• Transactions of the Korean hydrogen and new energy society
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• v.32 no.6
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• pp.534-541
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• 2021

In this study, a novel microwave-matrix reformer was proposed to convert CH₄, which is a major component, to a high quality hydrogen energy. And to identify this performance, it was investigated for O₂/C ratio, steam feed amount and reformed gas recirculation which are affected for methane conversion and product gas yield. Through the parametric screening studies, optimal operating conditions were that O₂/C ratio, steam feed amount and recirculation rate were 1.1, 10 mL/min and 30 L/min. In this conditions, CH₄ conversion was 68.1%, H₂ selectivity 77.2 and H₂/CO ratio 2.62 which are possible applying SOFC stack for RPG (residential power generator).

• Journal of Korean Society of Environmental Engineers
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• v.28 no.3
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• pp.323-328
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• 2006

The purpose of this paper was to investigate the reforming characteristics and optimum operating condition of the GlidArc-assisted $C_3H_8$ reforming reaction for the synthesis gas(SynGas) production without formation of carbon black from propane using GildArc plasma reforming. Also, in order to increase the hydrogen production and the propane conversion rate, 13 wt % nickel catalyst was filled into the catalytic reactor and parametric screening studies were conducted, in which there were the variations of vapor mole ratio$(H_2O/C_3H_8),\;CO_2$ mole ratio($CO_2/C_3H_8$), input power and injection flow rate. When the variations of vapor mole ratio, $CO_2$ mole ratio, input power and injection flow rate were 1.86, 0.48, 1.37 kW and 14 L/min, respectively, the conversion rate of the propane reached its most optimal condition, or 62.6%. Under the condition mentioned above, the dry basic concentrations of the SynGas were $H_2\;44.4%,\;CO\;18.2%,\;CH_4\;11.2%,\;C_2H_2\;2.0%,\;C_3H_6\;1.6%,\;C_2H_4\;0.6%\;and\;C_3H_4$ 0.4%. The conversion rate of carbon dioxide was 29.2% and the concentration ratio of hydrogen to carbon monoxide($H_2/CO$) in the SynGas was 2.4.

• Journal of Energy Engineering
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• v.22 no.4
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• pp.347-354
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• 2013

This study was carried out to examine different mole ratio of $H_2/CO_2$ and EBCT using the continuous system in the lab scale throughout biological methods with accumulated hydrogenotrophic methanogen that can convert $CO_2$ to $CH_4$. The experimental-based results with various gas mixtures of mole ratio of 4:1($H_2/CO_2$) and 5:1($H_2/CO_2$), $H_2$ was converted more than 99% conversion rate. In case of $CO_2$, 4:1($H_2/CO_2$) and 5:1($H_2/CO_2$) were $74.45{\pm}0.33%$, $95.8{\pm}10.7%$, respectively, in addition, the study was confirmed that the amount of $H_2$ was more needed than stoichiometric equations, where approach methods are empirical versus theoretical frameworks, for converting total $CO_2$. As such, we have noticed that $H_2$ was used for energy source of hydrogenotrophic methanogen for maintaining life. Regarding the results of the ratio of treatment by retention time, limitation of treatment capacity showed that $H_2$(99.9%) and $CO_2$(96.23%) at EBCT 3.3 hrs indicated stable conversion ratio, as well as appeared that methane production rate and $CO_2$ fixation rate were investigated $1.15{\pm}0.02m^3{\cdot}m^{-3}{\cdot}day^{-1}$ and $2.01{\pm}0.04kg{\cdot}m^{-3}{\cdot}day^{-1}$, respectively.

• Korean Journal of Materials Research
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• v.19 no.2
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• pp.90-94
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• 2009

The development of low-k materials is essential for modern semiconductor processes to reduce the cross-talk, signal delay and capacitance between multiple layers. The effect of the $CH_4$ concentration on the formation of SiOC(-H) films and their dielectric characteristics were investigated. SiOC(-H) thin films were deposited on Si(100)/$SiO_2$/Ti/Pt substrates by plasma-enhanced chemical vapor deposition (PECVD) with $SiH_4$, $CO_2$ and $CH_4$ gas mixtures. After the deposition, the SiOC(-H) thin films were annealed in an Ar atmosphere using rapid thermal annealing (RTA) for 30min. The electrical properties of the SiOC(-H) films were then measured using an impedance analyzer. The dielectric constant decreased as the $CH_4$ concentration of low-k SiOC(-H) thin film increased. The decrease in the dielectric constant was explained in terms of the decrease of the ionic polarization due to the increase of the relative carbon content. The spectrum via Fourier transform infrared (FT-IR) spectroscopy showed a variety of bonding configurations, including Si-O-Si, H-Si-O, Si-$(CH_3)_2$, Si-$CH_3$ and $CH_x$ in the absorbance mode over the range from 650 to $4000\;cm^{-1}$. The results showed that dielectric properties with different $CH_4$ concentrations are closely related to the (Si-$CH_3$)/[(Si-$CH_3$)+(Si-O)] ratio.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.1
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• pp.100-108
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• 2011

The use of biogas as an energy source reduces the chance of possible emission of two greenhouse gases, $CH_4$ and $CO_2$, into the atmosphere at the same time. Its nature of being a reproducible energy source makes its use even more attractive. This research if for the hydrogen production through the steam reforming of the biogas. The biogas utilized 3D-IR matrix burner in which the surface combustion is applied. The nickel catalyst was used inside a reformer. Parametric screening studies were achieved as Steam/Carbon ratio, biogas component ratio, Space velocity and Reformer temperature. When the condition of Steam/Carbon ratio, $CH_4/CO_2$ ratio, Space velocity and Refomer temperature were 3.25, 60%:40%, 19.32L/$g{\cdot}hr$ and $700^{\circ}C$ respectively, the hydrogen concentration and methane conversion rate were showed maximum values. Under the condition mentioned above, $H_2$ concentration was 73.9% and methane conversion rate was 98.9%.

• Analytical Science and Technology
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• v.28 no.3
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• pp.182-186
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• 2015

In this study, the porous CuO/MnO₂ catalyst was prepared through the co-precipitation process from an aqueous solution of potassium permanganate (KMnO₄), manganese(II) acetate (Mn(CH₃COO)₂·4H₂O) and copper(II) acetate (Cu(CH₃COO)₂·H₂O). The phase change in MnO₂ was analyzed according to the reaction molar ratio of KMnO₄ to Mn(CH₃COO)₂. The reaction mole ratio of KMnO₄ to Mn(CH₃COO)₂·4H₂O was varied at 0.3:1, 0.6:1, and 1:1. The aqueous solution of Cu(CH₃COO)₂ was injected into a mixed solution of KMnO₄ and Mn(CH₃COO)₂ to 10~75 wt% relative to MnO₂. The Cu ion co-precipitates as CuO with MnO₂ in a highly dispersed state on MnO₂. The physicochemical property of the prepared CuO/MnO₂ was analyzed by using the TGA, DSC, XRD, SEM, and BET. The different phase types of MnO₂ were prepared according to the reaction mole ratio of KMnO₄ to Mn(CH₃COO)₂·4H₂O. The results confirmed that the porous CuO/MnO₂ catalyst with γ-phase MnO₂ was produced in the reaction mole ratio of KMnO₄ to Mn(CH₃COO)₂ as 0.6:1 at room temperature.

• Applied Chemistry for Engineering
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• v.26 no.2
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• pp.205-209
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• 2015

CCU (Carbon Capture & Utilization) has a potential technology for the reduction and usage of carbon dioxide which is greenhouse gas emitting from a fossil fuel buring. To decompose the carbon dioxide, a three phase gliding arc plasma-catalytic reactor was designed and manufactured. Experiments of carbon dioxide reduction was performed by varying the gas flow rate with feeding the $CO_2$ only as well as the input power, the catalyst type and steam supply with respect to the injection of the mixture of $CO_2$ and $CH_4$. The $CO_2$ decomposition rate was 7.9% and the energy efficiency was $0.0013L/min{\cdot}W$ at a $CO_2$ flow rate of 12 L/min only. Carbon monoxide and oxygen was generated in accordance with the destruction of carbon dioxide. When the injection ratio of $CH_4/CO_2$ reached 1.29, the $CO_2$ destruction and $CH_4$ conversion rates were 37.8% and 56.6% respectively at a power supply of 0.76 kW. During the installation of $NiO/Al_2O_3$ catalyst bed, the $CO_2$ destruction and $CH_4$ conversion rates were 11.5% and 9.9% respectively. The steam supply parameter do not have any significant effects on the carbon dioxide decomposition.

• Journal of the Korean Society of Combustion
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• v.8 no.2
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• pp.1-6
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• 2003

Numerical simulations are conducted at atmospheric pressure in order to understand the effect of the oxygen enrichment level on structure of $CH_4/O_2/N_2$ premixed flames. Under several equivalence ratios the flame speeds are calculated and compared with those obtained from the experiments, the results of which are in good agreement. The effects of the oxygen enrichment are investigated on flames under fuel-rich conditions. As the oxygen enrichment level is increased from 0.21 to 1, the flame speed and the temperature are increased. The emission index of $CO_2$ is decreased in cases of flames for fuel rich mixtures, so the efficiency of combustion may be decreased. The maximum emission index of NO is obtained for 0.6 of the oxygen enrichment level.

• Proceedings of the Korea Society for Energy Engineering kosee Conference
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• 2010.04a
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• pp.199-199
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• 2010

Polymeric membranes have been widely used to separate gas mixtures, such as $O_2/N_2,\;CO_2/CH_4,\;CO_2/N_2$, and olefin/paraffin. The permeation selectivity is the ratio between composition ratio at the permeate side and composition ratio at the feed side. In addition, the permeation selectivity is a product of solubility selectivity and diffusivity selectivity. We present a novel idea and describe its experimental result, which was achieved by preparing polymer gel films that included a room temperature ionic liquid (RTIL) in a polymer matrix. It is known that $CO_2$ can dissolve easily in imidazolium-based RTILs. We prepared polymer-ionic liquid gel films using an ionic liquid, 1-ethyl-3-methylimidazolium acetate ([emim] acetate, C-tri) and a host polymer, poly (vinyl acetate) (PVAc, Aldrich).

• Korean Chemical Engineering Research
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• v.57 no.3
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• pp.420-424
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• 2019

In SNG (synthetic natural gas) process by proposed RIST(Research Institute of Industrial Science & Technology)-IAE(Institute for Advanced Engineering) (including three adiabatic reactors and one isothermal reactor), the methanation reaction and water gas shift (WGS) reaction take place simultaneously, and the supply of steam with syngas might control the temperature in catalyst bed and deactivate the catalyst. In this study for development of SNG process, the characteristics of the methanation reaction with a Ni-based catalyst by prepared RIST and using a low $H_2/CO$ mole ratio (including $CO_2$ 22%) are evaluated. The operating conditions ($H_2O/CO$ ratio of the $1^{st}$ adiabatic reactor, operating temperature range of $4^{th}$ isothermal reactor, etc.) were reflected the results from previous studies and in the same condition a pilot scale SNG process is carried out. As a results, the pilot scale SNG process is stable and the CO conversion and $CH_4$ selectivity are 100% and 96.9%, respectively, while the maximum $CH_4$ productivity is $660ml/g_{cat}{\cdot}h$.