• Journal of Powder Materials
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• v.24 no.1
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• pp.34-40
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• 2017

This study is carried out to obtain basic data regarding oxidation and reduction reactions, originated on the recycling of waste tungsten hard scraps by oxidation and reduction processes. First, it is estimated that the theoretical Gibbs free energy for the formation reaction of $WO_2$ and $WO_3$ are calculated as ${\Delta}G_{1,000K}=-407.335kJ/mol$ and ${\Delta}G_{1,000K}=-585.679kJ/mol$, from the thermodynamics data reported by Ihsan Barin. In the experiments, the oxidation of pure tungsten rod by oxygen is carried out over a temperature range of $700-1,000^{\circ}C$ for 1 h, and it is possible to conclude that the oxidation reaction can be represented by a relatively linear relationship. Second, the reduction of $WO_2$ and $WO_3$ powder by hydrogen is also calculated from the same thermodynamics data, and it can be found that it was difficult for the reduction reaction to occur at $1,027^{\circ}C$, in the case of $WO_2$, but it can happen for temperatures higher than $1127^{\circ}C$. On the other hand, $WO_3$ reduction reaction occurs at the relatively low temperature of $827^{\circ}C$. Based on these results, the reduction experiments are carried out at a temperature range of $500-1,000^{\circ}C$ for 15 min to 4 h, in the case of $WO_3$ powder, and it is possible to conclude that the reduction at $900^{\circ}C$ for 2h is needed for a perfect reduction reaction.

• Journal of the Korean Ceramic Society
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• v.55 no.1
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• pp.50-54
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• 2018

This study investigated the long-term durability of catalyst(Pd or Fe)-infiltrated solid oxide cells for $CO_2$/steam co-electrolysis. Fuel-electrode supported solid oxide cells with dimensions of $5{\times}5cm^2$ were fabricated, and palladium or iron was subsequently introduced via wet infiltration (as a form of PdO or FeO solution). The metallic catalysts were employed in the fuel-electrode to promote $CO_2$ reduction via reverse water gas shift reactions. The metal-precursor particles were well-dispersed on the fuel-electrode substrate, which formed a bimetallic alloy with Ni embedded on the substrate during high-temperature reduction processes. These planar cells were tested using a mixture of $H_2O$ and $CO_2$ to measure the electrochemical and gas-production stabilities during 350 h of co-electrolysis operations. The results confirmed that compared to the Fe-infiltrated cell, the Pd-infiltrated cell had higher stabilities for both electrochemical reactions and gas-production given its resistance to carbon deposition.

• Transactions of the Korean Society of Automotive Engineers
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• v.10 no.5
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• pp.228-234
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• 2002

The CO$_2$ laser beam irradiation strengthening of 35kgf/mm$_2$ grade steel sheet is investigated to reduce the weight of bumper beam. The increase of tensile strength is dominated by the number of fully penetrated melting lines. The optimal laser irradiation pattern is obtained by 3-point bending test of hat-type specimens. Laser should be irradiated not only on the center specimen densely in the width direction, but also on the edge densely in the longitudinal direction. Local laser strengthening may be effective for the weight reduction of automobile bumper beam.

• 한국태양에너지학회:학술대회논문집
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• 2009.04a
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• pp.91-96
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• 2009

First, the base model of multi-family residential buildings are selected, and then the $CO_2$ reduction building technologies that are applicable for multi-family residential buildings are induced by analyzing the examples and then an optimal plan for when the $CO_2$ reduction building technologies can be integrated and applied to the base model was formulated. In the results of converting the energy consumption and reduction amount from the building technologies into $CO_2$ emissions to analyze the distribution ratio compared to the entire $CO_2$ emissions; the heat recovery ventilator is 0.5%, the photovoltaic system is $1.9%{\sim}5.9%$, the solar hot water heating system is $6.3%{\sim}13.1%$ and the ge thermal heat-pump system is 39.0% when both heating and hot water heating are applied. An optimally integrated application method for the building technologies is in charge of heating and hot water heating through the geothermal source heat pump system and in charge of the electricity load through the photovoltaic system(45.2%).

• Journal of the Korean Solar Energy Society
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• v.30 no.3
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• pp.16-24
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• 2010

Recently environmental regulations like the Kyoto Protocol, adopted in 1997, required the 5.2% reduction of the greenhouse gas emission in 1990. And 13th General Assembly in 2007, held in Bali of India, have agreed to duty reduction even in developing countries in 2013. Korean government needs the researches on climate change and the strategic programs for greenhouse gas reduction. In this paper Colorado State University Mesoscale Model(CSU-MM) was applied to simulate the relationship between surface albedo and air temperature. Meteorological model simulation in region of Ansan-City, Shiheung-City showed that mean air temperature became lower with the increase of albedo value. Simulated air temperature became lower $-0.16^{\circ}C$ and $-0.66^{\circ}C$ by 5% and 20% increase of albedo values respectively. And cooling energy saving amount in air conditioning process was calculated according to lowered air temperature. The reduction of air temperature resulted the reduction of air conditioning energy in personal house and commercial buildings. The increase of albedo from 5% to 20% resulted the reduction of air conditioning energy from 44,493 MWh/yr to 183,796 MWh/yr. Additionally the reduction of greenhouse gas emission through the energy saving was calculated after IPCC guideline. In terms of greenhouse gas emission $CO_2$ was reduced form -30,414 ton-$CO_2$/yr to -125,638 ton-$CO_2$/yr according to the reduction of electric energy.

• Journal of Welding and Joining
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• v.16 no.3
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• pp.18-28
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• 1998

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.23 no.9
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• pp.823-830
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• 2013

The purpose of this study is to develop a noise reduction device installed at the top of noise barrier for further decreasing of noise level of 400 km/h class high-speed railroad. For this, the frequency spectrum of 400 km/h class high-speed railroad was analyzed through the field noise test, and the tuning frequency was determined to design a noise reduction device. The noise reduction device was designed to have noise reduction performance of at least 3 dB(A) using the prediction method(2D BEM) and through the laboratory test with the prototype. Finally, the outdoor test showed that this device could decrease noise level of 400 km/h class high-speed railroad even more than 3 dB(A).

• Journal of Hydrogen and New Energy
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• v.32 no.1
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• pp.53-62
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• 2021

Batch type reduction-oxidation tests were performed to check effects of temperature, pressure, gas velocity, and capacity on reduction characteristics of mass produced particle in a 0.5 MWth chemical looping combustion system. The fuel conversion and the CO2 selectivity increased as the temperature increased and as the gas velocity decreased. However the CO2 selectivity showed the maximum and decreased as the capacity increased because the CO emission increased. The results show that high temperature, low gas velocity and low inert gas concentration are preferable to ensure high reactivity of oxygen carrier in the fuel reactor.

• Journal of the Korean Chemical Society
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• v.7 no.1
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• pp.34-37
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• 1963

Cobalt(Ⅲ) ion gives two step waves with $E_{1/2}$－0.1V(?)(vs.S.C.E.) and $E_{1/2}$－1.37V(vs. S.C.E.) from a base electrolyte consisting of 0.1 M TEA＋sodium borate＋0.0002% gelatin. The first wave results from the reduction Co(Ⅲ) to Co(Ⅱ). The second wave corresponding to the reduction Co(Ⅱ) to Co(0) and this wave is diffusion controlled. The diffusion current constant of the second wave is 2.7. Under these-conditions, diffusion current of the second wave is proportional to the concentration of Co (Ⅱ) in the range of $10^{-3}{\sim}10^{-4}$ M.

• Bulletin of the Korean Chemical Society
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• v.20 no.11
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• pp.1303-1308
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• 1999

Conducting poly(3,4-ethylenedioxythiophene) (PEDT) films with metalloporphyrins incorporated as the counter ions were prepared by electropolymerization of the monomer in the presence of metal-tetra(sulfonatophenyl) porphyrin anions. Cathodic reduction of oxygen on the resulting conducting polymer films was studied. The overpotential for O2 reduction on electrodes with cobalt-porphyrin complex was significantly smaller in acidic solutions than on gold. In basic solutions, the overpotential at low current densities was close to those on platinum and gold. Polymer electrode with Co-complex yielded higher limiting currents than with Fe-complex, although the Co-complex polymer electrode was a poorer electrocatalyst for O2 reduction in the activation range of potential than the Fe counterpart. From the rotating ring-disk electrode experiments, oxygen reduction was shown to proceed through either a 4-electron pathway or a 2-electron pathway. In contrast to the polypyr-role-based electrodes, the PEDT-based metalloporphyrin electrodes were stable with wider potential windows, including the oxygen reduction potential. Their electrocatalytic properties were maintained at temperatures up to 80℃ in KOH solutions.