• Title/Summary/Keyword: $C_60^-

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ZnO/PMMA 나노복합소재와 $C_{60}$ 층과 결합하여 제작한 유기 쌍 안정성 소자의 메모리 성능 향상

  • Yu, Chan-Ho;Jeong, Jae-Hun;Kim, Tae-Hwan
    • Proceedings of the Korean Vacuum Society Conference
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    • 2010.02a
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    • pp.82-82
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    • 2010
  • 유기 쌍안정성 소자는 비휘발성 기억 소자 중에서 구조가 간단하고 제작비용이 저렴하며 유연성을 가지기 때문에 많은 연구가 진행되고 있다. 현재 유기물/무기물 나노복합소재를 사용하여 소자 성능 향상이 기억소자의 성능 향상을 위하여 여러 가지 유기물/무기물 나노복합소재를 사용하여 제작한 유기 쌍안정성 소자가 유연성을 가진 비휘발성 기억소자로 대두되고 있다. 본 연구에서는 ZnO 나노입자를 포함한 PMMA 복합층을 사용하여 제작한 유기 쌍안정성 기억소자를 제작하여 메모리 특성을 조사하였다. 이와 더불어 활성층에 효과적인 전하주입을 위하여 전극과 PMMA/ZnO 층 사이에 $C_{60}$ 층을 삽입한 구조를 가진 메모리 소자의 성능 향상에 대하여 연구하였다. Indium tin oxide 가 증착된 유리 기판위에 $C_{60}$ 층을 스핀코팅 방법으로 적층하였다. 1 wt% ZnO 나노입자와 1 wt% PMMA를 혼합하여 스핀코팅 방법으로 $C_{60}$ 층 위에 박막을 형성하였다. 그리고, 전극으로 Al을 열증착으로 형성하였다. $C_{60}$ 층이 있는 유기 쌍안정성 기억 소자와 $C_{60}$ 층이 없는 두 가지의 소자에 대하여 전류-전압 (I-V) 특성을 측정하여 각각의 소자에서의 전류 히스테리시스 현상이 발생하는 원인을 규명하였다. I-V 특성 결과와 전자적 구조를 사용하여 유기 쌍안정성 소자에서의 쓰기, 지우기 및 읽기 동작에 대한 과정을 설명하였다. 두 소자의 I-V 특성을 비교하므로 $C_{60}$ 층을 사용하여 유기 쌍안정성 소자의 성능이 향상됨을 알 수 있었다. 또한 $C_{60}$ 층을 사용하여 제작된 유기 쌍안정성 소자의 성능이 향상된 원인을 규명하였다.

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An Experimental Study on the Thermal Performance of the Flat Roof in Proportion to Directional Changes (평지붕의 방위별 열성능에 관한 실험적 연구)

  • 박병규;황하진;이경희
    • Journal of the Korean housing association
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    • v.12 no.2
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    • pp.191-198
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    • 2001
  • The aim of this research was to examine the thermal performance of the flat roof in proportion to various directional changes, the results of which were drawn from the miniature model experiment. In this process, various thermal environmental factors were measured and compared with one another to research their aspects of changes. The brief results of this research are as follows: 1) The indoor temperature and load per hour in proportion to directional changes shows the same degree of changes. As for the results of the clear-sky and cloudy-sky experiments, both of them generally appear advantageous in the order of S, $S-30^{\cire}C$-E, $S-30^{\cire}C$-W, $S-60^{\cire}C$-W, E, $S-60^{\cire}C$-E, despite slight differences in the indoor temperature and load per hour in proportion to directional changes. 2) As for the total load of degree day per direction of the clear-sky and cloudy-sky experiments, both of them shows their advantageous results in the order of S, $S-30^{\cire}C$-E, $S-30^{\cire}C$-W, $S-60^{\cire}C$-W, E, $S-60^{\cire}C$-E, despite minor differences in their loads. 3) As for the peak load of degree hour, while the clear-sky experiment shows its advantage in the order of $S-30^{\cire}C$-E, S, $-30^{\cire}C$-W, $S-60^{\cire}C$-W, E, $S-60^{\cire}C$-E, the cloudy-sky experiment does so in the order of S, $S-30^{\cire}C$-E, $S-30^{\cire}C$-W, E, $S-60^{\cire}C$-W, $S-60^{\cire}C$-E.

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Changes in Physio-Chemical Properties of Deer Meat During Storage at -30°C and -60°C (동결 온도와 저장기간에 따른 사슴고기의 이화화적 성질의 변화)

  • Shin, Teak-Soon;Lee, Kil-Wang;Kim, Seon-Ku;Kang, Han-Seok;Kim, Keun-Ki;Park, Hyean-Cheal
    • Journal of Life Science
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    • v.17 no.4 s.84
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    • pp.498-502
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    • 2007
  • A total of 5 female elk deer($220kg{\pm}10kg$) were included in a study on the changes in physico-chemical properties of deer meat during storage at $-4^{\circ}C\;and\;-2^{\circ}C$. The deers were exposed to normal pre-slaughter handling and put under anesthesia before slaughtered. The loin and leg cuts were deboned from the carcass after 24hrs slaughter. The samples weighing approximately 300g were packaged using wrap packaging and stored for 1, 2, 3, 4, 5 and 6 months at $-30^{\circ}C\;and\;-60^{\circ}C$. During the freezing period, the changes of moisture maintenance was slower for the meats kept at $-60^{\circ}C$ than that at $-30^{\circ}C$. The meat softness represented higher value after freezing, and it tended to be decreased with the passage of storage time. Comparing the values between freezing temperature, the value at $-30^{\circ}C$ was higher than at $-60^{\circ}C$. All meats frozen at $-30^{\circ}C\;and\;-60^{\circ}C$ were edible after storage for 6 months. Loin was inedible, and leg was edible after freezing storage for 6 months. The pH values of the meats were increased during freezing period, even though pH value of the meats stored for 6 months was less than 5.70. Luminosity of loin was significantly increased with the passage of storage time, although loin stored at $-60^{\circ}C$ was darker, and leg stored at $-30^{\circ}C$ was darker. The index of red color was rapidly decreased for loin stored at $-30^{\circ}C$, and for leg stored at $-60^{\circ}C$, respectively. There were no changes in the index of yellow color for loin stored at $-60^{\circ}C$, and the index for leg was increased with regardless of the freezing storage temperature after 6 months.

Synthesis of SnO2-Mn-C60 Nanocomposites and Their Photocatalytic Activity for Degradation of Organic Dyes

  • Li, Jiulong;Ko, Jeong Won;Ko, Weon Bae
    • Elastomers and Composites
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    • v.52 no.4
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    • pp.287-294
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    • 2017
  • Nanocomposites based on $SnO_2-Mn$ were synthesized by the reaction of tin (II) chloride dihydrate and manganese (II) chloride tetrahydrate at a molar ratio of 10:1 in the presence of ammonium hydroxide at $80^{\circ}C$. The $SnO_2-Mn$ nanocomposites were stirred with fullerene [$C_{60}$] in a mass ratio of 2:1 in tetrahydrofuran to prepare $SnO_2-Mn-C_{60}$ nanocomposites; these nanocomposites were obtained upon heating the mixture of $SnO_2-Mn$ nanocomposites and fullerene [$C_{60}$] in an electric furnace at $700^{\circ}C$ for 2 h. The synthesized $SnO_2-Mn-C_{60}$ nanocomposites were confirmed through various characterization methods such as X-ray diffraction and scanning electron microscopy. The photocatalytic activities of the $SnO_2-Mn-C_{60}$ nanocomposites were demonstrated by the degradation of the organic dyes BG, MB, MO, and RhB under 254 nm irradiation and evaluated using UV-Vis spectrophotometry.

Fullerene Dimers Connected through C24 and C36 Bridge Cages

  • Anafcheh, Maryam;Ghafouri, Reza
    • Bulletin of the Korean Chemical Society
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    • v.35 no.4
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    • pp.1005-1010
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    • 2014
  • We have performed DFT calculations to devise some possible fullerene dimers (from $C_{60}$ and $C_{80}$) connected through $C_{24}$ and $C_{36}$ bridge cages with the face-to-face linking model. The fullerene dimers with $C_{36}$ bridges have lower binding energies and greater HOMO-LUMO gaps than those of the fullerene dimers with $C_{24}$ bridges. Also, the replacement of $C_{60}$ cages with $C_{80}$ ones always leads to an increase in binding energies and HOMO-LUMO gaps in these systems. Dimerization of $C_{60}$ and $C_{80}$ fullerenes with $C_{24}$ and $C_{36}$ results in a significant decrease in antiaromaticity of the antiaromatic cages $C_{24}$ and $C_{80}$, and an increase in the aromaticity of the aromatic cages $C_{36}$ and $C_{60}$. Therefore, DFT results indicate that those fullerene dimers involving the initially harshly antiaromatic $C_{24}$ or $C_{80}$ cages are more energetically favorable configuration than the fullerene dimers involving the aromatic $C_{36}$ and $C_{60}$ cages.

Studies on Heat Sensitivity of Egg Albumen I. Effects of Heating Time and Temperature, pH and NaCl Concentration on Heat Sensitivity of Egg Albumen (난백 의 열감수성 에 관한 연구 I. 가열온도와 시간, pH 및 NaCl농도가 난백의 열감수성에 미치는 영향)

  • 유익종
    • Korean Journal of Poultry Science
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    • v.15 no.1
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    • pp.39-44
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    • 1988
  • This study was undertaken to find out the effect of heating time and temperature, pH and NaCl concentration on heat sensitivity of egg albumen during heat treatment. Sharp increase of the turbidity and rapid decrease of the foaming power were observed when egg albumen was heated at above $60^{\circ}C$. Egg albumen became opaque when it was heated at $60^{\circ}C$ for above 13 minutes or at $65^{\circ}C$ for above 5 minutes. The turbidity was markedly increased at below pH 7 and the foaming power was largely decreased at around pH 4.0 by the heat treatment ($60^{\circ}C$, 5 min). The foam stability was slightly decreased at alkaline pH range by the heat treatment (60t, 5 min). The addition of NaCl up to 0.3M decreased the turbidity. There was no effect of NaCl addition on the foaming power, but the foam stability was decreased by the addition of NaCl at above 0.2M before and after the heat treatment ($60^{\circ}C$, 5 min).

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Effect of Dying Method on the Quality of Red Pepper(Capsicum annuum var. longum) (건조방법이 고추의 품질에 미치는 영향)

  • Yoon, Wha-Mo;Lee, Jeong-Yeop
    • The Journal of Natural Sciences
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    • v.14 no.1
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    • pp.139-149
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    • 2004
  • It was aimed to find out an efficient method of drying hot pepper, of which powder is used as one of the main ingredients in Korean dish preparation including Kimchi. Before sun or heat drying fruits harvested were horizontally cut into three pieces punched with an auger of 4 mm in diameter, or used as the whole fruit. Various drying methods were used including sun drying, drying under a plastic house, sun drying after heat drying for 5 hours at $70^{\circ}C$, $80^{\circ}C$, or $90^{\circ}C$, heat drying only at $50^{\circ}C$, $60^{\circ}C$, or $70^{\circ}C$, and changing temperature of $70^{\circ}C$, $5hours+60^{\circ}C$ until coplete dry, $80^{\circ}C+60^{\circ}C$, or $90^{\circ}C+60^{\circ}C$. The results are summarized as follows. With sun drying of the whole fruit, in required about 10days to reach the satisfactory level of dryness as indicated by its moisture content of below 10% in general. In case of heat drying combined with sun drying, it required 5 to 7 days. For cut fruits, it required 1 or 2 days less than for whole or pinholed fruits until drying. Under heat of alternation temperature drying, cut fruits also dried 15-20 hours earlier compared with whole of pinholed fruits. There were not significant differences for the recovery rate of the fruit with various drying methods. The occurrence of white fruits, which are caused by one of physiological disorders during drying, and rotten fruits was reduced with the cut fruit drying. The damages were very high with the PE house drying, but very little with the heat drying.

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Organic photovoltaic effects using CuPc and $C_{60}$ depending on the layer thickness (CuPc와 $C_{60}$를 이용한 유기 광기전 소자에서 유기층의 두께에 따른 특성 연구)

  • Hur, Sung-Woo;Oh, Hyun-Seok;Lee, Joon-Ung;Lee, Sung-Il;Han, Won-Keun;Kim, Tae-Wan
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2004.04a
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    • pp.43-46
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    • 2004
  • CuPc와 $C_{60}$을 이용하여 ITO/CuPc/Al의 CuPc 단층구조와 $ITO/CuPc/C_{60}/Al$의 이종접합 구조에서의 광기전 특성을 연구하였다. CuPc 단층구조에서는 CuPc층의 두께를 10nm에서 50nm로 가변하여 전압-전류 특성을 측정한 결과 40nm 부근에서 최적화된 전기적인 특성이 나타났으며, $CUPC/C_{60}$의 이종접합 구조에서는 CuPc와 $C_{60}$의 두께 비율을 1 : 1 (20nm : 20nm), 1 : 2 (20nm : 40nm), 1 : 3 (20nm : 60nm)으로 가변하여 측정한 결과, 1 : 2의 두께비에서 최적화된 특성을 얻었다. 광원은 500W Xe lamp(ORIEL 66021)를 이용하였으며, 광원의 세기는 보정된 radiometer/photometer (International Inc. IL14004)와 Si-photodiode로 측정하였다.

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Light-regulated Translation of Chloroplast Reaction Center Protein D1 mRNA in Chlamydomonas reinhardtii

  • Kim, Jungmook
    • Proceedings of the Botanical Society of Korea Conference
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    • 1999.07a
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    • pp.57-62
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    • 1999
  • Light-regulated translation of chloroplast mRNAs requires nuclear-encoded trans-acting factors that interact with the 5' untranslated region (UTR) of these mRNAs. A set of four proteins (60, 55, 47, and 38 kDa) that bind to the 5'-UTR of the psbA mRNA had been identified in C. reinhardtii. 47 kDa protein (RB47) was found to encode a chloroplast poly (A)-binding protein (cPABP) that specifically binds to the 5'-UTR of the psbA mRNA, and essential for translation of this mRNA, cDNA encoding 60 kDa protein (RB60) was isolated, and the amino acid sequence of the encoded protein was highly homologous to plants and mammalian protein disulfide isomerases (PDI), normally found in the endoplasmic reticulum (ER). Immunoblot analysis of C. reinhardtii proteins showed that anti-PDI recognized a distinct protein of 56 kDa in whole cell extract, whereas anti-rRB60 detected a 60 kDa protein. The ER-PDI was not retained on heparin-agarose resin whereas RB60 was retained. In vitro translation products of the RB60 cDNA can be transported into C. reinhardtii chloroplast in vitro. Immunoblot analysis of isolated pea chloroplasts indicated that higher plant also possess a RB60 homolog. In vitro RNA-binding studies showed that RB60 modulates the binding of cPABP to the 5'-UTR of the psbA mRNA by reversibly changing the redox status of cPABP using redox potential or ADP-dependent phosphorylation. Site-directed mutagenesis of -CGHC- catalytic site in thioredoxin-like domain of RB60 is an unique PDI located in the chloroplast of C. reinhardtii, and suggest that the chloroplast PDI may have evolved to utilize the redox-regulated thioredoxin like domain as a mechanism for regulating the light-activated translation of the psbA mRNA.

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북한산국립공원의 식생개관

  • 임양재
    • Proceedings of the Botanical Society of Korea Conference
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    • 1985.08b
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    • pp.7-18
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    • 1985
  • Light-regulated translation of chloroplast mRNAs requires nuclear-encoded trans-acting factors that interact with the 5' untranslated region (UTR) of these mRNAs. A set of four proteins (60, 55, 47, and 38 kDa) that bind to the 5'-UTR of the psbA mRNA had been identified in C. reinhardtii. 47 kDa protein (RB47) was found to encode a chloroplast poly (A)-binding protein (cPABP) that specifically binds to the 5'-UTR of the psbA mRNA, and essential for translation of this mRNA, cDNA encoding 60 kDa protein (RB60) was isolated, and the amino acid sequence of the encoded protein was highly homologous to plants and mammalian protein disulfide isomerases (PDI), normally found in the endoplasmic reticulum (ER). Immunoblot analysis of C. reinhardtii proteins showed that anti-PDI recognized a distinct protein of 56 kDa in whole cell extract, whereas anti-rRB60 detected a 60 kDa protein. The ER-PDI was not retained on heparin-agarose resin whereas RB60 was retained. In vitro translation products of the RB60 cDNA can be transported into C. reinhardtii chloroplast in vitro. Immunoblot analysis of isolated pea chloroplasts indicated that higher plant also possess a RB60 homolog. In vitro RNA-binding studies showed that RB60 modulates the binding of cPABP to the 5'-UTR of the psbA mRNA by reversibly changing the redox status of cPABP using redox potential or ADP-dependent phosphorylation. Site-directed mutagenesis of -CGHC- catalytic site in thioredoxin-like domain of RB60 is an unique PDI located in the chloroplast of C. reinhardtii, and suggest that the chloroplast PDI may have evolved to utilize the redox-regulated thioredoxin like domain as a mechanism for regulating the light-activated translation of the psbA mRNA.

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