• Title/Summary/Keyword: $CO_2$ analysis method

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Development of Carbon-based Adsorbent for Acetylene Separation Using Response Surface Method (반응 표면 분석법을 활용한 Acetylene 분리용 탄소기반 흡착제 개발)

  • Choi, Minjung;Yoo, Kye Sang
    • Applied Chemistry for Engineering
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    • v.30 no.1
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    • pp.29-33
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    • 2019
  • Carbon nanotubes, nanofibers and powders were used for acetylene adsorption experiments. A total of 15 different experiments were designed by 3-level of Box-Behnken Design (BBD) with 3 factors including the Pd concentration of 0 to 5%, adsorption temperature of 30 to $80^{\circ}C$ and $C_2H_2/CO_2$ of 3 to 10. Based on those data, a second order polynomial regression analysis was used to derive the adsorption amount prediction equation according to operating conditions. The adsorption temperature showed the greatest influence index while the $C_2H_2/CO_2$ ratio showed the smallest according to the F-value measurement of the ANOVA analysis. However, there was little interaction between major factors. In the adsorption optimization analysis, a 22.0 mmol/g was adsorbed under the conditions of Pd concentration of 3.0%, adsorption temperature of $47^{\circ}C$ and $C_2H_2/CO_2$ of 10 with 95.9% accuracy.

A Study on Simultaneous Analysis of Velocity and Density Distributions for High-Speed $CO_{2}$ Flow (고속 이산화탄소 유동장의 속도 및 밀도 동시 분석에 관한 연구)

  • Kim Yong-Jae;Ko Han Seo;Okamoto Koji
    • 한국가시화정보학회:학술대회논문집
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    • 2005.12a
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    • pp.40-45
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    • 2005
  • Velocity and density distributions of a high-speed and initial $CO_{2}$ jet flow have been analyzed simultaneously by a developed three-dimensional digital speckle tomography and a particle image velocimetry(PIV). Three high-speed cameras have been used for tomography and PIV since a shape of a nozzle for the jet flow is asymmetric and the initial flow is fast and unsteady, The speckle movements between no flow and $CO_{2}$ jet flow have been obtained by a cross-correlation tracking method so that those distances can be transferred to deflection angles of laser rays for density gradients. The three-dimensional density fields for the high-speed $CO_{2}$ jet flow have been reconstructed from the deflection angles by a real-time tomography method and the two-dimensional velocity fields have been calculated by a PIV method simultaneously and instantaneously.

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Effects of vessel-pipe coupled dynamics on the discharged CO2 behavior for CO2 sequestration

  • Bakti, Farid P.;Kim, Moo-Hyun
    • Ocean Systems Engineering
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    • v.10 no.3
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    • pp.317-332
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    • 2020
  • This study examines the behaviors and properties of discharged liquid CO2 from a long elastic pipe moving with a vessel for the oceanic CO2 sequestration by considering pipe dynamics and vessel motions. The coupled vessel-pipe dynamic analysis for a typical configuration is done in the frequency and time domain using the ORCAFLEX program. The system's characteristics, such as vessel RAOs and pipe-axial-velocity transfer function, are identified by applying a broadband white noise wave spectrum to the vessel-pipe dynamic system. The frequency shift of the vessel's RAO due to the encounter-frequency effect is also investigated through the system identification method. Additionally, the time histories of the tip-of-pipe velocities, along with the corresponding discharged droplet size and Weber numbers, are generated for two different sea states. The comparison between the stiff non-oscillating pipe with the flexible oscillating pipe shows the effect of the vessel and pipe dynamics to the discharged CO2 droplet size and Weber number. The pipe's axial-mode resonance is the leading cause of the fluctuation of the discharged CO2 properties. The significant variation of the discharged CO2 properties observed in this study shows the importance of considering the vessel-pipe motions when designing oceanic CO2 sequestration strategy, including suitable sequestration locations, discharge rate, towing speed, and sea states.

An Exploratory Study on the Study Trend of Domestic Entrepreneurship Using Co-word Analysis Method (국내 기업가정신의 연구동향에 관한 탐색적 연구: 동시단어분석 방법을 중심으로)

  • Kim, Young-Su;Ko, Jong-Nam;Do, Man-Seung
    • Journal of the Korean Society for information Management
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    • v.28 no.3
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    • pp.295-312
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    • 2011
  • This study conducted time-series analysis on domestic studies related to entrepreneurship for more than last 50 years by integrating the co-word analysis method of intellectual structure analysis into the study of entrepreneurship. The co-word analysis method is a quantitative analysis method to analyze the overall trend of the study and further study topics by visualizing the information between study topics and arranging the topics on two-dimensional plane and the study result showed largely four phases and the direction of the study path. According to the analysis, the study is started at embryonic study phase(third quadrant), the study topic of independent study phase(second quadrant) is a phase to be a settled independent area as a study and the topics of the study include topics of the study reflecting the situation of the times. At growing study phase(first quadrant) study topics which are closely related to the study topic are arranged, and the topics, the center of the study, are positioned at the study topics of maturity phase(4th quadrant).

Zeolitification Characteristics of Coal Fly Ash by Amount of Na2CO3 Using the Fusion/Hydrothermal Method (용융/수열합성법으로부터 Na2CO3 첨가량에 따른 석탄비산재의 제올라이트화 특성)

  • Lee, Chang-Han
    • Journal of Environmental Science International
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    • v.28 no.6
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    • pp.553-559
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    • 2019
  • In this study, zeolitic materials at $Na_2CO_3/CFA$ ratio of 0.6 - 1.8 were synthesized from coal fly ash from a thermal power plant using a fusion/hydrothermal method. The zeolitic materials were found to have cubic crystals structure and X-ray diffraction (XRD) peaks of Na-A zeolite by XRD and SEM analysis. When the zeolitic materials were synthesized from the coal fly ash, the XRD peaks of the zeolitic materials at $Na_2CO_3/CFA$ ratios of 0.9-1.8 had the same location as the XRD peaks of commercial Na-A zeolite. The XRD peaks of the Na-A zeolite ($Na_{12}Al_{12}Si_{12}O_{48}27.4H_2O$) were confirmed in the $2{\theta}$ in the range of 7.18-34.18. However, it was also confirmed that peaks of $CaCO_3$, an impurity inhibiting synthesis of Na-A zeolite from CaO and $Na_2CO_3$ in the coal fly ash, occurred in the XRD peaks of the zeolitic materials at $Na_2CO_3/CFA$ ratio of 1.5-1.8. The crystallinities of the zeolitic materials tended to increase gradually within the $Na_2CO_3/CFA$ ratio range of 0.6-1.8.

Reduction Effect of CO2 Emission on BIS Using Tier 3 Methodology - A Case Study on Daejun-Chungjoo Project - (Tier 3 방법론을 활용한 BIS 사업의 CO2 저감효과 분석 - 대전-청주 간 광역BIS 사업을 중심으로 -)

  • Chung, Younshik;Song, Taijin;Kim, Jeongwan
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.31 no.3D
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    • pp.375-381
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    • 2011
  • This study presents an analysis of $CO_2$ emission reduction effect on bus information system (BIS) which is operated to improve various services of bus transit such as rapid and on-time service. Although the Intergovernmental Panel on Climate Change (IPCC) released three methodological types of models for analyzing the amount of greenhouse gas reduction, this study used the Tier 3 method that is the most concrete one. A case study was performed to a 8.3 km section of Daejun-Chungjoo BIS system, and dataset required to the Tier 3 method was obtained from ITS-based surveillance systems. The study result showed that the reduction effect of $CO_2$ on BIS operation was yearly $39.45tCO_2/km$. Therefore, such effect can be potentially useful to a measurement of effectiveness (MOE) of BIS projects hereafter.

Method of Crosstalk Analysis for CO-ORMDM Systems

  • Kyung Hee Seo;Jae Seung Lee
    • Current Optics and Photonics
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    • v.8 no.2
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    • pp.156-161
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    • 2024
  • Recently, a new kind of optical multiplexing called optical-receiver-mode (ORM)-division multiplexing (ORMDM) has been proposed, in which an optical channel is a linear sum of ORM subchannels modulated independently. Using coherent-optical (CO) techniques, it has been reported that COORMDM communication systems can have very high spectral efficiencies (SEs). To estimate the SEs of CO-ORMDM communication systems, we introduce a new method of crosstalk analysis. Using this method, we can allocate quadrature-amplitude-modulation (QAM) codes and QAM step sizes unevenly over ORM subchannels to obtain higher SEs. With 50 Gaussian ORMs, we obtain a SE of up to 15.29 bit s-1 Hz-1.

Optimization Analysis for Embodied Energy and CO2 Emission in Reinforced Concrete Column Using Sustainable Design Method (지속가능 설계법을 이용한 철근 콘크리트 기둥의 내재에너지 및 이산화탄소 배출 최적화 해석)

  • Kim, Kyeong-Hwan;Yeo, DongHun;Lee, Sang-Ho;Yoon, Young-Cheol
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.30 no.3
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    • pp.265-274
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    • 2017
  • This study presents a sustainable design method to optimize the embodied energy and $CO_2$ emission complying with the design code for reinforced concrete column. The sustainable design method effectively achieves the minimization of the environmental load and energy consumption whereas the conventional design method has been mostly focused on the cost saving. Failure of reinforced concrete column exhibits compressive or tensile failure mode against an external force such as flexure and compression; thus, optimization analyses are conducted for both failure modes. For the given sections and reinforcement ratios, the optimized sections are determined by optimizing cost, embodied energy, and $CO_2$ emission and various aspects of the sections are thoroughly investigated. The optimization analysis results show that 25% embodied energy and 55% $CO_2$ emission can be approximately reduced by 10% increase in cost. In particular, the embodied energy and $CO_2$ emission were more effectively reduced in the tensile failure mode rather than in the compressive failure mode. Consequently, it was proved that the sustainable design method effectively implements the concept of sustainable development in the design of reinforced concrete structure by optimizing embodied energy consumption and $CO_2$ emission.

A Study on The Evaluation Criteria of Carbon Emission and the Development of the Evaluation Method in Apartment House (공동주택을 대상으로 한 탄소배출 평가기준 구축 및 평가방법 개발)

  • Choi, Doo-Sung;Chun, Hung-Chan
    • KIEAE Journal
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    • v.13 no.5
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    • pp.79-88
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    • 2013
  • This study creates the evaluation criteria to analyze the $CO_2$ emission quantity in the complex of apartment house among domestic buildings and proposes how to calculate the $CO_2$ emission quantity by the only simple information of apartment house. The study shows that in order to create the index of carbon emission evaluation criteria, $CO_2$ emission quantity for its input materials in these 27 apartment houses are 445,412g-$CO_2/m^2$ for apartment building, 474,322g-$CO_2/m^2$ for the basement parking lot, 483,523g-$CO_2/m^2$ for welfare facility, 729,957g-$CO_2/m^2$ for sales facility, 743,560g-$CO_2/m^2$ for other facility, 26,782g-$CO_2/m^2$ for public facility, 43,659g-$CO_2/m^2$ for landscape, 1,113g-$CO_2/m^2$ for indoor facility, 11,251g-$CO_2/m^2$ for outdoor facility and 891g-$CO_2/m^2$ for common temporary based on the average $CO_2$ emission by facility. We can also see the analysis data that in case of using the selected factors only, the rate of error is 7.51% comparing with the emission quantity by using simplified LCA method this study suggests for the whole range of apartment houses and the rate of error is average 3.24% using selective and main materials. And this it is evaluated that we can get the result which is similar to the actual $CO_2$ emission quantity with only the simple information about the apartment house.

COMBUSTION TOXICITY ANALYSIS: ADVANCES USING A SPECIALIZED SAMPLING TECHNIQUE FOR FOURIER TRANSFORM INFRARED (FTIR) ANALYSIS

  • Talandis, Jonas;Innes, J.D.;Cox, A.W.
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 1997.11a
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    • pp.178-184
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    • 1997
  • The cone calorimeter as defined by ISO 5660, ASTM 1354, and NFPA 264A is used to assess the reaction to fire of almost any material that must be evaluated in the fire science field. Typical combustion gas analyses include oxygen, CO and CO2. Oxygen consumption is used to determine rate of heat release. Analysis of combustion gases other than oxygen, CO and CO2 has been attempted using filters to remove the solid smoke particles before analysis. This method has generated unreliable results due to the adsorption of many gas components on the active carbon . particles deposited on the filters. A technique using fourier Transform Infrared (FTIB) analysis without filtration will be disclosed and a discussion will be presented of the analytical results of toxic gases produced from various flame retarded polymeric materials. Use of such data in lethal toxic potency determinations is also reviewed.

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