• Title/Summary/Keyword: $CO_2$ 고정

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Pressure Gradient of Supercritical CO2 in Vertical Tobacco Beds in Down Flow Condition (담배 고정층 반응기에서 하부로 흐르는 초임계 CO2의 압력 구배)

  • 이성철
    • Journal of the Korean Society of Tobacco Science
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    • v.18 no.1
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    • pp.92-99
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    • 1996
  • A mathematical model of the pressure gradient of supercritical CO2 in a vertical tobacco bed was developed in this study. In particular, the compaction of the tobacco as a function of temperature and CO2 flow is included in the model. Downflow of CO2 (low condition is described. At velocities in excess of 0.6 cm/sec at 7$0^{\circ}C$, there is a large increase in pressure gradient for beds deeper than about 0.5 m. The proposed model offers a better understanding of operating the process using supercritical CO2.

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Oxidation Characteristics of Low Concentration CO Gas by the Natural Manganese Dioxide(NMD) in a Fixed Bed (고정층 반응기에서 망간광석(NMD)을 이용한 저농도 일산화탄소 산화특성)

  • Lee, Young Soon;Park, Jong Soo;Oh, Kwang Joong
    • Clean Technology
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    • v.2 no.1
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    • pp.60-68
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    • 1996
  • The oxidation of carbon monoxide of low concentration on the natural manganese dioxide (NMD) has been investigated in a fixed bed reactor. The experimental variables were concentration of oxygen (500ppm~99.8%) and carbon monoxide (500ppm~10000ppm) and catalyst temperature ($50{\sim}750^{\circ}C$). The NMD(Natural Manganese Dioxide) has been characterized by temperature - program reduction(TPR) using 2.4% $CO/H_2$ as a reducing agent, thermogravimetric analysis (TGA), and reduction of NMD by 2.4% $CO/H_2$. It was found that the NMD catalyst activity on the unit area was greater than the $MnO_2$ catalyst for oxidation of CO at the same temperature. The thermal stability of oxidation activity was considered to be maintained when the NMD was heated to $750^{\circ}C$. The TGA, reduction by CO, and TPR of the NMD showed that the NMD had active lattice oxygen which was easily liberated on heating in the absence and low concentration of oxygen. The reaction order in CO is 0.701 between 500~3500ppm and almost zero between 3500~10000ppm of CO.

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Supported Ionic Liquid Membrane Preparation for Carbon Dioxide Separation (이산화탄소 분리를 위한 이온성액체 지지분리막의 제조)

  • Choi, Mi Young;Chung, Kun Yong
    • Membrane Journal
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    • v.22 no.4
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    • pp.280-283
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    • 2012
  • The study is aiming to prepare supported ionic liquid membranes for carbon dioxide separation efficiently. The ionic liquid, [bmim][${PF_6}^-$] (1-butyl-3-methyl-imidazolium hexafluorophosphate) was fixed in the pores of PVDF micro-filtration membrane with a nominal pore size 0.1 ${\mu}m$. The permeabilities of $N_2$, $H_2$ and $CO_2$ gases through the prepared ionic liquid membrane were 0.075, 0.203 and 1.380 GPU, respectively. The selectivities of $CO_2/N_2$, $H_2/N_2$ were 14.2 and 2.69, respectively. Also, the supported ionic liquid membrane could be operated stably up to 2.0 bar with the immobilization of ionic liquid in the pores.

A Study on the Lab-scale process of $CO_2$ conversion to $CH_4$ (실험실규모의 생물학적 이산화탄소 저감 및 메탄전환 공정 연구)

  • Lee, Juncheol;Kim, Jaehyung;Jeon, Hyeyeon;Park, Hongsun;Chang, Wonseok;Pak, Daewon
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.111.2-111.2
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    • 2011
  • 최근 지구온난화로 인해 국제적으로 이산화탄소 저감에 대한 연구가 진행되고 있으며 특히, 이산화탄소의 분리 및 유용물질 전환 등의 다양한 방법에 대한 연구가 활발히 이루어지고 있다. 이산화탄소를 메탄으로 전환시키는 생물학적 반응은 acetotrophic methanogen, hydrogenotrophic methanogen 등의 미생물이 관여한다. 본 연구에서는 hydrogenotrohpic methanogen을 이용하여 메탄으로 전환하고자 하였다. 이를 위해 이산화탄소와 수소의 체류시간에 대한 연구를 진행하였으며, 선행 연구로 혐기성슬러지의 혼합배양균으로부터 hydrogenotrophic methanogen을 우점종화 하기 위해 고정층 반응기를 이용하여 이산화탄소와 수소 가스를 주입하여 고농도로 배양하였다. 그 결과, 반응기내의 이산화탄소의 메탄전환 균주로써 수소를 환원제로 이용하는 hydrogenotrophic methanogen이 배양되었음을 확인하였다. 이산화탄소와 수소가스의 체류시간에 따른 이산화탄소의 생물학적 메탄 전환 실험 결과, 약 4시간에서 이산화탄소의 저감률이 99%이었으며, 체류시간이 2시간, 1.5시간인 경우 이산화탄소의 저감률은 각각 71%, 68% 이었다.

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Moving magnet operator monitoring system with high-precision position control (고정밀 위치제어가 가능한 자석가동자 모니터링 시스템)

  • Kim, Hong-youn;Kim, Seu-hong;Piao, Hai-lian
    • Proceedings of the Korea Information Processing Society Conference
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    • 2021.11a
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    • pp.756-759
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    • 2021
  • 본 논문은 기존의 5축 치아가공기나 반도체장비등에 사용하고 있는 회전형 모터의 경우는 엔코더와 리졸버를 사용하고 있다. 엔코더와 레졸버는 고가이므로 실제 산업현장에서 전동기의 위치 센서로는 적용하기가 힘들다. 또한 엔코더와 레졸버와 같은 광학식 위치센서는 그 크기와 내구성에 있어 약점이 있기 때문에 취부 할 때에도 어려움이 있다. 따라서 본 연구에서는 5축치아가공기에 적용하기 위해서 자석가동자를 만들었으며, 이러한 문제점을 해결하는 방안으로 리니어모터를 고정자로 하고 자석플레이트를 이동자로 하는 시스템과 별도의 리니어 스케일을 배제하고 기존의 정현파를 발생하는 2개의 리니어홀센서 및 영구자석을 이용하여 가동자의 절대위치와 이동 위치를 검출할 수 있는 리니어 모터 및 그 제어방법, 안정성 및 신뢰성을 향상시킬 수 있는 자석가동자를 이용하여 구동시 실시간으로 데이터를 확인할 수 있고 제어할 수 있는 모니터링 시스템을 개발하는 연구이다.

Advances of Post-combustion Carbon Capture Technology by Dry Sorbent (건식흡수제 이용 연소배가스 이산화탄소 포집기술)

  • Yi, Chang-Keun
    • Korean Chemical Engineering Research
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    • v.48 no.2
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    • pp.140-146
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    • 2010
  • This paper addresses recent status and trends of carbon dioxide capture technologies using dry sorbents in the flue gas. The advantages of dry sorbent $CO_2$ capture technology are broader operating temperature range, less energy loss, less waste water, less corrosion problem, and natural properties of solid wastes. Recently, U.S.A. and Korea have been developing processes capturing $CO_2$ from real coal flue gas as well as sorbents improving sorption capacity to decrease total $CO_2$ capture cost. New class of dry sorbents have been developed such as chemisorbents with alkali metals of which material cost is low, amines physically adsorbed on silica supports, amines covalently tethered to the silica support, carbon-supported amines, polymer-supported amines, amine-containing solid organic resins and metal-organic framework. The breakthrough is needed in the materials on dry sorbents to decrease capture cost.

Growth of Soybean Sprouts and Concentration of $CO_2$ Produced in Culture Vessel Affected by Watering Methods (살수방식에 따른 재배용기내 Gas 조성 및 콩나물의 생육 변화)

  • 배경근;남승우;김경남;황영현
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.49 no.3
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    • pp.167-171
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    • 2004
  • The growth of soybean sprout was greatly influenced by watering systems: Fixed watering system (water tub was loaded at ceiling upper of culture box and water was showered by bottom holes) was estimated the better than that of reciprocating watering and tub immersing watering because it could cool down the temperature in culture box and wash the organic substances on the body of sprout. The fixed watering system showed good body color and preventing effect of partial rotting of sprout because it could discharge $\textrm{CO}_2$ gas effectively in culture box and keep the concentration below 5%. The concentration of gases at the bottom (about 30 cm height from basal plate) of culture box in fourth or fifth days was L6% for $\textrm{CO}_2$ and 13-16% for $\textrm{O}_2$, respectively. The optimum gas concentration in culture box was considered to be over 10% for $\textrm{O}_2$ and below 5% for $\textrm{CO}_2$.

Evaluation of Operating Factors for the Continuous CO2 Fixation with a Photobioreactor (폐탄산가스 고정화를 위한 연속식 광반응기의 운전 인자 평가)

  • Shin, Hang-Sik;Chae, So-Ryong;Jang, Min-Young;Park, Bong-Sun
    • Journal of the Korea Organic Resources Recycling Association
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    • v.8 no.2
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    • pp.71-76
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    • 2000
  • The biological carbon dioxide fixation using microalgae has been known as an effective carbon dioxide reduction technology. With many environmental factors influencing microalgal productivity, the desirable cultivation factors were investigated using a green alga, Euglena gracilis. It has the high protein and vitamin E to be used as fodder. In batch culture with a photobioreactor, initial pH, temperature, carbon dioxide concentration and light intensity in the optimum cultivation condition were 3.5, $27^{\circ}C$,5-10% and $520{\mu}mol/m^2/s$, respectively. After that, the optimum hydraulic retention time (HRT for the continuous cultivation was 4 days at carbon dioxide concentration of 10%. In this condition, the final dry cell weight was 1.2g/l.

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Effect of Pressure on HCl Absorption Behaviors of a K-based Absorbent in the Fixed Bed Reactor (고정층 반응기에서 K-계열 흡수제의 압력에 따른 HCl 흡수 거동 연구)

  • Kim, Jae-Young;Park, Young Cheol;Jo, Sung-Ho;Ryu, Ho-Jung;Baek, Jeom-In;Park, Yeong Seong;Moon, Jong-Ho
    • Clean Technology
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    • v.19 no.2
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    • pp.165-172
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    • 2013
  • In this study, the hydrogen chloride removal using K-based dry sorbents ($K_2CO_3/Al_2O_3$, KEPRI, Korea) was studied with varying the pressure in a fixed bed reactor (15 cm tall bed with 0.5 cm I.d.). Working temperature was $400^{\circ}C$ and feed gas concentration was 750 ppm (HCl vol%, $N_2$ balance). The chloride sorption capacity of sorbent increases with increasing pressure (1, 5, 10, 15 and 20 bar). Also, after forming KCl crystal by reaction with $K_2CO_3$ and HCl, owing to the strong bonding energy, sorbent regeneration was practically impossible. Its optical, physical and chemical characterizations were evaluated by SEM, EDAX, BET, TGA and XRD. At $400^{\circ}C$ and 20 bar condition, working condition for the dehalogenation process after gasification, K-based dry sorbent showed high HCl sorption capacity and HCl/$N_2$ separation performances comparing with Ca-based and Mg-based dry sorbents.