• Title/Summary/Keyword: $CO_2$ leakage

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Electrical Properties of $Pr_{6}O_{11}$-Based ZnO Varistors with CoO Content (CoO 첨가량에 따른 $Pr_{6}O_{11}$계 ZnO 바리스터의 전기적 특성)

  • 김향숙;류정선;남춘우
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2001.07a
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    • pp.419-422
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    • 2001
  • The electrical properties of Pr$_{6}$O$_{11}$-based ZnO varistors composed of ZnO-Pr$_{6}$O$_{11}$-CoO-Cr$_2$O$_3$-Dy$_2$O$_3$- based ceramics were investigated with CoO content in the range of 0.5~5.0 mol%. As CoO content is increased, the average grain size and the density were increased in the range of 9.86~27.22 $\mu$m and in the range of 5.25-5.55 g/cm$^3$, respectively. The varistor voltage was decreased in the range of 235.32~86.01 V/mm due to the increase of average grain size with CoO content. The varistors doped with CoO in the rage of 1.0~2.0 mol% exhibited a high nonlinearity, in which is above 55 in the nonlinear exponent and below 1.5 $\mu$A in the leakage current. Increasing CoO content further greatly decreased the nonlinearity.ity.ity.

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A Study on a Carrier Based PWM having Constant Common Mode Voltage and Minimized Switching Frequency in Three-level Inverter

  • Ahn, Kang-Soon;Choi, Nam-Sup;Lee, Eun-Chul;Kim, Hee-Jun
    • Journal of Electrical Engineering and Technology
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    • v.11 no.2
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    • pp.393-404
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    • 2016
  • In this paper, a carrier-based pulse with modulation (PWM) strategy for three-phase three-level inverter is dealt with, which can keep the common mode voltage constant with minimized switching frequency. The voltage gain and the switching frequency in overall operating ranges including overmodulation are investigated and the analytic equations are presented. Finally, the leakage current reduction effect is confirmed by carrying out simulation and experiment. It will be pointed out that the leakage current cannot be perfectly eliminated because of the dead time.

Scheme on Environmental Risk Assessment and Management for Carbon Dioxide Sequestration in Sub-seabed Geological Structures in Korea (이산화탄소 해양 지중저장사업의 환경위해성평가관리 방안)

  • Choi, Tae-Seob;Lee, Jung-Suk;Lee, Kyu-Tae;Park, Young-Gyu;Hwang, Jin-Hwan;Kang, Seong-Gil
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.12 no.4
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    • pp.307-319
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    • 2009
  • Carbon dioxide capture and storage (CCS) technology has been regarded as one of the most possible and practical option to reduce the emission of carbon dioxide ($CO_2$) and consequently to mitigate the climate change. Korean government also have started a 10-year R&D project on $CO_2$ storage in sea-bed geological structure including gas field and deep saline aquifer since 2005. Various relevant researches are carried out to cover the initial survey of suitable geological structure storage site, monitoring of the stored $CO_2$ behavior, basic design of $CO_2$ transport and storage process and the risk assessment and management related to $CO_2$ leakage from engineered and geological processes. Leakage of $CO_2$ to the marine environment can change the chemistry of seawater including the pH and carbonate composition and also influence adversely on the diverse living organisms in ecosystems. Recently, IMO (International Maritime Organization) have developed the risk assessment and management framework for the $CO_2$ sequestration in sub-seabed geological structures (CS-SSGS) and considered the sequestration as a waste management option to mitigate greenhouse gas emissions. This framework for CS-SSGS aims to provide generic guidance to the Contracting Parties to the London Convention and Protocol, in order to characterize the risks to the marine environment from CS-SSGS on a site-specific basis and also to collect the necessary information to develop a management strategy to address uncertainties and any residual risks. The environmental risk assessment (ERA) plan for $CO_2$ storage work should include site selection and characterization, exposure assessment with probable leak scenario, risk assessment from direct and in-direct impact to the living organisms and risk management strategy. Domestic trial of the $CO_2$ capture and sequestration in to the marine geologic formation also should be accomplished through risk management with specified ERA approaches based on the IMO framework. The risk assessment procedure for $CO_2$ marine storage should contain the following components; 1) prediction of leakage probabilities with the reliable leakage scenarios from both engineered and geological part, 2) understanding on physio-chemical fate of $CO_2$ in marine environment especially for the candidate sites, 3) exposure assessment methods for various receptors in marine environments, 4) database production on the toxic effect of $CO_2$ to the ecologically and economically important species, and finally 5) development of surveillance procedures on the environmental changes with adequate monitoring techniques.

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Detection of Potential Flow Paths of Leaked CO2 from Underground Storage Using Electrical Resistivity Survey (전기비저항탐사 방법에 의한 지중 저장 이산화탄소 누출 가능 경로 탐지)

  • Lim, Woo-Ri;Hamm, Se-Yeong;Hwang, Hak-Soo;Kim, Sung-Wook;Jeon, Hang-Tak
    • The Journal of Engineering Geology
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    • v.28 no.1
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    • pp.69-79
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    • 2018
  • The Korean government attempts to reduce $CO_2$ emissions by 37% to 314.7 Mt $CO_2$, down from the estimated 850.6 Mt $CO_2$ until 2030 in order to confront green house effect. In this context, in 2014, Korean government launched $CO_2$ Storage Environmental Management Research (K-COSEM) Center for carrying out pilot-scale research on $CO_2$ leakage from underground $CO_2$ storage facilities. For the detection of $CO_2$ leakage, it is necessary to identify hydrologeological and geophysical characteristics of the subject area. In the study site of Naesan-ri, Daeso-myeon, Eumseong-gun, Chungbuk Province, two times injection tests (June 28-July 24, 2017 and August 07-September 11, 2017) of $CO_2$ and $SF_6$ dissolved waters, respectively, was conducted to understand the leakage behavior of $CO_2$ from underground. The injection well was drilled to a depth of 24 m with a 21-m casing and screen interval of 21~24 m depth. Two times resistivity surveys on August 18, 2017 and September 1, 2017, were conducted for revealing the flow of the injected water as well as the electrical properties of the study site. The study results have shown that the high-resistivity zone and the low-resistivity zone are clearly contrasted with each other and the flow direction of the injected water is similar to natural groundwater flow. Besides, the low resistivity zone is widely formed from the depth of injection to the shallow topsoil, indicating that the weathered zone of high permeability has high $CO_2$ leakage potential.

Practical 2-Arch Road Tunnel Design in Mountainous area (산악지형에서 효율적인 2-Arch 터널의 설계사례)

  • Jeong, Kyeong-Han;Lee, Joo-Gong;Han, Sung-Su;Hwang, Yong-Sub;Kim, Ji-Sung
    • Proceedings of the Korean Geotechical Society Conference
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    • 2005.10a
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    • pp.601-612
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    • 2005
  • In mountainous area, Two parallel tunnels have been usually recognized as a road tunnel which has benefits in aspects of cost and stability. However, Design and construction of 2-Arch road tunnel are growing recently due to environmental destruction, compensation of land and difficulty of route separation. As studies are mainly undergoing on only guaranteeing stability and developing a waterproofing-drainage system to avoid water leakage through comprehension for characteristics of 2-arch tunnel behaviors, there is a tendency to evaluate quantity of support by empirical method with a tunnel which has a complicated cross-section and lack of construction ability. In this study, therefore, we made a plan of tunnel cross-section which had shown good construction ability and developed the waterproofing-drainage system which is able to solve the water leakage problem fundamentally by analyzing precedented 2-arch tunnels and investigating their sites in and out of nation. We also determined fixed quantity of support by a large-scale model test and numerical analysis. We want to contribute to 2-arch tunnel design hereafter introducing design procedure and method applied here.

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Dielectric and Magnetic Properties of Niobium and Cobalt Co-substituted Multiferroic BiFeO3 Thin Films (Niobium과 Cobalt를 첨가한 Multiferroic BiFeO3 박막의 유전 특성 및 자성 특성)

  • Jun, Youn-Ki;Hong, Seong-Hyeon
    • Journal of the Korean Ceramic Society
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    • v.45 no.9
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    • pp.556-560
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    • 2008
  • The effects of Nb and Co ion substitution on the dielectric and magnetic properties of the multiferroic $BiFeO_3$ thin films have been investigated. Heteroepitaxial $BiFeO_3$ thin films were deposited by Pulsed Laser Deposition method. Nb substitution decreased the leakage current by 6 orders of magnitude and Co substituted $BiFeO_3$ thin films showed an enhanced magnetization, 2 times larger than that of un-substituted $BiFeO_3$. Through the co-substitution of Co and Nb, $BiFeO_3$ thin films with a low leakage current and an enhanced magnetization could be obtained.

A Study on the Output Characteristics of AC Chopper Duty-Ratio $CO_2$ Laser System using 3 Electrode-type and Ring Blower (AC Chopper 3전극 방식의 듀티비에 따른 $CO_2$ 레이저 출력 특성에 관한 연구)

  • Park, Sung-Joon;Chung, Hyun-Ju;Kim, Geun-Yong;Lee, Yoo-Su;Kim, Whi-Young;Kim, Hee-Je
    • Proceedings of the KIEE Conference
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    • 2001.07c
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    • pp.1697-1699
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    • 2001
  • In this paper, the circuit of AC Choppers for $CO_2$ laser power supply are proposed and investigated. IGBT-controlled ac voltage regulators, operating at high frequency chopping mode. Chopping-to-supply duty ratio plays an important role in terms of laser output. Laser input energy is varied by controlling the leakage transformer used with the proposed system. This improved circuit employs a 3 electrode - type and Ring Blower. This improved circuit system has many advantages compared with the conventional SMPS such as simple design requirement, easy implementation, high reliability, low switching loss, and consequently high efficiency. As a result, the maximun output was 16W at duty-ratio of 92%, total gas mixture of $CO_2$ : $N_2$ : He = 1 : 9 : 15, total pressure of 15torr.

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Corn Growth and Development influenced by Potential CO2 Leakage from Carbon Capture and Storage (CCS) Site (지중저장 이산화탄소의 잠재적 누출 모사에 따른 옥수수 초기 반응 및 생장 연구)

  • Kim, You Jin;Chen, Xuanlin;He, Wenmei;Yoo, Gayoung
    • Journal of Climate Change Research
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    • v.8 no.3
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    • pp.257-264
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    • 2017
  • Carbon capture and storage (CCS) technology has been suggested as an ultimate strategy for mitigating climate change. However, potential leakage of $CO_2$ from the CCS facilities could lead to serious damage to environment. Plants can be a bio-indicator for $CO_2$ leakage as a cost-effective way, although plants' responses vary with plant species. In this study, a greenhouse experiment was conducted to investigate the relation between the $CO_2$ tolerance of corn species and the initial physiological responses to the elevated soil $CO_2$ concentration. Treatment groups included CI (99.99% $CO_2$ gas injection) and BI (no gas injection). Mean soil $CO_2$ concentration for the CI treatment was 19.5~39.4%, and mean $O_2$ concentration was 6.6~18.4%. The soil gas concentrations in the BI treatment were at the ambient levels. In the CI treatment, chlorophyll content was not decreased until the $13^{th}$ day of the $CO_2$ injection. On the $15^{th}$ day, leaf starch content and stomatal conductance were increased by 89% and 25% in the CI treatment compared to the BI treatment, respectively. This might be due to the compensatory reaction of corn to avoid high soil $CO_2$ stress. However, the prolonged $CO_2$ injection decreased chlorophyll content after 13 days. After $CO_2$ injection, plant biomass was reduced by 25% in the CI treatment compared to the BI treatment. Due to the inhibited root growth, leaf phosphorous and potassium contents were decreased by 54% on average in the CI treatment. This study indicates that corn has a high tolerance to soil $CO_2$ concentration of 30% for 2 weeks by its compensatory reactions such as an maintenance of chlorophyll content and an increase in stomatal conductance.

Microstructure and Electrical Properties of ZnO-$Pr_6$$O_{11}$-CoO-$Er_2$$O_3$ Based Varistors (ZnO-$Pr_6$$O_{11}$-CoO-$Er_2$$O_3$계 바리스터의 미세구조 및 전기적 성질)

  • 남춘우;박춘형
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.13 no.6
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    • pp.493-501
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    • 2000
  • The microstructure and electrical properties of ZnO-Pr$_{6}$/O$_{11}$-CoO-Er$_{2}$/O$_{3}$ based varistors were investigated with Er$_{2}$/O$_{3}$ additive content of the range 0.0 to 2.0 mol%. Most of the added Er$_{2}$/O$_{3}$ were segregated at the nodal points and grain boundaries and it coexisted with Pr$_{6}$/O$_{11}$ in the bulk intergranular layer. The average grain size was decreased in the range of 7.44 to 5.62${\mu}{\textrm}{m}$ at 130$0^{\circ}C$ and 18.36 to 9.11 at 135$0^{\circ}C$ with increasing Er$_{2}$/O sub 3/ additive content. The density of ceramics was in the range 4.87 to 5.08 g/cm$^3$ at 130$0^{\circ}C$ and 5.35 to 5.62 g/cm$^3$at 135$0^{\circ}C$. At 130$0^{\circ}C$ the varistors without Er$_{2}$/O$_{3}$ exhibited 29.66 in the nonlinear exponent and 28.23 $\mu$A in the leakage current whereas the varistors with 0.5 mol% Er$_{2}$/O$_{3}$ exhibited a high nonlinearity which is 52.78 in thenonlinear exhibited and 9.75 $\mu$A in the leakage current. At 135$0^{\circ}C$ the varistors without Er$_{2}$/O$_{3}$ exhibited a very poor nonlinearity indicating 2.08 in the nonlinear exponent and 133.79 $\mu$A in the leakage current whereas the varistors with 1.0mol% Er$_{2}$/O$_{3}$ exhibited a relatively high nonlinearity which is 36.79 in the nonlinear exponent and 5.92 $\mu$A in the leakage current. Therefore Er$_{2}$/O$_{3}$ was additive which greatly improve the nonlinearity. It is believed that ZnO-0.5 mol% Pr$_{6}$/O$_{11}$-1.0 mol% CoO-0.5 mol% Er$_{2}$/O$_{3}$ based ceramicss will be usefully used as a basic composition to develop the advanced pr$_{6}$/O$_{11}$-based ZnO varistors.ristors.ristors.

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A Study on the Electrical Properties of Cobalt Policide Gate (코발트 폴리사이드 게이트의 전기적 특성에 관한 연구)

  • Jeong, Yeon-Sil;Gu, Bon-Cheol;Bae, Gyu-Sik
    • Korean Journal of Materials Research
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    • v.9 no.11
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    • pp.1117-1122
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    • 1999
  • Amorphous Si and Co/Ti bilayers were sequentially evaporated onto 5- 10nm thick $\textrm{CoSi}_{2}$ and rapidly thermal-annealed(RTA) to form Co-polycide electrodes. Then, MOS capacitors were fabricated by doping poly-Si using SADS method. The C-V and leakage-current characteristics of the capacitors depending upon the RTA conditions were measured to study the effects of thermal stability of $\textrm{CoSi}_{2}$ and dopant redistribution on electrical properties of Co -polycide gates. Capacitors RTAed at $700^{\circ}C$ for 60-80 sec., showed excellent C-V and leakage-current characteristics due to degenate doping of poly-Si layers. But for longer time or at higher temperature, their electrical properties were degraeded due to $\textrm{CoSi}_{2}$ decomposition and subsequent Co diffusion. When making Co-polycide gate electrodes by SADS, not only degenerate doping of poly-Si layer. but also suppression of have been shown to be very critical.

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