• Korean Chemical Engineering Research
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• v.54 no.1
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• pp.101-107
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• 2016

This paper investigates the feasibility of applying the jet loop reactor for the neutralization of alkaline wastewater using carbon dioxide ($CO_2$). In this study, pH changes and $CO_2$ removal characteristics were examined by changing influent flow rate of alkaline wastewater (initial pH=10.1) and influent $CO_2$ flow rates. Influent flow rates of alkaline wastewater ($Q_{L,in}$) ranged between 0.9 and 6.6 L/min, and inlet gas flow rate ($Q_{G,in}$) of 1 and 6 L/min in a lab-scale continuous flow jet loop reactor. The outlet pH of wastewater was maintained at 7.2 when the ratio ($Q_{L,in}/Q_{G,in}$) of $Q_{L,in}$ and $Q_{G,in}$ was 1.1. However, the $CO_2$ removal efficiency and the outlet pH of wastewater were increased when $Q_{L,in}/Q_{G,in}$ ratio was higher than 1.1. Throughout the experiments, the maximum $CO_2$ removal efficiency and the outlet pH of wastewater were 98.06% and 8.43 at the condition when $Q_{G,in}$ and $Q_{L,in}$ were 2 L/min and 4 L/min, respectively.

• Journal of the Korean Society for Marine Environment & Energy
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• v.17 no.4
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• pp.283-296
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• 2014

The distribution of heavy metals in the stormwater runoffs from industrial sites around Shihwa Lake that implements the total pollutant load management system (TPLMS) was studied to characterize the temporal changes of metal concentrations and to assess the ecological risk in dissolved and particulate phases of the selected metals. The dissolved Co and Ni concentration demonstrated first flush and tended to decrease with increasing of the duration of rainfall. The intensity of precipitation was found to be the main controlling factor of particulate metals in the stromwater runoffs. The particulate concentration of Pb accounted for 97.2% so the particulate phase was its main form. Other metals followed the sequence: Pb>Cu>Cd>Co>Zn>Ni. The particulate-dissolved partitioning coefficient ($K_d$) indicated that the $K_d$ of Pb were bigger than that of other metals because the metal Pb in the stormwater runoffs is quickly removed into the particulate phase. In a single day rainfall event, total runoff fluxes for total metals as the sum of dissolved and particulate forms through only two sewer outlets were 2.21 kg for Co, 30.5 kg for Ni, 278.3 kg for Cu, 398.3 kg for Zn, 0.39 kg for Cd and 40.0 kg for Pb, respectively. Given the annual rainfall, the number of rain days and the basin area for total pollutant load management system (TPLMS) of Shihwa area, enormous amount of non-point metal pollutants were entered into Lake with any treatment. The dissolved metals (e.g., Ni, Cu and Zn) in the stormwater runoffs exceeded the acute water quality criteria. Additionally, all metals were significantly enriched in the particulate phase and exceeded the PEL criteria of sediment quality guidelines (SQGs). These results indicated that the heavy metals in the stormwater runoffs may pose a very high ecological risk to the coastal environments and ecosystem.

• Journal of the Speleological Society of Korea
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• no.89
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• pp.46-58
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• 2008

동굴 퇴적물의 형성과정은 1단계 기권 (Atmosphere): 빗방울 (H2O) 이 대기중에서 CO2의 혼합으로 산성비 (H2CO2)가 되어 석회암 (CaCO3)에 떨어져서 최초의 용식작용이 시작된다. 2단계 토양권 (Pedosphere): 산성비와 석회암성분이 합쳐 형성된 가용성 화합물 (Ca(HCO3)2)은 식생부식(植生腐植)에 의한 토양 (Humic acidic soils) 에 의해 기반암의 용식이 촉진 되어 지표에는 Karren과 석문 (석문(石門) Natural Bridge), 와지 (Dolines, Sinkholes) 지형을 형성시키고, 암석의 분순물은 지표에 남겨져서 결국 적색풍화토 (Residuum, Risidual Redish Soils) 를 만든다. 3단계 암권 (Lithosphere): 용식작용에 의해 지상에서 지하 로 확대되어진 모암의 균열을 타고, 지하의 공간이 지하수의 유입과 유출에 의해 점차 확대되어 동공형의 Conduites; Voids; Shaft 이라는 특수지형을 형성시키고,동굴의 천정으로부터 나온 Ca(HCO3)2 는 탄산염의 지속적인 분해 공급에 의해 동굴내에는 종류석, 석순, 유착석 (Speleothem)등의 새로운 동굴지형 (Speleoscape)을 조성하게 된다. 4단계 수권 (Hydrosphere): 동굴의 형성작용을 거친 물은 동굴지하수로 잔여 Calcite를 함유한 채로 유출 (Spring) 된다. 동굴을 떠난 잔여 Calcite는 또다시 하천유역에 침전시켜서 석회화 단구형의 집적지형 (Tufa Formation: Tufa Dam, Tufa Flowstone)을 최종적으로 동굴을 나와 외벽 이나 하천의 바닦에 형성하는 과정을 거치면서 카르스트 지형의 발달과정이 1차적인 순환을 마치게 된다.

• Journal of Korea Water Resources Association
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• v.34 no.5
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• pp.511-519
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• 2001

Global warming has begun since the industrial revolution and it is getting worse recently. Even though the increase of greenhouse gases such as $CO_2$is thought to be the main cause for glogal warming, its impact on global climate has not been revealed clearly in rather quantitative manners. The objective of this research is to predict the hydrological environment changes in the Daechung Dam basin due to the global warming. A mesoscale atmospheric/hydrologic model (IRSHAM96 model) is used to predict the possible changes in precipitation and temperature in the Daechun Dam basin. The simulation results of IRSHAM96 model and a conceptual water balance model are used to analyze the changes in soil moisture, evapotranspiration and runoff in the Daechung Dam basin. From the simulation results using the water balance model for 1x$CO_2$and 2x$CO_2$situations, it has been found that the runoff would be decreased in dry season, but increased in wet season due to the global warming. Therefore, it is predicted that the frequency of drought and flood occurrences in the Daechung Dam basin would be increased in 2x$CO_2$condition.

• Tunnel and Underground Space
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• v.28 no.4
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• pp.372-386
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• 2018

The air quality near the backfilled site area is significantly deteriorated during and even after the curing period of the backfill materials. Hazardous gases such as NH3 and CO2 may leak out prolongedly from the mined-out sites backfilled with the composite carbonate-based material; leakage can be observed at the underground working sites as well as on the surface. At operating mines, underground gas leakage will severely aggravate the workplace environment. The ventilation schemes should supply sufficient air to dilute the contaminated air, and control the toxic gas leakage and dispersion. This study shows the applicability of pressurization ventilation system to control gas leakage and dispersion at the backfilled underground mine site.

• Korean Journal of Soil Science and Fertilizer
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• v.44 no.6
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• pp.1232-1238
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• 2011

This experiment was conducted to measure concentration of dissolved $N_2O$ in ground-water of 59 wells and to make emission factor for assessment of indirect $N_2O$ emission at agricultural sector in agricultural areas of Gyeongnam province from 2007 to 2010. Concentrations of dissolved $N_2O$ in ground-water of 59 wells were ranged trace to $196.6{\mu}g-N\;L^{-1}$. $N_2O$ concentrations were positively related with $NO_3$-N suggesting that denitrification was the principal reason of $N_2O$ production and $NO_3$-N concentration was the best predictor of indirect $N_2O$ emission. The ratio of dissolved $N_2O$-N to $NO_3$-N in ground-water was very important to make emission factor for assessment of indirect $N_2O$ emission at agricultural sector. The mean ratio of $N_2O$-N to $NO_3$-N was 0.0035. It was greatly lower than 0.015, the default value of currently using in the Intergovernmental Panel on Climate Change (IPCC) methodology for assessing indirect $N_2O$ emission in agro-ecosystems (IPCC, 1996). It means that the IPCC's present nitrogen indirect emission factor ($EF_{5-g}$, 0.015) and indirect $N_2O$ emission estimated with IPCC's emission factor are too high to use adopt in Korea. So we recommend 0.0034 as national specific emission factor ($EF_{5-g}$) for assessment of indirect $N_2O$ emission at agricultural sector. Using the estimated value of 0.0034 as the emission factor ($EF_{5-g}$) revised the indirect $N_2O$ emission from agricultural sector in Korea decreased from 1,801,576 ton ($CO_2$-eq) to 964,645 ton ($CO_2$-eq) in 2008. The results of this study suggest that the indirect Emission of nitrous oxide from upland recommend 0.0034 as national specific emission factor ($EF_{5-g}$) for assessment of indirect $N_2O$ emission at agricultural sector.

• Korean Journal of Soil Science and Fertilizer
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• v.44 no.6
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• pp.1207-1213
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• 2011

This study was conducted to assess $N_2O$ emissions in agricultural soils of Korea. According to 1996 and 2006 IPCC (Intergovernmental Panel on Climate Change) methodology, $N_2O$ emission was calculated the sum of direct emission ($N_2O_{DIRECT}$) and indirect emission ($N_2O_{INDIRECT}$). To calculate $N_2O$ emissions, emission factor was used default of IPCC and activity data was used the food, agricultural, forestry and fisheries statistical yearbook of MIFAFF (Ministry for Food, Agriculture, Forestry and Fisheries). It was emitted 8,608 $N_2O$ Mg resulted from direct emission by application of chemical fertilizer and animal manure, input in n-fixation crops and input of crop residues and emissions converted $N_2O$ into $CO_2$ equivalent was 2,668 $CO_2$-eq Gg. Indirect emission as $N_2O_{(G)}$ (atmospheric deposition of $NH_3$ and $NO_X$) and $N_2O_{(L)}$ (leaching and runoffs) were 4,567 and 6,013 $N_2O$ Mg and emissions converted $N_2O$ into $CO_2$ equivalent were 1,416 and 1,864 $CO_2$-eq Gg, respectively. Total $N_2O$ emission in Korea agricultural soil in 2009 was 5,948 $CO_2$-eq Gg.

• Journal of the Korea Organic Resources Recycling Association
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• v.30 no.1
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• pp.41-47
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• 2022

In this study, rainfall water outlet water quality monitoring was performed on the C industrial complex to evaluate the characteristics of non-point pollutant runoff from the industrial complex during rainfall and to use it as basic data for calculating the load and unit of non-point pollutant. As a result of calculating EMC according to the outflow amount by rainfall event, the 1st rainfall showed EMCs ranges of BOD, COD_Mn, SS, T-N, and T-P of 1.32~48.76, 3.32~43.75, 2.89~199.43, 2.76~8.93, 0.08~068, and the 2nd rainfall was 0.5~2.9, 2.71~7.13, 2.82~174.94, 1.33~4.03, 0.01~1.28 mg/L, respectively. As a result of calculating the ratio of cumulative outflow and cumulative pollution load, most of the pollution load was less than the rainfall outflow, but over time, the initial washing phenomenon occurred as the ratio of cumulative rainfall outflow and cumulative pollution load increased to more than 1.

• Journal of Korean Society of Disaster and Security
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• v.16 no.2
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• pp.99-104
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• 2023

In recent years, the occurrence of abnormal weather has increased rapidly, increasing the frequency of torrential rain. As a result, stable water resource management is difficult, and human and material damage is increasing. Various measures are being established to reduce damage caused by torrential rains, but small-scale mountain catchments are relatively difficult to manage due to lack of basic plan. In this study, the risk of flooding was evaluated using the rainfall-flow model in the Yeonhwa-dong catchment national park among national parks in Korea. The Yeonhwa-dong catchment of Mt. Sobaeksan was simulated to cause flooding when rainfall of more than 50 years occurred, and it was confirmed that there was a high risk of water resource structures, safety facilities, and trails.

• Journal of Korea Soil Environment Society
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• v.3 no.3
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• pp.75-86
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• 1998

This paper is going to show the way we can sample the landfill gases flowing out to the air through final cover soil by using an closed chamber in the field for a short time. In addition, we came to the following results through the application of model with actual measurements. 1) Analyzing changes of concentration in the chamber(H: 10-30cm) every 5 minutes, considering analysis time of gas chromatograph for an half hour. 2) The proportion of $CE_4$to $CO_2$changes rapidly near the surface of final cover soil by the influence of methane oxidation reaction. 3) When flux of landfill gas is F=$10^{-5}$mol/$\textrm{m}^2$.s), methane oxidation reaction has an influence on composition of gases, however there is little influence when F=$10^{-6}$ mol/($\textrm{m}^2$.s).