• Title/Summary/Keyword: $CO_2$ Recovery

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Study on the Multi-stage Hollow Fiber Membrane Modules for SF6 Gas Separation (불화가스 분리를 위한 중공사막 모듈의 다단 기체분리공정 연구)

  • Jeong, Su Jung;Lim, Joo Hwan;Koh, Hyung Chul;Ha, Seong Yong
    • Membrane Journal
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    • v.26 no.2
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    • pp.159-165
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    • 2016
  • Polyimide hollow fiber membrane modules were prepared in order to investigate the process of multi stage gas separation. The modules performance was carried out using 50/50 of $N_2/SF_6$ mixed gas. The membrane modules has been tested for measuring gas flow rate and concentration under various stage cut at 0.5 MPa. The membrane modules showed a high recovery ratio at the same stage cut as $N_2/SF_6$ selectivity increased. Two stage process was fulfilled for improving $SF_6$ recovery ratio and $SF_6$ concentration. Eventually, two stage process showed higher performance of $SF_6$ recovery ratio and concentration ($SF_6$ recovery ratio = 95%, $SF_6$ conc. = 98%).

CD40 Co-stimulation Inhibits Sustained BCR-induced $Ca^{2+}$ Signaling in Response to Long-term Antigenic Stimulation of Immature B Cells

  • Nguyen, Yen Hoang;Lee, Ki-Young;Kim, Tae-Jin;Kim, Sung-Joon;Kang, Tong-Mook
    • The Korean Journal of Physiology and Pharmacology
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    • v.15 no.3
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    • pp.179-187
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    • 2011
  • Regulation of B cell receptor (BCR)-induced $Ca^{2+}$ signaling by CD40 co-stimulation was compared in long-term BCR-stimulated immature (WEHI-231) and mature (Bal-17) B cells. In response to long-term pre-stimulation of immature WEHI-231 cells to ${\alpha}$-IgM antibody (0.5~48 hr), the initial transient decrease in BCR-induced $[Ca^{2+}]_i$ was followed by spontaneous recovery to control level within 24 hr. The recovery of $Ca^{2+}$ signaling in WEHI-231 cells was not due to restoration of internalized receptor but instead to an increase in the levels of $PLC{\gamma}2$ and $IP_3R-3$. CD40 co-stimulation of WEHI-231 cells prevented BCR-induced cell cycle arrest and apoptosis, and it strongly inhibited the recovery of BCR-induced $Ca^{2+}$ signaling. CD40 co-stimulation also enhanced BCR internalization and reduced expression of $PLC{\gamma}2$ and $IP_3R-3$. Pre-treatment of WEHI-231 cells with the antioxidant N-acetyl-L-cysteine (NAC) strongly inhibited CD40-mediated prevention of the recovery of $Ca^{2+}$ signaling. In contrast to immature WEHI-231 cells, identical long-term ${\alpha}$-IgM pre-stimulation of mature Bal-17 cells abolished the increase in BCR-induced $[Ca^{2+}]_i$, regardless of CD40 co-stimulation. These results suggest that CD40-mediated signaling prevents antigen-induced cell cycle arrest and apoptosis of immature B cells through inhibition of sustained BCR-induced $Ca^{2+}$ signaling.

An Experimental Study on Performance Improvement for Exhaust Heat Recovery Ventilation System in a Lightweight Wall (벽체매립형 폐열회수 환기시스템의 열회수 성능 향상에 관한 실험적 연구)

  • Chung, Min-Ho;Oh, Byung-Kil
    • Korean Journal of Air-Conditioning and Refrigeration Engineering
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    • v.26 no.2
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    • pp.61-66
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    • 2014
  • Exhaust heat recovery ventilation systems conserve energy through enthalpy recovery between air intake and exhaust, and they are being increasingly used. An exhaust heat recovery ventilation system can be installed in the ceiling of a balcony or emergency evacuation space. However, in the case of fire, the emergency evacuation space has to by law remain as empty space, and therefore, a ventilation system can't be installed in an emergency evacuation space. Therefore, the need for a proper installation space for a ventilation system is emphasized. In this study, to install a heat recovery ventilation system in a lightweight wall, a heat exchanger was assembled of thickness below 140 mm. The efficiency of heat recovery was analyzed through performance experiment, in the case of the cooling and heating mode. The heat recovery efficiency increases when the surface area is increased, by using closer channel spacing in the heat exchanger, or by increasing the size of the heat exchanger.

Recovery According to Follow-up Period and Compliance in Osteoarthritic Patients after Knee Replacement Arthroplasty (인공 슬관절 치환술 후 치료순응도와 경과기간에 따른 회복 양상)

  • Park, Su-A;Kang, Hyun-Sook;Choi, Jin-Yi
    • Journal of East-West Nursing Research
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    • v.16 no.2
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    • pp.164-171
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    • 2010
  • Purpose: The aim of study was to investigate relationship between compliance and recovery of patients with osteoarthritis of the knee patients after knee arthroplasty. Methods: 193 patients living in Seoul were participated in this study. Data were collected using the Knee Society Clinical Rating System and Medical Outcomes Study Short Form 36(SF-36) and analyzed by ANCOVA, t-test, and repeated measure ANOVA. Results: There was a significant difference of physiological recovery based on the number of co-morbidity patients have. Physical recovery level was different according to age, religion, and the number of co-morbidity. Age and education level of patients were different in emotional recovery. The level of physiological and physical recovery were significantly different consistent with compliance. Compared to preoperative scores, physiological and physical scores showed significant improvement at six weeks, three months, and six months after surgery while emotional scores did not showed significant improvement. Conclusion: The results of this study suggest that nursing interventions to increase compliance are needed for better recovery of patients after knee arthroplasty.

Capture and Reduction Technology of Greenhouse Gas Using Membrane from Anaerobic Digester Gas (분리막을 이용한 혐기성 소화가스로부터 온실가스 회수저감 기술)

  • Hwang, Cheol-Won;Jeong, Chang-Hun
    • Journal of Environmental Science International
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    • v.20 no.10
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    • pp.1233-1241
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    • 2011
  • The main objective of this experimental investigation was $CH_4$ recovery from biogas generated in municipal and wastewater treatment plant. The polysulfone hollow fiber membrane was prepared in order to investigate the permeation properties of $CH_4$ and $CO_2$. Permeability of $CO_2$ in Polysulfone membrane was 11-fold higher than of $CH_4$ gas. A membrane pilot plant for upgrading biogas was constructed and operated at a municipal wastewater treatment plant. The raw biogas contained 66 ~ 68 Vol % $CH_4$, the balance being mainly $CO_2$. The effect of the operating pressure of feed and permeate side and feed flowrate on $CH_4$ recovery concentration and efficiency were investigated with double stage membrane pilot plant. The $CH_4$ concentration in the retentate stream was raised in these tests to 93 Vol % $CH_4$.

The Impact of Side Reactions in Sulfur Recovery Unit Design (황 회수 공정 설계에서 부 반응의 영향)

  • Kim, Sung Ho;Jung, Won Seok;Lee, Hee Mun;Chang, Geun Soo
    • Plant Journal
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    • v.13 no.3
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    • pp.36-46
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    • 2017
  • In the reaction furnace of modified Claus process, chemical equilibrium reactions and kinetic reactions occur simultaneously. The main kinetic components are hydrogen ($H_2$), carbon monoxide (CO), carbonyl sulphide (COS) and carbon disulphide ($CS_2$). The equilibrium calculations, empirical correlations and sulfur recovery technology providers' (licensors) data for kinetic components (COS and $CS_2$) in the reaction furnace were analyzed to evaluate the amount of kinetic components by applying them to five different projects in which GS Engineering & Construction participated. Kinetic components ($H_2$ and CO) are also calculated and the results are analyzed to evaluate the impact of temperature in the reaction furnace and the waste heat boiler. Total required $O_2$ deviations for combustion in the reaction furnace are additionally shown, with and without side reactions. A full understanding of side reactions in the modified Claus process can help to improve sulfur recovery efficiency and optimize equipment design.

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Enhanced Oil Recovery (EOR) Technology Coupled with Underground Carbon Dioxide Sequestration (CO2 지하저장과 연계한 원유회수증진 기술)

  • Kim, Hyung-Mok;Bae, Wi-Sup
    • Tunnel and Underground Space
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    • v.23 no.1
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    • pp.1-12
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    • 2013
  • Enhanced oil recovery (EOR) technology coupled with underground carbon dioxide sequestration is introduced. $CO_2$ can be injected into an oil reservoir in order to enhance oil production rate and $CO_2$ EOR can be turned into CCS in a long term sense. Coupling $CO_2$ EOR with CCS may secure a large scale and consistent $CO_2$ source for EOR, and the $CO_2$ EOR can bring an additional economic benefit for CCS, since the benefit from enhanced oil production by $CO_2$ EOR will compensate costs for CCS implementation. In this paper, we introduced the characteristics of $CO_2$ EOR technology and its market prospect, and reviewed the Weyburn $CO_2$ EOR project which is the first large-scale $CO_2$ EOR case utilizing an anthropogenic $CO_2$ source. We also introduced geotechnical elements for a successful and economical implementation of $CO_2$ EOR with CCS and they were a miscroseismic monitoring during and after injection of $CO_2$, and determination of minimum miscible pressure (MMP) and maximum injection pressure (MIP) of $CO_2$.

A Study on the Cobalt and Lithium Recovery from the Production Scraps of Lithium Secondary Battery by High Efficient and Eco-friendly Method (이차전지(二次電池) 제조공정(製造工程)스크랩으로부터 고효율(高效率) 親環境(친환경) 코발트(Co)와 리튬(Li)의 회수(回收)에 관(關)한 연구(硏究))

  • Lee, Jeong-Joo;Chung, Jin-Do
    • Resources Recycling
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    • v.19 no.6
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    • pp.51-60
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    • 2010
  • A study on the recovery of cobalt and lithium from Lithium Ion Battery(LIB) scraps has been carried out by a physical treatment - leaching - solvent extraction process. The cathode scraps of LIB in production were used as a material of this experiment. The best condition for recovering cobalt from the anode scraps was acquired in each process. The cathode scraps are dissolved in 2M sulfuric acid solution with hydrogen peroxide at $95^{\circ}C$, 700 rpm. The cobalt is concentrated from the leaching solution by means of a solvent extraction circuit with bis(2-ethylhexyl) phosphoric acid(D2EHPA) and PC88A in kerosene, and then cobalt and lithium are recovered as cobalt hydroxide and lithium carbonate by precipitation technology. The purity of cobalt oxide powder was over 99.98% and the average particle size after milling was about 10 lim. The over all recoveries are over 95% for cobalt and lithium. The pilot test of mechanical separation was carried out for the recovery of cobalt from the scraps. The $Co_3O_4$ powder was made by the heat treatment of $Co(OH)_2$ and the average particle size was about 10 ${\mu}m$ after grinding. The recovery was over 99% for cobalt and lithium each other and the purity of cobalt oxide was over 99.98%.

Lithium Recovery from NCM Lithium Ion Battery by Hydrogen Reduction Followed by Water Leaching (NCM계 리튬이온 배터리 양극재의 수소환원과 수침출에 의한 리튬 회수)

  • So-Yeong Lee;So-Yeon Lee;Dae-Hyeon Lee;Ho-Sang Sohn
    • Resources Recycling
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    • v.33 no.1
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    • pp.15-21
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    • 2024
  • The demand for electric vehicles powered by lithium-ion batteries is continuously increasing. Recovery of valuable metals from waste lithium-ion batteries will be necessary in the future. This research investigated the effect of reaction temperature on the lithium recovery ratio from hydrogen reduction followed by water leaching from lithium-ion battery NCM-based cathode materials. As the reaction temperature increased, the weight loss ratio observed after initiation increased rapidly owing to hydrogen reduction of NiO and CoO; at the same time, the H2O amount generated increased. Above 602 ℃, the anode materials Ni and Co were reduced and existed in the metallic phases. As the hydrogen reduction temperature was increased, the Li recovery ratio also increased; at 704 ℃ and above, the Li recovery ratio reached a maximum of approximately 92%. Therefore, it is expected that Li can be selectively recovered by hydrogen reduction as a waste lithium-ion battery pretreatment, and the residue can be reprocessed to efficiently separate and recover valuable metals.

Difference of Neuronal Recovery by Incubation Condition after Transient Hypoxia (배양조건에 의한 일과성 저산소상태 후 신경세포회복의 차이)

  • Moon, Soo-Hyeon;Oh, Jae-Inn;Park, Youn-Kwan;Chung, Heung-Sub;Lee, Hoon-Kap;Lee, Ki-Chan
    • Journal of Korean Neurosurgical Society
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    • v.29 no.9
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    • pp.1161-1170
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    • 2000
  • Objective : The transverse hippocampal slice is one of the most commonly studied in vitro models of mammalian brain physiology. However, despite its broad usage, there has been no standardization of slice preparation techniques or recording condition. It is well known that variations in recording conditions can result in profound different effects to neuronal responses. Evoked field potentials, recorded extracellularly, were used to investigate the effects of variations in hippocampal slice preparation protocol on hypoxia responses of CA1 neurones. Material & Methods : Before hypoxic injury, hippocampal slices were incubated for 4 hours. During incubation period, the slices were placed in a incubation chamber($21^{\circ}C$) for recovery from preparation injury and then transferred to recording chamber($34^{\circ}C$) for more recovery and baseline electric recording with current stimulation(0.1Hz). Various time periods in incubation chamber and recording chamber were applied to each experimental group(group 1=60min : 180min, group 2=90min : 150min, group 3=180min : 60min, time in incubation chamber : time in recording chamber) before 10 min hypoxia produced by replacing 95% $O_2$+5% $CO_2$ mixed gas to 95% $N_2$+5% $CO_2$ gas. Calcium, Magnesium ions and several drugs effecting on glutamate receptor also were studied. Recoveries from hypoxic injury of hippocampal slices were estimated by percent recovery of population spike(PS). Statistic analysis of study were performed using paired t-test. Results : The percent recovery of PS after 10min hypoxia was considerably enhanced by increasing the period of current stimulation during incubation period before hypoxic injury. Temperature effect on the result of this experiment was also studied(group 4) but the result from this showed no statistic significance. Low magnesium ion concentration of artificial CSF(Mg-free aCSF) during incubation period enhanced the recovery of PS but low calcium (calcium-free) and high magnesium ion concentration(2mM) reduced it after hypoxic injury. L-glutamate($100{\mu}M$) and AP-5($50{\mu}M$) had no effect on the recovery of PS but CNQX($10{\mu}M$) in artificial CSF during incubation period markedly enhanced the recovery of PS. Co-treatment of AP-5($50{\mu}M$), CNQX($10{\mu}M$) and high magnesium concentration(2mM) enhanced recovery of PS in immediate following period of hypoxic injury but the effect of cotreatment after then decayed rapidly and lost statistic significance. Conclusions : Judging from above results, the condition of baseline recording is important in observing the recovery of population spike after hypoxia, and the time and the condition should be controled more strictly to obtain reliable results.

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