• Journal of the Korea Institute of Building Construction
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• v.24 no.3
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• pp.285-295
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• 2024

This study investigated the impact of accelerated carbonation on Ordinary Portland Cement(OPC) paste that had undergone steam curing at 500℃·hr. Two carbonation environments were examined: atmospheric carbonation(1atm, 20% CO₂) and pressurized carbonation(5atm, 99% CO₂). Chemical analysis using X-ray diffraction(XRD) and Fourier-Transform Infrared spectroscopy(FT-IR) were conducted, along with physical characterization via scanning electron microscopy(SEM) and compressive strength testing. Results indicated that atmospheric carbonation with 20% CO₂ concentration significantly densified the internal microstructure of the OPC paste, leading to enhanced compressive strength. Conversely, pressurized carbonation at 5atm with 99% CO₂ concentration resulted in rapid densification of the surface structure, which hindered CO₂ diffusion into the sample. This limited the extent of carbonation and prevented the improvement of physical properties.

• Transactions of the Korean hydrogen and new energy society
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• v.17 no.1
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• pp.109-116
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• 2006

The heat treatment characteristics of natural talc sample was investigated in diverse analytical view point. The mass decrease comes to heat treatment was resulted by the continuous and the discontinuous process and the obtained result show very similar two step profiles with 8.9 % mass decrease. The dehydroxylation of -OH groups contained talc crystal was analyzed by spectroscopic method and the crystallographic variations was also observed after heat treatment. According to XPS result, the magnesium hydroxide($Mg(OH)_2$) of untreated talc powder changed to magnesium oxides(MgO) after heat treatment.

• Geophysics and Geophysical Exploration
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• v.9 no.1
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• pp.44-49
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• 2006

In this study, the resolution capabilities of electrical resistivity tomography (ERT) in the monitoring of $CO_2$ injection are investigated. The pole-pole and bipole-bipole electrode configuration types are used between two uncased boreholes straddling the $CO_2$ plume. Forward responses for an initial pre-injection model and three models for subsequent stages of $CO_2$ injection are calculated for the two different electrode configuration types, noise is added and the theoretical data are inverted with both L1- and L2-norm optimisation. The results show that $CO_2$ volumes over a certain threshold can be detected with confidence. The L1-norm proved superior to the L2-norm in most instances. Normalisation of the inverted models with the pre-injection inverse model gives good images of the regions of changing resistivity, and an integrated measure of the total change in resistivity proves to be a valid measure of the total injected volume.

• Korean Journal of Air-Conditioning and Refrigeration Engineering
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• v.15 no.9
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• pp.718-726
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• 2003

Carbon dioxide ocean disposal is one of the promising options to reduce carbon dioxide concentration in the atmosphere because the ocean has vast capacity for carbon dioxide sequestration. However, the dissolution rate of liquid carbon dioxide in seawater must be known in advance in order to estimate the amount of carbon dioxide sequestration in the ocean. Therefore, in the present study, calculations of the solubility, the surface concentration and the dissolution behavior of carbon dioxide when liquid carbon dioxide is released at 1,000m and 1,500m in depth are peformed. The results show that the droplet is completely dissolved below 500 m in depth if the carbon dioxide droplet is released both at 1,000m in depth with the initial droplet diameter of 0.011m or less and at 1,500m in depth with the diameter of 0.016 or less. Also, the surface concentration of carbon dioxide droplet with the hydrate film is about 50% of carbon dioxide solubility at 1,500 m in depth and about 60% of carbon dioxide solubility at 1,000 m in depth.

• Fisheries and Aquatic Sciences
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• v.12 no.4
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• pp.350-353
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• 2009

As a result of human industrial development, carbon dioxide ($CO_2$) is currently accumulating in the atmosphere and dissolving into the oceans. Sequestration into the deep sea has been proposed as a possible solution to this increasing atmospheric $CO_2$, although the impact of such a program on marine ecosystems is unknown. We examined the effects of increased $CO_2$ levels on the growth of the olive flounder, Paralichthys olivaceus. Juvenile olive flounder 40 days post hatching were exposed to two levels of $CO_2$ (3.60-7.55 and 4.05-11.46 kPa) in running seawater for 26 days. During the exposure period, the pH and $CO_2$ levels of the water were measured, and the numbers of dead individuals were counted in each aquarium. Following the exposure period, the total lengths (mm) and body weights (mg) of the juvenile fish were measured. Both $CO_2$ treatments significantly increased fish mortality compared to controls ($19.87\pm4.53%$ vs. 7.14% and $75.96\pm1.36%$ vs. 7.14% for high and low doses, respectively). After the high $CO_2$ treatment, total length ($14.98\pm6.58$ mm vs. $19.52\pm1.83$ mm) and body weight ($28.92\pm13.85$ mg vs. $67.35\pm18.32$ mg) of the exposed flounder were reduced compared to the control fish; however, no significant differences in these values were observed after the low $CO_2$ dose. These results suggested that $CO_2$ exposure inhibits growth in the juvenile stage and that $CO_2$-enriched seawater is toxic in the early life stages of olive flounder.

• Journal of Soil and Groundwater Environment
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• v.20 no.4
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• pp.73-82
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• 2015

Despite significant effects on macroscopic migration and distribution of CO₂ injected during geological sequestration, only limited information is available on wettability in microscopic scCO₂-brine-mineral systems due to difficulties in pore-scale observation. In this study, a micromodel had been developed to improve our understanding of how scCO₂ flooding and residual characteristics of porewater are affected by the wettability in scCO₂-water-glass bead systems. The micromodel (a transparent pore structure made of glass beads and glass plates) in a pressurized chamber provided the opportunity to visualize scCO₂ spreading and porewater displacement. CO₂ flooding followed by fingering migration and dewatering followed by formation of residual water were observed through an imaging system. Measurement of contact angles of residual porewater in micromodels were conducted to estimate wettability in a scCO₂-water-glass bead system. The measurement revealed that the brine-3M NaCl solution-is a wetting fluid and the surface of glass beads is water-wet. It is also found that the contact angle at equilibrium decreases as the pressure decreases, whereas it increases as the salinity increases. Such changes in wettability may significantly affect the patterns of scCO₂ migration and porewater residence during the process of CO₂ injection into a saline aquifer at high pressures.

• Proceedings of the Korea Water Resources Association Conference
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• 2022.05a
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• pp.462-462
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• 2022

Wetlands are one of the most vital natural habitats on the planet. India is incredibly blessed to have a number of multifunctional wetland ecosystems. Wetlands, in addition to their functional importance, can act as sources or sinks for greenhouse gases (GHGs) depending on their intrinsic factors. Carbon (CO2) and Methane (CH4) are the major greenhouse gases (GHG's) emitted in wetlands. It is demonstrated that, despite having 4.6 percent of its area covered by natural or man-made wetlands, being home to a large number of wetlands, and being the world's second largest cultivator of paddy, India's wetlands, including paddy fields that are intermittently flooded as typical wetlands, have been very poorly studied in terms of GHG emissions. The purpose of this paper is to examine the status of Indian wetlands and wetlands in terms of CH4 and CO2 emissions. The present study also reviews various literature to provide the equations, parameters that are required for estimating carbon and methane and some of the best strategies for conserving carbon in wetlands. The findings suggest that both non-manipulative and manipulative measures can be used to improve Carbon Sequestration (CS). Non-manipulative measures aim to improve CS by increasing the spatial extent of wetlands, whereas manipulative measures aim to change the characteristics of specific wetland components that influence CS. Uncertainty in carbon dynamics projections under changing environmental conditions is caused by a number of Knowledge gaps: i) There is a lack of knowledge on how organic matter mineralizes and partitions into carbon dioxide, methane, and dissolved organic carbon, ii) With the notable exception of methane dynamics, models that represent the dynamic interaction of processes and their controls have yet to be established. As a result, more research is needed to fully understand the importance of wetlands in terms of GHG emissions and carbon sequestration in India.

• Korean Journal of Environmental Biology
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• v.34 no.4
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• pp.257-263
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• 2016

Objective of this study was to evaluate the carbon budget on 40 years old pear orchard at Naju. For carbon budget assessment, we measured the soil respiration, net ecosystem productivity of herbs, pear biomass and net ecosystem exchange. In 2015, pear orchard released about $25.6ton\;CO_2\;ha^{-1}$ by soil respiration. And $27.9ton\;CO_2\;ha^{-1}$ was sequestrated by biomass growth. Also about $12.6ton\;CO_2\;ha^{-1}$ was stored at pruning branches and about $5.2ton\;CO_2\;ha^{-1}$ for photosynthesis of herbs. As a result, 25.6 ton of $CO_2$ per ha is annually released to atmosphere. At the same time about 45.7 ton of $CO_2$ was sequestrated from atmosphere. When it sum up the amount of $CO_2$ release and sequestration, approximately $20.1ton\;CO_2\;ha^{-1}$ was sequestrated by pear orchard in 2015, and it showed no significant differences with net ecosystem exchanges ($17.8ton\;CO_2\;ha^{-1}\;yr^{-1}$) by eddy covariance method with the same period. Continuous research using various techniques will help the understanding of $CO_2$ dynamics in agroecosystem and it can be able to present a new methodology for assessment of carbon budget in woody crop field. Futhermore, it is expected that the this study can be used as the basic data to be recognized as a carbon sink.

• Bulletin of the Korean Chemical Society
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• v.33 no.7
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• pp.2325-2332
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• 2012

A series $[C_3Omim]$[X] of imidazolium cation-based ILs, with ether functional group on the alkyl side-chain have been synthesized and structure of the materials were confirmed by various techniques like $^1H$, $^{13}C$ NMR spectroscopy, MS-ESI, FTIR spectroscopy and EA. More specifically, the influence of changing the anion with same cation is carried out. The absorption capacity of $CO_2$ for ILs were evaluated at 30 and $50^{\circ}C$ at ambient pressure (0-1.6 bar). Ether functionalized ILs shows significantly high absorption capacity for $CO_2$. In general, the $CO_2$ absorption capacity of ILs increased with a rise in pressure and decreased when temperature was raised. The obtained results showed that absorption capacity reached about 0.9 mol $CO_2$ per mol of IL at $30^{\circ}C$. The most probable mechanism of interaction of $CO_2$ with ILs were investigated using FTIR spectroscopy, $^{13}C$ NMR spectroscopy and result shows that the absorption of $CO_2$ in ether functionalized ILs is a chemical process. The $CO_2$ absorption results and detailed study indicates the predominance of 1:1 mechanism, where the $CO_2$ reacts with one IL to form a carbamic acid. The $CO_2$ absorption capacity of ILs for different anions follows the trend: $BF_4$ < DCA < $PF_6$ < TfO < $Tf_2N$. Moreover, the as-synthesized ILs is selective, thermally stable, long life operational and can be recycled at a temperature of $70^{\circ}C$ or under vacuum and can be used repeatedly.

• IMMUNE NETWORK
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• v.9 no.1
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• pp.12-19
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• 2009

Heme oxygenase (HO)-1 is an inducible enzyme that catalyzes the first and rate-limiting step in the oxidative degradation of free heme into ferrous iron, carbon monoxide (CO), and biliverdin (BV), the latter being subsequently converted into bilirubin (BR). HO-1, once expressed during inflammation, forms high concentrations of its enzymatic by-products that can influence various biological events, and this expression is proven to be associated with the resolution of inflammation. The degradation of heme by HO-1 itself, the signaling actions of CO, the antioxidant properties of BV/BR, and the sequestration of ferrous iron by ferritin all concertedly contribute to the anti-inflammatory effects of HO-1. This review focuses on the anti-inflammatory mechanisms of HO-1 actions and its roles in inflammatory diseases.