• 제목/요약/키워드: $CO_2$ curing

검색결과 285건 처리시간 0.097초

A Study on the Application in Site of the Concrete Using Fly Ash Produced in Combined Heat Power Plant (열병합발전소 플라이애쉬를 사용한 콘크리트의 현장적용에 관한 연구)

  • 김무한;이상수
    • Journal of the Korea Concrete Institute
    • /
    • 제11권5호
    • /
    • pp.41-49
    • /
    • 1999
  • This study dealt with the applicability and quality control of the concrete using fly ash produced in combined heat power in a construction site. Firstly, chemical and physical characteristics of the fly ash produced in combined heat power plant re analysed. Also, after investigating the properties of flesh and hardened concrete through various experiments, the fly ash concrete was placed in depositing construction in Ulsan Petrochemical Service Co. This field application was focussed on the quality control system in the site as production, placing and curing of concrete. As the result of this study, the quantity of CaO in the fly ash is relatively high based on the chemical analysis. The fly ash concrete showed slumping maintenance and high viscosity properties in the optimal mixing conditions (W/B:44~45%, S/a:$45\pm$2%, W:185kg/m). And, quality control and assurance of the fly ash concrete in actual site were verified by various testing methods.

Microstructure modeling of carbonation of metakaolin blended concrete

  • Wang, Xiao-Yong;Lee, Han-Seung
    • Advances in concrete construction
    • /
    • 제7권3호
    • /
    • pp.167-174
    • /
    • 2019
  • Metakaolin (MK), which is increasingly being used to produce high performance concrete, is produced by calcining purified kaolinite between 650 and $700^{\circ}C$ in a rotary kiln. The carbonation resistance of metakaolin blended concrete is lower than that of control concrete. Hence, it is critical to consider carbonation durability for rationally using metakaolin in the concrete industry. This study presents microstructure modeling during the carbonation of metakaolin blended concrete. First, based on a blended hydration mo del, the amount of carbonatable substances and porosity are determined. Second, based on the chemical reactions between carbon dioxide and carbonatable substances, the reduction of concrete porosity due to carbonation is calculated. Furthermore, $CO_2$ diffusivity is evaluated considering the concrete composition and exposed environment. The carbonation depth of concrete is analyzed using a diffusion-based model. The proposed microstructure model takes into account the influences of concrete composition, concrete curing, and exposure condition on carbonation. The proposed model is useful as a predetermination tool for the evaluation of the carbonation service life of metakaolin blended concrete.

Analyzing the Strength Development of Concrete with Function of Non-Sintered Hwangto Admixture Ratio at Early Ages (초기 재령에서 비소성 황토 혼입율에 따른 콘크리트의 강도 발현 분석)

  • Kim, Tae-Hyung;Kim, Won-Chang;Choi, Hyung-Gil;Choi, Hee-Yong;Lee, Tae-Gyu
    • Proceedings of the Korean Institute of Building Construction Conference
    • /
    • 한국건축시공학회 2023년도 봄 학술논문 발표대회
    • /
    • pp.39-40
    • /
    • 2023
  • In this study, the compressive strength development was analyzed at early ages of concrete specimens admixed with non-sintered hwangto to reduce the CO2 emissions generated during cement production. The W/B of the specimens was set at 0.41, the percentage of non-sintered hwangto admixture was set at three levels of 15, 30, and 45%, and the compressive strength were measured at 1, 3, 7, and 28 days. The results showed that the compressive strength decreases as the percentage of non-sintered hwangto increases, but the strength development rate increases, and the NHTC41-15 test specimen developed a compressive strength close to NC41 at 28 days.

  • PDF

A Study on the Fracture Behavior of Composite Laminated T-Joints Using AE (AE를 이용한 복합재료 T 조인트부의 파괴거동에 관한 연구)

  • Kim, J.H.;Ahn, B.W.;Sa, J.W.;Park, B.J.
    • Journal of the Korean Society for Nondestructive Testing
    • /
    • 제19권4호
    • /
    • pp.277-287
    • /
    • 1999
  • Quasi-static tests such as monotonic tension and loading/unloading tension were performed to investigate the bond characteristics and the failure processes for the T-joint specimens made from fiber/epoxy composite material. Two types of specimens, each consists of two components, e. g. skin and frame. were manufactured by co-curing and secondary bonding. During the monotonic tension test, AE instrument was used to predict AE signal at the initial and middle stage of the damage propagation. The damage initiation and progression were monitored optically using m (Charge Coupled Device) camera. And the internal crack front profile was examined using ultrasonic C-scan. The results indicate that the loads representing the abrupt increase of the AE signal are within the error range of 5 percent comparing to the loads shown in the load-time curve. Also it is shown that the initiation of crack occurred in the noodle region for both co-cured and secondarily bonded specimen. The final failure occurred in the noodle region for the co-cured specimen. but at the skin/frame termination point for the secondarily bonded specimen. Based on the results, it was found that two kinds of specimen show different failure modes depending on the manufacturing methods.

  • PDF

EFFECT OF LIGHT IRRADIATION MODES ON THE MARGINAL LEAKAGE OF COMPOSITE RESIN RESTORATION (광조사 방식이 복합레진 수복물의 변연누출에 미치는 영향)

  • 박은숙;김기옥;김성교
    • Restorative Dentistry and Endodontics
    • /
    • 제26권4호
    • /
    • pp.263-272
    • /
    • 2001
  • The aim of this study was to investigate the influence of four different light curing modes on the marginal leakage of Class V composite resin restoration. Eighty extracted human premolars were used. Wedge-shaped class Y cavities were prepared on the buccal surface of the tooth with high-speed diamond bur without bevel. The cavities were positioned half of the cavity above and half beyond the cemento-enamel junction. The depth, height, and width of the cavity were 2 mm, 3 mm and 2 mm respectively. The specimens were divided into 4 groups of 20 teeth each. All the specimen cavities were treated with Prime & Bond$^{R}$ NT dental adhesive system (Dentsply DeTrey GmbH, Germany) according to the manufacturer's instructions and cured for 10 seconds except group VI which were cured for 3 seconds. All the cavities were restored with resin composite Spectrum$^{TM}$ TPH A2 (Dentsply DeTrey GmbH, Germany) in a bulk. Resin composites were light-cured under 4 different modes. A regular intensity group (600 mW/${cm}^2$, group I) was irradiated for 30 s, a low intensity group (300 mW/${cm}^2$, group II) for 60 s and a ultra-high intensity group (1930 mW/${cm}^2$, group IV) for 3 s. A pulse-delay group (group III) was irradiated with 400 mW/${cm}^2$ for 2 s followed by 800 mW/${cm}^2$ for 10 s after 5 minutes delay. The Spectrum$^{TM}$ 800 (Dentsply DeTrey GmbH, Germany) light-curing units were used for groups I, II and III and Apollo 95E (DMD, U.S.A.) was used for group IV. The composite resin specimens were finished and polished immediately after light curing except group III which were finished and polished during delaying time. Specimens were stored in a physiologic saline solution at 37$^{\circ}C$ for 24 hours. After thermocycling (500$\times$, 5-55$^{\circ}C$), all teeth were covered with nail varnish up to 0.5 mm from the margins of the restorations, immersed in 37$^{\circ}C$, 2% methylene blue solution for 24 hours, and rinsed with tap water for 24 hours. After embedding in clear resin, the specimens were sectioned with a water-cooled diamond saw (Isomet$^{TM}$, Buehler Co., Lake Bluff, IL, U.S.A.) along the longitudinal axis of the tooth so as to pass the center of the restorations. The cut surfaces were examined under a stereomicroscope (SZ-PT Olympus, Japan) at ${\times}$25 magnification, and the images were captured with a CCD camera (GP-KR222, Panasonic, Japan) and stored in a computer with Studio Grabber program. Dye penetration depth at the restoration/dentin and the restoration/enamel interfaces was measured as a rate of the entire depth of the restoration using a software (Scion image, Scion Corp., U.S.A.) The data were analysed statistically using One-way ANOVA and Tukey's method. The results were as follows : 1. Pulse-Delay group did not show any significant difference in dye penetration rate from other groups at enamel and dentin margins (p>0.05) 2. At dentin margin, ultra-high intensity group showed significantly higher dye penetration rate than both regular intensity group and low intensity group (p<0.05). 3. At enamel margin, there were no statistically significant difference among four groups (p>0.05). 4. Dentin margin showed significantly higher dye penetration rate than enamel margin in all groups (p<0.05).

  • PDF

The Hydraulic Characteristics of Liquid Shotcrete Accelerators within Cement System (시멘트 계에서 액상 숏크리트용 급결제의 수화 특성에 관한 연구)

  • Shin Jin-Yong;Kim Jae-Young;Hong Ji-Sook;Suh Jeong-Kwon;Rho Jae-Seong
    • Journal of the Korea Concrete Institute
    • /
    • 제17권6호
    • /
    • pp.1011-1018
    • /
    • 2005
  • The influence of liquid shotcrete accelerators(alkali aluminate, two types of alkali-free) was investigated. Comparing to the existing alkali aluminate accelerator, new alkali-free accelerator, AF2, shortened initial and final setting of cement system, and after curing for 1 day compressive strength was analogous with others. On the other hand, compressive strength of specimen cured for 12 hour was the highest by the addition of alkali aluminate accelerator, but final strength was the lowest by that. But compressive strengths of AF1, AF2 were similar to Plain up to 28day. Further from XRD(X-Ray Diffractometer) and DSC(Differential Scanning Calorimeter) analyses, we confirmed that setting promoted by alkali aluminate was mainly because of Ca(OH)2(calcium hydroxide), but the accelerating behavior of alkali-free was influenced by the needle-like ettringite$(6CaO{\cdot}Al_2O_3{\cdot}3SO_3{\cdot}32H_2O)$ crystal.

Study on the Compositions of Photosensitive Resistor Paste Using Epoxy Acrylate Oligomers and Conductive Carbonblack (에폭시 아크릴레이트 올리고머와 전도성 카본블랙을 이용한 감광성 저항 페이스트 조성 연구)

  • Park, Seong-Dae;Kang, Nam-Kee;Lim, Jin-Kyu;Kim, Dong-Kook
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
    • /
    • 한국전기전자재료학회 2008년도 추계학술대회 논문집 Vol.21
    • /
    • pp.421-421
    • /
    • 2008
  • Generally, the polymer thick-film resistors for embedded organic or hybrid substrate are patterned by screen printing so that the accuracy of resistor pattern is not good and the tolerance of resistance is too high(${\pm}$20~30%). To reform these demerits, a method using Fodel$^{(R)}$ technology, which is the patterning method using a photosensitive resin to be developable by aqueous alkali-solution as a base polymer for thick-film pastes, was recently incorporated for the patterning of thermosetting thick-film resistor paste. Alkali-solution developable photosensitive resin system has a merit that the precise patterns can be obtained by UV exposure and aqueous development, so the essential point is to get the composition similar to PSR(photo solder resist) used for PCB process. In present research, we made the photopatternable resistor pastes using 8 kinds of epoxy acrylates and a conductive carbonblack (CDX-7055 Ultra), evaluated their developing performance, and then measured the resistance after final curing. To become developable by alkali-solution, epoxy acrylate oligomers with carboxyl group were prepared. Test coupons were fabricated by patterning copper foil on FR-4 CCL board, plating Ni/Au on the patterned copper electrode, applying the resistor paste on the board, exposing the applied paste to UV through Cr mask with resistor patterns, developing the exposed paste with aqueous alkali-solution (1wt% $Na_2CO_3$), drying the patterned paste at $80^{\circ}C$ oven, and then curing it at $200^{\circ}C$ during 1 hour. As a result, some test compositions couldn't be developed according to the kind of oligomer and, in the developed compositions, the measured resistance showed different results depending on the paste compositions though they had the same amount of carbonblack.

  • PDF

Preparation of the Inexpensive Fiberglass-Reinforced Activated Carbon Assemblies, and Development of Dry De-NOXSO System as Its Application (저렴한 유리강화 활성탄소섬유를 이용한 건식 동시 탈황 탈질 시스템의 개발)

  • Jeong, Ae-Young;Lee, Si-Hyun;Kim, Dong-Pyo
    • Proceedings of the KIEE Conference
    • /
    • 대한전기학회 1998년도 추계학술대회 논문집 학회본부 C
    • /
    • pp.1065-1068
    • /
    • 1998
  • On the study, The activated carbon assemblies(ACA) were prepared by activation of the coated glass mate(woven type) with phenolic resin at $700^{\circ}C$ under $N_2$ after drying and curing processes. Surface of the ACA was continuously modified with $N_2$, $CO_2$ or $NH_3$ at $700^{\circ}C$ for 2 hour for comparison of adsorptive characteristics between the ACA and commercial activated carbon cloth. The ACA showed high surface areas up to $2440\;m^2/g$ when converted into the coated carbon base, and the surface was investigated by FT-IR and XPS. The basic ACA modified with $NH_3$ displayed the efficient removal capability of $SO_2$, which is 75% of that in commercial activated carbon cloth. Therefore, it has proved the applicability of ACA as an inexpensive materials for Dry de-SOX system.

  • PDF

Preparation of the Inexpensive Fiberglass-Reinforced Activated Carbon Assemblies, and Development of Dry De-NOXSO System as Its Application (저렴한 유리강화 활성탄소섬유를 이용한 건식 동시 탈황 탈질 시스템의 개발)

  • Jeong, Ae-Young;Lee, Si-Hyun;Kim, Dong-Pyo
    • Proceedings of the KIEE Conference
    • /
    • 대한전기학회 1998년도 추계학술대회 논문집 학회본부 B
    • /
    • pp.717-720
    • /
    • 1998
  • On the study, The activated carbon assemblies(ACA) were prepared by activation of the coated glass mat(woven type) with phenolic resin at $700^{\circ}C$ under $N_2$ after drying and curing processes. Surface of the ACA was continuously modified with $N_2$, $CO_2$ or $NH_3$ at $700^{\circ}C$ for 2 hour for comparison of adsorptive characteristics between the ACA and commercial activated carbon cloth. The ACA showed high surface areas up to $2440\;m^2/g$ when converted into the coated carbon base, and the surface was investigated by FT-IR and XPS. The basic ACA modified with $NH_3$ displayed the efficient removal capability of $SO_2$, which is 75% of that in commercial activated carbon cloth. Therefore, it has proved the applicability of ACA as an inexpensive materials for Dry de-SOX system.

  • PDF

Preparation of the Inexpensive Fiberglass-Reinforced Activated Carbon Assemblies, and Development of Dry De-NOXSO System as Its Application (저렴한 유리강화 활성탄소섬유를 이용한 건식 동시 탈황 탈질 시스템의 개발)

  • Jeong, Ae-Young;Lee, Si-Hyun;Kim, Dong-Pyo
    • Proceedings of the KIEE Conference
    • /
    • 대한전기학회 1998년도 추계학술대회 논문집 학회본부A
    • /
    • pp.397-400
    • /
    • 1998
  • On the study, The activated carbon assemblies(ACA) were prepared by activation of the coated glass mat(woven type) with phenolic resin at $700^{\circ}C$ under $N_2$ after drying and curing processes. Surface of the ACA was continuously modified with $N_2$, $CO_2$ or $NH_3$ at $700^{\circ}C$ for 2 hour for comparison of adsorptive characteristics between the ACA and commercial activated carbon cloth. The ACA showed high surface areas up to $2440\;m^2$/g when converted into the coated carbon base, and the surface was investigated by FT-IR and XPS. The basic ACA modified with $NH_3$ displayed the efficient removal capability of $SO_2$, which is 75% of that in commercial activated carbon cloth. Therefore, it has proved the applicability of ACA as an inexpensive materials for Dry de-SOX system.

  • PDF