• Title/Summary/Keyword: $CO_2$ emitted

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Coincidence Summing Corrections in HPGe Gamma Ray Spectrometry in Marinelli-beakers with Efficiency (효율을 적용한 마리넬리 비이커에서 HPGe 감마선 분광분석법의 동시합성보정)

  • Jang, Eun-Sung;Lee, Hyo-Yeong
    • Journal of the Korean Society of Radiology
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    • v.12 no.5
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    • pp.557-563
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    • 2018
  • Coincidence summing correction effects are known to be greater as the efficiency of the detector increases and as the distance between the source and the detector increases. A point source($^{60}Co$) was used to vary the distance in the direction of the detector's center axis and in the radial direction to obtain the P/T ratio for Coincidence summing correction calibration. In this study, values for coincidence summing corrected calibration of the values in the central and radial directions were applied to the mixed volume source(450 ml CRM source) to compare the overall peak efficiency change according to P/T with Geant4. In addition, the efficiency obtained from the mapping method is applied to the seaweed, a marine sample, and the compatibility of the P/T ratio with the detector and sample very dose together. The efficiency corrected to 1,836 keV was applied to the energy zone affected by the efficiency of 500 keV and the relative error of the measured and corrected values was well matcched by the 3.2 % peak efficiency correction. As with 450 mL CRM source, the larger the volume, the lower the P/T ratio was by ${\pm}5%$. This is due to the increased scattering of gamma-rays emitted as the source becomes farther away from the detector, and this change in P/T has been confirmed to affect the Coincidence summing corrected peak efficiency.

Basic Research of Self Compacting Concrete Using Alkali-Activated Slag Binder (알칼리 활성 슬래그 결합재를 이용한 자기충전 콘크리트의 기초 연구)

  • Song, Keum-Il;Shin, Gyeong-Sik;Gong, Min-Ho;Song, Jin-Kyu
    • Journal of the Korea Concrete Institute
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    • v.25 no.6
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    • pp.657-665
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    • 2013
  • The purpose of this study is the basic research of self-compacting concrete using Alkali-Activated Slag (AAS) binder in order to emphasize the durability of structures and facilitate casting the fresh concrete in field. The AAS binder emitted low carbon dioxide ($CO_2$) is eco friendly material of new concept because AAS products not only emit little $CO_2$ during production but also reuse the industrial by-products such as ground granulated blast-furnace slag (GGBS) of the steel mill. Until now, almost of domestic and foreign research are using Ordinary Portland Cement (OPC) for self-compacting concrete, and also, nonexistent research about AAS. The self-compacting concrete must get the performance of flowability, segregation resistance, filling and passing ability. Nine concrete mixes were prepared with the main parameter of unit amount of binder (400, 500, 600 $kg/m^3$) and 3 types of water-binder (W/B) ratio. The results of test were that fresh concretes were satisfied with flowability, segregation resistance, and filling ability of JSCE. But the passing ability was not meet the criteria of EFNARC because of higher viscosity of AAS paste than OPC. This high viscosity of AAS paste enables the manufacturing of self compacting concrete, segregation of which does not occur without the using of viscosity agent. It is necessary that the development of high fluidity AAS binders of higher strength and the study of better passing ability of AAS concrete mixes in order to use self compacting AAS concrete in field.

Life Cycle Assessment (LCA) of the Wind Turbine : A case study of Korea Yeongdeok Wind Farm (한국 영덕 풍력단지 사례 연구를 통한 풍력 발전의 환경 영향 평가)

  • Jun Heon Lee;Jun Hyung Ryu
    • Korean Chemical Engineering Research
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    • v.61 no.1
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    • pp.142-154
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    • 2023
  • As the importance of the environment has been recognized worldwide, the need to calculate and reduce carbon emissions has been drawing an increasing attention throughout various industrial sections. Thereby the discipline of LCA (Life Cycle Assessment) involving raw material preparation, production processes, transportation and installation has been established. There is a clear research gap between the need and the practice for Korean Case of renewable energy industry, particularly wind power. To bridge the gap, this study conducted LCA research on wind power generation in the Korean area of Yeongdeok, an example of a domestic onshor wind power complex using SimaPro, which is the most widely used LCA system. As a result of the study, the energy recovery period (EPT) of one wind turbine is about 10 months, and the GHG emitted to generate power of 1 kwh is 15 g CO2/kWh, which is competitive compared to other energy sources. In the environmental impact assessment by component, the results showed that the tower of wind turbines had the greatest impact on various environmental impact sectors. The experience gained in this study can be further used in strengthening the introduction of renewable energy and reducing the carbon emission in line with reducing climate change.

The Role of Organic Amendments with Different Biodegradability in Ammonia Volatilization during Composting of Cattle Manure (우분뇨 퇴비화 중 암모니아 휘산에 대한 이분해성 및 난분해성 유기 첨가물의 역할)

  • Lim, Sang-Sun;Park, Hyun-Jung;Lee, Sun-Il;Lee, Dong-Suk;Kwak, Jin-Hyeob;Choi, Woo-Jung
    • Korean Journal of Environmental Agriculture
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    • v.28 no.1
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    • pp.20-24
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    • 2009
  • This study was conducted to investigate the roles of co-existed organic materials (OM) with different biodegradability in composting of cattle manure in terms of $CO_2$ emission and $NH_3$ volatilization. Either sawdust (SD, low biodegradability) or rice bran (RB, high biodegradability) was mixed with cattle manure at a various rate and the amounts of $CO_2$ emission and $NH_3$ volatilization were determined periodically during 4 weeks of composting. Percentage of dry matter loss during the composting period was also calculated. The amount of $CO_2$ emitted increased with increasing rate of OM and was significantly (P<0.01) higher in the RB treatment than in the SD treatment by 43 to 122% depending on the rate of OM Accordingly, % of dry matter loss during 4 weeks of composting was higher in the RB (rang: from 35.1 % to 41.5%) than that in the SD treatments (from 18.7% to 22.6%), showing that RB is more biodegradable than SD. During the early composting period up to 8 days, negligible amount of ammonia volatilization was detected in both treatments regardless of application rates. In the RB treatment, substantial amount of ammonia volatilization was detected thereafter, however, no meaningful ammonia volatilization was observed in the SD treatment until the end of composting. Such differences could be attributed to the different properties of SD and RB. For example, the high C/N ratio of SD could enhance $NH_4^+$ immobilization and thus decrease $NH_4^+$ concentration that is susceptible to ammonia volatilization. Binding of $NH_4^+$ on to phenolic compounds of SD may also contribute to the decrease in $NH_4^+$ concentration. Meanwhile, as RB has a relatively low C/N ratio, remineralization of immobilized $NH_4^+$ could increase $NH_4^+$ concentration as high as the level for the occurrence of ammonia volatilization. Therefore, our study suggests that OM which is resistant to biodegradation can reduce $NH_3$ volatilization largely by physico-chemical pathways across the entire composting period and that easily biodegradable OM can retard $NH_3$ volatilzation via microbial immobilization in the early period of composting followed by rapid remineralization, leading to substantial volatilization of $NH_3$ in the middle stage of composting.

Changes of Soil-Emission Gases and Microbial Diversity by Different Fertilizers Supplemented after Application of Livestock-Manure Compost in Greenhouse Soil (시설재배지(施設栽培地)에서 축분퇴비(畜糞堆肥) 시용시(施用時) 보충비종(補充費種)에 따른 토양배출(土壤排出)가스 및 미생물다양성(微生物多樣性)의 변화(變化))

  • Kang, Hang-Won;Ko, Jee-Yeon;Park, Hyang-Mee;Lee, Jae-Saeng;Rang, Ui-Gum;Park, Kyeong-Bae
    • Korean Journal of Soil Science and Fertilizer
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    • v.33 no.1
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    • pp.52-60
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    • 2000
  • This study was conducted to gain basic data for alleviation of gas emission and conservation of healthy soil environment by investigating an aspect of gas emission and microbial diversity due to the supplement of different fertilizers after application with a livestock manure compost in greenhouse soils. Green pepper was cultivated in clay loamy soil from April to August. Before planting, a livestock manure compost was applied with $741mg\;ha^{-1}$ on the basis of the phosphate content contained in compost. And then, deficient nitrogen for cropping was supplemented with either quick-acting fertilizer of urea or a controlled slow release fertilizer made from urea formaldehyde(U/F). $NH_3$ and R $NH_2$ gases emitted from soil showed a low concentration in the early stage but a maximum in 27 days after planting, then decreased rapidly and not detected after 33 days. Their average concentrations were 42% and 85% lower in the treatment of slow release fertilizer than that of urea fertilizer, respectively. $CO_2$ gas emitted under urea fertilization was ranged from 1,200 to $3,200mg{\ell}^{-1}$ and that in slow release fertilizer was $900{\sim}2,650mg\;{\ell}^{-1}$. The average concentration of urea treatment was $2,260mg{\ell}^{-1}$ and 30% higher than that of slow release fertilizer. The treatment of slow release fertilizer with the lapse of cropping time populated larger in numbers of bacteria, actinomycetes, nitrate bacteria and nitrate reduction bacteria, and ratios of bacteria and actinmycetes to fungi than that of urea fertilizer. But the number of fungi was higher in the treatment of urea fertilizer and denitrifying bacteria showed a similar trend in both treatments. The microbial diversity index, which calculated with numbers of 6 species of microorganisms, was decreased with increasing of growing stage in the range of 0.1 to 0.35 and that was higher in the tratment of slow release fertilizer than urea.

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Applied Technologies and Effects for the Carbon Zero Office Building (업무용 탄소제로건물의 적용기술 및 효과)

  • Lee, Jae-Bum;Hong, Sung-Chul;Beak, Name-Choon;Choi, Jin-Young;Hong, You-Deog;Lee, Suk-Jo;Lee, Dong-won
    • Journal of Climate Change Research
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    • v.2 no.4
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    • pp.283-295
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    • 2011
  • Many actions against climate change have been taken to reduce greenhouse gases (GHGs) emissions at home and abroad. As of 2007, the GHGs emitted from buildings accounted for about 23 % of Korea's total GHGs emission, which is the second largest GHG reduction potential following industry. In this study, we introduced Carbon Zero Building (CZB), which was constructed by the National Institute of Environmental Research to cut down GHGs from buildings in Korea, and evaluated the main applied technologies, the amount of energy load and reduced energy, and economic values for CZB to provide data that could be a basis in the future construction of this kind of carbon-neutral buildings. A total of 66 technologies were applied for this building in order to achieve carbon zero emissions. Applied technologies include 30 energy consumption reduction technologies, 18 energy efficiency technologies, and 5 eco-friendly technologies. Out of total annual energy load ($123.8kWh/m^2$), about 40% of energy load ($49kWh/m^2$) was reduced by using passive technologies such as super insulation and use of high efficiency equipments and the other 60% ($74.8kWh/m^2$) was reduced by using active technologies such as solar voltaic, solar thermal, and geothermal energy. The construction cost of CZB was 1.4 times higher than ordinary buildings. However, if active technologies are excluded, the construction cost is similar to that of ordinary buildings. It was estimated that we could save annually about 102 million won directly from energy saving and about 2.2 million won indirectly from additional saving by the reduction in GHGs and atmospheric pollutants. In terms of carbon, we could reduce 100 ton of $CO_2$ emissions per year. In our Life Cycle Cost (LCC) analysis, the Break Even Point (BEP) for the additional construction cost was estimated to be around 20.6 years.

Analysis of the Association between Air Pollutant Distribution and Mobile Sources in Busan Using Spatial Analysis (공간 분석을 통한 부산광역시 대기오염물질의 분포와 이동오염원 간의 관련성 연구)

  • Jae-Hee Min;Byoung-Gwon Kim;Hyunji Ju;Na-Young Kim;Yong-Sik Hwang;Seungho Lee;Young-Seoub Hong
    • Journal of Environmental Health Sciences
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    • v.50 no.3
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    • pp.191-200
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    • 2024
  • Background: Busan is a rapidly industrializing city with many mixed residential and industrial areas. Fine dust emissions from mobile pollution sources such as ships and vehicles are particularly high in Busan. Objectives: This study analyzed the spatial distribution of air pollutants over the past three years and identified the impact of air pollutants through mobile source data in Busan. Methods: We obtained air pollutant data on fine particulate matter (PM10), ultrafine particulate matter (PM2.5), nitrogen dioxide (NO2), sulfurous acid gas (SO2), and ozone (O3) for the last three years (source: airkorea.or.kr) and analyzed the spatial distribution using SAS 9.4 and Surfer 23. For the mobile pollutant data, we used CCTV data from major intersections in Busan to identify truck and car traffic, and visualized traffic density with QGIS. Results: The analysis of the concentration of air pollutants over three years (2020~2022) showed that all were lower than the annual environmental standards with the exception of PM2.5. PM10 and PM2.5 were found to be highly concentrated in the western part of the area, while NO2 was high in the port area of Busan and SO2 was high in the western part of the area and near the new port of Busan. In the case of O3, it was high in the eastern part of the city. The traffic volume of freight vehicles by intersection was concentrated in the West Busan area, and the traffic volume for all cars was also confirmed to be concentrated at "Mandeok Intersection" located in the West Busan area. Conclusions: This study was conducted to determine the relationship between air pollutants emitted from motor vehicles and the distribution of air pollutants in Busan. The spatial distribution of PM10 and PM2.5 correlates with traffic volume, while high concentrations of SO2 and NO2 near the port are associated with ship emissions.

The Study on Design of lead monoxide based radiation detector for Checking the Position of a Radioactive Source in an NDT (비파괴검사 분야에서 방사선원의 위치 확인을 위한 산화납 기반 방사선 검출기 설계에 관한 연구)

  • Ahn, Ki-Jung
    • Journal of the Korean Society of Radiology
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    • v.11 no.4
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    • pp.183-188
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    • 2017
  • In recent years, the automatic remote control controller of the gamma ray irradiator malfunctions, and radiation workers are continuously exposed to radiation exposure accidents. In the non-destructive testing field, much time and resources are invested in establishing a radioactive source monitoring system in order to prevent potential incidents of radiation. In this study, the gamma-ray response properties of the lead monoxide-based radiation detector were estimated through monte carlo simulation as a previous study for the development of a radioactive source location monitoring system that can be applied universally to various non-destructive testing equipment. As a result of the study, the optimized thickness of the radiation detector varies according to the gamma-ray energy emitted from the radioactive source, and the optimized thickness gradually increases with increasing energy. In conclusion, the optimized thickness of the lead monoxide-based radiation detector was $200{\mu}m$ for the Ir-192, $150{\mu}m$ for the Se-75 and $300{\mu}m$ for the Co-60. Based on these results, the appropriate thickness of lead monoxide-based radiation detector considering secondary-electron equilibrium was evaluated to be $300{\mu}m$ for general application. These results can be used as a basic data for determining the appropriate thickness required in the radiation detector when developing a radiation source location monitoring system for universal application to various non-destructive testing equipment in the future.

Products and pollutants of half dried sewage sludge and waste plastic co-pyrolysis in a pilot-scale continuous reactor (반 건조 하수슬러지와 폐플라스틱 혼합물의 파일롯 규모 연속식 열분해에 의한 생산물과 발생 오염물질)

  • Kim, YongHwa;Chun, Seung-Kyu
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.2
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    • pp.327-337
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    • 2017
  • A continuous low temperature ($510^{\circ}C{\sim}530^{\circ}C$) pyrolysis experiment in a pilot-scale of 85.3 kg/hr was carried out by the mixed feedstock of half dried digested sewage sludge and waste plastics. As a result, the amount of pyrolysis gas generated was maximum 68.3% of input dry mass and scored $40.9MJ/Nm^3$ of lower heating value (LHV), and the percentage of air inflow caused by continuous pyrolysis was 19.6%. The oil was produced 4.2% of the input dry mass, and the LHV was 32.5 MJ/kg. The sulfur and chlorine contents, which could cause corrosion of the facility, were found to be 0.2% or more respectively. The carbide generated was 27.5% of the input dry mass which shows LHV of 10.2 MJ/kg, and did not fall under designated waste from the elution test. The concentration of carbon monoxide, sulfur oxides and hydrogen cyanide of emitted flu gas from pyrolysis gas combustion was especially high, and dioxin (PCDDs/DFs) was within the legal standards as $0.034ng-TEQ/Sm^3$. Among the 47 water pollutant contents of waste water generated from dry flue gas condensation, several contents such as total nitrogen, n-H extract and cyanide showed high concentration. Therefore, the merge treatment in the sewage treatment plants after pre-treatment could be considered.

Depolymerization of Kraft Lignin at Water-Phenol Mixture Solvent in Near Critical Region (물-페놀 혼합 용매의 근임계 하에서의 크래프트 리그닌의 저분자화)

  • Eom, Hee-Jun;Hong, Yoon-Ki;Chung, Sang-Ho;Park, Young-Moo;Lee, Kwan-Young
    • Journal of Energy Engineering
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    • v.20 no.1
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    • pp.36-43
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    • 2011
  • Plant biomass has been proposed as an alternative source of petroleum-based chemical compounds. Especially, aromatic chemical compounds can be obtained from lignin by depolymerization processes because the lignin consist of complex aromatic materials. In this study, kraft lignin, the largest emitted substance among several kinds of lignin in Korea, was used as a starting material and was characterized by solid-state $^{13}C$-Muclear Magnetic Resonance($^{13}C$-NMR), Fourier Transform Infrared Spectroscopy(FT-IR), Elemental Analysis(EA). The depolymerization of kraft lignin was studied at water-phenol mixture solvent in near critical region and the experiments were conducted using a batch type reactor. The effects of water-to-phenol ratio and reaction temperature($300-400^{\circ}C$) were investigated to determine the optimum operating conditions. Additionally, the effects of formic acid as a hydrogen-donor solvent instead of $H_2$ gas were examined. The chemical species and quantities in the liquid products were analyzed using gas chromatography-mass spectroscopy(GC-MS), and solid residues(char) were analyzed using FT-IR. GC-MS analysis confirmed that the aromatic chemicals such as anisole, o-cresol(2-methylphenol), p-cresol(4-methylphenol), 2-ethylphenol, 4-ethylphenol, dibenzofuran, 3-methyl cabazole and xanthene were produced when phenol was added in the water as a co-solvent.