• Title/Summary/Keyword: $CO_2$ sequestration

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Deep Borehole Disposal of Nuclear Wastes: Opportunities and Challenges

  • Schwartz, Franklin W.;Kim, Yongje;Chae, Byung-Gon
    • Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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    • v.15 no.4
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    • pp.301-312
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    • 2017
  • The concept of deep borehole disposal (DBD) for high-level nuclear wastes has been around for about 40 years. Now, the Department of Energy (DOE) in the United States (U.S.) is re-examining this concept through recent studies at Sandia National Laboratory and a field test. With DBD, nuclear waste will be emplaced in boreholes at depths of 3 to 5 km in crystalline basement rocks. Thinking is that these settings will provide nearly intact rock and fluid density stratification, which together should act as a robust geologic barrier, requiring only minimal performance from the engineered components. The Nuclear Waste Technical Review Board (NWTRB) has raised concerns that the deep subsurface is more complicated, leading to science, engineering, and safety issues. However, given time and resources, DBD will evolve substantially in the ability to drill deep holes and make measurements there. A leap forward in technology for drilling could lead to other exciting geological applications. Possible innovations might include deep robotic mining, deep energy production, or crustal sequestration of $CO_2$, and new ideas for nuclear waste disposal. Novel technologies could be explored by Korean geologists through simple proof-of-concept experiments and technology demonstrations.

Sequestration of Orthophosphate by D(+)-Mannose Feeding Increases Nonphotochemical Quenchings in Chinese Cabbage Leaves (Mannose 처리된 배추 잎의 무기인산 감소에 따른 비광화학성 소산의 증가)

  • 박연일
    • Journal of Plant Biology
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    • v.34 no.4
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    • pp.303-309
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    • 1991
  • Limitation of photosynthesis in detached Chinese cabbage (Brassica campestris L.) leaves was induced by feeding of mannose (25 mM) for 12 h in the light, and changes in the basic thylakoid functions under this condition were investigated. The acid soluble phosphate contend and CO2 uptake rate was decreased by 66% and 67%, respectively. However, the starch content was increased by 24% compared to those of controls. From the fast induction curves of chlorophyll fluorescence, dark level fluorescence (Fo) slightly increased while intermediate plateau fluorescence level (FI) to peak level fluorescence (Fp) transient was significantly decreased with a slight decrease in the Fo-to-FI transient. This data means that reduction of secondary electron acceptor of PSII (QB) might be more severely inhibited than that of primary electron acceptor of PSII (QA) by decrease in phosphate level. The strong decline of (Fv)m//Fm ratio suggests that efficiency of excitation energy capture by PSII was decreased markedly. The quenching of Fo (qO), an indicator of state transition, was also occurred over the slow induction kinetics of chlorophyll fluorescence. From quenching analysis, fluorescence was dominantly quenched by nonphotochemical quenchings (qE+qT). These results showed that the capture and transfer efficiency of excitation energy to PSII reaction center in thylakoid was decreased with the decline of leaf phosphate level, and that the state transition was occurred during the induction of photosynthesis under these conditions.

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Finite Element Analysis of Partially Saturated Soil Considering Pore-air Pressure (간극공기압을 고려하는 불포화토의 유한요소해석)

  • Kim, Jae-Hong;Hwang, Young-Cheol
    • Journal of the Korean Geotechnical Society
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    • v.27 no.3
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    • pp.95-102
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    • 2011
  • A model of solid-water-air coupling in triphasic mixture is compared to that of solid-water coupling in biphasic mixture with an application to partially saturated soils. Based on thermodynamics, the mathematical framework governing the behavior of a partially saturated soil is derived by using balance equations, and numerical implementation through drainage experiment of a sand column is carried out to validate the obtained formulations. The role of the air phase in the hydro-mechanical behavior of triphasic mixture can be analyzed from the interaction among phases and from the solid skeleton's constitutive behavior, and the three-phase model found applications in geotechnical engineering problems, such as $CO_2$ sequestration and air storage in an aquifer.

Towards Sustainability of Tropical Forests: Implications for Enhanced Carbon Stock and Climate Change Mitigation

  • Rahman, Mizanur;Islam, Mahmuda;Islam, Rofiqul;Sobuj, Norul Alam
    • Journal of Forest and Environmental Science
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    • v.33 no.4
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    • pp.281-294
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    • 2017
  • Tropical forests constitute almost half of the global forest cover, account for 35% of the global net primary productivity and thereby have potential to contribute substantially to sequester atmospheric $CO_2$ and offset climate change impact. However, deforestation and degradation lead by unsustainable management of tropical forests contribute to the unprecedented species losses and limit ecosystem services including carbon sequestration. Sustainable forest management (SFM) in the tropics may tackle and rectify such deleterious impacts of anthropogenic disturbances and climatic changes. However, the existing dilemma on the definition of SFM and lack of understanding of how tropical forest sustainability can be achieved lead to increasing debate on whether climate change mitigation initiatives would be successful. We reviewed the available literature with a view to clarify the concept of sustainability and provide with a framework towards the sustainability of tropical forests for enhanced carbon stock and climate change mitigation. We argue that along with securing forest tenure and thereby reducing deforestation, application of reduced impact logging (RIL) and appropriate silvicultural system can enhance tropical forest carbon stock and help mitigate climate change.

[ $CO_2$ ] Sequestration on Various Structures of Natural Gas Hydrate Layer for Effective Recovery of $CH_4$ Gas

  • Park, Young-June;Choi, Suk-Jeong;Shin, Kyu-Chul;Seol, Ji-Woong;Lee, Hu-En
    • 한국신재생에너지학회:학술대회논문집
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    • 2006.06a
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    • pp.410-411
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    • 2006
  • On the continental margins and in permafrost regions, natural gas, which has been expected to replace petroleum energy, exists In solid hydrate farm. World hydrate reserves Including natural gas are estimated at about twice as much as the energy contained In total fossil fuel reserves. Because of its vast quantities, the efficient recovery of natural gas from natural gas hydrate becomes the most important factor on evaluating the economic feasibility in the sense of commercialization. It has been noted that carbon dioxide, one of the well-known green house gases, possibly can be stored in the ocean floor as a carbon dioxide hydrate. If the natural gas hydrate could be converted into carbon dioxide hydrate, natural gas hydrate deposits would serve as energy sources as well as carbon dioxide storage sites in the deep ocean sediments. In this study, we first attempted to examine the real swapping phenomenon occurring between guest molecules and various structures of gas hydrate through spectroscopic identification such as NMR spectroscopy.

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Measurement of Thermal Expansion Coefficient of Rock using Strain Gauge (스트레인 게이지를 이용한 암석의 열팽창계수 측정)

  • Park, Chan;Kim, Hyung-Mok;Synn, Joong-Ho;Park, Yeon-Jun;Cheon, Dae-Sung
    • Tunnel and Underground Space
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    • v.17 no.6
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    • pp.475-483
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    • 2007
  • With increasing demand for LNG as energy resources and need for $CO_2$ sequestration as greenhouse gas, more storage facilities are required in Korea. Due to the recent acute safety concerns and land shortage, storage facilities tend to be located underground. In design and construction of underground storage for low and high temperature materials, besides their mechanical characteristics, the thermal characteristics of rock under temperature variation should be understood. In this study, laboratory experiments for the measurement of the thermal expansion coefficient of rock were performed using strain gauge in consideration of the particle size of mineral and experiment temperature range. Experiment results show that thermal expansion coefficient decreased as the temperature decreases. In addition, linear thermal expansion coefficient was developed for typical Korean rocks such as granite. The results of this study can be utilized for the evaluation of thermal propagation in rock mass and the thermo-mechanical stability of underground facilities.

Usage of Coal in the Paradigm Shift toward Sustainable Energy (지속가능 에너지 패러다임 변화속에서 석탄의 활용)

  • Park, Jay Hyun;Yang, In Jae;Lee, Jin Soo;Lee, Cheong Ryong
    • Economic and Environmental Geology
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    • v.53 no.6
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    • pp.793-807
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    • 2020
  • The policy for Green New Deal will promote the shift of the application to coal as feedstock from coal as fuel. Coal can be used as fuel for production of hydrogen and as feedstock materials such as synthetic graphite or activated carbon. Hydrogen is obtained from syngas produced through Steam carbon(SC), Water-Gas Shift(WGS), and Carbonation reactions, and these processes should be used in conjunction with CO2 sequestration technology. Anthracite has a potential in terms of cost advantage as a feedstock compared to a petroleum pitch, because Synthetic graphite is prepared by heat treating an anthracite with high rank to a graphitization temperature which is in the range of 2400~2800℃, in the presence of inorganic catalyst such as silicon or iron. From several studies, it has been confirmed that coal-based activated carbon(AC) is manufactured with quality similar to the large specific surface area and much micropore volume of lignin-based AC, can be prepared. Therefore it is expected that lignin-based AC is replaced to coal-based AC.

Carbon balance and net ecosystem production in Quercus glauca forest, Jeju Island in South Korea

  • Jeong, Heon Mo;You, Young Han;Hong, Seungbum
    • Journal of Ecology and Environment
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    • v.46 no.3
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    • pp.250-258
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    • 2022
  • Background: To assess the carbon sequestration capacity and net ecosystem productivity (NEP) of Quercus glauca forests, we analyzed the net primary productivity (NPP), carbon storage, and carbon emission of soil in a Q. glauca forest on Jeju Island (South Korea) from 2016 to 2018. Results: The average carbon stock in the above- and below-ground plant biomass was 223.7 Mg C ha-1, while the average amount of organic carbon fixed by photosynthesis was 9.8 Mg C ha-1 yr-1, and the average NPP was 9.6 Mg C ha-1 yr-1. Stems and branches contributed to the majority of the above- and below-ground standing biomass and NPP. The average heterotrophic carbon emission from the soil was 8.7 Mg C ha-1 yr-1, while the average NEP was 1.1 Mg C ha-1 yr-1. Although the carbon stock, carbon absorption, and soil respiration values were higher than those reported in other oak forests in the world, the NEP was similar or lower. Conclusions: These results indicator that Q. glauca forests perform the role of a large carbon sink through the CO2 absorption in the plants in terms of carbon balance. And it is judged to be helpful as data for assessment of carbon storage and flux in the forests and mitigation of elevated CO2 in the atmosphere.

Seismic Data Processing and Inversion for Characterization of CO2 Storage Prospect in Ulleung Basin, East Sea (동해 울릉분지 CO2 저장소 특성 분석을 위한 탄성파 자료처리 및 역산)

  • Lee, Ho Yong;Kim, Min Jun;Park, Myong-Ho
    • Economic and Environmental Geology
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    • v.48 no.1
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    • pp.25-39
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    • 2015
  • $CO_2$ geological storage plays an important role in reduction of greenhouse gas emissions, but there is a lack of research for CCS demonstration. To achieve the goal of CCS, storing $CO_2$ safely and permanently in underground geological formations, it is essential to understand the characteristics of them, such as total storage capacity, stability, etc. and establish an injection strategy. We perform the impedance inversion for the seismic data acquired from the Ulleung Basin in 2012. To review the possibility of $CO_2$ storage, we also construct porosity models and extract attributes of the prospects from the seismic data. To improve the quality of seismic data, amplitude preserved processing methods, SWD(Shallow Water Demultiple), SRME(Surface Related Multiple Elimination) and Radon Demultiple, are applied. Three well log data are also analysed, and the log correlations of each well are 0.648, 0.574 and 0.342, respectively. All wells are used in building the low-frequency model to generate more robust initial model. Simultaneous pre-stack inversion is performed on all of the 2D profiles and inverted P-impedance, S-impedance and Vp/Vs ratio are generated from the inversion process. With the porosity profiles generated from the seismic inversion process, the porous and non-porous zones can be identified for the purpose of the $CO_2$ sequestration initiative. More detailed characterization of the geological storage and the simulation of $CO_2$ migration might be an essential for the CCS demonstration.

Assessment for $CO_2$ Biomineralization Characteristics and its Applicability for Solidified Sludge (이산화탄소 생광물화 특성 및 슬러지 고화물 적용성 평가)

  • Min, Dong-Hee;Ahn, Chang-Min;Han, Ji-Sun;Yoon, Soon-Uk;Jeon, Eun-Jeong;Won, Jong-Choul;Chun, Seung-Kyu;Kim, Chang-Gyun
    • Journal of Korean Society of Environmental Engineers
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    • v.33 no.11
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    • pp.812-820
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    • 2011
  • This study was conducted to characterize $CO_2$ biomineralization on several minerals (i.e., CaO, MgO, $SiO_2$) by bottle test in an aqueous solution and solidified sludge using different aerobic bacterial strains like Bacillus megaterium and Bacillus pasteurii by batch test. These bacteria promote the formation of microenvironments that facilitate the precipitation of mineral phases that were unsaturated in the bulk solution. For one type of mineral solely amended, the $CO_2$ was reduced at the highest of 4.0 mmol for MgO while it was not that much lower for CaO and $SiO_2$ showing 1.1 and 0.3 mmol $CO_2$2, respectively. For two types of minerals simultaneously amended, the $CO_2$ was reduced at the greater extent for both Ca + Mg and Mg + Si showing 2.7 and 2.3 mmol, respectively whereas it was less for Ca + Si at 1.8 mmol. For solidified sludge, the $CO_2$ reduction rate changed depending on the volume of solidified sludge placed in the medium and the input $CO_2$ concentration.. The reduction rate of $CO_2$ was increased with increasing the volume of solidified sludge. Results of XRD analysis indicate that $CaCO_3$ (Calcite) was dominantly formed among others (e.g., Aragonite, Dolomite). SEM analysis showed that the sample with Bacillus pasteurii, could more form minerals rather than control. As demonstrated in this study, $CO_2$ would be effectively sequestered in biomineralization process.