• 제목/요약/키워드: $CO_2$ Absorber

검색결과 113건 처리시간 0.028초

CO2 흡수제 함유 김치포장에서 CO2 농도와 제품 숙성도의 상호관련성 (Interrelationship between Kimchi Ripening and CO2 Concentration of the Headspace in Flexible Packages Included with CO2 Absorber)

  • 정수연;이동선;안덕순
    • 한국포장학회지
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    • 제26권2호
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    • pp.71-76
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    • 2020
  • CO2 concentration in kimchi package has emerged recently as a potential index of product ripening to be monitored or sensed in intelligent packaging. Considering that addition of CO2 absorber into the flexible kimchi package changes behavior of its CO2 concentration, ripening of kimchi in total acidity, package CO2 concentration in partial pressure (PCO2) and package volume at 10℃ were estimated by mathematical model for two size packages included with different CO2 absorbers. In small size package containing 0.5 kg of kimchi, relatively less gas permeable low density polyethylene (LDPE) sachet of the absorber was found to give rise of PCO2 linearly correlated with acidity at acceptable conditions of absorber amount and size. The levels of PCO2 at optimum ripening were different with absorber amount. However, highly gas permeable microporous spunbonded film (Tyvek) sachet did not show the linear relationship except a condition of 1.5 g of CO2 absorbent. In large size package containing 2.0 kg, absorber sachets of LDPE and Tyvek could give the linear relationship between product acidity and package PCO2 but at different levels (PCO2 of package with LDPE sachet: 0.46~0.79 bar, PCO2 of package with Tyvek sachet: 0.00~0.75 bar). The PCO2 at optimal ripening was found to be less variable with LDPE sachets than with Tyvek ones. Use of package CO2 concentration as an indicator of kimchi ripening was shown to be possible on the limited conditions where the linear relationship between them is established or confirmed.

포장 김치의 숙성에 맞춘 CO2 흡수제 배합비율 설계 (Design of CO2 Absorber Mix Tuned for Ripening of Packaged Kimchi)

  • 정수연;이동선;안덕순
    • 한국포장학회지
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    • 제27권1호
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    • pp.35-40
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    • 2021
  • Calcium hydroxide (CH) reacts with CO2 to produce moisture, and sodium carbonate (SC) reacts with CO2 in the presence of moisture. Using these different characteristics of these two reactants, a CH/SC mixture of CO2 absorber tuned for kimchi ripening to produce CO2 in a flexible package was selected. A ratio of CH:SC (1:2) in highly gas permeable microporous spunbonded film (Tyvek) sachet was found to be appropriate for delayed and consistent CO2 absorption useful for kimchi package. Addition of superabsorbent polymer (SAP) as moisture buffer was helpful for boosting the consistency of CO2 absorption. In a package of 0.5 kg kimchi at 10℃, the sachet consisting of 0.794 g of CH + 2.276 g of SC + 0.4 g of SAP suppressed its volume expansion and maintained a suitable range of CO2 partial pressure (PCO2) steadily inside. These optimal conditions may vary depending on the type and salinity of kimchi, storage and distribution temperature, and the material and area of the absorber sachet. This study showed a potential of mixture CO2 absorber to be tuned for CO2 producing packaged kimchi for the purpose of keeping consistent PCO2 at tolerable volume expansion.

$Ni/{\gamma}-Al_2O_3/Metallic$ device를 이용한 고온 태양열 메탄-이산화탄소 개질반응 (Solar $CO_2$ Reforming of Methane Using $Ni/{\gamma}-Al_2O_3/Metallic$ foam device)

  • 신일융;이주한;이진규;서태범
    • 한국태양에너지학회:학술대회논문집
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    • 한국태양에너지학회 2011년도 춘계학술발표대회 논문집
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    • pp.275-281
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    • 2011
  • Solar reforming of methane with $CO_2$ was successfully tested with a direct irradiated absorber on a parabolic dish capable of $5kW_{th}$ solar power. The new type of catalytically activated metallic foam absorber was prepared, and its activity was tested. Ni was applied as the active metal on the gamma - alumina coated Ni metal foam for the preparation of the catalytically-activated metal foam layer. Compared to conventional direct irradiation of the catalytically-activated ceramic foam absorber, this new metallic foam absorber is found to exhibit a superior reaction performance at the relatively low insolation or at low temperatures. In addition, unlike direct irradiation of the catalytically-activated ceramic foam absorber, metallic foam absorber has better thermal resistance, which prevents the emergence of cracks caused by mechanical or thermal shock. The total solar power absorbed reached up to 2.1kW and the maximum $CH_4$ conversion was almost 40%.

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고강력 PET Interlace Yarn 밀도변화가 Pack Style Shock Energy Absorber의 물성에 미치는 영향 (Effect of Density Variation of High Tenacity PET Interlace Yarn on the Physical Properties of Pack Style Shock Energy Absorber)

  • 조진원;권상준;최종덕;김상태;지병철;양성백;염정현
    • 한국염색가공학회지
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    • 제27권2호
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    • pp.132-141
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    • 2015
  • Fall-arrest systems(maximum arrest force and allowable free-fall) have been widely applied to provide a safe stop during fall incidents for various industrial activities. Fabric structure affects on the mechanical properties of shock energy absorber. The object of this study is to perform the basic research for the evaluation of the capacity of fall arrest energy absorber in relation to the different interlace yarn density. In this work, pack style energy absorber was prepared by weaving 10 types(Interlace yarn density used high tenacity PET 1000D : 60, 59, 58, 57, 56, 55, 54, 53, 52, 51). The paper presents the results of theoretical investigations of the performance of adjustable absorber during fall arrest. Dynamic load tests based on the EU fall protection equipment standard(CE : EN355:2002) were conducted. Results showed that the maximum arrest force by dynamic load test of energy absorber was satisfied with global standard(below 6,000N). Also, Maximum allowable free-fall of energy absorber showed below 1.75m.

떡국 떡의 품질유지에 미치는 변형기체포장(MAP) 효과 (Effect of Modified Atmosphere Packaging on Quality Preservation of Rice Cake (Ddukgukdduk))

  • 정수연;안덕순
    • 한국포장학회지
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    • 제28권1호
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    • pp.9-14
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    • 2022
  • Packages of different atmospheres (air (control), 100% CO2, vacuum, and vacuum + O2 absorber) were prepared for 0.4 kg rice cake (ddukgukdduk) using gas-barrier plastic film and stored at 10℃ for 11 days. The stored products were evaluated in their packages atmosphere, total aerobic bacteria, yeast and molds, texture and sensory quality during storage period. In the air package, the O2 concentration decreased from initial 21% to 16% on storage 4 days and the CO2 concentration increased to 23% on storage of 11 days, which resulted from the growth of microorganisms. CO2 concentration decreased from initial 98% to 36% on storage 11 days in the 100% CO2 package. It is reasoned that CO2 was dissolved into the product reducing the volume of the package. Vacuum and vacuum +O2 absorber package maintained shrunk vacuum condition until 11 days of storage. Total aerobic bacteria count increased significantly in the control package (6.41 log (cfu/g) after 11 days) compared to the 100% CO2 package (4.96 log (cfu/g) after 11 days). Yeast and molds were 6.66 in control package, 3.43 in 100% CO2 package, 4.66 in vacuum package, and 3.78 in vacuum + O2 absorber package after 11 days. There was no significant difference between control and the other treatments for the texture of the stored products. Sensory quality was the worst in control package on the storage of 8 days. All treatment groups except control improved the quality preservation, but vacuum and vacuum + O2 absorber packages suffered from cracking of the product. Thus 100% CO2 flushing is suggested as a desired packaging condition.

더블 레이어 흡수기를 이용한 고온 태양열 메탄-이산화탄소 개질반응 (Solar CO2-Reforming of Methane Using a Double-Layer Absorber)

  • 김동연;이진규;이주한;서태범
    • 한국태양에너지학회:학술대회논문집
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    • 한국태양에너지학회 2012년도 춘계학술발표대회 논문집
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    • pp.267-273
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    • 2012
  • Solar reforming of methane with CO2 was successfully tested with a direct irradiated absorber on a parabolic dish capable of 5kWth solar power. And the new type of double-layer absorber-the front layer, porous metal foam which absorbs the radiation and transfers the heat from material to gas, and the back layer, catalytically-activated metal foam-was prepared, and its activity was tested by using electric furnace. Ni was applied as the active metal on the gamma-Al2O3 coated Ni metal foam for the preparation of the catalytically-activated metal foam layer. Compared to conventional direct irradiation of the catalytically activated metal foam absorber, this new type of double layer absorber is found to exhibit a superior reaction and thermal storage performance at the fluctuating incident solar radiation. In addition, unlike direct irradiation of the foam absorber, double layer absorber has better thermal resistance, which prevents the emergence of cracks caused by mechanical or thermal shock. The total solar power absorbed reached up to 3.25kW and the maximum CH4 conversion was almost 59%.

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더블 레이어 흡수기를 이용한 고온 태양열 메탄-이산화탄소 개질반응 (Solar CO2-Reforming of Methane Using a Double-Layer Absorber)

  • 김동연;신일융;이주한;서태범
    • 한국태양에너지학회:학술대회논문집
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    • 한국태양에너지학회 2011년도 추계학술발표대회 논문집
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    • pp.80-86
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    • 2011
  • Solar reforming of methane with CO2 was successfully tested with a direct irradiated absorber on a parabolic dish capable of 5kWth solar power. And the new type of double-layer absorber - the front layer, porous metal foam which absorbs the radiation and transfers the heat from material to gas, and the back layer, catalytically-activated metal foam - was prepared, and its activity was tested by using electric furnace. Ni was applied as the active metal on the gamma-Al2O3 coated Ni metal foam for the preparation of the catalytically-activated metal foam layer. Compared to conventional direct irradiation of the catalytically activated metal foam absorber, this new type of double layer absorber is found to exhibit a superior reaction and thermal storage performance at the fluctuating incident solar radiation. In addition, unlike direct irradiation of the foam absorber, double layer absorber has better thermal resistance, which prevents the emergence of cracks caused by mechanical or thermal shock. The total solar power absorbed reached up to 3.25kW and the maximum CH4 conversion was almost 59%.

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대면적 CIGS 광흡수층 증착을 위한 선형증발원 개발 (Linear Source for Evaporating Large Area CIGS Absorber Layer)

  • 서제형;정승욱;이원선;최윤성;최명운;최진철;최광호
    • 한국진공학회지
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    • 제22권1호
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    • pp.1-6
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    • 2013
  • $600{\times}1,200mm$ 기판에 대면적 CIGS 광흡수층 증착을 위한 선형증발원 개발을 위해 다른 크기의 노즐과 일정한 노즐 간격을 가지는 선형증발원의 플럭스 밀도를 전산 모사하여 플럭스 균일도 ${\pm}5%$의 조건을 구하였다. 이를 바탕으로 제작된 선형증발원을 이용하여 Cu, In의 단일막 두께균일도를 확인하였고, CIGS 광흡수층을 동시증발법으로 증착하여 박막의 두께균일도 및 증착 조성의 균일도로 선형증발원을 평가하였다. XRF 조성 분석을 통해 구한 조성불균일도는 600 mm 폭에서 $$Cu{\leq_-}5%$$, $$In{\leq_-}7%$$, $$Ga{\leq_-}4%$$, $$Se{\leq_-}3%$$으로 균일한 조성비로 성막된 것을 확인하였고 SEM 분석을 통해 표면 결정립의 형상을 확인하였다. 또한 XRD측정을 통해 선형증발원 방향의 대면적 CIGS 광흡수층이 칼코피라이트 구조임을 확인하였다. 이를 통해서 개발된 하향 선형증발원이 CIGS 광흡수층 증착에 적합함을 확인하였다.

Effects of substrate temperature on the performance of $Cu_2ZnSnSe_4$ thin film solar cells fabricated by co-evaporation technique

  • 정성훈;안세진;윤재호;곽지혜;조아라;윤경훈;김동환
    • 한국신재생에너지학회:학술대회논문집
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    • 한국신재생에너지학회 2009년도 추계학술대회 논문집
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    • pp.400-400
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    • 2009
  • Despite the success of Cu(In,Ga)$Se_2$ (CIGS) based PV technology now emerging in several industrial initiatives, concerns about the cost of In and Ga are often expressed. It is believed that the cost of those elements will eventually limit the cost reduction of this technology. One candidate to replace CIGS is $Cu_2ZnSnSe_4$ (CZTSe), fabricated by co-evaporation technique. Co-evaporation technique will be one of the best methods to control film composition. This type of absorber derives from the $CuInSe^2$ chalcopyrite structure by substituting half of the indium atoms with zinc and other half with tin. Energy bandgap of this material has been reported to range from 0.8eV for selenide to 1.5eV for the sulfide and large coefficient in the order of $10^{14}cm^{-1}$, which means large possibility of commercial production of the most suitable absorber by using the CZTSe film. In this work, Effects of substrate temperature of $Cu_2ZnSnSe_4$ absorber layer on the performance of thin films solar cells were investigated. We reported on some of the absorber properties and device results.

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이산화탄소 분리를 위한 중공사막 모듈에서의 물질전달 거동 (On the Mass Transfer Behaviors in Hollcw-Fiber Membrane Modules for $CO_2$ Separation)

  • 전명석;김영목;이규호
    • 한국막학회:학술대회논문집
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    • 한국막학회 1994년도 춘계 총회 및 학술발표회
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    • pp.51-52
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    • 1994
  • High permeability, selectivity and stability are the basic properties also required for membrane gas separations. The $CO_2$ separation by liquid membranes has been developed as a new technique to improve the permeability and selectivity of polymeric membranes. Sirkar et al.(1) have atlempted the hollow-fiber contained liquid membrane technique under four different operational modes, and permeation models have been proposed for all modes. Compared to a conventional liquid membrane, the diffusional resistance decreased by the work of Teramoto et al.(2), who referred to a moving liquid membrane. Recently, Shelekhin and Beckman (3) considered the possibility of combining absorption and membrane separation processes in one integrated system called a membrane absorber. Their analysis could be predicted effectively the performance of flat sheet membrane, however, there are restrictions for considering a flow effect. The gas absorption rate is determined by both an interfacial area and a mass transfer coefficient. It can be easily understood that although the mass transfer coefficients in hollow fiber modules are smaller than in conventional contactors, the substantial increase of the interfacial area can result in a more efficient absorber (4). In order to predict a performance in the general system of hollow-fiber membrane absorber, a gas-liquid mass transfor should be investigated inevitably. The influence of liquid velocity on both a mass transfer and a performance will be described, and then compared with experimental results. A present study is attempted to provide the fundamentals for understanding aspects of promising a hollow-fiber membrane absorber.

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