• Title/Summary/Keyword: $C_{60}$

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Performances of $C_{60}$ based n-type Organic Thin Film Transistor with A Doped Interlayer Using Bathophenanthroline (Bathophenanthroline를 interlayer로 적용한 $C_{60}$ 기반의 n형 유기박막트랜지스터의 성능)

  • Kim, Jeong-Su;Son, Hee-Geon;Yi, Moon-Suk
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.47 no.8
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    • pp.7-12
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    • 2010
  • In this paper, $C_{60}$ based Organic thin film transistor OTFTs) have been fabricated using BPhen(Bathophenanthroline) and BPhen doped with Cs interlayers between $C_{60}$ active layer and Al electrodes to improve the electrical performance. The addition of the BPhen layer resulted in enhanced performances by reducing surface roughness between organic-metal interface. And the contact resistance was reduced by using the BPhen doped with Cs interlayer with co-evaporation method. These performances suggests that the $C_{60}$ based OTFT with BPhen doped with Cs interlayer is a promising application in the fabrication of n-type organic transistors.

Effect of 2-Chloromethyl-1-Dihydroxyphosphinylpyrrolidine(2C-1DPP) on Differentiation Induction of Human Leukemia HL-60 Cells (2-Chloromethyl-1-Dihydroxyphosphinylpyrrolidine (2C-1DPP)에 의한 백혈병 세포주 HL-60의 분화유도 효과)

  • Kim, Youg-Mi;Ju, Seong-Min;Park, Jun-Ho;Oh, Jung-Mi;Lee, Chae-Ho;Kim, Eun-Cheol;Jeon, Byung-Hun;Kim, Won-Sin;Kim, Won-Sin
    • Journal of Physiology & Pathology in Korean Medicine
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    • v.21 no.4
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    • pp.940-945
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    • 2007
  • We have examined the induction of HL-60 cell differentiation by treatment of 2-chloromethyl-1-dihydroxyphosphinyl pyrrolidine(2C-1DPP), which is derivative of piperidine and pyrrolidine by ${\alpha}-phosphoramidoakylation$ reaction. It was observed that HL-60 cell proliferation was dose- and time-dependently inhibited by treatment with 2C-1DPP. 2C-1DPP treatment caused a significant change in NBT reduction and enhanced ATRA-induced NBT reduction. Treatment of 2C-1DPP to HL-60 cells increased only CD11b expression in the cells, and also increased markedly G0/G1 stage arrest of HL-60 cells. These results can suggest that 2C-1DPP induced the differentiation of HL-60 cells to granulocytes lineage and enhanced ATRA-induced differentiation. Moreover, DNA expression levels of p27 were up-regulated during 2C-1DPP-dependent HL-60 cell differentiation. Our results suggest that 2C-1DPP have potential as a therapeutic agent in human leukemia.

A TEM Investigation on the Crystal Structure of $C_{60}$ Thin Crystals ($C_{60}$ 얇은 결정의 결정구조에 관한 투과형전자현미경 연구)

  • Song, Se-Ahn;Kim, Sung-Hoon;Suh, Young-Doug;Kim, Seong-Keun
    • Applied Microscopy
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    • v.21 no.2
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    • pp.67-75
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    • 1991
  • [ $C_{60}$ ] molecule, the Buckminsterfullerene, has generated great interest because of its unique molecular structure and of superconductivity exhibited in its alkali-doped solids. We have investigated the molecular stacking and crystal structure of $C_{60}$ thin crystals formed on amorphous carbon film. The $C_{60}$ powder which was chromatographically purified was dissolved in benzene. The thin crystals of $C_{60}$ were observed with a 300 keV transmission electron microscope. Electron diffraction analysis and direct imaging of its molecular stacking were carried out. It was found from this work that the molecules of $10.0{\AA}$ diameter are arrayed hexagonally on substrate surface and $8.7{\AA}$ lattice planes are quite often found in several types of ED patterns, which can never be explained with a fcc model. Therefore the structure of $C_{60}$ thin crystals is hcp, although we cannot fully exclude the possibility of co-existence of hcp and fcc.

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Electrical Properties of Organic Photovoltaic Cell using CuPc/$C_{60}$ double layer (CuPc/$C_{60}$ 이중층을 이용한 유기 광기전 소자의 전기적 특성)

  • Lee, Ho-Shik;Cheon, Min-Woo;Park, Yong-Pil
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2007.06a
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    • pp.505-506
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    • 2007
  • Organic photovoltaic effects were studied in a device structure of ITO/CuPc/Al and ITO/CuPc/$C_{60}$/BCP/Al. A thickness of CuPc layer was varied from 10 nm to 50 nm, we have obtained that the optimum CuPc layer thickness is around 40 nm from the analysis of the current density-voltage characteristics in CuPc single layer photovoltaic cell. From the thickness-dependent photovoltaic effects in CuPc/$C_{60}$ heterojunction devices, higher power conversion efficiency was obtained in ITO/20nm CuPc/40nm $C_{60}$/Al, which has a thickness ratio (CuPc/$C_{60}$) of 1:2 rather than 1:1 or 1:3. Light intensity on the device was measured by calibrated Si-photodiode and radiometer/photometer of International Light Inc(IL 14004).

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Facile Synthesis of MoS2-C60 Nanocomposites and Their Application to Catalytic Reduction and Photocatalytic Degradation

  • Li, Jiulong;Ko, Weon Bae
    • Elastomers and Composites
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    • v.51 no.4
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    • pp.286-300
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    • 2016
  • $MoS_2$ precursors were synthesized by reacting thioacetamide ($C_2H_5NS$) with sodium molybdate dihydrate ($Na_2MoO_4{\cdot}2H_2O$) in aqueous HCl solution. $MoS_2$ nanoparticles were prepared from dried $MoS_2$ precursors by calcination in an electric furnace at $700^{\circ}C$ for 2 h under an inert argon atmosphere. $MoS_2-C_{60}$ nanocomposites were obtained by heating $MoS_2$ nanoparticles and fullerene ($C_{60}$) together in an electric furnace at $700^{\circ}C$ for 2 h. Their morphological and the structural properties were characterized by powder X-ray diffraction and scanning electron microscopy. The $MoS_2$ nanoparticles and $MoS_2-C_{60}$ nanocomposites were used as catalysts in the reductions of 2-, 3-, and 4-nitrophenol in the presence of sodium borohydride. The photocatalytic activities of the $MoS_2$ nanoparticles and $MoS_2-C_{60}$ nanocomposites were evaluated in the degradation of organic dyes (brilliant green, methylene blue, methyl orange, and rhodamine B) under ultraviolet light (254 nm).

A Study on the Cookery of Andong Sikhe(II) -Physicochemical Changes upon Fermentation Temperature and Time- (안동식혜의 조리법에 관한 연구(II) -발효온도와 시간에 따른 이화학적 변화-)

  • 윤숙경
    • Korean journal of food and cookery science
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    • v.4 no.2
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    • pp.21-30
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    • 1988
  • To study the optimum fermentation and aging conditions for preparation of Andong Sikhe which is consumed in the northern Kyungbuk province as a traditional beverage, Sikhe were fermented and aged at $12^{\circ}C$ for 48, 60 and 72hrs and fermented at 40, 50. and $60^{\circ}C$ for 2, 3, and 4hrs and then aged at $12^{\circ}C$ for 20 hrs, Non-volatile organic acids and free sugars were analyzed by GC and HPLC, respectively, and sensory test was performed. Sikhe fermented at $40^{\circ}C$ for 3hrs and aged at $12^{\circ}C$ for 20hrs was evaluated the most favorable one by sensory test. This Sikhe had the lowest pH 4.6~4.7 among sample and 14.6% of sugar. The sugar content was lower than those of Sikhe Fermented at $50^{\circ}C$ and $60^{\circ}C$. In organic acid analysis, the concentration of malate 67.53%/mg in this Sikhe was the highest. Lactate, succinate and maleate were produced more in this Sikhe than in any other ones. Oxalate which was existed before fermentation was not found in the Sikhe, and a small amounts of citrate and fumarate were produced. In sugar analysis, maltose was dominant 11.56%, glucose 1.25% and fructose 0.45%.

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Synthesis of ZnS:Mn-Gly-C60 Nanocomposites and Their Photocatalytic Activity of Brilliant Green

  • Li, Jiulong;Ko, Weon Bae
    • Elastomers and Composites
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    • v.53 no.2
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    • pp.75-79
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    • 2018
  • ZnS:Mn-glycine (ZnS:Mn-Gly) nanocomposites were synthesized by capping ZnS:Mn nanocomposites with glycine. Zinc sulfate heptahydrate ($ZnSO_4{\cdot}7H_2O$), glycine ($C_2H_5NO_2$), manganese sulfate monohydrate ($MnSO_4{\cdot}H_2O$), and sodium sulfide ($Na_2S$) were used as the source reagents. $ZnS:Mn-Gly-C_{60}$ nanocomposites were obtained by heating the ZnS:Mn-Gly nanocomposites and fullerene ($C_{60}$) at a 2:1 mass ratio in an electric furnace at $700^{\circ}C$ for 2 h. X-ray diffraction (XRD) was used to characterize the crystal structure of the synthesized nanocomposites. The photocatalytic activity of the $ZnS:Mn-Gly-C_{60}$ nanocomposites was evaluated, via the degradation of brilliant green (BG) dye under 254 nm irradiation, with a UV-vis spectrophotometer.

Effect of Phosphate on Rheological Properties of Rice Starch Suspension (인산염이 쌀전분 현탁액의 리올로지에 미치는 영향)

  • Kim, Il-Hwang;Kim, Sung-Kon;Lee, Shin-Young
    • Korean Journal of Food Science and Technology
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    • v.19 no.3
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    • pp.239-244
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    • 1987
  • Rheological properties of 5% starch suspension were investigated using a capillarity tube viscometer. Nonglutinous and glutinous rice starch suspensions at $30-60^{\circ}C$, and $30-55^{\circ}C$, respectively, had no yield stress and showed dilatant flow behavior in the absence or presence of phosphate. However, flow behavior of nonglutinuous starches at $65^{\circ}C$ and glutinous starch at $60^{\circ}C$ was pseudopalastic. Flow activation energies for rice starch suspensions were 0.88-1.45 kcal/mole at $30-50^{\circ}C$ and about 45-73 kcal/mole $60-65^{\circ}C$. Flow activation energy in the presence of phosphate was 90-182 kcal/mole at $60-65^{\circ}C$. Akibare starch had the highest activation energy, and glutinous starch the lowest.

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Photocatalytic Degradation of Organic Dyes with Nanomaterials (나노소재를 이용한 유기염료 광촉매 분해 반응)

  • Hong, Sung-Kyu;Yu, Gu-Yong;Lim, Chung-Sun;Ko, Weon-Bae
    • Elastomers and Composites
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    • v.45 no.3
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    • pp.206-211
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    • 2010
  • Zinc oxide(ZnO) nanoparticles were synthesized by reacting an aqueous-alcoholic zinc nitrate solution to sodium hydroxide under ultrasonic irradiation at room temperature. The fullerene($C_{60}$) and ZnO nanoparticles were heated individually in an electric furnace for two hours at $700^{\circ}C$. The morphology and optical properties of the $C_{60}$ and ZnO nanoparticles were characterized by X-ray diffraction(XRD), scanning electron microscopy(SEM), transmission electron microscopy(TEM) and ultraviolet/visible (UV-vis) spectroscopy. The photocatalytic activity of the heated and unheated the $C_{60}$ and ZnO nanoparticles for the decomposition of methylene blue(MB), methyl orange(MO) and rhodamine B(RhB) was examined using UV-vis spectroscopy.

Electrical Properties of Organic Photovoltaic Cell using CuPc/$C_{60}$ double layer (CuPc/$C_{60}$ 이중층을 이용한 유기 광기전 소자의 전기적 특성)

  • Lee, Dong-Shin;Park, Yong-Pil
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2008.05a
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    • pp.744-746
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    • 2008
  • Organic photovoltaic effects were studied in a device structure of ITO/CuPc/Al and ITO/CuPc/$C_{60}$/BCP/Al. A thickness of CuPc layer was varied from 10 nm to 50 nm, we have obtained that the optimum CuPc layer thickness is around 40 nm from the analysis of the current density-voltage characteristics in CuPc single layer photovoltaic cell. From the thickness-dependent photovoltaic effects in CuPc/$Cu_{60}$ heterojunction devices, higher power conversion efficiency was obtained in ITO/20nm CuPc/40nm $C_{60}$/Al, which has a thickness ratio (CuPc:$C_{60}$) of 1:2 rather than 1:1 or 1:3. Light intensity on the device was measured by calibrated Si-photodiode and radiometer/photometer of International Light Inc(IL14004).

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