$ at $5^{\circ}C$ and $61.0mg\;L^{-1}$ at $25^{\circ}C$. At $5^{\circ}C$, the amounts of T-P releases in Carex dimorpholepis and Miscanthus sacchariflorus were 5.65 and $7.10mg\;L^{-1}$, respectively. At $25^{\circ}C$, the amounts of T-P releases in Carex dimorpholepis and Miscanthus sacchariflorus were 8.70 and $8.18mg\;L^{-1}$, respectively. In the column experiment, the amounts of COD, T-N and T-P releases by submerged plants at $25^{\circ}C$ were generally higher than those at $5^{\circ}C$.